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By D. A. Rice

As part of a cooperative effort between the U.S. Bureau of Mines and the Florida Institute of Phosphate Research (FIPR), with input-from the phosphate industry, the conversion of phosphor-gypsum to sulfur is being investigated. The proposed process incorporates a thermal reduction of phosphogypsum to calcium sulfide (CaS) and a hydrometallurgical treatment to convert calcium sulfide to ammonium bisulfide (NH4SH), which is then oxidized using a catalyst to produce elemental sulfur. The paper summarizes the results of continuing laboratory studies using an activated carbon catalyst which was loaded with sulfur through oxidation of ammonium bisulfide solution. The extraction of the sulfur that forms in situ on the catalyst is a key area in the development of the sulfur recovery process. Two approaches for removing the sulfur are being investigated: 1) thermal treatment to volatilize sulfur, and 2) leaching the sulfur using liquid anhydrous ammonia. The research has shown that it is technically feasible to recover over 90% of the sulfur from the carbon by either volatilization or ammonia leaching. Locked-cycle testing has demonstrated that the carbon has the potential to be recycled after ammonia leaching.

Jan 1, 1988

By Peter Zhang, Daniel Su, Bo Kim, Zoheir Khademian

Building on the research results and knowledge obtained from the ongoing National Institute for Occupational Safety and Health (NIOSH) Gas Well Stability Research, researchers from the NIOSH provided detailed analyses on potential longwall mining and gas well casing interactions at an unconventional shale gas well pad in a West Virginia longwall mine. Following the recommendations from recent research findings, the 5-1/2-inch production casings in all five wells were left uncemented from 4,200 feet below the surface to the surface. Prior to the first longwall panel excavation, NIOSH researchers conducted sophisticated three-dimensional numerical modeling to predict longwall-induced deformations and gas well casing stresses, which were compared with post-first panel and post-second panel mining 40-arm caliper surveys. The pre-mining predictions and comparisons with post-mining 40-arm caliper surveys were presented to all parties involved, including the coal and gas operators, Mine Safety and Health Administration (MSHA), Pennsylvania Department of Environmental Protection (PADEP), and West Virginia Department of Mines (WVDOM), prior to the re-entry operation on December 13, 2022. To date, the re-entry operation is a resounding success.

Jul 1, 2023

By J. H. Tylczak, R. Blickensderfer

Impact and abrasion properties of various commercial US grinding halls were evaluated and compared by the Bureau of Mines, US Department of the Interior. Laboratory tests were conducted on balls obtained from eight major US manufacturers. The halls included forged steel, cast steel, and alloyed white cast iron and were subjected to repeated impacts until they broke or until 300,000 impacts were exceeded. Pin abrasion tests also were conducted. The results showed wide differences in impact lives, ranging from a few thousand to over 500,000 impacts. The life of inferior commercial halls was increased five to six times by a laboratory tempering heat treatment. For halls that did not break, the major impact wear mode was spalling and ranged from an average rate of 0.28 to 4.46 mg per impact. The softest halls (steel) had excellent impact resistance but low abrasion resistance. The abrasion resistance of the steel halls generally increased with hardness. The alloyed white cast irons had about twice the abrasion resistance of the steel halls. Users should become aware of the wide variations among commercial halls, and ball manufacturers should be aware that their product can he improved.

Jan 1, 1990

By I. H. Warren

Hydrometallurgy has a well-known and established role in the production of manganese metal (1) and manganese compounds, including battery grade manganese dioxide (2). Also, several leaching processes have been developed and applied at various times for the recovery of manganese from low grade ores (3). Recently, interest in the hydrometallurgy of manganese has been stimulated by the problems presented in the processing of sea nodules (4). Fumes and dusts from the ferro-manganese furnaces also offer a potential field for the application of manganese leaching techniques (5). In treating low grade manganese ores a major requirement of the leaching process is that it should dissolve manganese from a mixture of manganese and iron oxides. The most selective reagent for this purpose is ammonium carbamate applied after preliminary pyrometallurgical reduction of the ore (6). Since soluble carbamate complexes of the postulated type (7) are formed by both manganous and ferrous, but by neither manganic nor ferric, ions, selectivety of manganese leaching is achieved by control of the reduction operation to yield, essentially MnO and Fe304? A potential improvement to this two step process would be to simultaneously reduce and selectively leach the manganese in one hydrometallurgical operation. This possibility has been experimentally studied and the results are described below. During the preliminary study of the stability of solutions of ammonium, ferrous and manganous carbamates at elevated temperatures, it was observed, contrary to the observation of Welsh (8) at lower temperatures, that

