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By S. Kelebek, B. Ingram, C. Gibson, T. MacNeil, M. Aghamirian

"The beneficiation and upgrading of pyrochlore from its ores is carried out through flotation. In industrial practice, upgrading is conducted in a two-stage flotation process in which pyrochlore flotation is carried out after gangue mineral pre-flotation (carbonate, silicate, sulphide or phosphate reverse flotation). In this study, the flotation of pyrochlore from a low grade carbonatite ore was performed at the laboratory scale following a two-stage flotation process in which carbonate minerals were floated in advance of niobium minerals. In parallel, a simplified flotation process was developed in which pyrochlore was floated directly from gangue minerals at increasingly acidic pH. Laboratory results indicated that both two-stage and direct flotation provided similar results in terms of niobium grade-recovery. Based on these results, a large scale, integrated pilot plant was conducted using a direct flotation flowsheet. While the elimination of reverse gangue flotation resulted in flowsheet simplification, the dissolution of carbonate minerals and the subsequent effect of dissolved cations on the floatability of pyrochlore added an element of complexity. A comparison of results from locked-cycle laboratory testing and pilot plant testing highlights the challenges of scaling up a complex flowsheet. A case is made for the direct flotation process and the key parameters to achieving success in large scale direct flotation of pyrochlore are discussed.INTRODUCTIONPyrochlore (Ca,Na)2Nb2O6(OH,F) is a niobium bearing mineral which has been the primary global source of niobium since the first pyrochlore mine commenced operations in the late 1960s (Gibson et al., 2015a). Preceding the discovery and development of high grade pyrochlore deposits in North and South America, the majority of global niobium supply came from gravity concentration operations of columbite (Fe,Mn)Nb2O6, across Africa (Perrault and Manker, 1981)."

Jan 1, 2016

By C. Mills, A. O. Burt

"The paper examines the role of gravity concentration in both an historical context and within the modern mineral processing industry. It discusses the principles of the process on both a theoretical and practical level. The importance of more mineralogy and its effect on the choice of the wide range of equipment available is discussed. The paper concludes with a discussion on the relative merits of gravity concentration with other forms of processing.IntroductionIt is an unfortunate, albeit popular, misconception among otherwise enlightened engineers in the mineral processing industry that gravity concentration was a process developed in the dark ages, perfected in the middle ages, and abandoned in the modern ages.Gravity concentration was developed in the dark ages - long indeed before that. Agricolau: cited examples of gravity concentration, crude examples admittedly, being practiced over 3000 years ago. However, gravity concentration is not dead. Far from it. As recently as 1978 it was reported that the total mineral tonnage treated by this process in the United States was greater than that processed by flotation. Coal represents the bulk of the or e treated by gravity separation in the U.S.A., with iron ore representing a major portion of the balance."

Jan 1, 1985

By Joseph D. Martinez

"The benefits of modern technology can readily be identified with energy availability. A clear correlation has been established between per-capita energy consumption and the GNP for various nations. The United States is an outstanding example of a nation which has benefited from vast energy reserves. The nation is now challenged, how¬ever, by dwindling reserves and the need to develop new sources consistent with the preservation of environmental quality. The development of new, virtually inexhaustible and environmentally acceptable sources cannot be expected for several decades. Meanwhile, we will have to depend on coal, nuclear energy and/or rigorous conservation measures.The net effect of environmental considerations has been to delay and perhaps ultimately eliminate the nuclear energy option as a national energy alternative. This forces a more positive move toward coal as the next major source of electrical power. Our coal resources are large, but the use and production of coal is also a threat to the environment. Thus, we seem to be moving from one major accessible source to another due to environmental concern only to face the probability that the alternative is also environ¬mentally unacceptable.Controversies revolving about energy choices must be resolved by an analysis of the relative benefits and impacts of these two sources and others. The pattern of changing energy sources is not new. We have moved from wood to coal to oil and gas in the past and must learn to adapt in the future. Rational decisions must be made relative to the utilization of intermediate energy sources pending development of promising future approaches. A collapse of current levels of energy supply could threaten our technological society and the means to develop a new energy base."

