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By D. L. Jones

The leaching of natural chalcopyrite was studied in both ferric sulfate and ferric chloride solutions. The chemistry of the two reactions is quite different, with substantial sulfur oxidation occurring only in sulfate solutions. Ferric chloride is a more effective reagent, for the leaching rate is greatly increased with finer particles and higher (Fe+++), and unaffected by high (Fe++); none of these advantages are found with ferric sulfate. In addition, the morphology of leaching appears to be different, with ferric sulfate leaching preferentially along fissures or grain boundaries. The kinetics were found to be linear over an extended period, rather than parabolic as reported elsewhere. An explanation of the observed phenanena is proposed using the electrochemical theory of leaching, and experimental measurement of the mixed potential of the mineral during leaching.

Jan 1, 1976

By S. I. Sobol

Completeness of cobalt recovery from slag requires decomposition of maggemite and non - ferrous metal desorption with polymerized silicon-acid. Cobalt losses are reduced in leaching tai1s up to 200 g/t of iron.

Jan 1, 1993

By C. Alexandru Sonoc

Donnan Dialysis uses ion exchange membranes to extract and separate cations. The driving force is provided by differences in chemical potential, rather than by electric fields or pressure. A Donnan Dialysis based process to recover lithium, nickel, cobalt, manganese, and organic acid lixiviant from recycled lithium ion battery cathodes is under development. In this paper we present a model of Donnan Dialysis and results of simulations of the aforementioned process. The simulations show that 170 m2 of membranes can process 1000 L of leachate ([Li+] = 0.285 M, [Co2+] = [Ni2+] = [Mn2+] = 0.095 M, pH 2) in two days and recover 94.1% of the lithium (as lithium carbonate), 99.4% of the transition metals (as mixed sulphates ready for solvent extraction), and all of the organic acid using 423 mol of H2SO4 and 268 mol of KHCO3.

By B. L. Chulu

In the carbothermic reduction of lead sulfate to produce lead, the inclusion of soda ash (Na,CO,) in the charge provides for the control of sulfur dioxide in the effluent gas. An important mechanism in the process appears to be the carbothermic reduction of the sodium carbonate whereby sodium gas and carbon monoxide are produced. These intermediates then participate in the reduction of the lead sulfate to produce lead metal and stable sulfur species in the molten slag phase. In addition, there is some evidence that the presence of lead metal in the charge may also serve to increase the lead recovery in the process. These aspects were investigated by conducting laboratory-scale smelting tests with small charges (;3g), at 1173°K(9000C). Recovery did not exceed 74w% and the role of incipient lead metal in the charge could not be clearly assessed.

Jan 1, 1993

By Doon Gibbs

In this talk, we review highlights of x-ray magnetic scattering studies performed during the last decade, concentrating at the beginning on experiments on the rare earth metal holmium.(1-4) Besides intrinsic interest in the x-ray scattering cross-section and its description, studies of this type are motivated by the possibility that new structural and magnetic properties of rare earth metals might be revealed, and that new techniques may thereby be developed. As a result, interest in x-ray magnetic scattering experiments. has grown rapidly during the last 10 years particularly, with the regular application of synchrotron radiation techniques- Magnetic scattering experiments have by now been performed at most of the x-ray synchrotrons around the world. In addition, insertion .device beamlines dedicated to x-ray magnetic scattering experiments are planned at each of the next-generation storage rings presently under construction in the United States (APS), Europe (ESRF), and Japan (SPRING-8). Generally, the results of x-ray magnetic scattering experiments may be analyzed within two regimes of the incident x-ray energy, namely, in the limit of high x-ray energies, when the incident x-ray energy lies above the excitation energy of any absorption edge, and at resonance, when the incident energy lies near an absorption edge. In the high energy limit, the amplitude for x-ray magnetic scattering has the simple form [L(Q)?A + S(Q)?B](5-7) Here, L(Q) and S(Q) refer to the Fourier 'transforms of the atomic orbital and spin magnetization densities, respectively, and the vectors A and B depend on the incident and scattered wavevectors and on the: incident and scattered polarization vectors. 7) Because the vectors A and B are not identical, the polarization dependence of the orbital contribution to the magnetic cross-section differs from that of the spin contribution. This leads to the possibility that the orbital and spin magnetization densities maybe distinguished, in x-ray scattering experiments. The same distinction is not directly possible by neutron diffraction techniques (in dipole approximation, where the polarization dependence of the orbital contribution is identical to that of the spin contribution), and is important to a fundamental understanding of the electronic structure of magnetic materials. A particular

