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By Chen Wen, Li Zhao-jia, Zhao Qiang, Ning Shun-ming, Tang Sanchuan, Wang Hong-qiang

"The carbon-burdened and cold-bonded pelletizing-electrosmelting process is used to dispose low-grade manganese, and the qualified rich-manganese slag is obtained. On the condition that reduction roasting temperature was 1000?, reduction time was 45min, particle-size was -1mm, reductant dosage was 1.6%, basicity was 0.3, smelting temperature was 1410?, smelting time was 60min, it had a good effect on the melting between slag and metallographic phase, the manganese content was 32.58%, manganese recovery was 92.16% in the slag; while the iron content was 94.40%, iron recovery was 95.32% in the metallographic phase. It was proved by the demonstration tests.IntroductionManganese is an important raw material for steelmaking, which is extensively utilized in modern industry, the consumption of manganese for iron and steel industry accounts for 90% to 95%. After mining over 30 years, the high-grade manganese resources drop markedly, especially with the hypergrowth of steel industry, the domestic manganese is far from the requirement, as a result, we have to buy significant quantities of manganese overseas. Besides, the property of imported manganese is more and more complex, and the high-grade and lump manganese decrease year by year, while the fines and high-crystal water manganese are on the increase. Therefore, how to make effective use of domestic low-grade manganese and intensify the manganese’s smelting is an effective approach to reduce the cost of manganese series ferroalloy and improves market competitiveness[1-4]. It has important practical meaning."

Jan 1, 2012

By Wenxian Zhu, Xuema Li, Patrick R. Taylor

"Experiments were performed in a non-transferred arc, thermal plasma flow reactor to investigate the synthesis of ultra fine boron nitride (BN) powder from the reaction system of boron oxide (Bz03), methane (CH4), ammonia (NH3) and hydrogen (H2). Argon (Ar) and nitrogen (N2) were used as plasma gases. The thermodynamics and kinetics of the synthesis reactions were examined and a chemical reaction mechanism was proposed. The powders produced under certain operating conditions had high purity and good conversions. All the products were extremely fine powders (< 30nm) and were uniform in size distribution. The powder products were analyzed by chemical and physical characterization. The effects of the reaction variables on the conversions from B203 to BN and the purity of the products were investigated.IntroductionIn the past few decades, boron nitride (BN) has attracted a great deal of interest because of its excellent thermal, chemical and electrical properties (1-4) It has a high thermal stability and thermal conductivity. Chemically, it is very stable and is not wetted by most molten metals and slag. It is also an excellent low loss insulator. Since hexagonal boron nitride (h-BN) is light in weight, strong and easily fabricated, it has applications in a variety of specialized high temperature areas, such as a high temperature lubricant, crucibles for molten metals, thermocouple protection tubes, break rings for horizontal continuous casting of steel, and friction reducing coatings. In cubic form, boron nitride is one of the hardest materials known, second only to diamond, and it is an excellent material for tools in which the use of carbon based materials is limited by oxidation or reaction with metals."

Jan 1, 1998

By Hiroyuki Matsuura

Treatment of electric arc furnace (EAF) dusts has become an important issue from the viewpoint of the environmental protection and recycling of variable resources because these dusts contain considerable amount of zinc and lead. A new recovery process of these metals has been proposed, in which the metals in the dusts react with waste polyvinyl chloride to form metal chlorides. Therefore, it is important to clarify the physicochemical properties and behaviors of zinc, lead and those chlorides and oxychlorides. In the present study, the kinetics of chlorination of ZnO, PbO and ZnFe2O4 mainly contained in the EAF dusts were investigated at 1023 K to 1273 K with Ar-O2-Cl2 gas. Based on these results, the selective chlorination and evaporation process of zinc and lead from the mixture of Fe2O3-ZnFe2O4-ZnO-PbO was examined and the high efficiency of selectivity has been demonstrated.

