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By M. C. Fuerstenau

Collophane, cryptocrystalline fluorapatite, is examined as a substrate for plant water and wastewater remediation. The attenuation of Fe3+, Cr3+, Fe2+, Cd2+, Hg2+ and Pb2+ is presented as a function of metal ion concentration, amount of collophane, initial pH and conditioning time. TCLP results for Pb2+ contaminated collophane are presented. Mechanisms of adsorption for divalent and trivalent species are suggested. Key words: Collophane, Wastewater remediation, Heavy metal removal

Jan 1, 2003

By G. V. Krishna Roa, G. Vijaya Kumar

One of the main objectives while planning ventilation systems for mines with multiple fans is minimization of the total airpower consumption of the mine. Solution of this problem by conventional ventilation network analysis programs is tedious and time consuming, and may not yield optimum results in all the cases. The paper presents an algorithm for solving multiple fan networks by finding optimum combination of fan operating points for required airflow distribution in the ventilation system.

Jan 1, 1995

By M. Tarshan, M. C. Williams, T. P. Meloy

A methodology is presented for the spreadsheet solution of separation processing networks. With the methodology developed, a spreadsheet grid is used to represent networks both with and without recycle loops. In this manner, network solutions are numerically approximated by spreadsheet grid solutions. The methodology was used to explore the ramifications of networks developed by the Chinese for tungsten and molybdenum processing Nonlinear stage-transfer functions for two-component sharp separations can be used.

Jan 1, 1996

By David P. Keller, George Podolsky

Iron oxides are unique in that they are the only significant colored mineral found in a natural state suitable for use as a pigment after being pulverized to pigmentary size. The world production of iron oxide pigments is estimated by the authors to be between 350 and 400 kt. The fact that highly colored natural deposits of iron ore are found throughout the world accounts for its use in prehistoric man's artistic cave paintings. These early artists did not realize that they had established man's first paint test which now has some 20,000 years of exposure. In addition to abundance, iron oxides (about 7% of the earth's crust) have the advantage of low cost, permanency, and are non- toxic. Through the centuries, succeeding civilizations have utilized iron oxides as a major source for decoration and protection when these properties were desired. In the last century the chemical industry has improved on nature by developing a complete range of synthetic iron oxide pigments which surpass the pigments produced from natural iron ores in uniformity, color quality, and chemical purity. In the United States, the combined production of natural and synthetic iron oxides produced sales of over $97 million in 1980 (Spimad, Jr., 1980), increasing to $138 million by 1990 (Templeton, 1990) NOMENCLATURE With the increasing importance of the synthetic iron oxides it is necessary to make a distinction between the natural or mineral pigments and the synthetic pigments. Natural pigments are those products that are derived from selected ores and should not be confused with iron ores mined for steel production. Iron ores that are mined for steel must be capable of being mined and reduced to iron on a competitive commercial basis. These ores are selected on the basis of iron content and processing economics. It is therefore unusual when iron ores for steel production are suitable for use as mineral pigments. Natural pigment ore sources are selected for their special physical-chemical properties and are able to command a premium price over iron ores used for steel manufacturing. Synthetic pigments, and in this instance iron oxides, are those pigments produced from basic chemicals. Through chemical synthesis pigmentary particles are produced as opposed to the use of comminution, the major procedure common to all natural iron oxide pigments.

Jan 1, 1994

By Michael J. Virnig, Murdoch W. MacKenzie, Michael R. Davis

The objective of this paper is to present preliminary capital and operating cost estimates (±25%) comparing conventional carbon-in-solution (CIS) with resin-in­solution (RIS) using AuRIX® 100 for the recovery of gold and silver from typical heap leach solutions. Preliminary testwork was carried out with AuRIX® 100 using real and synthetic leach solutions to determine the technical viability of the resin for gold/silver recovery and to provide process design parameters for the preliminary RIS circuit. The scope of the resin testwork was sufficient to support the level of accuracy applied in the capital and operating cost estimates. No parallel testwork was carried out with activated carbon. Industry standard design data and operating data from existing CIS operations were used as a basis for the comparison. Both the capital and operating cost comparisons indicate a substantial savings for a RIS circuit using AuRIX® 100 (- 14 to 18% in terms of capital and 25 to 35% in terms of operating costs) over a conventional CIS circuit depending upon solution flows and grade.

