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By E K. Chiw, S-M Jung, S M. Masuka, ika

The world reserves of high-grade iron ore have depleted necessitating the need to utilise any existing natural iron ore deposits to meet the demands of the world’s expanding economy using hydrogen in the reduction process to curb CO2 emission. These low-grade ores include iron ores with high phosphorus content. The thermodynamic conditions in the blast furnace allow for the reduction of phosphorus that readily dissolves into the molten iron. Phosphorus in the gaseous state readily dissolves into the molten iron and therefore must be removed due to its negative influence on the mechanical properties of steel. The removal of phosphorus from molten iron is difficult causing the phosphorus to concentrate in metallic iron. The aim of this study is to provide basic knowledge on the phosphorus distribution after reduction using the CO-H2 and possibly provide the optimum conditions for phosphorus partitioning into slag, increasing the probability of its removal by magnetic separation. Total porosity, pore size distribution and surface area of the pellets used were measured using a mercury pressure porosimeter. The reduction was carried out using thermogravimetric analyses (TGA). The reduction rate increased with increasing H2 and was highest when 100 per cent H2 was used. Metal elements distribution in the reduced pellet was clarified using electron probe microanalysis (EPMA) and showed that phosphorus was distributed in the same areas as Ca. More phosphorus was concentrated in slag when 50 per cent CO–50 per cent H2 was used, increasing the probability of dephosphorization using magnetic separation. The concentration of phosphorus into slag was related to the rate of reduction. Further investigations into the reduction kinetics of this ore by CO-H2 is suggested to validate these findings. Nevertheless, a comprehensive thermodynamic analysis of the reduction of phosphorus containing phases found in iron ore with carbon, CO and H2 was provided to assist in selecting the optimal reduction experimental conditions.

Sep 18, 2023

By Armstrong AB

It has been identified that particulate matter in the form of suspended solids and bed load has the ability to adsorb heavy metals. Each year Ranger Uranium Mines Pty Ltd (RUM) identifies potential danger areas which could become major sediment sources during the wet season. Methods of suppressing sediment uptake such as hydromulching and coating areas with Poly Vinyl Acetate (PVA) glue are used. Other methods of reducing the sediment load after uptake such as diversion bunds, filters across drains, stone filters, minor sumps and settling ponds are also used. The 1983/84 wet season saw drain sediment loads reduced to acceptable levels before the water reached the outside environment. Studies to qualify and quantify flows from minor drains are still underway.

Jan 1, 1984

By Taylor R. N

Flow simulations have been performed on the flash-smelting burners currently used at KNS. This paper presents studies of the heat transfer between gas and particles at the burner exit. Gas and particle temperatures, velocity and concentration profiles of the two-phase flow are calculated by the mathematical model. The predicted gas temperatures have been favourably compared against values measured by thermocouples placed near the burners in the flash furnace. The predicted particle temperatures are also reasonable when compared with the measured temperatures.

Jan 1, 1992

By Tagawa H

In Japan, geological condition do not only vary in a wide range of strata but are also extremely complex with the existence of faults and aquifers. With respect to rocks, in particular, it is very rare that homogeneous rocks are distributed uniformly. In general, geological conditions are distributed in a wide variety, ranging from earth, sand, soft and medium rocks to hard rocks. Under these geological conditions, when planning of the tunnel construction is to be made out, either blasting method or tunnel boring machines must be selected taking into consideration the geological structures along with the designed tunnel route,' possibility of encountering aquifers, hardness of rocks anticipated and also, the adjacent environ- mental conditions. In the process of select- ing an excavation method,, it is important to make a comparative investigation between the above two methods considering the advantages and disadvantages with regard to the respective operating efficiency, economical efficiency and the conditions and scope of application as well. Furthermore, in addition to these considerations, the recent environmental restriction, which does not allow the blasting in the surroundings of residential areas, must also be taken into account. Because of this, in some cases there is no alternative but to use a static excavation method or a tunneling machine even when these are less efficient than blasting.

Jan 1, 1987

The discovery of bauxite in 1955 at Weipa on the NW coast of Queensland's Cape York Pen- insula enabled Australia to join the Caribbean and West Africa as one of the major world sources of bauxite. Weipa, today, is the largest bauxite mining operation in the world and holds a significant position on the world bauxite scene as the operation 1. supplies 15 per cent of the Western World's metallurgical grade bauxite requirements, Z. produces 50 per cent of the world's demand for abrasive grade calcined bauxite, and 3. is the world's largest bauxite shipp ing port.