Jan 1, 2006

By Hong N. Vu, Jitka Jandova

"Gypsum and limestone methods were examined in this study to process zinnwaldite wastes originating from dressing Sn-W ores mined in the Czech Republic. These wastes containing 0.20-0.30% Li and 0.10-0.20% Rb were subjected to magnetic separation to obtain a zinnwaldite concentrate with 1.36% Li and 0.94% Rb. It was observed that processing of the zinnwaldite concentrate with gypsum resulted in almost 96% recovery of Li into aqueous liquors, whilst rubidium extraction was only 25%. At the same time, it is possible to extract almost 92% Li and Rb from the identical zinnwaldite concentrate if the concentrate is processed by limestone method. Lithium carbonate, a final product of both methods was recovered from the refined sulphate solution using K2CO3 as a precipitation agent and/or from unrefined hydroxide solution using gaseous CO2. In the continuation of this study, rubidium will be separated from carbonate solutions after Li2CO3 precipitation as RbAl(SO4)2, an intermediate for Rb2CO3 production. IntroductionLithium is used as an alloying constituent in lightweight alloys, as a heat transfer medium in nuclear reactors and as a component in primary and secondary batteries. With the development of a new generation of electric vehicles, the lithium demand will dramatically grow. Lithium chemicals find extensive application in many industrial branches such as metallurgical, glass, ceramic and pharmaceutical industries. Rubidium compounds are predominantly used in psychiatry and medicine, in magneto-optic modulators, solid-state lasers, phosphors and components of electrolytes for fuel cells. The four most important lithium minerals are amblygonite, spodumene, petalite, and lepidolite. Spodumene LiAlSi2O6 (6.0-7.5% Li2O) and petalite LiAlSi4O10 (3.5-4.5% Li2O) belong to aluminosilcate minerals. Lepidolite (Li.Al)3(Al.Si)4O10(F.OH)2 (3.30-7.74% Li2O), lithium mica, is the most important representative of the mica minerals, a subgroup of the aluminosilicates. It frequently contains 3–5% Rb2O and eventually caesium. Zinnwaldite, which has the general formula K(Li.Al.Fe)3(Al.Si)4O10(F.OH)2 (2-5% Li2O), is regarded as a variety of lepidolite with a high iron content. Commercial amblygonite is a complex phosphate (Li.Na)Al(F.OH)PO4 (up to 9.88% Li2O), however, its deposits have not been commercially exploited because of their small size. Natural brines with a high lithium chloride content are important in the industrial production of lithium [l]"

Jan 1, 2008

By Li Qian

Mechanisms of bio-dephosphorization from iron ore was investigated in this Paper. The results show that there are two bio-dephosphorization ways from iron ore, the one is that Acidithiobacillus ferrooxidans directly derive phosphorus from the ore, the other is phosphorus is able to be leached acid produced during metabolizing of Acidithiobacillus ferrooxidans, and the latter is more important than the other. Adding suitable pyrite can enhance the bio- dephosphorization process through providing nourishment and producing acid directly due to S 3oxidized or indirectly due to Fe3 as oxidant. The potential varies in the range of 0.434~0.498V and pH is in the range of 2.5 ~ 1.25 during bio-leaching process. It can be founded that, according 2+to the E-pH graph of Fe-H2O system, Fe wouldn?t be oxidized under sterile system in this potential and pH ranges. It can be obviously concluded that the Acidithiobacillus ferrooxidans are 2+able to reduce the potential for the oxidization of Fe and make the oxidization occur in the above pH and potential zone, so the bio-leaching process can proceed. the investigation of E-pH graph of P-H2O system show that H3PO4 can exist steadily.