Jan 1, 1976

By E. G. Joe

The continuing increase in costs for power and fuel are affecting significantly the cost of milling Canadian ores. In order to ascertain the scope and source of energy consumption in Canadian mills for further energy conservation opportunities, CANMET, in cooperation with the Canadian Mineral Processors, carried out a detailed survey on the metallic mineral processing plants. Sixty-seven mills representing almost 300 million tons of annual capacity participated in the survey. The results indicated that, in general, copper and iron ore mills, representing the bulk of the tonnage, consumed relatively low levels of energy per ton. Nickel-copper, zinc-copper and lead-zinc .ore mills were moderate in energy consumption, and uranium and some copper-lead-zinc mills reported much higher energy consumptions due primarily to the increased heat requirements of the ore pulp. Although plant heating costs varied somewhat with location, it was apparent that the lowest heating costs were achieved by those plants built with proper insulation and energy conservation design. If the cost per million British thermal units is taken as $2.00, the mill energy costs generally ranged from 40ft to $1.20 per ton.

Jan 1, 1979

By Nathan Ferdinands

Outline Overview of Site and Partners ?MeanduMine ?Thiess?GroundProbe Technology ?Work Area Monitor (WAM) ?Software control ?Alarms MeanduMine King2East pit failures ?Background, and Northern Failure ?Southern Failure Recovery and conclusion

Nov 1, 2011

By E. Topuz, C. Duan

"INTRODUCTIONOperations research (OR) applications have experienced a substantial growth within the mining industry during the last three decades. The purpose of this paper is to present a summary of the results of a comprehensive survey of the application of various OR techniques to the major mining activities. It is hoped. through this sur vey , that the most widely used OR approaches, the important areas of application, and future trends have been identified.This survey included more than 500 articles published in this field in English since the late 1950s. Most of the relevant literature was found in mining publications, but, in terms of quality and originality, important applications were also found in literature not related to the mining industry. The sources constituted periodicals, proceedings research reports, and a few books. A listing of selected publications from which three or more articles reviewed in this survey appear is given at the end. Operations Research MethodologiesOperations research is concerned with optimal decision making in, and modeling of, deterministic and probabilistic systems that originate in real-life situation s. One basic feature of the OR methodologies is the attempt to optimize certain design parameters, subject to a set of constraints. This distinction has been employed in the survey as a guideline for selection of the techniques covered under the title "" OR methodologies"". The methodologies thus encountered in the literature are listed below. In a few cases, simulation has not been considered because it is not an optimization method per se."

Jan 1, 1989

By Norman J. Tienkaivip, Christopher J. Preston

"This paper describes the use of electronics for physical measurement and computer analysis in both open-pit and underground mining operations for the ultimate purpose of optimizing production blasts. Techniques in monitoring single borehole blasts using both pressure and vibration sensors to establish in-situ dynamic rock properties are outlined, including characterization of multiple borehole production blasts with regard to stress generation.Once field derived measurements are computer analyzed, they are channelled as input parallel to other data, such as the explosives thermochemical performance properties generated by a sophisticated computer program called ""HT-65"" into BLASPA . BLASPA, a blast simulation computer program, then couples these input with a mathematical model which defines the blasting processes. Aspects such as the blast geometry, explosive loads and distribution, hook-up, and costs are studied. The final output table gives specific blast performance or quality factors for each blast procedure. These results are then easily compared and rapidly optimized to achieve maximum performance at lowest blasting and drilling cost."