Jan 1, 1992

By R. H. Lien

The Bureau of Mines, U. S. Department of the Interior, is investigating chemical and biological decontamination of complex wastewaters such as tailings pond water containing 280 ppm CN and 5 ppm Se as well as significant concentrations of arsenic, copper, iron, silver, and zinc. The most effective chemical procedure involves cyanide oxidation using hydrogen peroxide or sodium hypochlorite followed by selenium reduction using ferrous hydroxide. The effluent contains <l ppm CN and 20 ppb Se; concentrations of other major contaminants meet EPA drinking water standards. Preliminary research indicates that biological cyanide oxidation is possible even in highly alkaline solutions (pH 10.5) containing high cyanide concentrations; indigenous bacteria destroyed 85 pet of the cyanide. Exploratory research shows that other bacteria removed up to 79 pet of the selenium from chemically oxidized, low-cyanide water. These promising results may lead to a final processing scheme that involves a combination of chemical and biological techniques.

Jan 1, 1990

By Akram Salah Eddine Belaidi, Lakhdar Azzouz, Benchaa Benabed

"The dunes sand is a material of a large availability in Algeria. This material is practically unexploited. The introduction of this material as a new element in the construction can be more relieve the domain of building, and contribute to the development of the southern regions of Algeria, which are very rich in this material. The main objective of our work is to exploit a largely available material in the Algerian south which is the dunes sand, as a material of construction in the region of Laghouat.In this study, first we investigated the effect of the curing environment and the nature of the sand on the mechanical properties of the mortar, such as; flexural and compressive strengths. Then after, we studied the durability of the mortar under cycles of wettingdrying and the chemical attack of sodium sulfate (Na2SO4 5%).According to the results, we note that the mortar of the sand mixes (river sand plus dunes sand) present the best mechanical performances under different environment of curing. In addition result of durability studies put forward that the mortar of the sand mixes is more resistant to the sulfates attack."

Jan 1, 2008

By R. Padilla, M. C. Ruiz, R. Villa

"Bismuth is an impurity in copper minerals where it occurs mainly as the mineral bismuthinite (Bi2S3). In smelting of copper minerals, most of the bismuth reports to the white metal, as a result, a substantial amount of bismuth accompanies the copper to the electrorefined cathodes. Thus understanding the behavior of Bi2S3 at high temperatures is crucial to eliminate bismuth before electrorefining. In this paper, some experimental data on the decomposition/volatilization of bismuthinite in nitrogen- oxygen atmospheres is discussed. The results indicated that in nitrogen atmosphere, bismuth volatilization occurs through a fast decomposition of bismuthinite to metallic bismuth and sulfur with subsequent volatilization of bismuth in the range 850-1100 °C. Similarly, in the presence of oxygen, bismuthinite decomposes to bismuth too, followed by oxidation to the non-volatile bismuth trioxide at temperatures higher than 750 °C. Both, temperature and partial pressure of oxygen affect significantly the bismuth volatilization and the oxidation rates.IntroductionCopper sulfide minerals are the major source for the production of metallic copper by pyrometallurgical processes, which are the dominant processes in the production of copper by selectively oxidizing the sulfide sulfur to SO2 and the accompanying iron in the concentrates to iron oxide, which can be conveniently removed as a stable slag.Generally, copper concentrates contain some deleterious minor elements such as arsenic, antimony, bismuth and lead, which are present as sulfides. These elements depending on their concentration may originate problems in the copper smelting processes and they can ultimately lead to a final copper product with unacceptable high levels of impurities.During the treatment of these copper concentrates by smelting, the impurities generally distribute themselves in the condensed and gas phases and they are eliminated mainly through the gas phase [1-3]. Thus, smelter off gases contains substantial amounts of volatilized impurity elements. For example, in the case of bismuth, the estimated distribution of bismuth in flash furnace smelting [2] was 15 % in the matte, 5 % in the slag and 80 % in the gas phase, and recently, for Outokumpu flash smelting Davenport [3] reported the distribution of bismuth as 30-75% in matte, 5-30% in slag and 15 -65 % in the off gas."