Jan 1, 1999

By Thomas J. Feeley

The US Department of Energy (DOE) is supporting the engineering development of three advanced physical coal cleaning technologies: selective agglomeration, advanced flotation and advanced cycloning. Each is capable of significantly reducing the pyritic-sulfur content of US coals. The objective is to provide the coal and electric-utility industries with a cost-effective option for addressing the SO, emission reductions required by the 1990 Clean Air Act Amendments (CAA). A secondary objective is to evaluate the potential of advanced coal cleaning for removing trace elements that are precursors to the formation of hazardous air pollutants (HAS). The proposed National Energy Strategy (NEE) and the 1990 CAA lay a foundation for a more efficient and environmentally sustainable energy future (1991). The need to use energy resources in an environmentally sound manner presents critical challenges and opportunities for coal preparation during the next decade, particularly regarding the control of SOS and HAY emissions. The principal challenge is the development of cost-effective coal preparation approaches for sulfur and HAY precursor removal.

Jan 1, 1993

By Ronald B. Gabitzsch, Norbert P. Hanke

During 1982, record advances have been achieved in the excavation of vertical shafts with a V-Mole (a vertical shaft boring machine). The V-Mole, supplied by Wirth GmbH in Erkelenz, West Germany, has been used in West German coal mines since the early seventies, mainly for the construction of internal shafts. In 1981, it was brought into the United States for the construction of a series of ventilation shafts with depths varying between 512 m (1680 ft.) and 622 m (2040 ft.) excavated to 7.0 m (23 ft.) diameter. These shafts were needed for the development of coal mines for Jim Walter Resources, Inc. in Brookwood, Alabama. After a description of the mechanized shaft excavation system with the V-Mole, the conditions and parameters, such as ground, shaft dimensions, and linings are discussed. These factors are important considerations for a technically and economically feasible utilization of the V-Mole. In addition, the advantages and disadvantages of using the V-Mole technology in comparison to other shaft construction methods are evaluated.

Jan 1, 1983

By Richard H. Adams

INTRODUCTION With the discovery and depletion over the years of near surface ore bodies, exploration targets are tending to be at greater depth or overlain by various types of overburden which in some cases extends to considerable depth or is heavily water bearing. Access to these types of deposits for exploration and development often requires vertical shafts. This paper discusses the concept of small shaft engineering and construction, primarily for underground exploration but also for use as a low tonnage production facility or for mine ventilation. The option of a small shaft may be attractive in a number of cases, some of which are: The underground exploration of a deposit at depth where minimal expenditure is desirable until the potential of the deposit has been determined. The exploration shaft in many cases later serves as a ventilation way and second means of egress. Production of ore in a small tonnage/high-grade operation where decline access is impractical. For ventilation where other types of openings are impractical or would delay start-up of mine operations.

Jan 1, 1987

By Betty L. Gibbs

A clear and accurate knowledge of the status of ventilation in an underground mine is essential to continuing safe operation. In a small mine with a few working faces, the problem is simple and can easily be solved by choosing the appropriate fan. In larger, more complex mines the problem of supplying the working faces with fresh air is a problem beyond the scope of 'finger in the wind' analysis. In today's climate of stiffer government regulation and mining company concern for the safety of workers, computer programs which analyze ventilation networks are helping mining companies meet the standards. The development of computer programs for ventilation network analysis is summarized. Early programs were developed at universities or government agencies and required large expensive computers. As computers have become smaller and less expensive, the development or revision of programs for micro computers has become more available. Prices have lowered to the point of affordability even for medium and small companies. A list of ventilation network analysis programs is provided along with a summary of capabilities, costs, and hardware requirements for each program.

