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By Yufeng Guo, Tao Jiang, Jianjun Fan, Haizheng Hao

"Function of High Pressure Roll Grinding (HPRG) in production of oxidized pellets from magnetite concentrate as raw material was systematically studied. It was found that bentonite dosage decreased from 1.3% to 0.8% if specific surface area of magnetite concentrate pretreated by HPRG was up to 2553.41cm2.g-1. The green ball quality improved obviously due to the increase of specific surface area and fine particles content, and the improvements of size distribution and the ballability of pretreated materials. However, the decrease of pellet porosity accelerated the primary solid phase reaction and oxidation reaction, which made the pellets surface form compacted layer that handicapped the diffusion and migration of oxygen, promoting the formation of double layer structure of finished pellet. Consequently, the compression strength of preheated and roasted pellets was not markedly improved by HPRG.IntroductionWith the increase of proportion of pellets in the BF recently, the technical-economic index of BF has obviously been improved. Consequently, the production and the quality of BF pellet are given more attention [1]. However, with the decrease of the quality of iron ore concentrate, the problems such as poor ballability, high bentonite dosage, high preheating and roasting temperature are becoming the great challenges to not only the quality of finished pellets, but also the energy consumption [2, 3]. In order to overcome these problems, mechanical pretreating technologies such as the High Pressure Roll Grinding (HPRG) and Damp-grinding are widely applied. HPRG has a number of advantages such as low energy consumption, high productivity and easy-maintaining. It is more economic and environmentally friendly than the Damp-grinding technology [4, 5]. A great number of experiments have revealed that HPRG can improve the quality of hematite pellets. Although there are some studies of function of HPRG in the magnetite oxidized pellet production, they are not comprehensive and systematic, especially to the preheating and roasting system [1, 2, 6, 7]. Accordingly, the influence of HPRG on the pelletizing system and the preheating and roasting system are systematically studied in production of magnetite oxidized pellets in this article."

Jan 1, 2011

By Jorge Alberto Soares Tenório, Victor Bridi Telles, Denise Crocce Romano Espinosa, Felipe Fardin Grillo, Vicente de Paulo Ferreira Marques Sobrinho, José Roberto de Oliveira

"This research aims to study the process of incorporation of the metal iron in electric arc furnace dust (EAFD), from a steel mill producing long steel by liquid iron in addition to the changing temperature of 1400 degree Celsius altering experimental conditions such as how to add the EAFD (as received and in the form of briquettes), the percentage of EAFD to be added (10, 20 and 30% of initial weight of sample pig iron) and the time of withdrawal of the sample of pig iron and slag (30 minutes after the addition of EAFD). Previously, the EAFD will be characterized using the following techniques: chemical analysis, particle size analysis, X-ray diffraction, scanning electron microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) microanalysis. After characterization, the eletric arc furnace dust to be added to the bath of liquid iron, will be divided into 2 types: the first order of addition will be in the form ""as received"" from the plant and the second is through the agglomeration of EAFD in the form of briquettes. The achievement of fusion experiments in laboratory scale, will take place in a vertical tubular furnace with temperature control. The fusion experiments to assess the incorporation of the metal iron will use graphite crucibles. A flow of inert gas (argon) will be maintained inside the furnace during the experiments. It is expected that the results obtained at the end of the research allow the evaluation of the iron metal incorporation of eletric arc furnace dust in hot metal bath.IntroductionThe steel industry generates a variety of solid wastes, liquid effluents and gaseous emissions at various stages of processing. The electric furnace dust (EAFD), generated in electric arc furnaces, represents a major problem for their content of chemical elements such as zinc, iron, chromium, cadmium, among others, issued to the atmosphere during the manufacture of steel[1]."