Jan 1, 1971

By Paula N. Wilson, W. T. Parry

Carbonaceous and metalliferous black shales occur in close proximity to Mercur-type gold deposits in the southern Oquirrh Mountains, Utah. These shale units, the Manning Canyon shale and the Long Trail shale, have undergone regional hydrothermal alteration. Hydrothermal solutions oxidized organic matter and pyrite, replaced shale by hydrothermal phyllosilicates and silica, and replaced fossils by phyllosilicates. The shales are depleted in organic carbon, calcium carbonate, alkali and alkaline earth metals, and enriched in aluminum and hydrogen. Hydrothermal veins containing illite, chlorite, pyrophyllite, kaolinite, Fe-oxides, and sulfides are present throughout the study area.The illite in veins is an ammonium illite that contains up to 2 % NH4 and is correspondingly depleted in K. Correlations among Au, As, Hg, TI, Sc, and rare earth elements indicate that hydrothermal fluids responsible for formation of ammonium illite were gold bearing. K/Ar ages of illite veins and illite-rich, clay-size separates of altered shales indicate hydrothermal activity occurred in the time range 193 to 122 Ma. Several ages from clay-size separates within the Mercur district cluster near 160 Ma. These ages are coeval with thrust faulting recognized to the north and west.

Jan 1, 1990

By L. B. Hales

The advent of the process control computer with its capabilities of monitoring, storage, and real-time control has revolutionized control technology in the mineral industry. Initial efforts to introduce the computer into process control began in the early 1960's. However, it wasn't until the last decade with the introduction of integrated circuits and minicomputers that truly successful applications became visible. Computer hardware and real-time operating software have improved to the point that they rarely provide major problems in the implementation of successful control systems. At this time the most prevalent problems and obstacles affecting the successful implementation of a control system are as follows: (1) reliable and representative sampling systems; (2) rugged and reliable process sensors; (3) the availability of well-defined control strategies; (4) the willingness of plant management to provide the continuous support necessary to acquire and/or train appropriate personnel in the operation and maintenance of advanced control systems. Discussion of these problems and of the instrumentation required for the successful application of computers in minerals processing plants follows. In order to enhance this discussion the remainder of this subsection is broken up into individual mineral processing categories.

Jan 1, 1979

By A. E. Hall

INTRODUCTION Underground gold mining operations are found in South Africa, U.S.S.R., Canada, the United States, Zimbabwe, Ghana , Brazil. Australia, China and many other countries. The methods used for extraction differ from highly mechanized trackless mining in the developed countries to the labour intensive systems of the third world nations. The climatic conditions in which mines are situated vary from equatorial to arctic. The rock temperatures and the depth of workings also vary significantly from shallow to extreme depth. The Western Deep Levels mine in South Africa is the deepest and exceeds 4.000 metres in depth with strata temperatures above 55°C. These major differences between mining fields result in significantly different ventilation problems in underground gold mines. The ore types also vary and some deposits have high silica contents while other mines extract sulphide ores. Methane may also be encountered in underground gold mines and can have a large influence on the ventilation practice. Several topics are currently of concern to operating mines and are reviewed here:- a) Air circulation and fans b) Mine cooling c) Permafrost operations d) Mine heating e) Control of diesel exhaust f) Gases, fires and explosions

Jan 1, 1988

By A. P. Schissler, S. Badr, U. Ozbay, M. D. G. Salamon

Yield pillars are used in deep coal longwall mines, where the depth of cover is so great that a conventional chain pillar design tends to be unsuccessful. The design of yield pillars in deep U.S. mines has been based mainly on experience, pressure arch theories, numerical modeling, and empirical methods that originated in the eastern U.S. coal mines. This paper offers field experience based guidelines for the design of yield pillars through analysis and evaluation of numerous case histories. Case histories of yield pillar applications were collated and critically reviewed to identify trends in data that can be used to formulate the design guidelines. Convincing trends observed in the case of successful case histories indicate that yield pillars should have a width to height ratio in the range from 2.8 to 6.0, a stability factor during development between 0.4 and 0.6, and shed between 94% to 98% of the cover and abutment load, as provided by the Carr-Wilson (1982) method. Also, yield pillars should be utilized in coalmines only where the roof and floor rock have a CMRR rating of 50 or better.