Jan 1, 1987

By Julia R. Budden, Peter A. Spencer

Bacterial oxidation processes have often been repo1ted as releasing large amounts of energy so that a large scale operation would require cooling to maintain the required operating temperature for the bacterial culture. These reports are based on the chemical heat release which in some eases has been adjusted for the energy required to fonn the mass of bacterial cell matter per unit volume of solution. There are two flaws in this approach for calculating energy release in the fonn of heat. The first flaw is that it only considers the bacteria in solution. The second assumption is that the only bacterial reaction is the fonnation of cell material and others such as energy for respiration and locomotion are not considered.

Jan 1, 1992

By Harrie van Dijk

Feeding laterite nickel slurry into high pressure acid­leach (HPAL) autoclaves in an aggressive environment with slurries heated up to 200°C requires a special pump design. For decades the GEHO piston diaphragm pumps have been used for autoclave feeding at gold ore pressure oxidation plants with slurries up to l 77°C. Lessons learned from these installations have been instrumental in designing second generation feed pumps for processing laterite nickel with operating temperatures of 200°C and a flow rate of 400 m3/h. The Australian nickel industry is using momentarily 8 GEHO positive displacement piston diaphragm pumps. For this application six GEHO ZPM 900 "dropleg" pumps have been supplied to the Murrin Murrin project and two to Bulong.

Jan 1, 2000

By Rob Henson, Te-Lin Yau, Darryl Amick

The process industry faces tightening environmental regulations. In order to comply with these mandates, environmentally safe chemicals, such as oxygen and hydrogen perox­ide are becoming attractive oxidants. These oxidants appear benign but must be respected when involved in harsh environments. It is therefore important to address both the safety and suitability of materials selected for these environments. Otherwise, severe prob­lems, such as equipment failure or fire and explosion can occur. Laboratory and field experience will be used to discuss the perfor­mance of titanium, zirconium and Ti-45Nb alloy in piping systems for handling these environ­ments. Sealing methods for piping, pumps and valves of these metals will also be reviewed. For comparison, information on the performance of stainless alloys will be given.

Jan 1, 1993

By W. Kennedy Gauger, Tim Oolman, Debra L. Bisson

Radian Corporation (Radian) has developed a process for treating Cr(V1)-contaminated soils that involves: 1) soil washing using an alkaline extractant, 2) biological reduction of Cr(V1) to Cr(II1) in the soil wash effluent, and 3) separation of Cr(II1) from the biologically treated effluent. Biological treatment has been demonstrated for immobilized cells in fluidized bed bioreactors and suspended cells in slurry bioreactors for Cr(V1) levels ranging from 30 to 600 mg/L which have been reduced to non-detectable levels (< 0.05 mg/L; method detection limit [MDL]) during hydraulic residence times as short as 12 hours. The resulting Cr(II1)-containing effluent stream was chemically treated to precipitate chromium hydroxide for removal by physical separation.

Jan 1, 1995

At periodic intervals-typically at the end of each month, quarter, and year- the accounting department in each division of a company distributes a set of reports to the division&apos;s managers. These reports describe the financial performance of the division and its major departments over the time period. They identify the revenues generated from the division&apos;s products and the costs incurred in their production. The results from individual departments are combined to determine divisional results, and the results from individual divisions are in turn consolidated to determine the results for the overall corporation. Cost reports for each of these activities show actual amounts, budgeted amounts, and the differences between the two. This reporting is carried out for the individual period and for the year to date.