Jan 1, 1984

By A. Noël, R. Lapierre, M. Provencher

"Modem aluminum smelters are facing significant operating cost pressure. Key methods used by smelters to manage this pressure are automation and production-information systems to optimize processes, manage quality, anticipate problems and reduce operating costs. In 2002, Aluminerie Alouette Inc. began its Phase II Expansion project, and retained the joint venture of SNC-Lavalin and Hatch (SLH) as its engineering, procurement and construction management (EPCM) team. Alouette had the distinction of being one of the most efficient aluminum smelters in the world. Alouette already understood the importance of systems integration in project delivery. For Phase II, key objectives were identified to ensure ""a state of the art"" integrated architecture that would support Alouette's production goals to integrate the existing facilities with the expansion, to form a single efficient facility and meet project schedule and budget targets. Achieving those objectives within the context of a large project often creates major challenges due to the nature of the traditional EPCM delivery model, which relies on several vendors and third-party-systems integrators. In this case, an integrated Alouette-SLH team was made responsible for all aspects of the systems integration, taking over the task from most suppliers. The integrated team was responsible for delivering an automation system and plant-wide-production IT system for the new facilities while accommodating migration for the existing systems. Through the use of rigorous methodology and advanced state of the art technology, the IT and automation strategy led to significant value creation and is recognized today as one of the key factors of the project's success. The primary results were: fast and efficient start-up of facilities, due to quality programming and implementation; a plant able to operate as a single entity; automation and IT systems delivered before time and under budget; standard programming methods implemented throughout the plant; and reduced and simplified maintenance."

Jan 1, 2006

By X. -G. Chen, A. M. Nabawy

A novel manufacturing technique for Al-TiB2 nanocomposites has been developed, in which TiB2 nanoparticles were incorporated into liquid aluminum under mechanical stirring and in the presence of a K2ZrF6 flux-wetting agent. The microstructure of the Al-TiB2 nanocomposites was studied using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The microhardness test was conducted to investigate the strengthening effect of TiB2 on the aluminum matrix. The TiB2 nanoparticles were successfully incorporated and dispersed into the aluminum melt in the presence of the K2ZrF6 flux during mechanical stirring. In the as-cast microstructure, most nanoparticles segregated in the interdendritic regions as a result of particle redistribution during solidification. The addition of 2, 5 and 10 wt% TiB2 nanoparticles increased the composite hardness by 60, 90 and 150% respectively when compared to commercial purity aluminum, indicating that the TiB2 nanoparticles imposed a significant strengthening effect on the aluminum matrix. The role of K2ZrF6 flux agent on the incorporation of nanoparticles into aluminum melt was discussed.

Jan 1, 2014

In this study, we develop a detailed model of the likely future carbon footprint of primary copper supply. We develop a peak copper production model, based on a detailed copper resource data set, and combine this with a comprehensive life cycle assessment model of copper mining and milling to predict greenhouse gas emission rates and intensities of Australian and global copper production up to 2100. By establishing a quantitative prediction of both copper production and corresponding greenhouse gas emissions of Australian and global copper industry, we then analysed the emissions intensity of various energy input scenarios, such as business-as-usual, solar thermal electricity and solar thermal electricity with biodiesel. The Australian Government has an aspirational goal for long-term greenhouse gas emissions of an 80% reduction from the 2000 level by 2050. For the copper sector, this means moving from about 12.6 Mt CO2e in 2000 to a goal of some 2.52 Mt CO2e in 2050 (assuming equal emissions reductions across the economy). Based on the energy sources modelled, only the solar thermal plus biodiesel scenario was capable of achieving this goal at about 0.15 Mt CO2e, since the solar thermal alone scenario still includes normal petro-diesel as a major source of emissions. Overall, it is clear that there are abundant resources which can meet expected long-term copper demands, the critical issue is more the carbon (and environmental) footprint of different copper supplies and use rather than how much is available for mining. It is clear that the switch to renewable energy can have a profound impact on the carbon intensity of copper supply, even allowing for increased energy intensity as ore grades decline, and a complete conversion to renewable energy will position the copper sector to meet existing annual greenhouse gas emissions targets and goals.