Jan 1, 2012

By Ali P. Gordon, James Williams

Joints gasketed with viscoelastic seals often receive an application of a secondary torque, i.e., retorque, in order to ensure joint tightness and proper sealing. The motivation of this study is to characterize and analytically model the load and deflection re-torque response of a single 25% glass-fiber reinforced polytetrafluorethylene (PTFE) gasket-bolted joint with serrated flange detail. The Burger-type viscoelastic modeling constants of the material are obtained through isolating the gasket from the bolt by performing a gasket creep test via a MTS electromechanical test frame. The re-load creep response is also investigated by re-loading the gasket after a period of initial creep to observe the response. The modeling constants obtained from the creep tests are used with a Burger-type viscoelastic model to predict the re-torque response of a single boltgasket test fixture in order to validate the ability of the model to simulate the re-torque response under various loading conditions and flange detail.

Jan 1, 2015

By Jafar Safarian, Merete Tangstad, Leiv Kolbeinsen

"Silicon and its binary alloys have several applications in metallurgical, chemical, photovoltaic and semiconductor industries. Silicon goes to its liquid state within its production, refining and when it is alloyed with other elements. Therefore, the characterization of silicon melts thermodynamics is important and useful. The liquidus and activities in several silicon binary systems have been recently calculated by the application of two liquidus constants, which were established using the experimentally determined liquidus data. In the present study, the thermodynamic properties of six silicon binary melts, which are simple eutectics, are calculated by analytical approaches. In this case, the changes in the partial and integral Gibbs free energies and enthalpies of mixing are calculated and compared with the experimental data in literature. The enthalpies are calculated by two methods and the calculation results are compared to the data from the literature. It is shown that thermodynamic properties of silicon binary melts can be accurately predicted without the use of complicated thermodynamic software.IntroductionSilicon and its alloys have several industrial applications. Silicon is used for making aluminium-silicon alloys to produce cast parts, mainly for automotive industry. Silicon in the form of ferro-silicon is used to deoxidize and alloy steel and cast iron. The photovoltaic (PV) industry has had a rapid growth in the recent years and silicon is the dominant material used for the fabrication of solar cells. Silicon is primarily produced through carbothermic reduction of quartz in electric arc furnaces and the produced metallurgical grade silicon (MG-Si) contains around 1 wt% impurities. It is further refined to produce solar grade silicon (SoG-Si) with above 99.9999 wt% Si to fulfil the chemical requirement for PV application. Since molten silicon is processed all along the metallurgical route, obtaining fundamental thermodynamics knowledge about silicon melts is valuable for the related industries."

Jan 1, 2012

By Michael E. Stout

M.A. Industries, Inc. has developed and is now offering on a commercially available basis, complete systems to recover and recycle lead from spent SLI batteries. The system begins with the breaking and separation of the component parts of the batteries and subsequent treatment of the effluent water produced by this operation. The recyclable materials recovered from this process are metallic lead, lead paste and polypropylene. The lead paste is introduced into a process to convert it from a lead sulfate to a lead carbonate. The process also regenerates the salt solutions into reusable carbonate. The lead carbonate is then leached into an acid bath where it is later recovered by a proprietary electrolytic process. The metallic lead is recovered in a short rotary furnace producing metal for further refining and alloying. The polypropylene is further washed and then introduced to a reclaim extruder along with the proper modifiers and additives. The resulting resin can then be sold on the open market to injection molding processors. This complete system greatly reduces the amount of waste to be disposed of and completely complies with all applicable EPA guidelines.

Jan 1, 1993

By Joseph D. Lessard

A process simulation of the conversion of molybdenum disulfide concentrates into molybdenum dioxide via the Looping Sulfide Oxidation process has been performed using HSC 7.1 thermodynamic software. By decoupling molybdenite conversion and molybdenum oxidation, Looping Sulfide Oxidation changes the paradigm by turning molybdenite processing into an energy generator while producing a molybdenum dioxide, which has a lower vapor pressure and lower oxygen content than molybdenum trioxide. The Looping Sulfide Oxidation process selectively produces molybdenum dioxide over molybdenum trioxide. This process uses a stoichiometric mixture of oxygen and molybdenum trioxide as oxidants in the conversion of the molybdenum sulfide to the molybdenum oxide. The model simulates the two reactor scheme required by Looping Sulfide Oxidation and incorporates thermodynamic equilibrium simulations performed in FactSage 6.3.1 thermodynamic software. Energy capture is also maximized with heat exchanger systems to transfer heat released in reactions to preheat air.