Jan 1, 1999

By William A. Dupree, Mark J. Schultz, William J. Francart

Maintaining intake escapeways clear of contaminants from mine fires has been an issue for many years. Removing fire sources from these entries reduces the risk of contamination greatly. In recent years, concerns have been raised related to contamination of the intake escapeways by leakage when fires occur in adjacent airways. This paper discusses measured leakage rates for multiple stoppings at various pressure drops across stopping lines in a number of actual coal mines. Also addressed are methods for reducing the contamination risks for the intake escapeways, considering the ventilation system employed. The Effects of Air Leakage The effects of air leakage through ventilation controls has been well documented. While normal leakage is expected through stoppings, overcasts and other structures, abnormally high leakage results in an inefficient ventilation system and can increase operational costs for a mine. In addition, excessive leakage results in less control over mine ventilation airsplits. This may compromise the isolation of mine escapeways, and allow adjacent entries to be rapidly contaminated by products of combustion in the event of a mine fire. A study was conducted at ten mines in which air pressure and quantity measurements were taken near the active sections. The method used to construct the ventilation controls to separate airways was also noted. Stopping Construction Table 1 shows the type of stopping construction commonly used in the 10 mines included in this study. Main entry stoppings were normally built with mortared joints (wet stacked) with sealant applied to the high pressure side of the stopping. In most cases the entire face of the stoppings were sealed. In one case only the joints between blocks were sealed but the perimeters were sealed in all cases. Some mines also sealed the low pressure side of the stopping. Solid blocks were normally used for main entry construction and hollow blocks were sometimes used for longwall panel development. [ ]

Jan 1, 1993

By Adrian Smith

14.1 INTRODUCTION From the time the last recoverable gold is extracted from ore on a heap leach, the ore - now spent ore - changes from being the resource, indeed the raison d&apos;etre of the operator, to a potential liability. The spent ore contains process chemicals and constituents leached from the ore both in the interstitial pore water in the heap and on the surfaces of spent ore. If these chemical species were released to the environment, it could have a potential impact on the quality of both surface water and groundwater resources. Accordingly, the spent ore must be left in a condition where it does not present a potential environmental liability. This can be accomplished either on a decommissioned pad or, if the heap leach is operated as a load/unload scheme, in a waste facility. In general, the residual cyanide level in the spent ore is the perceived controlling factor when determining whether the leached material is suitable for abandonment. Regulatory authorities set permit conditions for heap leach abandonment in terms of residual cyanide levels, for example, Smith and Struhsacker (1987). This chapter discusses cyanide degradation and methods for detoxifying a heap leach in order to meet regulatory limits/permit conditions for abandonment. Cyanide degradation and detoxification by "natural" processes are described initially, based on the chemistry and geochemistry discussed in Chapter 13. This leads to a review of chemical treatment processes for detoxification of spent ore. The advantages and apparent disadvantages are then appraised. 14.2 NATURAL DEGRADATION AND DETOXIFICATION For the purposes of discussion, "natural" detoxification processes can be divided into two alternatives: • Passive abandonment (the so-called "do nothing" option); and • Water In the first alternative, the spent ore is merely left on the leach pad to age; the second alternative involves the flushing of the spent ore with water.

Jan 1, 1988

By T. B. Whitmoyer, J. E. Sneckenberger, M. A. Jerabek, C. F. Stanley

The measurement of acoustic impedance at frequencies up to 6,400 Hz has been proposed as a diagnostic tool to yield more detailed information about lung condition. A three generation branching system of plastic Y-tubes has been constructed. The impedance of the branched system is measured by an impedance tube using the two-microphone technique. The impedance spectrum is used to calculate the reflection coefficient spectrum, which is converted to an impulse response by an inverse FFT. The area function is extracted from the impulse response by the Ware-Aki algorithm. Measurements of acoustic impedance of the branched system were made for several different end conditions of the eight terminal outlets. The outlets were either blocked with modeling clay, plastic packing material, or aluminum blocks or were unblocked. Six measurements were made of each configuration. In general, the more outlets blocked, the larger the shift to the right of the impedance magnitude peaks for frequencies above 3000 Hz. The impedance magnitude peaks for the plastic packing material were shifted in frequency to the right relative to the peaks of the other system terminations. The impedance magnitude peaks for the clay and aluminum system terminations were significantly different in magnitude but not shifted in frequency. The area functions at the end of the branched system were significantly different (a > 99%) for most of the end conditions. Area functions for the modeled branched lung systems between the end of the impedance tube and the termination outlets of the branched system were similar but distinctively different for the various end conditions. These results indicate that the two-microphone technique can sense small changes in the terminating end conditions of a rigid system of branched tubes and thus may sense impedance changes due to lung disease in the conducting airways. Keywords: acoustic impedance, lung model, area function.