Jan 1, 2003

By N. S. Margaris

The vegetation of Mediterranean ecosystems is distinguished by its resistance to adverse environmental conditions, and that is the reason for examining the possibility of growing species of this flora in waste disposal sites (WDSs). The survival and growth of vegetation established at a waste disposal site is dependent to a large extent on the qualitative and quantitative characteristics of the material used in the final soil cover. In the Ano Liossia WDS, where extensive remediation work is under way, three areas were examined, which met certain criteria in relation to the age of the underlying waste and the existence of impermeable material in the final soil cover. Laboratory analyses have determined soil parameters and nutrient and heavy metal content. Alongside this, at all three sites a network has been installed to monitor the qualitative characteristics of the gaseous phase of the soil cover material. The results showed the existence of a soil material containing few nutrients and the prevalence of oxygen-poor conditions, accompanied by large concentrations of CH4, CO2 and H2S, at depths of up to about one meter.

Jan 1, 2002

By Zhuang Jianming, Liu Qinxia, Yuan Mingliang, Mei Xiangong, Chen Jin

Up to now, the leaching of manganese carbonate ore is usually performed at high temperature of 363K and the leaching rate is lower than 90%. Although in laboratory test, the leaching rate is only 90%. This paper introduced an improved method for leaching of manganese carbonate ore. Certain ammonium salt was added to the pulp to raise the solubility of Mn2+ and reduce the adsorption quantity of Mn2+ on the ore surface. Experimental results show that a leaching rate over 95% can be obtained at the temperature >273K. The activation energy is calculated to be 7.15 KJ/mol and is lower than that of normal leaching technique. The effects of the parameters, such as particle size, pulp density and initial acid concentration on the process results are investigated. A leaching rate higher than 95% can be obtained under the following conditions: particle size below 0.25mm, leaching time 60 min, stirring speed higher than 960 r.pm. H2SO4:MnCO3>1 .2, pulp density 105-205 g.L-l. A kinetic model was deduced, verifying with actual experiments. It showed that the model can describe the leaching process successfully.

Jan 1, 1995

By D. A. Rice, R. G. Swanton, A. May, O. C. Carter

As part of a cooperative effort between the US Bureau of Mines and the Florida Institute of Phosphate Research (FIPR), with input from the phosphate industry, the conversion of phosphogypsum to sulfur is being investigated. The proposed process incorporates a thermal reduction of phosphogypsum to calcium sulfide (CaS) and a hydrometallurgical treatment to convert calcium sulfide to ammonium bisulfide (NH4SH), which is then oxidized using a catalyst to produce elemental sulfur. The paper summarizes the results of continuing laboratory studies using an activated carbon catalyst which was loaded with sulfur through oxidation of ammonium bisulfide solution. The extraction of the sulfur that forms in situ on the catalyst is a key area in the development of the sulfur recovery process. Two approaches for removing the sulfur are being investigated: (1) thermal treatment to volatilize sulfur. and (2) leaching the sulfur using liquid anhydrous ammonia. The research has shown that it is technically feasible to recover over 90% of the sulfur from the carbon by either volatilization or ammonia leaching. Locked cycle testing has demonstrated that the carbon has the potential to be recycled after ammonia leaching.

Jan 1, 1987

By G. A. Plakhin, A. V. Luganov, V. A. Luganov, G. V. Gorbatenko

In order to extract gold from the complex sulphur-arsenic bear­ing raw materials and to remove arsenic and sulphur from the process in an ecologically safe form we have studied oxidizing roasting of highly arsenic gold bearing concentrates with soda, leaching of cinders, processing of the obtained solution and extraction of gold from the cake. There were processed concen­trates containing from 5 to 28% of arsenic, 12-20% of sulphur in the form of pyrite and arsenopyrite. The content of gold in the concentrates was 4-75 git. The roasting temperature was changed in the range of 773-l 173K, the consumption of calcined soda was 75-200% of stoichiometric necessarily for bonding of arsenic and sulphur into the water soluble compounds, the dura­tion of the process was varied in the range of 10-120 minutes. Under roasting in optimal conditions up to 97% of arsenic and 95% of sulphur go into water soluble compounds. The out­put of cake is 65-70% of the concentrates. The extraction of gold from the cake is higher than from the raw concentrates. The technology has been tested on a pilot plant scale

Jan 1, 1996

By Henry E. Bakkila

Introduction United States Steel Corporation's, Texas Uranium Operations operates in-situ mines located approximately 70 miles north of Corpus Christi near the town of George West in Live Oak County, Texas. In 1977, Texas Uranium Operations became the operating entity for the Burns Ranch mines 100% United States Steel ownership and also operates the Clay West mines a 50150 joint venture of United States Steel Corporation and N M Uranium, Inc. Until mid-1982, Texas Uranium operated eight (8) satellites where uranium was captured on resin and two central plants where the loaded resin was eluted, acidized, precipitated and dried to yellowcake. At present, the Clay West Central Plant is operating, as are four (4) satellite plants in a mode designed to optimize results while depleting remaining reserves. United States Steel's Texas Uranium Operations, as have some other uranium producers, managed to continue successful production during the plunge to the recent floor price of $17. Despite the fact that United States Steel does not intend to continue as--a uranium producer beyond the life of its present reserves, we naturally hope the recent trend to the pre- sent price of $24 will continue to increase.