Jan 1, 2014

By D. P. Cook, Jr. Jones, J. W. Evans

"It is well understood that the flow of liquid metal in the mold region of the caster can have a notable effect on the overall solidification behavior in aluminum casting. Previously our group has characterized the flow in this region in a water model, using particle imaging velocimetry. The flow is significantly effected by the specifics of the metal delivery system, i.e. size, geometry, used during the cast. Recently, a time-averaged 3D numerical model of the nozzle, combo bag and sump region has been developed and its validity has been tested against experimental data. Cases were run for different sized combo bags as well as bags that have been blocked. The results show satisfactory agreement between the physical and mathematical models.IntroductionFluid flow in the head of an electromagnetic (EM) and direct chill (DC) ingots has been shown to effect many important operational parameters in casting such as superheat removal, macrosegregation, and hot cracking. In most cases, the momentum from the nozzle is diverted through a delivery system, termed a bag, before entering the mold region. The specific geometries of the bags vary widely from operator to operator suggesting that there is still some question as to the optimum design. Several studies [1-4] have been carried out to understand the influence of the bag design on the solidification behavior in aluminum casters. However, few studies have included numerical prediction with experimental verification. Unfortunately, many simulations performed today still do not accurately account for flow in such devices.Recently, a significant amount of research into the flow resulting from the metal delivery systems has been performed [5-8]. The thrust of this research has been characterizing the flow patterns by a measurement technique called particle imaging velocimetry. The data suggest that the method of delivering the liquid metal into the mold region has a significant effect on the nature of the flow. With a detailed set of quantitative data from a water model, a numerical model can be built and tested to ensure a proper description of the flow field. The computational model used in these simulations is designed to represent a laboratory scale model of a caster in which ""combo"" bags were simulated. Such bags are mostly of a densely woven glass fiber material with low permeability to aluminum. ""Windows"", of a more open weave, permit aluminum to flow from the bag, see Fig. I. Two different sized combo bags were modeled, each subject to two different outflow window configurations. Furthermore, experimental measurements [9] were used to validate the model results."

Jan 1, 1999

By H. Eccles

BNFL, an internationally acclaimed company noted for its nuclear fuel cycle services and waste management technologies, collaborated with Viridian BioProcessing Ltd, a small company acknowledged for developing environmental biological processes, and an internationally recognised professor of biological sciences, to develop an unique bioremediation process for treating toxic, heavy metal contaminated land. This paper describes the process, with particular reference to the problem and scope of land contamination with toxic, heavy metals and the current available technologies. The process technologies are based on using indigenous, soil micro-organisms which can be stimulated to produce acid or sulphide ions to mobilise or precipitate the heavy metals respectively. Laboratory studies have indicated metal removal efficiencies of greater than 90 % can be achieved, whilst recovery efficiencies from the metal loaded leachate are even higher at approximately 95%.

Jan 1, 1996

By Kazuyuki Kikuta

MMAJ, a govemmental organization in Japan, has carried out a 4 year project for the development of the decontamination and metals recovering technology for the fly ashes from municipal waste incineration. Heavy metals (zinc, lead and copper) are recovered as raw materials for the non-ferrous metals production, without formation of any waste materials to be disposed. More than 500 thousands tonnes a year of fly ashes generation from the municipal waste incineration has been one of the main social issues in Japan, because most of them need to be disposed to the registered areas after decontamination, and occupy 5% of the municipal wastes disposed. The segregation, flotation and chemical process are applied to the treatment of the primary fly ash from municipal waste incineration, and MF (Mitsui-type blast furnace) Process after the chlorine removal to the secondary fly ash. The main results of experiments are -About 90% of heavy metals, zinc, lead and copper, can be recovered from the primary and the secondary fly ashes to the products for the non-ferrous metals production. -Both of the leaching residue from the primary fly ash treatment and the slag from the secondary fly ash treatment can be used as a raw material for the cement production, meaning that the decontamination technology for the ashes without the landfill has been established. -Dioxins in the primary ash can be decomposed satisfactorily, and the dioxins content in the segregation furnace gas is less than O.lng-TEQ/Nm3 without any gas cleaning system