Jan 1, 1991

By Pentti Seppanen

The activities of Outokumpu Oy in the mining industry span all branches from prospecting to the production of refined metals and the manufacture of semifinished products. Products include copper, zinc, mercury, cadmium, nickel, cobalt, sulfur, gold, silver, iron ore, stainless steel, selenium, ferrochromium, lead and chromium concentrates, as well as chromite foundry sand. In addition, the activities of Outokumpu Oy extend to development and production of instruments, planning of industrial projects and instrumentation as well as the manufacture of specialized machines for ore concentration. The company now operates ten mines, eight of which are underground and all of which are in sulfide deposits except one. The fully automated monitoring and control of underground mine ventilation at the Pyhasalmi mine are an important technological contribution to the industry. Development work on the ventilation control was started in 1969, and since May 1973 it has operated in a fully automated computer-controlled mode. The Pyhasalmi mine has been in production since 1962, having begun as an open-pit operation. Development of underground mining began in 1967. The present annual production is one million tons all from underground mining. The underground mine is equipped with a main shaft and an auxiliary shaft, and two raises for ventilation. There is also a rampway from the surface to a depth of 500 m. The main shaft is for ore hoisting and the auxiliary shaft is used for waste-rock hoisting and for downcast ventilation. One of the raises is for downcast ventilation and the other is for upcast ventilation. The mining methods employed at Pyhasalmi are sublevel stoping with backfill, sublevel caving, and sublevel shrinkage stoping. Copper and zinc concentrates are produced. The Pyhasalmi mine is highly mechanized with about 4000 installed diesel horsepower underground. The maximum capacity of fresh air is 150 m3/s.

Jan 1, 1979

By Angus M. Henderson, Charles R. Lilley

Underground mining at Kanowna Belle commenced in July 1998, using a sublevel open stoping method. The use of this stoping method necessitated the use of a cemented fill material for filling primary and secondary stope voids. A detailed engineering study recommended the construction of a cemented aggregate fill (CAF) system for Block A, in favour of paste fill. The CAF system consisted of a crushing and screening plant, a surface binder preparation plant and an underground fill station. Conventional underground dump trucks were used for CAF delivery. Since CAF plant commissioning in March 1999, 1.2 million tonnes of CAF have been placed underground. CAF segregation was the most significant quality control issue during CAF system operation. At the hangingwalls of filled stopes, CAF segregation sometimes occurred to such the extent that the resulting fill material was essentially uncemented coarse aggregate. This caused some CAF dilution during the extraction of adjacent secondary stopes. Numerous CAF were prepared on site for strength testing. A relationship has been formulated that allows estimation of the CAF uniaxial compressive strength in MPa, based on the cement content (c) and porosity (n), as follows. [ ] Practice at Kanowna Belle has confirmed that laboratory testing results cannot be applied for optimising the mix design of cemented rock fills that do not exhibit debris flow behaviour during placement. The grain flow characteristics and consequent marked segregation dominate the in situ fill strength. A detailed review of backfill requirements for the lower mine indicated that the total net present cost of CAF and paste systems was similar. Several significant operational advantages offered by a paste system have resulted in its selection for the remaining mine life. The construction of a paste fill system at Kanowna Belle is currently in progress.

Jan 1, 2001

By S. D. Thompson, J. C. Dzurino

This investigation mainly focused on designing a bunker system for a large underground coal mine. The primary purpose of this bunker system was to keep high- and low-sulfur coal segregated on the underground belt system. These bunkers were also required for protecting the mine faces from out by belt delays. Methodologies used in developing this plan are briefly discussed. The final design and the procedures formulated for implementing it are also presented.

Jan 1, 1987