Jan 1, 2009

By Jay. M. Khodadadi, Josef Štetina, František Kavicka

"With the aid of the proper original numerical model of solidification the instruction for preparation of input parameters for numerical simulation of technological processes, with change of the phase or structure, will be presented. A method of calculation analysis of influence of therrpophysical properties of materials entering the system of casting-mould-cores environment, and also of boundary conditions on the required simulation accuracy will be suggested. For the cast material, the influence of heat .conductivity, specific heat capacity, density and latent heat of phase transformation also has been analysed. For metallic or non-metallic moulding material"" the influence of the see main parameters has been analysed and, furthermore, their combination, influence of thermal conductivity, and of heat storage. The order of influence of all quoted parameters of a casting and moulding material was established. For example heat conductivity in the liquid state is on the last place. From the boundary conditions the -most important influence on the total solidification time and · on the mechanism of forming of temperature field has the ·boundary condition on the casting mould boundary, then follows the boundary condition on the level of a molten metal. The negligible influence has the boundary condition on the mould frame and on the bottom.IntroductionThe original and universal mathematical model of solidification, cooling and heating has been set up and checked, in order to be capable of analysing a one- to three-dimensional steady or unsteady temperature field of the casting-mould-environment system and, namely, of the system as a whole or its arbitrary parts, during any industrial technological process whose individual processes could be solidification, cooling, heating, refrigeration and others, in any sequence or singly. The model enables the simulation of traditional and also non-traditional technologies of casting in foundries, metallurgical plants, forging operations, heat treatment processes, etc. If solidification is not the matter, the metal part of the system need not be called the casting but a component, a block, a forging and the like."

Jan 1, 2000

By Lv Guozhi, Niu Liping, Liu Yan, Zhang Zhiqi, He Jicheng, Zhang Ting’an, Dou Zhihe

"CuCr alloy can be extensively used as contact materials in integrated circuit, electrodes, electric contact and high strength conductor. We proposed thermit reduction-electroslag remelting method of preparing the large scale CuCr alloy. But there are pores and oxide inclusions in CuCr alloy prepared by thermit reduction process. This paper studied mainly the effects of ratio of reactant and additive on the inclusion type and their occurrences in CuCr alloy. The slags and CuCr alloy were characterized respectively by XRD and SEM. The results show that when the additive is Na3AlF6, the slag consist of Al2O3 and Cr. When the additive is CaF2, the slag consist of Al2O3, Cr, CaF2 and CaAl4O7. The inclusions in CuCr alloy are mainly Al2O3 and pores which disperse in Cu-rich zone and Cu-Cr phase interface. When 5% CaF2 and 5% KClO3 are added, there are fewer pores and inclusions, and the more better microstructure.1 IntroduceCuCr alloy is the contact terminal material with an eximious properties[1,2], which gradually replaces CuBi alloy becoming the first choice for contact terminal material in the medium and high power vacuum switch after the 1970s. The traditional preparation methods of CuCr alloy mainly contain powder metallurgy, infiltration process and vacuum electric arc melting methods. But the above methods exist some shortcomings, such as poor product quality, high cost of production, processes complex ect[3-9]. CuCr alloy is made by the thermit reduction self-propagating method, which uses CuO, Cr2O3 and Al as raw material to get the high-temperature melt, and then casts to manufacture CuCr alloy ingot, which response equation follows as:"

Jan 1, 2012

By Jayagopal Uchil, M. Krishna, Shanta Sastcy

"Damping behaviour of aluminite particulate reinforced ZA-27 alloy metal matrix composites processed by compocasting method is studied. The weight percentage of particulate reinforcement is 0,1,2,3, and 4%. A dynamic mechanical· analyzer is used ·to measure the damping capacity and dynamic modulus at the natural frequency of the specimen over a temperature range of 30°C to 300 °C both in the heating and cooling cycle. The damping capacity of the material is found to increase with increase in temperature and weight percentage of aluminite reinforcement although this is accompanied by a decrease in dyliamic modulus.The damping capacity and dynamic young's modulus exhibit a sharp decrease in their values around 300 °C a8 ZA-27 alloy undergoes a first order phase transition in this region which is confirmed by Differential scanning calorimetric studies. Several damping mechanisms have been evaluated theoretically for the material under study. The damping capacity at low temperatures is attributed primarily to coefficient of thermal expansion mismatch induced dislocations and high intrinsic damping of the matrix. At higher temperatures the damping capacity is attributed to ZA-27/aluminite interface, phase transformations and thermoelastic damping.IntroductionMetal matrix composites. (MMCs) offer designers many added benefits, as they are particularly suited for applications requiring good strength at high temperature, good structural rigidity, dimensional stability, and lightweight [1-5]. At present, the usage of ceramic particles as reinforcement in MMCs has attracted considerable interest from scientists and engineers. The MMCs show substantially improved elastic modulus, strength, stiffiless, and tribological properties with low coefficient of thermal expansion compared with the unreinforced matrix material."