Jan 1, 2011

By Tae-Hyun Kim, Kang-In Rhee, Jeong-Soo Sohn

The synthesis of Mn-Zn ferrite powder from spent zinc-carbon batteries was investigated using a series of physical treatment, sulfuric acid leaching and coprecipitation. Physical separation methods such as crushing, magnetic separation and sieving were applied to generate a non-magnetic material of 8- mesh undersize for subsequent leaching process. The 8-mesh undersize of the spent zinc-carbon batteries was assayed 23.9% Mn, 14.9% Zn, and 4% Fe. Metal extractions obtained in sulfuric acid leaching at the solid/liquid ratio of 1:10, 2 M H2SO4, and 60? with 6 vol.% H2O2 addition were 97.9% Mn, 98.0% Zn and 55.2% Fe. The leach liquor was finally adjusted to the Mn:Zn:Fe mole ratio of 1:1:4 suitable for producing MnZnFe4O8 ferrite powder by the addition of Mn, Zn and Fe sulfates followed by pH control. A co-precipitation test for Mn-Zn ferrite powder was performed at 80?, O2 gas flowing at 1.3 L/min. As a result of co-precipitation, Mn-Zn ferrite nanoparticles in 20 nm size with spinel structure were successfully synthesized. The saturation magnetizations of Mn-Zn ferrite powder (Mn1-xZnxFe2O4) were determined to be 39-91 emu/g with various zinc contents (X=0.2-0.8).

Jan 1, 2008

By S. Tandon

Equilibria studies of selenium distribution for sodium-borate slags were initiated at 1473k under reducing condition as a function of slag composition and alloy composition. The Se distribution coefficient (% Se in slag/% Se in metal) increased from 0.4 to 2.9 with increase in basicity (0.53 to 0.86) for Cu-0.446% Se alloy. However, the results are not very useful from industrial application viewpoint. Therefore, in order to improve the distribution of Se, CaO (10% to 50%) was added to the sodium-borate slag of basicity 0.864. On addition of 502 CaO, the distribution coefficient increased roughly by 100% for slag composition - 44.5% Borax, 22.2% Na2C03, 33.3% CaO and Cu-0.44677 Se alloy. Further, the value of this distribution coefficient has been found to increase by an additional 80% on addition of 20% CaF2 to the above slag for all Cu-Se alloy compositions. Also with increase in initial concentration of Se, the distribution coefficient has been noted to increase.

Jan 1, 1992

By Alan James Parker

Chalcopyrite can be converted to pure copper by the following five steps. An exothermic sulfation roast of chalcopyrite; leaching of cupric sulfate from the calcine with dilute acid; precipitation of Chevreul&apos;s salt and or other copper sulfites with ammonium sulfite or precipitation of crude copper by autoclaving ammonium sulfite and cupric sulfate at 150°C; dissolution of Chevreul&apos;s salt, or the crude copper, as cuprous sulfate, using acidic cupric sulfate in an acetonitrile-water solution as oxidant; precipitation of pure copper by thermal disproportionation of the cuprous sulfate solution. Acetonitrile and acidic cupric sulfate solution recycle. Advantages over conventional processes include lower cost, lower energy consumption as waste heat, sulfur removal as ammonium sulfate or gypsum, rather than as sulfur dioxide and rapid throughput. The net reaction is: 2 CuFeS2 + 4H20 + 15/2 02 + 8 NH3?2Cu + 4 (NR4)2 SO4 + Fe2O3

Jan 1, 1976

By Pandey H. D.