Jan 1, 1984

By Levent Ozdemir, Russell Miller, Fun-Den Wang

The full utilization of tunnel boring machines for excavation in medium hard and hard rock has been limited by insufficient knowledge of rock behavior under the action of mechanical cutters. An understanding of factors affecting the rock removal process will permit: (1) the more efficient design of tunneling machines, (2) the prediction of boring performance from geologic data and cores taken from the proposed tunnel alignment, and (3) an improved excavation rate, thus a lower tunneling cost.. The Colorado School of Mines, under the sponsorship of the National Science Foundation, is studying the effects of a number of parameters in regard to tunnel boring using both full and small scale laboratory tests, analyzing field boring performance and comparing the laboratory and field data. Results indicate: (1) the field boring performance can be reproduced in the laboratory, (2) the optimum spacing of cutters or optimum spacing to penetration ratios may be found in laboratory testing, (3) it is promising to use small core samples and laboratory testing to predict field machine performance and (4) effect of joints on boring rate is significant and should be included in predicting tunnel boreability.

Jan 1, 1974

By L. W. Scott, T. H. Dubaniewicz, F. T. Duda, P. G. Kovalchik

Recent research conducted by NIOSH's Pittsburgh Re¬search Laboratory showed that electrical current levels permitted under present regulations may not limit cable temperatures to less than 90°C in reeled trailing cables. Reeled cables, which are tightly wrapped with many turns and which carry current in an enclosed space, can become overheated due to poor heat transfer. This overheating can cause the cable insulation to soften, making them prone to damage. The damaged insulation reduces the life of the cable and can lead to shock, electrocution and mine fires. This paper describes a method of measuring the conductor tem¬perature of mine trailing cables during normal operation. The temperature is measured using a 50/125-, µm graded index multimode optical fiber located in the center of the metallic conductors. Distributed temperature measurements are made using an optical time domain reflectometer (OTDR). This system is capable of measuring temperatures with an accuracy of ± I °C over a length of 4 km at I -mintervals. With this unique way of measuring temperature, tests can be conducted that simulate actual mine conditions. The tests provide important data that allows MSHA's Approval and Certification Center to develop approval criteria for cycli-

Jan 1, 2000

By John D. Shaw

1. Introduction 2. The Hydraulic Mine _ (i ) Development (i i ) Extraction ( i i i ) Transport 3. The Water Circuit 4. Manpower and Results 5. Modifications 6. Conclusions 1. Introduction The Kaiser Resources Ltd. hydraulic coal mine is located in south eastern British Columbia, Canada, at the western end of the Crowsnest Pass, next to the Town of Sparwood. The seam presently being mined is the number 10, known locally as the Balmer seam, which is a high quality coking coal, 50 feet in thickness and of an average inclination of 35 degrees. The mine was designed in the late sixties as a small scale trial unit, and was to use a single monitor unit, working 3 shifts per day on a 5 day per week basis. Experience has proved the method to be so successful as to warrant the expansion of the ancilliary facilities to cater for the increased production. The annual raw coal production from this single monitor unit has risen from 108,988 short tons in 1970 to 942,334 short tons in 1975, with a total mine labour force of about 160 men including the surface de-watering plant, mine supervision and mine administration.

Jan 1, 1977

By John Stroiazzo, Bernard C. Aubé

Brenda Mines, located 22 km Northwest of Peachland in British Columbia, Canada was an open pit copper- molybdenum mine which closed in 1990 after 20 years of operation. The primary concern in Brenda's tailings and waste rock drainage is molybdenum at a concentration of approximately 3 mg/L. The mine drainage is alkaline and contains little or none of the typically problematic heavy metals. Given that the waters downstream are used for municipal water supply and some irrigation, a discharge limit of 0.25 ma molybdenum was imposed with specific water quality guidelines in the receiving creek. A review of all existing and potential molybdenum removal methods was undertaken prior to mine closure. The chosen process is a two-step iron co-precipitation with clarification and sand filration at a slightly acidic pH. A 4,000 usgpm (912 m3/h) treatment plant was constructed and commissioned in 1998, at a cost of $10.5M. The successful removal of molybdenum from the drainage water is explained with details on some design innovations and operational challenges encountered during plant start-up. Investigated sludge disposal options are discussed although the long term disposal scenario has not yet been finalised.