Jan 1, 2000

By Bin Xu, Qian Li, Yong-bin Yang, Tao Jiang, Jian-jun Hu

It could significantly increase the leaching rate of refractory gold concentrate containing sulfur and arsenic by roasting pretreatment with adding certain amount of sodium sulfate, and the mechanism of that was systematically researched with DSC, XRD and SEM in this paper. Results indicated that the mechanism of Na2SO4 on double refractory gold concentrate at roasting pretreatment can be summed up in the following three aspects：Firstly, Na2SO4 can react with SO2 and SO3 which is produced by the oxidation of sulfides and generate Na2S2O7(l), which plays buffer effect on sulfides exothermic oxidation, avoiding the secondary-encapsulated of gold. Secondly, the liquid phase of Na2S2O7 can cover mineral particles' surface that possesses a sintering effect, it leads to internal cracks of the particles. Finally, mineral particles will gather with sodium sulfate particles as the center that can improve the permeability of the layer.

Jan 1, 2015

By Bowen Li, Matthew D. Andriese, Jiann-Yang Hwang, Zhiwei Peng

"Magnetic iron sulfide ore particles heat rapidly by microwave (MW) irradiation generating plasma during oxidation of surfaces. The high temperatures produced by the exothermic event decompose local portions of samples forming a differentiated flux of partially melted silicate (si-mt) with entrained metal-sulfide (sul-mt) droplets. The si-mt forms crystals of olivine (01) in Ca-rich pyroxene (Cpx) melt that resorbs a portion of iron sulfide (Po). The immiscible sul-mt droplets of (Fe,Ni,Cu)1-xS contain magnetic subsolidus Ni-pyrrhotite (Ni-Po) with Cr-bearing ferrospinel (Mag). Sub-micron sized flecks of Au are found on the surface of a sul-mt droplet with scanning electron microscope (SEM).IntroductionSulfide ore deposits supply the world's mineral resource in the production of non-ferrous metals. Particularly, Cu-Ni deposits are chemically enriched in metals from high sulfur saturation during magmatic formation that creates the proper geochemical environment for metals enrichment [1, 2]. The sulfur and oxygen fugacity control redox conditions of a differentiated silicate/sulfur magmatic melt with the concentration of iron playing a dominate role in the chemical partitioning of metals in sulfide liquid [3, 4]. The initial magnetic crystallization of (Fe,Ni)i-xS monosulfide solution (mss) from metal-sulfide liquid has an exclusive effect on the fractionation of mineral assemblages (zoning) [5].Phase equilibria of sulfide melt (sul-mt) components are related by a miscibility gap with mss forming Ni-rich pyrrhotite (Ni-Po) followed by the crystallization of (Fe,Cu)1-xS intermediate sulfide solution (iss) [6]. Precious metals form stable chacogenides and are retained in solution until the final liquid solidifies. The redistribution of metals now occurs by subsolidus cooling of mss and iss that exsolve low-temperature Fe-Cu-Ni bearing mineral assemblages [7]. The proper interpretation of ore genesis increases processing capabilities by isolating chemically enriched zones during extraction and should be used to aid in sustainable mine site development [8-11]."

Jan 1, 2013

By Paul L. Wichlacz

A mathematical model of growth and ferrous iron oxidation for attached bacteria was applied to rotating biological contactor (RBC) units treating acidic mine drainage. The model describes attached bacterial growth as a saturation function, where the rate of substrate utilization is determined by a maximum substrate oxidation rate constant, a half saturation constant, and the concentration of substrate within the RBC. The maximum oxidation rate constant was proportional to flow rate and the substrate concentration in the reactor varied with influent substrate concentration. The model was tested at three separate sites and with three different size RBC units. The ability of the model to predict the rate of iron oxidation under all test conditions was significant. The accuracy of the model was found to be affected by unit size and vary with specific test site.