Aug 1, 2013

By P. A. Studemeister

"A trondhjemite stock intrudes a volcanic sequence that has massive sulphide lenses and that is metamorphosed to the greenschist facies at Gutcher Lake, 25 km north of Wawa, Ontario. The stock is 4 km2 in plan and is partly enveloped by an aureole of chlorite-epidote-amphibolehornfels up to 1 km wide. Within this contact aureole, biotite is partly pseudomorphosed by chlorite;epidote and hornblende are mottled by chlorite, calcite, plus quartz; albite has 0% An to 8% An; and hornblende porphyroblasts have actinolite rims. The stock has chlorite pseudomorphous after biotite; and feldspar is mottled by white mica plus calcite and has a clear rim of albite. Fractures filled with quartz, calcite, ankerite, chlorite, white mica, pyrite, and native gold cross-cut the stock and its hornfels aureole. These gold-bearing veins are enveloped by foliated rocks with quartz, calcite, white mica, and chlorite that grade outward from the veins into trondhjemite or hornfels.The stock, emplaced into a submarine volcanic series, emanated heat that caused seawater to convect and formed a contact aureole of hornblende hornfels. The stock eventually intruded its aureole and this culminated with regional metamorphism to the greenschist facies. Regional metamorphism hydrated the stock and its hornfels aureole. Native gold precipitated with quartz along fractures from metamorphic flu ids in response to cooling and wallrock hydration. exploration for this type of gold deposits should focus around felsic intrusions that have albite and that have contact aureoles retrograded by regional metamorphism."

Jan 1, 1985

By N. Katsikaros, A. Lewis-Gray, P. Richards

"To optimize gold recovery in complex leach-to-electrowinning processes, Gekko Systems developed the Gekko resin exchange column (G-REX) as an intermediate step, using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin. Operational experience has been gained at the Castlemaine Goldfields Ballarat gold mine. In near-continuous operation since 2008, the Ballarat plant treats unclarified concentrate leach solution. The extension of this technology to higher throughputs and more complex chemistry is discussed.RÉSUMÉ Afin d’optimiser la récupération de l’or dans des procédés complexes impliquant la lixiviation suivie de l’extraction électrolytique, Gekko Systems a développé la colonne Gekko de résines échangeuses d’ions (G-REX) comme étape intermédiaire, à l’aide d’une résine hautement sélective pour la récupération de l’or qui permet d’isoler les métaux contaminants. Gekko détient la licence exclusive pour la résine AuRIX®100 produite par Purolite, et la colonne G-REX a été spécifiquement conçue pour cette résine. C’est à la mine d’or Ballarat de Castlemaine Goldfields que l’expérience opérationnelle a été acquise. L’usine de Ballarat, en exploitation quasi-continue depuis 2008, traite une solution concentrée non clarifiée de lixiviation. L’extension de cette technologie à des capacités supérieures et à une chimie plus complexe est examinée.AURIX®100 RESINAuRIX100 resin is a crosslinked polystyrene alkaline resin developed by Henkel (Virnig, Mackenzie, & Adamson, 1996). The resin beads are off-white in colour and spherical, with a nominal size of 100% +600 µm. This resin is highly selective for gold and silver over many metals, by way of extracting precious metal–cyanide complexes from leach solutions with a pH of less than 11.5. The higher end of the pH scale produces the best selectivity according to the order of preference: Au > Ag > Hg > Zn > Ni > Cu > Co > Fe. Purolite produces the resin and Gekko Systems maintains licensing of AuRIX100 resin for use in its G-REX column, as part of its unique suite of gravity gold–handling equipment.Significant cost savings over carbon-in-solution (CIS) systems are realized with AURIX100 resin: approximately 4–12% in capital savings and 27–40% in operating costs (Virnig, Mackenzie, Katsikaros, & Gray, 2004). Additionally, AuRIX100 resin is not susceptible to fouling; that is, the resin does not load with inorganic salts or organic compounds that would affect the loading and extraction of precious metals. To counter any potential for fouling by inorganic salts, a dilute acid wash is periodically conducted in service on the resin to unblock resin pores."