Jan 1, 1978

The Gympie Province is a unique tectono-stratigraphic unit which does not fit into the overall palaeogeographic pattern of the New England Fold Belt (NEFB), and part of it has been proposed as an exotic terrane more closely linked to New Zealand. From E to W the Gympie Province comprises 6 distinct units which can be evaluated as suspect or exotic terranes.

Jan 1, 1990

By King RP, Kientzler P

In recent years, ultrasonic comminution technology has been developed at the Utah Comminution Center. An ultrasonic grinding device was assembled and investigated. An ultrasonic transducer system has been significantly improved by using a special type of piezoelectric ceramic and preloading to 4.1 x le kPa to obtain maximum strength. The improved system provides constant and rapid vibratory promotion of fatigue fracture resulting in more effective breakage. The design principles for an ultrasonic mill are developed in this paper. Size reduction was successfully achieved in the ultrasonic nip-roll device for a variety of materials. Ultrasonic comminution has repeatedly demonstrated the capability of producing fine particles from a variety of materials. A comparison between ultrasonic grinding and dry ball milling of limestone showed that the ultrasonic device produced much narrower size distributions than the ball mill. This trend is especially obvious in the coarse size range where few particles remain, and in the fine size range where overgrinding is prevented. This behavior might have some interesting applications in areas other than mineral processing like powder metallurgy or material science where narrow and controlled product sizes are required for the successful elaboration of high-technology ceramics and glasses. Ultrasonic comminution has a significant advantage in the accurate control of the product size.

Jan 1, 1993

By Murakami T, Tamiya M, Mizokawa T, Matsumoto T

In the expansion program of the iron ore pelletizing plant at Kakogawa Works of Kobe Steel Ltd., an automatic computer control of products fineness on grinding department is practised. The main problem of the process control of a grinding system is scattering of measured fineness values of products. The scattering comes from the inherent nature of grinding systems, sampled powders and measuring systems. A method is developed to presume the exact status of the plant from scattering products (fineness values and to achieve a stable con trollability of the plant by utilizing the computer. An on-line fineness analyzer, an automatic sampling device and vari-speed air separators are also developed to compose the automatic grinding plant. This report introduces the fundamental epts and results of the automatic fineness rol system of the grinding plant.

Jan 1, 1977

By Simpson JF, Murrie SJ

In determining new areas for slag disposal a foamed slag aggregate has been developed for use as a skid resistant material. The foaming of the slag does not rely on the use of water, but rather on the slag chemistry. Laboratory test results indicated that a product having good skid resistant properties has been prod- uced. A section of road is being assessed for performance of the aggregate in a surface dressing application under heavy load. The results from the test section after seven months have shown that the foamed slag is suitable for this application. Further test sections are now being considered.

Jan 1, 1979

By Marshall B, Gee R. D

Geological data processing by machine enables'an increased rate of coverage, better supervision and control of field programmes, increased effectiveness of field operators, and vastly improved access to old and new field data. Even a system of restricted felxibility enables a mapping programme to be organ- ized and conducted independent of personnel changes, whilst elimination of much compilation time increases the rate of cover- age such that it relates to mode of transport and geological complexity rather than to personality factors. A machine is useful only if applied to tasks suited to its capabilities, and must be aimed at those types of mapping in which a limited number of attributes adequately define the problem, and the data is of a form suited to coding and is normally collected in sufficient abundance to make compilation wearisome. Machine systems are therefore unsuited to most types of lithological mapping and to most types of exploration in new areas, but have proved useful in many branched of cartographic geophysics (e.g. gravity and magnetics), and in cartographic Geochemistry.

Jan 1, 1969

Both safety and productivity in underground gassy coal mines can be improved substantially if an appropriate gas management system is introduced. A strong direct relationship exists between the gas emission rate, roof and floor strata relaxation zones characteristic, mining activities and gas drainage practices. Detailed knowledge of geological factors, gas and coal-rock properties, as well as mining systems are necessary for the methodology used in predicting overall underground gassiness, and planning gas capture and ventilation systems. Early gas emission calculations for various mining activities, particularly for the longwall mining system are essential. A reasonably accurate prediction of gas make as well as the design of ventilation, gas recovery (drainage holes) techniques can be made using 'Floorgas' and 'Roofgas' computer simulations, provided sufficient geological, mining, and gas data are made available.