Jan 1, 1985

By R. Y. Wan, S. L. Chryssoulis

"Gold associations were established in a·biooxidized, chlorinated CIL residue assaying 0.02 oz Ault and in a biooxidized thiosulfate leach residue assaying 0.01 oz Au/t. A detailed mineralogical study involved: assays of screened fractions; light microscopy; ion probe microanalysis to quantify 'invisible' gold in sulfide minerals; proton probe microanalysis to detect and quantify preg-robbed gold. In the CIL residue, most of the gold is preg-robbed (71 %). In the thiosulfate leach residue, gold occurs mainly as submicroscopic disseminations in microcrystalline quartz (chert). In both residues, the 'invisible' gold in pyrite accounts for a minor fraction of the gold assay. Quantitative determination of the gold occurrence in the two residue samples established conclusively that gold adsorption on carbonaceous matter in the thiosulfate leach is of minor importance.Acknowledgement: published with permission of Newmont Gold Company."

Jan 1, 1997

By N. Menad

The formation of the dioxins can be dependent on the quantities of carbon, hydrogen, chlorine and oxygen present in a given system, as well as on parameters such as temperature and pressure. Inadequate supply of combustion air ( incomplete oxidation ), low combustion temperatures ( incomplete combustion ), and insufficient turbulence in the combustion are factors which can favour their formation. Dioxins were produced also calatytically from chlorinated phenol precursors, non-chlorinated compounds that were chemically, and reaction of phenol with inorganic chloride. In this paper different precursors such as combination of C, H, 0, Cl, rapid formation/combustion intermediates and routes to PCDFs are reviewed, and the influence of PVC amount on the formation of these isomers is discussed.

Jan 1, 2000

By Ricardo Ponce

In recent years, ENAMI implemented modernisation plans at its two smelters in order to meet the government&apos;s environmental regulations introduced in the early 1990s. The modernisation plans defined the new SO2 and particulates emission targets, deadlines for compliance, and the revised treatment capacities of the smelters. At Las Ventanas smelter, the principal process change consisted of eliminating the reverberatory furnace. All the smelter feed is currently processed in a 4m diameter, 14m long Teniente Converter, using up to 34% oxygen enriched air. Dry concentrate is injected into the bath through tuyeres. A fuel oil burner compensates for any process heat deficiency. The Teniente Converter high copper content slag is cleaned in an electric furnace. This furnace is also used to melt internal reverts. This paper will discuss the successful operation of the slag cleaning electric furnace.

Jan 1, 1999

By C. Flores

A novel process using solid metals for the direct reduction of more noble metal ions from solvent extraction organics has been developed. Base metals recovery has been the principal focus of investigations to date but feasibility tests have now also been made on galvanically stripping selected precious metals. In this study gold (III) was loaded from an aqueous HAuCI4 .3H20 solution into a mixed organic 40 vol.% TBP, 10 vol. % D2EHPA in kerosene. The direct precipitation of metallic gold from the loaded organic phase using zinc powder and iron, aluminum and copper slabs at 70 °C was successfully demonstrated. The gold reduction rates were relatively fast even though the conductivity of the organic solutions is very low. The reaction rates were studied as a function of the variables zinc particulate size, oxygen and nitrogen atmosphere, water content in the organic phase, organic ratios and temperature. The gold morphology was usually powdery or dendritic in nature but continuous films were obtained in some instances. Activation energies were calculated and possible reaction mechanisms are discussed. In general, the results obtained were very promising and showed that gold can be successfully cemented from selected organic solvents by galvanic stripping using less noble solid metal reductants.

Jan 1, 1995

By Grigore Matei

The thermodynamic properties of CU2S-FeS system are important not only in the case of copper smelting but also in the case of general pyro-mctallurgy, However there are not many reported activity data In this study, activities of FeS and CU2S in the CU2S-FeS system were calculated using the Darken&apos;s method from the activity data of the CU2S-FeS-Sb2SJ systems measured by the transportation method at 10S0°C. The activities of CU2S and FeS in the CU2S-FeS system showed negative deviation from the ideal behaviour and satisfied the relation of the Gibbs-Duhem equation,

