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By Gyeonghye Moon, Inhyeok Choi, Jyothi Rajesh Kumar, Jin-Young Lee

"This paper deals with the recovery of the tungsten and vanadium from spent SCR catalyst leach liquors by different hydrometallurgical methods. The first part consists of pressure leaching of spent SCR catalyst using caustic soda followed by metal recovery by liquid-liquid extraction. In a leaching process, the following experimental parameters were tested and optimized: NaOH, particle size of feedstock, temperature, and solid to liquid ratio. The optimum condition for leaching of tungsten and vanadium was under the following conditions: NaOH 3 mol/L, temperature 250°C, particle size <300 µm, and solid to liquid ratio 0.4. From these optimum conditions in this experiment, the dissolution efficiency of vanadium and tungsten was 91.5and 87%, respectively. Liquid-liquid extraction following commercial extractants were tested: TBP, Cyanex 272, D2EHPA, Aliquat 336, Primeme JM-T, Alamine 308, Alamine 304-1, and methyl-tri-octyl-ammonium chloride. The conditions for both valuable metal recoveries were optimized.INTRODUCTIONSelective Catalytic Reduction (SCR) catalyst has become the most effective to reduce nitrogen oxide (NOx) emissions from stationary segments such as power plants and waste incinerations around the world due to the reinforcing regulatory trend and emerging environmental issues (Forzatti, 2001; Spivey, 2002; Li et al., 2011).Currently, the most widely used SCR catalyst is V2O5-WO3/TiO2 system due to its great catalytic properties (Li et al., 2011; Marshneva et al., 1995; Marbergeret al., 2015). In general, the composition of the SCR catalyst used in the stationary application is 0.5 to 1 wt% of V2O5and 7 to 10 wt% of WO3(Marberger et al., 2015; Chen &Yang, 1992, Vuurman et al., 1991; Alemany et al., 1991). Currently spent SCR catalysts are treated as waste and disposed of in landfills. This causes a lot of waste of secondary resources of vanadium and tungsten. In terms of industrial value of vanadium and tungsten (Gupta &Mukherjee, 1990; Moskalyk &Alfantazi, 2003) and reduction of pollutant emissions, it should not be disregarded for their recovery for their material recycling from spent SCR catalyst. However, investigations for recovery of metal values from spent SCR catalyst has been rarely carried out."

Jan 1, 2017

By E. C. Goodhue, R. D. Coleman, I. E. Puddington, A. F. Sirianni

Iron ore samples containing apatite are fractionated to acceptable products by spherical agglomeration methods. The phosphorus is upgraded by a factor of 10 at an elevated pH. High-grade iron products are obtained in good yields from the tailings in a second step of the operation. The grade of the phosphorus separated appears to reach a maximum at about pH = 10; recovery of iron decreases below about pH = 4. Both the recovery and grade of iron are found to be reduced sharply above about pH = 8.

Jan 1, 1968

By X Dai

This paper investigated the loss of cyanide via oxidation in CIP or CIL processes by relating the cyanide oxidation to its major oxidation product, cyanate. The results showed that the oxidation of both free cyanide and copper cyanide complexes are substantially enhanced by the presence of carbon. The rate of cyanide oxidation was found to occur in the order: Cu(CN)32- > CN- > Cu(CN)2-. The cyanide oxidation rate in the presence of copper and carbon increased significantly with increasing dissolved oxygen concentration, typical of CIL vs. CIP conditions. Cyanide oxidation rate of iron, zinc or nickel cyanide complexes was minimal.

Jan 1, 2011

By J. Paturaud, A. G. Villemiane, J. Y. Buffiere, D. Fabregue, M. Perrier

In this work, a detailed characterization of the cyclic damage mechanisms on duty in car heat exchangers has been carried out in order to improve their reliability. The material which consists in very thin (<0.3 mm thick) sheets formed of 3 co-rolled aluminum alloys (4045 /3916/ 4045) has been brazed in order to obtain metallurgical and surface conditions representative of those of the real components. Fatigue tests at constant stress amplitude have been performed at room temperature and 120°C in order i) to characterize the cyclic resistance of the studied materials and ii) to study the effect of temperature on the fatigue damage mechanism. The mechanisms leading to failure have been identified from post mortem fractographic analysis. The Wohler curves obtained show that, contrary to common structural Al alloys, this type of thin sheet brazed multi material can be cycled for several hundred thousand cycles at very high stress level (> ~ 80 % of the tensile strength). This behaviour is analysed with respect to the microstructure resulting from the brazing process and the low number of grains present in the sample thickness (around 5 grains).