Jan 1, 2003

By Baokuan Li, Qiang Wang, Zhu He

"A mathematical model has been developed to investigate the magnetohydrodynamic (MHD), thermal, and solidified behavior in electroslag remelting process. Based on the finite volume method, a multiphase coupling MHD approach is employed to investigate the droplet formation as well as movement in molten slag under the action of an alternating current. The VOF formulation is adopted for interface tracking. The electrical potential method is adopted for the electric current and magnetic field. The Electromagnetic force and Joule heating are recalculated at each time step and then is implemented in the momentum and energy equations as a source term, respectively. Moreover, solidification of the metal is described by an enthalpy-based formulation, while the mushy zone is treated as a porous medium with porosity equal to the liquid fraction. The model is used to investigate the effect of electrode tip shape on MHD, thermal, and solidified behavior and provide valuable information.IntroductionElectroslag remelting (ESR) process has been used widely to produce high-performance alloys dedicated to critical application, such as hot work tool steels, nickel base alloys, the manufacture of components in aerospace and landbased turbines, etc. Figure 1 shows a schematic diagram of ESR process including a consumable electrode, a molten slag pool, a liquid metal pool, a solidified ingot, and a water-cooled mold. Alternating or direct current flows from the electrode to the water-cooled baseplate through the high resistivity calcium-fluoride-based molten slag which result in Joule heating and Electromagnetic force (EMF). Part of the Joule heating melts the electrode and the droplets travel through the slag and accumulate the liquid metal pool. The electrode is continuously advanced into the slag as it melts to build up an ingot of improved structure and composition by controlled solidification and chemical refinement. The metallurgical properties of the remelted ingot are really related to the solidification structure, which strongly depends on magnetohydrodynamic, thermal, and solidified behavior in the molten slag, liquid metal pool, and mushy zone."

Jan 1, 2014

By Qian Xu, Xionggang Lu, Xingli Zou, Zhongfu Zhou, Shuhua Geng, Hongwei Cheng

Herein we report an electrochemical route from oxides (SiO2, TiO2)/sulfide (MoS2)/carbon mixture precursors to Mo-Si-Ti-C composites in molten salt. The electrochemical process was carried out in molten CaCl2 at 800 °C with a potential of 3.1 V, and a graphite-based anode was used in the electroreduction process. The reaction mechanism and the influences of the stoichiometry of the initial mixture precursor on the morphology and phase composition of the final products were investigated. It has been found that Mo5Si3/MoSi2/Mo3Si/Mo, Mo5Si3/MoSi2/Mo2C/SiC, and Mo5Si3/Mo2C/Ti3SiC2/TiC/Mo composites can be electrosynthesized directly from their oxides/sulfide/carbon mixture. The preliminary experimental results suggest that the electroreduction process can be used for the controllable electrolytic production of alloys/carbide-containing composites from oxides/sulfides/carbon precursors.

Jan 1, 2016

By Ehsan Khajeh

In this study, the permeabilities of Al-15.5wt%Cu and Al-19.5wt%Cu have been determined by solving the full Navier-Stokes equations on 3D geometries of interdendritic channels obtained by X-ray microtomography (XMT). The samples for XMT were sectioned from different positions in directionally solidified cylinders in order to obtain a variety of microstructures for each composition. The flow has been solved using a 2nd-order accurate Finite Volume Method (FVM) approach. The effect of employing uniform or unstructured mesh on the calculated permeability has been studied. The Marching-cube triangulation method was necessary to extract accurate surfaces for unstructured volume meshing. Calculated values of permeability for this range of solid fractions show partial agreement with previous experiments. Observed deviations are attributed to the difficulties of experimental permeability measurements.