Jan 1, 2003

By Hongbo Yang, Tongbo Zhang, Ting Huang, Jingshe Li, Fangfang Song

"Liquid core length is a very important parameter of the process of continuous casting, which directly reflects the cooling status in secondary cooling zone and solidification rate of the slab. In this paper, the billet caster in some steel plant in China was chosen as the prototype of simulating. A numerical simulating model for calculating the liquid core length of continuous casting billet was built by ProCAST software, which was verified reasonable and accurate by pin-shooting technique. Based on the model, the relationships between casting speed, casting temperature and liquid core length of casting billet were found, which was very practically useful for the workers on sit to improve casting billet quality. IntroductionContinuous casting process developed very rapidly because of the high metal yield, energy saving, and low-cost 111• And the quality requirements of continuous casting billet for customers became higher and higher with the fast development of economic121• Internal defect usually is the major quality problem for continuous casting billet[3•61 , which is influenced by the solidification process of casting billet, especially the solidification process of liquid core17•81 • So it is very important to study on the relationship between casting parameters and the liquid core length which means the distance between the crystallizer meniscus and the casting billet solidification end-point. In practical production process, the workers usually control the quality of casting billet according to the liquid core length."

Jan 1, 2013

By William Petruk

The concentrator of the Iron Ore Company of Canada consists of spiral circuits, a cone plant and a magnetics plant with regrind. The proportions of liberated and unliberated grains of iron oxides at each point throughout the concentrator were measured by image analysis, and recoveries were calculated for each particle type by the MATBAL materials balancing program. The results show that spirals and cones recover more than 92% of the liberated iron oxide grains in the size range of 848 to 150 um,, but the recovery drops off rapidly for finer grained particles. The tailings from the spirals and cones are reground and low intensity magnetic separators are used to recover liberated magnetite in the -37.5 um size range. The concentrator does not have a unit that efficiently recovers iron oxide grains in the size range of 150 to 37.5 um Consequently about 25% of the iron oxides in the ore are lost to tailings as liberated. grains in the size range of 150 to 37.5 um

Jan 1, 1989

By P. A. Botha

Most sinter producers prefer to use a range of iron ores with the aim to optimize their sinter blends. ISCOR is however limited to the use of ore from two deposits, namely Sishen and Thabazimbi. Only sinter produced from Sishen ore is described in this report. The Sishen iron ore deposit provides high-grade hematite ore with a mean iron content of 65 per cent. Three major ore types are developed: massive, laminated and conglomeratic. The main ore mineral is hematite with minor to trace amounts of quartz, mica, phosphates and, in places, carbonates. A sinter product is characterized by its mineralogical composition and metallurgical properties. The production rate also plays an important role in the economic evaluation of sinter quality. Sinter-pot tests were conducted with varying basicities, given as the ratio of CaO to SiO:< and coke content. The results of these tests were characterized by mineralogical and metallurgical methods. Basicity of a sinter mix directly influences the mineralogical composition and metallurgical properties. The content of calcium ferrite and calcium silicate increases with increasing basicity, thereby increasing the reducibility and cold strength of the sinter product. Experiments performed during this study provided a model for the optimization of the sinter mix with respect to its mineralogical and metallurgical parameters.

Jan 1, 1991

By Zeng Zheng, Liu Chen, Yu Xing-Fu, Tian Su-Gui, Zhang Chao

"Single crystal nickel-base superalloy is prepared by using the various withdrawing rates. By measuring creep properties and microstructure observation, the influence of the element segregation on creep properties of the superalloys is investigated. Results show that the dendrite spacing and the segregation extent of the elements decrease with the enhancing withdrawing rate. The superalloy with smaller dendrite spacing has lower segregation of the elements and better creep resistance. The dislocations climbing over the rafted y’ phase is thought to be the deformation mechanism of the alloy during steady state creep. In the later stage of creep, the fact that some dislocations shear into the rafted y’ phase may twist the rafted y’ phase. As the creep goes on, the initiation and propagation of the cracks occur up to occurring creep fracture, which is thought to be the fracture mechanism of the superalloy during creep.1. IntroductionSingle crystal nickel-based superalloys consist of high volume fraction of ?? strengthening phase and ? matrix, and possess the excellent high-temperature mechanical and creep properties, therefore, they have become the main material to make the blades of the advanced aeroengines[1-3]. Some literatures report that the temperature-bearing and creep-resistance properties of the single crystal nickel-based superalloys can be remarkably improved as the increases content of the refractory elements, such as W and Re[4-6]."

Jan 1, 2012