Jan 1, 2017

By G. K. Lee, Whaley. H., F. D. Friedrich, I. C. G. Ogle

"IntroductionCurrent coal combustion activities at the Canadian Combustion Research Laboratory (CCRL) reflect the increasingly important contribution that coal is expected to make in meeting our future energy requirements and in reducing our dependence on foreign oil. Widespread use of coal will, however, be heavily dependent on the ability of conventional and emerging combustion systems to cope with the disruptive conflicts caused by variations in fuel quality, on requirements for better equipment availability .and on the implementation of progressively more stringent environmental constraints.To minimize these conflicts, Energy, Mines and Resources Canada has embarked on a systematic sequence of research, development and demonstration- scale (R, D and D) initiatives to stimulate the utilization and competitiveness of thermal coal in both domestic and export markets through a number of complementary in-house projects and external contracts, considered to have short- to intermediate-term benefits to industry and society.Many of the in-house projects are funded in part by industry, whereas the external contracts are either fully funded (100070 government funding) or jointly funded (50% government - 50% project proposer).External contracts and shared-cost projects are an important adjunct to the CCRL in-house effort on coal combustion, because research data can be more effectively transferred to industry and because the commercialization of novel combustion systems can be accelerated significantly."

Jan 1, 1980

By A. Dave Mackintosh

The Current demand for potash has pushed world prices to record levels and allowed Saskatchewan producers to operate at maximum capacity. Several years of strong demand has resulted in a permitting rush not seen since the 1960?s. Even though Saskatchewan has a huge potash resource, mining and processing constraints will limit the areas of economic development. Introduction In 1969 M. E. Holter prepared a report ?The Middle Devonian Prairie Evaporite of Saskatchewan?, published by the then Dept. of Mineral Resources. Holter?s report has remained the bible of geologists working in potash ever since. It is astounding that a report written before there was really much potash mining history in the province, is as valid today as when it was first published. This paper re-iterates much of Holter?s report and adds a little mining experience to essentially confirm the importance of his work.

May 1, 2008

"This paper describes an alternative method of vehicle control which uses a micro-processor to control the field current and armature voltage concurrently. The field tests carried out and the conclusions drawn from the basis of the paper.IntroductionIt is generally accepted that the main obstacle to a greater use of electric vehicles is the relatively poor range and performance when compared to alternatives such as diesel and petrol-engine vehicles. Much effort has been applied to the problem of increasing the energy storage density of batteries and considerable improvements are now being reported.Improvements in the efficient use of the stored energy, although unlikely to achieve the necessary increase in range and performance for a widespread acceptance of electric vehicles, can nevertheless make a useful contribution. Because the improvement in efficiency is achieved by a reduction in losses, it follows that the temperature rise in drive-train components is reduced. These advantages, coupled with the increasing cost of energy, make improvements in the efficient use of the stored energy desirable, if not absolutely necessary. To achieve this with the large and rapidly varying loads encountered during the operational use of a vehicle will require a more flexible system of control than that provided by the current limit. This paper describes an alternative method of control which uses a micro-processor to control the field current and armature voltage concurrently.The value of these parameters is selected to supply the power demand at the motor shaft, with the minimum losses in electrical transmission, thus increasing the efficiency with which the stored energy is used."