Jan 1, 2009

By Masayasu Kawahara

"The extraction and separation of nickel, cobalt and copper were investigated with a solvent impregnated resin which was produced from UX84-I and XAD-4. The extraction behavior of metals with the solvent impregnated resin is similar to that with solvent extraction. The extraction ability of solvent impregnated resin improves when using finer particle resin and with a higher concentration of extraction solvent.IntroductionSolvent extraction is well known-as a method for separation of metallic elements in solution. However there are problems with intermediate phase and solvent loss. Ion exchange resin is also used in hydrometallurgy, but it is not fit for separating a large quantity of metals. Amberlite XAD-4 resin is known as a absorption agent of organic matter in water. It is expected that the resin which has the ability of extracting metals can be made by absorbing organic extractant on XAD-4 resin In this study, solvent impregnated resin (SIR) was produced from LIX84-I and XAD-4, and extraction and separation of nickel, cobalt and copper were conducted using SIR. The extraction properties of SIR were investigated, and a comparison between ordinary solvent extraction and SIR was made.Experimental ProcedureAmberlite XAD-4 was used as absorption resin for the organic extractant in this study. The physical properties of XAD-4 are shown in Table I. Amber lite XAD-4 has a large surface area and shows good ability to absorb organic matter in water, but the: resin does not have the ability of exchanging metallic ion."

Jan 1, 2000

By Felipe Daroch, Maria C. Ruiz, Rafael Padilla

Copper concentrates with high arsenic contents must be pretreated before conventional smelting to prevent environmental pollution with arsenic compounds. In this work, experimental results concerning the selective removal of arsenic and antimony from copper concentrates are presented. The process consists of an alkaline digestion using concentrated NaHS-NaOH solutions to transform the arsenic and antimony sulfides into soluble compounds. A water leaching follows the digestion to dissolve the arsenic and antimony, leaving clean copper sulfide solid residues. The laboratory scale tests were carried out using a copper–arsenic concentrate with 15.05% As and 1.42% Sb. The results showed that the most important digestion variables were temperature and concentrations of NaHS and NaOH. Over 97% of arsenic and 92% of antimony could be removed in 10 min of digestion using 8.9 M NaOH and 100% excess of NaHS at 80 °C. The subsequent water leaching was performed at 80°C for 20 min.

Jan 1, 2015

By R. C. Hubli

A chemical model has been developed to investigate the dissolution of sulphide minerals in brine solutions containing copper and iron chlorides. The model has been employed to study the dissolution .of synthetic NiS using different initial concentrations of Cu(II), Cu(I), Fe(III) and temperature. The speciation of copper with particular reference to the formation of hydroxy-chlorides as a function of total chloride and H+ has been computed. The model predictions are in agreement with experimental results. It has been found that addition of Fe(III) results in the maintenance of a high Cu(II)/Cu(I) ratio leading to enhanced rates of dissolution and suppresses the loss of Cu(II) due to the formation of hydroxyl-complexes.

Jan 1, 1997

By Xiang-dong XING, Zhen-yang wang, Jian-Liang Zhang

Distribution behavior of titanium between CaO-SiO2-MgO-Al2O3-TiO2 and hot metal was studied between 1350 °C to 1600 °C. Experimental results indicate that the reaction temperature influenced the activity coefficients of titanium and resulted in the variation of equilibrium constant. Finally, the Gibbs free energy formula of titanium carbothermic reduction was fit out using the thermodynamic model of Wagner and congregated electron phase models.