Jan 1, 2015

By Steve Custer, Chris Bennett, Patrick Garretson, Glenn Dobby, Jacques McMullen

"Barrick Gold is in the process of expanding one of its grinding circuits at the Goldstrike property as a response to both increasing ore hardness and increased ore sensitivity to finer grinding as it relates to gold recovery. The plant currently operates with two parallel grinding lines, each with a SAG mill, a pebble crusher, and a ball milling arrangement. As part of determining what additional equipment was to be required, a CEET evaluation program was conducted (CEET is an acronym for Comminution Economic Evaluation Tool). The work included: Development of a hardness ‘model’ for the ore body, as described by SAG Power Index and Bond Work Index;Site benchmarking surveys to fine tune the SAG and ball mill calibrations within CEET;Conducting CEET studies to examine the process options;Comparing CEET results to standard grinding circuit design techniques.The recommendation of the study, presently being implemented, is the installation of an additional ball mill on one of the two grinding lines. This paper reviews the sizing techniques applied, providing a CEET case study for circuit performance analysis and circuit design. OVERVIEW OF COMMINUTION AT GOLDSTRIKEOre feeding the autoclaves at Goldstrike are first processed through two parallel grinding lines. Both lines use SAG mills with cone crushing of pebbles followed by ball milling. A summary of the key circuit parameters is provided in Table 1. Line 1 primarily processes underground Meikle ore, although when no Meikle ore is available, it processes open pit Betze ore. Line 2 processes Betze ore exclusively. The Mill Line 1 P80 objective for Meikle ore is 74 microns. According to the recovery optimization analysis, a P80 of 90 microns was recommended for Betze ore. The potential however exists to perform co-mingling of both ore types and feed the higher grade Betze ore to Line 1, in which case the P80 of 74 microns would be retained."

Jan 1, 2001

By L. C. So, S. Faucher, S. Mostaghel, D. Sauter, S. -Y. Oh, S. K. Lee

"Molten material from pyrometallurgical furnaces is tapped at high temperature, carrying a large amount of heat. Traditional handling methods of slow air cooling or water granulation do not allow for the recovery of heat from slag and matte. Furthermore, water granulation adds an inherent safety risk of explosions. Recently, there have been numerous studies into processes attempting to recover waste heat. However, most of them have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple dry atomization system that allows for heat recovery while eliminating the use of water. Comparisons of pilot and commercialized dry atomization and heat recovery technologies will be presented and challenges of these technologies will be highlighted.INTRODUCTION Slag has traditionally been regarded as an undesired waste product from smelting operations with slag management focused on removal and disposal of “waste”. Over 500 million tonnes of slag are produced per year, carrying with it ~220 TWh of energy (Barati, Esfahani, & Utigard, 2011). Depending on the process, the energy content of slag ranges from 10-90% of the total energy input (Barati, 2011, Rodd, 2010). There has therefore been great interest in recovering energy from slag. Slag handling methods can broadly be classified into three categories: (1) dumping and slow cooling, (2) wet granulation and (3) dry granulation. As discussed below, only dry granulation routes are amenable to heat recovery. Slag dumping involves the slow cooling of molten material and crushing of the resulting solid. In this process, slag is dumped on the ground directly from furnaces or transferred to slag pots that are moved by rail or haulers and then dumped on the ground. The molten material is left to cool and solidify until it can be broken and handled by heavy machinery."

Jan 1, 2017

By G. P. Demopoulos

The solubilities of calcium sulfate in HCl-CaC1z-H20 solutions up to 100°C were successfully modelled with the aid of OLI software after bringing proper modification to it. Modelling, more specifically, was carried out with the help of the Environmental Simulation Program, V-6.6.0.4 (www.olisystems.com). New model parameters were obtained by regressing the solubility data. A private databank was established by adding the newly defined model parameters and the calcium sulfate hemihydrate phase that is not included in the original OLI database. The McGill-modified OLI software was successfully applied not only to modelling solubilities but also the transformation of the various CaS04 phases, namely dihydrate, hemihydrate and anhydrite. In this paper, the modelling methodology will be discussed along with a comparison of the capabilities of the newly developed model vs the original OLI model.

Jan 1, 2005

By T. Motegi

Semisolid casting provides grain refinement of the cast structure and prevents macro-segregation. The conventional semisolid slurry is obtained by electromagnetic or mechanical stirring. In our process, the magnesium alloy (AZ31) slurry is made using an inclined cooling plate instead of the conventional methods. The slurry obtained is cast into a twin-roll caster and makes a continuous sheet of 2 or 3 mm thick. The most important factors that influence the sheet casting are the casting temperature and twin-roll speed.