The paper describes a fluidised bed ion exchange method for simultaneous removal of phenols and cyanide from the effluent. Use of an eluant enables regeneration of the resin in the continuous operation mode. The breakthrough experiments conducted both on the laboratory scale and on a pilot plant scale have shown that while the level of phenol can be brought down from 462 ppm to about 6 ppm, the free cyanide is almost totally removed. An examination of data indicates that the method can serve the twin objectives of pollution control and phenolic compounds recovery.

Jan 1, 1992

By James C. Sever

Two green field magnesium reduction plants are under consideration using dolomite as the raw material. The Calix calciner was independently selected for both plants. The unique design of this calciner is detailed and the advantages defined for the specific application. The low carbon foot print of this unit combined with the ability to capture food grade carbon dioxide makes this an environmentally proactive approach to carboniferous ore calcination.

Jan 1, 2015

By Yuanbo Zhang, Zhixiong You, Daoxian Duan, Guanghui Li, Tao Jiang, Xiaohui Fan

"Presently, high-grade manganese oxide ores are usually utilized by a coal-based reduction roasting process. However, there were some obvious drawbacks, including serious environmental pollution, high energy consumption, etc. The reduction temperature is relatively high (850-900 °C). In this study, a kind of biomass, pine black charcoal, was used as a reductant to reduce low-grade manganese oxide ores. Under the optimal conditions of reduction temperature of 600~650 °C, roasting time of 30~45 min and ratio of ore to reductant 5:1, the leaching efficiency of manganese reached more than 98%. Compared with the traditional coal-based reduction process, the reduction temperature is reduced by 250-300 °C.IntroductionManganese plays a very important strategic role in the national economy, and it is widely used not only in the metallurgical industry, but also in the light industry, chemical industry, medicine, agriculture, etc [1]. The average grade of manganese ores in China is evenly about 21%, which belongs to typical low-grade manganese ores [2]. Therefore, large quantity of high-grade manganese ores is required to import in order to meet the rapid development of Chinese manganese industry. As reported, the conventional treatment of reduction roasting has been widely applied for processing manganese oxide ores, in which coals or reducing gases (CO, H2 or CHi) were usually used as reducers [3]. However, there were some insuperable problems, such as high energy consumption, poor operating conditions, serious environmental pollution, etc [ 4-9]."

Jan 1, 2013

By Tong Zhilin

The reasons why the pits were formed on the cathode in the process of Ni electrowinning and the methods how to prevent these pits from forming are described. Some examples are presented. It has &apos;been proven that P507 and P204 present in the electrolyte can effectively prevent pits from forming on the cathode.

Jan 1, 1993

By Wenbin Liu

A novel route for rapid synthesis of ultrafine WC-Co cemented carbides with homogeneous binder phase distribution is reported. The composite powder is produced by in situ reduction-carbonization reactions by using WO2.9, Co3O4 and carbon black as raw powders. The reaction equilibrium and phase stability are studied by thermodynamic calculations. The WC-Co composite powder is condensed by spark plasma sintering (SPS) to obtain the cemented carbides bulk. The sintering temperature is lower than that in the conventional sintering methods by 1500C, while the sintering time is remarkably reduced by 3-5 times. The high performances of the hardness and the fracture toughness are obtained. The experimental results confirm that the present processing scheme of in situ reduction-carbonization reactions and subsequent SPS sintering is an efficient way to prepare WC-Co cemented carbides, and is apparently superior to the conventional long-period techniques of preparing composite powder and cemented carbides bulk.