Jan 1, 2015

By Bernd-Arno Behrens, Klaus-Georg Kosch

"In times of increasing energy costs automotive lightweight construction is gaining in importance. This paper deals with the production of hybrid steel-aluminum compounds by forging. The compound forging process is a promising method to successfully manufacture functional parts by applying resource-saving process steps. Nevertheless, challenges resulting from different material properties must be solved.The heating of hybrid material work pieces made of steel and aluminum is a great challenge. Steel is forged at a temperature of at least TSt =900 °C, while aluminum should not exceed a temperature of TA1= 500 °C. For achieving the required temperature gradient extensive experimental investigations have been carried out. Intermetallic phases form during the manufacturing process and can influence the bonding and the global part quality. In addition, methods for the characterization of the joining zone between the materials steel and aluminum are analyzed and the factors influencing the formation of intermetallic phases are determined experimentally.IntroductionIn times of increasing energy costs and stricter conditions relating to environmental protection, automotive lightweight construction is gaining in importance. The production of hybrid compounds by forging is a promising method to manufacture functional parts by applying resource-saving process steps. In compound forging a hybrid raw part consisting of a solid core, which is enclosed by a hollow casing, is joint in the forming process. This results in a graded material structure in the part in which the mechanical properties can be specifically adapted to the requirements. Compound forging is the form joining and/or firmly bonded joining of at least two different materials while plastic shape forming occurs (Figure 1)."

Jan 1, 2012

By Lei Wang, Jianjun Wang, Lingen Luo, Zhengbang Li

Dearsenication in molten steel was studied by adding Ca-Fe Alloy-based arsenic removal agent. In order to improve the utilization rate of Calcium Iron Alloy and improve arsenic removal ratio, [O] is less than 0.0005% and [S] is less than 0.0035%, Al is added into the molten steel. In the processes of adding CaO-Al2O3 based alkalinity slag for arsenic removing in molten steel (initial arsenic content is 0.0080%), arsenic removal ratio reaches 50% when Ca-Fe Alloy addition amount is 18%. During the arsenic removal experiment, adding Rare Earth promotes the arsenic removal reaction and makes the arsenic removal more effectively.

Jan 1, 2015

By J. F. White

An experimental study was undertaken to evaluate the feasibility of a selective chloridizing roasting pre?treatment process for the elimination of impurities from zinc feed?stocks prior to recovering zinc by conventional unit operations. In this investigation, a number of chemistries that might serve as a basis for such a pre? treatment process were examined. A variety of chloridizing agents were admixed with EAF dust to promote the selective removal of lead and cadmium by the formation of volatile metal chlorides, he results of the experimentation firmly establish that selective chloridizing roasting is a technically feasible means of eliminating lead and cadmium from EAF dust. Excellent extraction efficiencies were accomplished with a number of chloride additives; as high as 98 percent lead extraction and 88 percent cadmium extraction were attained with minimal zinc losses, Continuous pilot?scale tests reinforced the trends established by laboratory?scale experimentation, Attempts of chlorine elimination using pyrohydrolysis were less successful. The extent of chlorine elimination was found to be highly dependent upon EAF dust sample type and treatment temperature.

Jan 1, 1996

By Jiangwei Shen, Cong Wang, Haibin Zuo

The research on the formation of Silico-Ferrite of Calcium and Aluminium (SFCA) in the process of cooling and solidification is rarely reported. The crystallization process was observed by using scanning electron microscopy (SEM) and optical microscope in this paper. The effect of different cooling system on the microstructure and phase composition of the sinters was investigated to obtain the appropriate cooling rate to improve the metallurgical properties of sinters. The experimental results show that the crystallization of calcium ferrite is getting better when the cooling rate is decreased from water quenching to cooling in the air. There are a large number of hematite phases with interconnected crystal structure in the sample cooled in the air. In the case of the compressive strength, it was determined by the mineral composition and pore structure, higher SFCA and hematite contents in sinter cooling in the air lead to a higher strength. Glass phase in the water quenching sinter was the major reason for the lowest strength. High porosity contributes to a decrease in compressive strength for the sinter cooling in the furnace. Therefore the air cooling was the appropriate cooling rate to achieve high quality sinter under this experimental condition.

Jan 1, 2016