Jan 1, 2007

By L. Narhi, K. Haavanlammi

"Approximately two thirds of annual nickel production is used as a raw material in the making of stainless steel, and about 60% of these nickel products are in the form of metallic nickel such as nickel cathode or briquettes. In the stainless-steel production process nickel is blended with iron and chrome-based raw materials, and metallic nickel is typically only required for final steel fine-tuning. Outotec offers a new FeCrNi technology to enhance the nickel value chain for stainless steel producers. This involves the use of an HPAL-based intermediate nickel product (e.g., mixed hydroxides or NiO) as raw material in the Outotec FeCrNi process, for the production of a FeCrNi Master Alloy. The new process, designated as the FeCrNi process, offers multiple benefits compared to existing technologies such as: higher tolerance for impurities in the HPAL intermediate product, avoiding the need for further nickel refining, and the improved recovery of all metals in the FeCr process. The complete new FeCrNi value chain is based on proven technologies such as HPAL and the Outotec FeCr-process. This new innovative and promising value chain offers improved efficiencies for the HPAL based nickel production process combined with excellent sustainability aspects.INTRODUCTION In today’s global economy there is a constant need to improve the efficiency and sustainability of the metals production. The requirements for modern metal refining are tightening and cost efficient, safe and sustainable operation is the precondition for all investment. Outotec is offering now a novel way to combine FeCr and Nickel production to create a completely new value chain to source nickel to stainless steel. BACKGROUND Nickel The current nickel mine production is in the level of 2,000 tons annually and it is split 44% from sulphide based deposits and 56% from laterite deposits (Figure 1). Most (40%) of the nickel is refined to pure nickel metal whereas other products are FeNi (19%) and Nickel Pig Iron NPI (20%) (Roskill). The remaining part, roughly 21%, is nickel chemicals and intermediates. Most of the new investments in nickel are in the direct shipping of laterite to produce nickel pig iron. HPAL process is considered in few projects but no major HPAL projects have been started since the Ambatovy plant in Madagascar. Ambatovy reached the commercial production in 2014. The main primary nickel used is stainless steel manufacturing. In the year 2016 about 68% (~1,360 kt) of primary nickel production was used in stainless steel."

Jan 1, 2017

By Michael L. Free

The hydrometallurgy curriculum for undergraduate students at the University of Utah has evolved to contain a variety of tools to help students understand and apply hydrometallurgy in a context that has industrial relevance. In order for students to perform as engineers in an industrial hydrometallurgy setting, they need to understand thermodynamic and kinetic fundamentals and be able to apply these fundamentals to extraction, concentration, and recovery applications. Students must also understand related environmental, economic, and assessment issues in hydrometallurgy and be able to work with others. In order to meet these needs, the hydrometallurgy curriculum includes a variety of relevant subject information, on-line resources, laboratory experiences, and team work opportunities to help prepare students for careers involving hydrometallurgy. The development and use of these resources will be discussed in this paper.

Jan 1, 2014

By J. W. McCammon

WHEN times are booming and metal prices are high, most mining men pay little attention to the industrial mineral industry. However, when metal prices drop and mines close down, many mining eyes begin to scan the less glamorous non-metallic field. For some this proves a temporary diversion, but others find this branch of mining, with its generally more stable conditions, to their liking and enter it permanently. The resulting gradual influx of trained mining men into the industrial mineral industry ?has been one of several factors responsible for the rise in production of non-metallic materials in our Province. Another and ?perhaps the most important factor influencing the production of industrial minerals has been the growth in the population of British Columbia. Because most industrial minerals .are low priced and either heavy or bulky commodities they are normally sold on relatively local markets. Thus the extent of the development of the industrial mineral industry of a region is largely governed by the size of the population and the level of industrialization of that region. This point is well shown by com-paring population and industrial mineral production statistics for 1936, 1946, and 1956 (see Figure 1)9. Note that not only has the overall production rate grown with the population increase, but that the per capita production has risen greatly.