Jan 1, 1998

By Ho E

Analyses of several nickel mattes from around the world show a significant variation in their copper content. Typically, matte contains an alloy, heazlewoodite and a copper sulphide phase. The various commercial methods of processing these mattes are reviewed and some of the fundamental factors which determine the choice of leaching system are discussed. Electrochemical studies on pure heazlewoodite and millerite in sulphate and chloride media are compared which show that nickel sulphides react via a series of nickel deficient sulphides and exhibit passivation as nickel is removed. Differences in the electrochemical behaviour of nickel sulphides in chloride media are attributed to greater crystallinity of sulphur and less formation of'NiS2. The electrochemistry of mattes differs because of the presence of alloy and copper. Copper in the matte modifies the potential for alloy dissolution and the rate of anodic dissolution of nickel. At elevated temperatures, Cu(II) in solution exchanges with NiS and completes the leaching of nickel at relatively low potentials without significant oxidation of sulphur to sulphate. It is concluded that there are fundamental advantages to leaching nickel matte in chloride media using Cu(II)/Clz as the oxidant.

Jan 1, 1996

By D Thornton, R Hodson, D Sprott

Blast fragmentation size distribution and thus blast design have been found to have a direct impact on the load and haul cycle through excavator dig time and bucket payload. Previous studies have demonstrated that by reducing the excavator dig time and increasing bucket payload, significant improvements can be made in both productivity and unit cost. Simulation work reported in the literature indicates that a 20 per cent improvement in dig time may result in only a three per cent improvement in load and haul productivity and unit cost. At the same time, a ten per cent improvement in bucket payload will directly translate to a ten per cent improvement in load and haul productivity and unit cost. Based upon these findings, extensive laboratory and field work have been undertaken in the past to correlate blast fragmentation distribution to bucket payload. In contrast, the literature reports limited studies quantifying the impact of blast fragmentation on excavator dig time. Field work was conducted at Placer Dome Asia PacificÆs Granny Smith Mine (Wallaby Pit) in Western Australia, concentrating on quantifying the impact of blast fragmentation on the dig time of a Liebherr 994 hydraulic excavator (shovel attachment with 14 m3 bucket). Fragmentation was assessed for each truck load of material using the Split Desktop system, while the excavator cycle analysis was conducted manually. Measured fragmentation P80 (fragment size at which 80 per cent of material passes) values ranged from 200 mm to 1200 mm. The field study investigated the impact of various fragmentation parameters (P20, P50, P80, cumulative per cent passing 250 mm size fraction, and uniformity index) on the average and total dig times. The results indicate that the fragmentation P80 provides the best correlation to average dig time (total dig time divided by the number of bucket passes to load a truck). The total dig time was found to be dependant upon the fragmentation P80 and the number of bucket passes to fill a truck. Monte Carlo simulation results, based upon these relationships, indicate a 26 per cent improvement in average dig time and a 12 per cent to 46 per cent improvement in total dig time (bucket passes ranging from 4 to 8), with a change in fragmentation P80 from 600 mm to 200 mm.

Jan 1, 2003

By Paine GG

The in-situ retorting of shallow oil shale deposits is an attractive alternative to the material handling problems of conventional open pit mining techniques, which involve removing overburden, fragmenting and transporting the shale to a fixed retort, and finally disposing of the hot spent shale.For in-situ retorting to be successful, the oil shale has to be fractured and the fragmented rock expanded into a void, to allow controlled propagation of a flame front through the in-situ retort. The principles of cratering with explosives have been used to develop a process for the in-situ fracturing of a thin oil shale deposit overlain by a formation of porous rock. The overlying porous rock formation is first compressed by explosive charges to create voids in the porous rock. The oil shale is then fragmented and pushed in to the voids with separate explosive charges. This paper discusses methods of creating voids in porous rocks with minimal surface disturbance, and then methods of obtaining the most uniform fragmentation of the shale. The whole process can be completed, in practice, in one blast. The results of an experimental blast are presented, and possible modifications are then discussed.