Jan 1, 2000

By Ken A. Phillips

Like the Arizona jeans commercial says: Arizona's not just a state, its a state of mines. Nearly 300 mines operate in Arizona making it the largest nonfuel mining state in the nation. Although copper is king in Arizona's mineral complex, nonmetallic minerals play important roles both regionally and nationally. Throughout Arizona's mineral resource development history industrial minerals have dominated over the metals for most, but not recent years. The State's metal mining industry which makes Arizona the number one mining state in the United States is a relatively young phenomenon. Arizona was an important industrial mineral producer long before her metal mining industry got started. Salt, phosphates, silicates, and oxides as food additives, tanning chemicals, gemstones, components of aboriginal ordnance, pigments, and construction materials are among the minerals produced long before copper, gold, silver, and the other metals became important. Around 92 % of Arizona's mineral industry is made up of nonfuel minerals, 86 % of that is accounted for by copper. Another 4 % is taken up by copper byproducts of molybdenum, silver, and gold. The remaining 10% of the production is occupied by non-fuel, non-metallic minerals. Arizona's 1994 industrial mineral production of nearly $380 million ranks us among the top 25 in the nation and higher than the total mineral production of at least 15 states.

Jan 1, 1996

By E. P. Reed

We are proud that one of our predecessor companies originated the phrase "Safety First". That phrase remains today as the guiding principle that governs our total approach to safety and well being in U. S. Steel. U. S. Steel management is totally committed to this attitude and our objective is to have every employee as deeply conscious of his safety responsibilities. Safety is a state of mind but like most things it must have a physical side - both intertwined and inseparable. You might say each promotes the other; and this gives us confidence that with hard work, cooperation from all individuals, and proper application of knowledge and experience, our ultimate objective of frequency "0" will be attained. It is in this vein of thought we present a paper today which gives you briefly our progress, mainly in the physical, or mechanical, protection of miners at work in the Southern District mining operations of U. S. Steel. The Southern District not only includes the underground mining of coal but the underground mining of zinc ore in Jefferson City, Tennessee, and the quarrying of dolomitic limestone near Bessemer, Alabama.

Jan 1, 1970

By P. R. Taylor

This work is concerned with the extraction of refractory metals using an electro-reduction process, in which a molten oxide melt, instead of halide, is used as the electrolyte. The process may provide an alternative method of producing refractory metals from their ores through use of a reverse-polarity direct current (DC) plasma arc heating process. In such a process, the plasma torch itself acts as an anode, and resulting liquid or solid product metals work as a cathode, whereas the molten oxide melt plays the role of an electron transfer layer. The focus of this study is: the electro-reduction of scheelite; vanadium pentoxide; and chromite. For the vanadium pentoxide, the proposed melt is mainly composed of CaO-V2O5/Li2O-B2O3-V2O5or FeO-CaO-SiO2-V2O5-Li2O with the addition of other alkali and alkaline metal oxides. In the case of scheelite ore, the SiO2-CaO-Li2O-WO3system is used as melt and metal aluminum or nickel could be used as a collecting media. As for the reduction of chromite ore, SiO2-CaO-Cr2O3-Li2O system with trace amount of CaF2is used as the melt. As a demonstration, chromium was successfully produced at a laboratory scale through the plasma driven electro-reduction process. One of the studied slags had a composition of 13.8% CaO; 4.9%CaF2; 36.4% Cr2O3; 6.9% Li2O; and 38.0% SiO2. Two observations are significant in this laboratory scale study. The first one was that the amount of Cr2O3and FeO, which were predominantly electronic conductors in the oxide melt, greatly affected the conducting mechanism of the melt. With high concentration of Cr2O3and FeO in the melt, the current efficiency was fairly low. In this case, chromium was found to be barely reduced because of electronic conducting mechanism. For example, with initial slag of 60% Cr2O3, no chromium was found reduced. With low concentration of Cr2O3and FeO in the studied melt, typically no more than 30% Cr2O3, it was observed that chromium was readily reduced due to the dominant ionic conducting mechanism. The second observation was that the addition of SiO2tothe melt helped to make the oxide melt more ionic, which was apparently desirable to the molten oxide electrolysis. However, high content of silica had a negative effect on the fluidity of the melt. This was resolved by adding trace amounts of CaF2to the melt. Therefore, by judicious selection of oxide melt, refractory metal oxides might be dissolved into it and yet the melt itself retains the required ionicity. A reverse-polarity DC plasma driven molten oxide electrolysis may prove to be a viable alternative route for the extractive metallurgy of refractory metals.

Jan 1, 2003