Jan 1, 1982

By Greg M. Hollyer

The search for minerals in the future will be dominated by deeper exploration and the need to accurately target ?blind? deposits as more and more of the ?easy? near surface targets are exhausted. In this context, key technologies are emerging for deep exploration both in grassroots and minesite exploration, including the Titan 24 Deep Penetrating geophysical technology. Introduced in 2001, this technology has grown rapidly into an accepted approach for exploration in a variety of geologic environments, including brownfield environments where discovering additional reserves would most quickly benefit companies. Titan 24 belongs to a new class of sophisticated Distributed Acquisition Systems (DAS) which record high-volume, high-quality data simultaneously at multiple receiver stations. This data is then processed digitally, modeled using specialized inverse modeling software, and interpreted according to geologic and other parameters. The result is a robust, high-quality, high-volume data sets which provide a basis for improved imaging to depth. In this paper, the Titan 24 distributed technology is discussed. Illustrations of the vast improvement to overall exploration are showcased through results in several case studies. These include examples from two gold deposits, a porphyry deposit and a minesite. These examples show the range of applicability of the technology and the ability to effectively image mineralization, lithology, structure and alteration to depth as an aid to understanding prospective mineral deposits and targeting drills more accurately.

May 1, 2008

By G. Gabra

"A process of leaching niobium oxide from pyrochlore concentrate using hydrofluoric acid is described. Variables such as acid concentration, temperature, reaction time, solid/acid ratio, agitation speed and particle size are correlated to the recovery of niobium oxide.The relatively low activation energy (1,86 Kcal/mole) and the dependence of reaction rate on agitation suggest that the process is diffusion controlled. The optimum conditions for extracting niobium oxide from the leach solution, using either methyl isobutyl ketone or tributyl phosphate have been determined.IntroductionMost of the commercial production of niobium and tantalum has been derived from the treatment of columbite - tantalite minerals.In recent years (1960) , pyrochlore mineral has been found to be an alternate source of niobium . This mineral varies widely in composition and contains in addition to the main elements of calcium , sodium and niobium, some tantalum, fluorine, rare earth elements, titanium, alkali an d alkaline earth elements.It is well known that the province of Quebec possesses several pyrochlore niobium deposits totalling approximately 151 million ton s at an average 0.45% niobium oxide(1). One of the deposits, the St-Honor carbonatite, was brought into production by Niobec Inc. in 1976. Flotation o f this material produces a concentrate of about 60% Nb205(2).In view of an expanding niobium market in recent years and the presence of large niobium deposits in the province, a research and development program was initiated at the Centre de Recherches Miner ales to evaluate known processes for the separation of niobium and tantalum from each other as well as their purification . Some work has also been undertaken at the CRM to develop an improved extraction process. T his work will be the subject of further communication s."

Jan 1, 1985

By Eric D. Jamieson

"How well is the Canadian coal industry able to expand in the tough competition with other fuels in Canada and with other suppliers in the international, metallurgical and thermal coal trade? Coal production as a whole decreased between 1950and 1960 and, although there has been a tripling of production since then, underground production continued to decrease until 1975. This trend has been reversed to a certain extent as a result of the modernization of mines in Cape Breton, but in 1978 over 85% of coal production came from surface mining.Against this background, the paper reviews current Canadian mining operations as described in papers presented at the 1979 CIM Annual General Meeting. Conclusions are then drawn regarding some of the longer-term mining applications in relation to the latest coal demand forecast, which indicates a potential Canadian production requirement of 160 million tonnes per year by 2000. IntroductionThe Canadian 'coal industry is experiencing a period of expansion and a new record for production is set with each passing year. This growth pattern over the last IS years has been based on two main markets-the generation of electricity in Canada and the export of coking coal to Japan. Supply to those markets has entailed either the development of mining, coal preparation and transportation systems for the delivery of large volumes of products with predetermined specifications or the establishment of minesite plants designed specifically to suit the characteristics of the coal in the adjacent deposits (Fig. I).Coal is a low-value commodity in relation to its bulk, and the economics of coal use become progressively less attractive with increasing distance from the producing mine. The transportation component in the export trade and in the movement of western coal to Ontario is a major cost factor. In the latter case, it approaches the cost of coal produced at the mine. In addition, the .international competition among coking coal producers chasing diminishing markets in a worldwide steel recession as well as the competition from U.S. coals and other fuel s for Canadian thermal coal have introduced a tight set of parameters to govern mining practices in all parts of the country. Some appreciation of the required changes in mining techniques brought about by declining traditional markets and the rigorous demands of the new bulk markets can be gained by comparing production from surface and underground mines over the past 25 years (Fig . 2)."