Jan 1, 1985

By Zhansen P

This paper describes the test re- sults which give a complete proccess of failure of concrete lining embedded in sand medium under load, including the order of appearance of crack along the lining up to failure. nor each crack appearance corresponding calculation being made to assess the redistribution of moment and thrust force in critical section including crown section, section making 45¦ with the vertical etc. De- flection at the above stated critical sections are also measured at each stage of loading. The pressure along the top hori- zontal surface of embedded lining and the vertical sides are measured by pres -sure gauges embedded in sand medium. fhe test results show a complete figure of rupture characteristics of concrete lining embedded in soft ground which approximates alluvial deposite often occur in metro construction at cities near the river side. These test results have been taken as a reference in assessing the action behavior of concrete lining in certain cities in China.

Jan 1, 1987

From the ventilation aspect, there is a basic difference between advancing and ezreating longwall layouts. Particular rroblems with retreating, using differing mining methods and layouts include high gas emissions, spontaneous combustion and -radients. There is an acceptable method of crntrolling the environment at the return end a retreating longwall face without the use a multiple heading system. Incorporated in the design is the facility to practice xtensive methane drainage, thus ensuring a ntrol of the rate of methane emission into the main roadways. Case studies highlight varying mining editions under which the proposed system of Ctised.

Jan 1, 1982

By Bailey S, Avraamides J

Laboratory-scale experiments were conducted in a mechanically stirred aeration vessel to determine the rusting abilities of aerated water in the presence of various catalysts compared to the industrially used ammonium chloride. The catalysts used were tartaric acid and citric acid, firstly by themselves, and then in later experiments mixed with ammonium chloride. From these experiments it was found that leaching of iron from reduced ilmenite in the presence of either tartaric acid or its sodium salt was much slower than in the presence of ammonium chloride. Citric acid or its sodium salt also give a slower rate of leaching than the ammonium chloride system, but citric acid and its sodium salt mixed in equal proportions produced a rate of leaching approximately twice as fast as the standard ammonium chloride system. When tartaric acid was mixed with ammonium chloride the leaching rate was found to be equivalent to the leaching rate of the same amount of ammonium chloride alone, thus indicating that tartaric acid made no contribution to the leaching in this svstem_

Jan 1, 1996

The effect of accurate detonator delay timing on blast results can now be studied with the development of the ICI Electronic Detonator. This detonator has an accuracy and precision orders of magnitude greater than the current range of pyrotechnic delay detonators. A series of field trials have been conducted to quantify the effect of delay accuracy and timing on blast performance. These trials have demon- strated that delay timing can have a marked influence on blast fragmen- tation, muckpile displacement, blast vibration and airblast.

Jan 1, 1989

By Jorgensen FRA, Moyle FJ, Turner TM

Laminar flow furnace techniques and thermal analysis were used to study the combustion of Kambalda nickel concentrate and Collie coal. The study was made to ascertain the suitability of the latter as a replacement for the fuel oil currently burnt in a flash furnace at the Kal- goorlie Nickel Smelter. The coal was found to ignite at temperatures between 500-600¦C which was the same as that required for the most reac- tive component of the concentrate, namely py- rite. The rates of reaction of both the coal and concentrate were dependent on oxygen con- centration. Sulfur dioxide hindered the combus- tion of concentrate and of coal, the effect on the concentrate being the more pronounced. The effects of moisture content and the tendency for spontaneous combustion of the coal were also noted.

Jan 1, 1982

By Pietrobon M. C, Ralston J, Smart St C R

In an on-going study of the chemistry of base metal sulphide flotation, the effect of the inclusion of cyanide in the reagents suite has been studied, with special reference to ore from Pasminco Mining's Elura mine. Cyanide has been variously described as an iron sulphide depressant, a preventor of sphalerite activation and as an activator of galena. In the case described here, the cyanide appeared to act as an enhancer of the galena flotation performance, raising the lead recoveries by 25 per cent but leaving the sphalerite and pyrite responses unaffected. The lead rougher flotation performance with and without cyanide was investigated over a wide range of redox potentials (0 mV to 400 mV SHE). In all cases, the inclusion of the cyanide brought about an increase in the galena recovery and was responsible for a faster rate of galena flotation during the initial stages of the beneficiation. A surface characterisation study (XPS) of the lead flotation stage, with and without cyanide, indicated that the reagent interacted specifically with the galena and pyrite minerals. It was possible to correlate the surface absorption of the cyanide on the lead and iron sulphides with improvements to the flotation performance using the combination of surface spectroscopy and laboratory flotation Testwork.

Jan 1, 1991