Jan 1, 2008

By Xia Hong-ying, Peng Jin-hui, Zheng Zhao-qiang, Zhang Li-bo

"Preparation of activated carbon from the walnut shell by microwave assisted steam activation was studied. Influences of the three parameters, activation temperature, activation duration and steam flow rate on the adsorption capacity and yield of walnut shell activated carbon(WSAC) were investigated,optimization process was obtained by the Response Surface Methodology (RSM). The optimum preparation conditions were as follows: activation temperature of 980°C, activation duration of 41 min and steam flow rate of 1.66 ml/min. The optimum conditions resulted in an activation carbon with an iodine number of 1025 mg/g and a yield of 52.17%, while the BET surface area, total pore volume and average pore diameter of WSAC were 1328m2/g, 0.72ml/g and 2.2nm respectively. The study supported the potentiality of comprehensive utilization ofWalnut shell and the benefits of the microwave heating.IntroductionActivated carbons are one of the most important adsorbent materials in modern society because of its abundantly developed pore structure, strong adsorption ability, high surface area and thermo stability. They have extensive application in many industries fields which include gas purification [1], catalyst supports [2] and other pollutants [3]. However, in recent years, the industrial production of activated carbon is facing the problem of raw material scarcity and high cost, which limit to be widely used. Therefore, the selection of an appropriate precursor plays an important role and it has become hot sport to seek cheap raw material to lower preparation cost. As a kind of reproducible resource, the waste from agriculture and forestry is a high-grade raw material for preparing activated carbon due to is high carbon content, such as palm shell [4], rice hull [5], and coconut shell [6]. At present Walnut shell is widely accepted to be a renewable source of biomass. According to statistics, there is more than 1000,000 tonnes of walnut shells are produced in China annually [7]. As a good precursor for activated carbon production, Walnut shell is a major agricultural waste, to make better use of the cheap and abundant agricultural waste, it is proposed for activated carbon production."

Jan 1, 2014

By F. Rivard, L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. Retrofitting plasma torches in place of fuel oil burners lead to lower operating costs, capital cost and greenhouse gas emissions.INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes [!]. Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid start-up and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate [2]. Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates."

Jan 1, 2013

By Martin Reyes, Juan Hernández, Julio Cesar Juárez, Isauro Rivera, Ma. de los Ángeles Hernández, Francisco Patiño

The dissolution of Ag contained in metallurgical tailings was studied by adding ions Cu2+ and Zn2+ in S2O3 2- medium. Chemical analysis of mine tailings by cupellation revealed a Ag concentration of 71 g/ton. The XRF and XRD analysis confirmed the preponderance of SiO2 in the mineral matrix. The experimental dissolution process was conducted in alkaline solution using six concentrations of NaOH and five of S2O3 2-, at different temperatures, also using five concentrations of Cu2+ and Zn2+ as a catalyst. The results showed similar values for both systems (96.8% and 97.13%). The ion Cu2+ and Zn2+ increases the dissolution of Ag, and decrease the reaction time of dissolution. Under the conditions used, pH and stirring rate did not affect the dissolution of Ag.

Jan 1, 2015

By K. C. Liddell, B. Dou

"In producing multilayer films for magnetic data storage applications, the interfacial roughness must be controlled in order to obtain high quality materials with reproducible properties. The present understanding of the effect of roughness on multilayer properties such as magnetoresistance is sketchy, particularly for electrodeposited films. In this study, quantitative atomic force microscopy was used to characterize surface morphology before and after Ni films of varying thickness were deposited on Cu cathodes. A multinuclear multilayer growth mechanism is supported by both the deposition conditions and the AFM images, and a multinuclear multilayer model gave a satisfactory fit to measurements of the density of peaks on ultrathin Ni films between 0 and 8 nm thick.Alloys consisting of alternating ferro-and paramagnetic layers have begun to replace Permalloy in the sensing elements of magnetic hard drives. The operating principle of the new read heads is giant magnetoresistance (GMR), and they are smaller and more sensitive than previous inductive heads (1). Experimental studies on sputtered multilayers have emphasized the role of layer thickness and interlayer roughness in determining the presence and size of the GMR effect (e.g., 2,3,4,5,6). However, roughness in electrodeposited multilayers has rarely been measured, even though read heads are likely to continue to be made by this process for some time to come. Cu/Ni can be considered a model system for understanding processing-microstructure-property relationships in electrodeposited multilayers and is the most widely investigated of all such systems (e.g., 7,8,9,10,11,12). Nevertheless, the roughness of the interfaces in Cu/Ni electrodeposits has not been systematically characterized by quantitative techniques, and in all studies reported so far, the total deposit thicknesses were considerably greater than the 10 nm needed for most sensor applications (1). The thinnest such films were about 50 nm (7)."

Jan 1, 1998