Jan 1, 1980

By M. Celikin, M. Isac, R. I. L. Guthrie, S. Ge

Horizontal Single Belt Casting (HSBC) is a near-net-shape casting process in which molten metal is directly cast into thin strips, at high cooling rates (order of several 100°C/s), with the potential for high volume, friction-free, continuous production of metal strips. This casting process was used in the present work to produce strips of Al-Mg alloys in the AA5000 series, with additions of Sc and Zr. Such aluminum alloys show exceptional potential as a structural material for transportation/aerospace applications. To demonstrate the suitability of the HSBC process to manufacture competitive strip products of Al-Mg-Sc-Zr, the mechanical properties and microstructures of the strips produced using the HSBC process were compared with conventionally cast products. The effects of annealing on the mechanical properties of the strip-cast Al-Mg-Sc-Zr alloys were also investigated.

Jan 1, 2014

By D. Warkentin, M. Tomlinson, A. Nacu

"This study focuses on comparing the “blinding” effectiveness of various organic additives as part of a general review of using organic additives to mitigate preg-robbing and improve gold recovery during cyanide leaching of carbonaceous gold ores. The laboratory results compared the impact of various organic additives on the prevention of gold adsorption using both activated carbon and ore samples containing carbonaceous matter, generally referred to as total carbonaceous matter (TCM). Although several organic reagents were found to have a significant blinding effect on activated carbon, these results did not translate into increased gold leaching efficiencies with actual ore samples.INTRODUCTION Preg-robbing refractory ores, which contain carbonaceous matter, have been problematic in cyanide plants for many years. In industry, preg-robbing by carbonaceous matter may be mitigated using various techniques including flotation, to remove the carbonaceous matter; addition of blinding agents, to passivate the carbon surface and prevent adsorption of gold cyanide complex; roasting, to partially or fully destroy the carbonaceous matter; chemical oxidation (Abotsi & Osseo-Asare, 1986); pressure oxidation; or microbial deactivation (Dunne, Staunton, & Afewu, 2013). Carbon-in-Leach and Resin-in-Leach are also used as process alternatives in which activated carbon or resins are used to compete with the carbonaceous matter for gold cyanide adsorption. For highly preg-robbing ores, thiosulphate leaching may be considered as an alternative to conventional cyanide chemistry (Baláz, et al., 2000). Natural carbonaceous matter is composed mainly of hydrocarbons, organic acids, and graphitic/amorphous elemental carbon. Natural elemental carbon that behaves as activated carbon is considered to be the main reason for preg-robbing, although the true nature of this phenomenon is not fully understood (Tan, Feng, Lukey, & van Deventer, 2005). In general, the hydrocarbon fraction is assumed to have negligible interaction with gold, while organic acids, such as humic acids, may form complexes with gold, inhibiting its extraction in cyanide solutions. Organic reagents have been used for blinding carbonaceous matter in gold ores prior to cyanidation. Abotsi & Osseo-Asare (1987) tested various organic compounds, with two possible effects in mind. First, the organic compounds were expected to adsorb onto the surface of the solids as anionic/cationic species; the resulting electrostatic interactions between the Au(CN)2- anion and the negatively/positively charged surface would inhibit/enhance the gold uptake. Second, the organic reagents were expected to coat the surface of the carbonaceous component in the ore, limiting the available adsorption sites and reducing gold losses. Optimal reagent dosage depends on ore mineralogy, maturity and surface area of the carbo"

Jan 1, 2019