Jan 1, 1958

By D. Gaboury

Most hydrothermal gold deposits contain quartz with fluid inclusions that record composition and temperature of the mineralizing event. Quartz has strong chemical and mechanical resistances to weathering and abrasion. Hence, quartz fragments occurring on weathered surfaces or in till cover have the potential to be used for gold exploration as far as we know what is the signification of the volatile content of the fluid inclusions for gold mineralization. In this perspective, fluid inclusions were analyzed in pure quartz by solid-probe mass spectrometry from gold deposits hosted in the Archean Abitibi (Canada) and Paleoproterozoic Birimian (Western Africa) belts. This approach provides the relative abundance of volatiles from families of fluid inclusions decrepitating at specific temperatures (Td). Fluids in gold deposits are aqueous-dominated with CO2 and minor H2S in accordance with their fundamental role as gold-ligands (H2S) and for pH-buffering (CO2) of the gold-bisulfide solubility. However, there is no correlation between CO2 and H2S contents of fluid inclusions with the gold grade of the samples. This suggests that trapped fluids represent a marginal portion of the fluid history recorded by the veins. However, in barren quartz veins away from known mineralization CO2 or H2S are commonly absent. Wide ranges in H2O Td from 250 to 450°C and CO2-H2O Td offsets are common, indicating phase separation. The content of other volatiles seems to be more dependent on the geological setting. Helium content may suggest proximity to a crustal-rooted fault, a critical parameter for gold mineralization. Methane and especially C2H6 appear to be indicative of fluid buffering by organic-rich material such as graphitic-shale. These rocks may provide an important primary gold reservoir from sedimentary metal-rich pyrite. Nitrogen-bearing fluids may be related to a magmatic component but can also be derived from organic-rich sedimentary rocks. For gold exploration, quartz containing CO2- H2S-bearing fluid inclusions and having H2O-CO2-Td offsets within 250 - 450°C has strong vectoring potential.

Jan 1, 2011

By J. E. Dodge

Tasu, currently an open-pit operation, services the primary crusher from two areas by ore-pass raises. The problems encountered and advantages gained are discussed. Mine equipment and operating practices are covered, together with blasting practices, line drilling and the pre-shearing necessary to stahilize the pit walls.

Jan 1, 1968

By P. M. Chapman

Risks to aquatic receiving environments from uranium mining and milling fall into three categories: physical (habitat change), chemical (e.g., uranium, selenium, total dissolved solids [TDS], metals including vanadium), and radiological. Although all categories of risk need to be managed, chemical risks are the most significant and are typically chronic rather than acute. For instance, selenium toxicity is primarily manifested as reproductive impairment due to maternal transfer, resulting in embryotoxicity and teratogenicity in egg-laying vertebrates. Risk is best assessed using a weight of evidence approach focused on ecosystem services. Risk management should be based on both risk assessment and adaptive monitoring.

Aug 1, 2010

By W. S. Szolga, M. Moser, M. D. Soderstrom, L. Cohen

"CYANEX® 272 is a phosphinic acid-based solvent extraction reagent used commercially since the early 80’s to recover and purify cobalt from sulfate solutions. Historically, the design of CYANEX 272 circuits has involved the selection of an optimal pH profile during pilot-scale testing using mixbox pH control. The desired pH profile is required to be carefully controlled in the same manner during commercial operation. To assist operators in the design and optimization of their circuits, Solvay developed CYANEX 272-specific solvent extraction modeling software, which has enabled determination of the ideal pH profile and staging configuration. Solvay’s recent advances in modeling capabilities have allowed the simulation of circuits without direct mixbox pH control. Modeling has indicated that circuits operated without direct pH control can achieve the desired metal separation while simplifying the commercial operation significantly. This paper reviews a number of potential circuit configurations for the use of CYANEX 272 and demonstrates the separations achievable under the right design and operational conditions, some of which have historically been considered too difficult.INTRODUCTION CYANEX® 272 is a phosphinic-acid based reagent designed specifically for the separation of cobalt from nickel by solvent extraction from weakly acidic sulfate solutions (Rickelton, Robertson, & Burley, 1982; Rickelton, Flett, & West, 1984; Rickelton & Nucciarone, 1997). Following commercial introduction in the 1980’s, CYANEX 272 has been used in a number of hydrometallurgical flowsheets for cobalt purification and/or recovery. CYANEX 272 metal extraction occurs by means of a cation exchange mechanism. Extraction of a divalent metal ion M2+ is represented by the following equation where RH represents the CYANEX 272 ligand and MR2 represents the ligand-metal complex."

Jan 1, 2017

By Hung-Ming Chen

This paper presents a Cloud-based system framework for providing a web-based building information model (BIM) service. Cloud computing technologies were used to develop a BIM data center, which can handle the big data of massive BIMs using multiple servers in a distributed manner. In addition, the system allows multiple users to access the BIM data center online to submit and review BIMs concurrently. In this study, the advanced technologies/tools of web development and Cloud computing were applied and incorporated to develop a prototype system, named CloudBIM. On the client side, this study applied WebGL and HTML5 in the web-based interface development to achieve the 3D display of BIMs and the dynamic interaction with viewers through browsers. Users can access the services of CloudBIM by using PCs, laptops and tablets anytime anywhere to view the 3D model via browsers, which support WebGL. On the server side, this study used Apache Hadoop, an open-sourced distributed file system based on Google?s technologies, to establish a BIM data center. The Hadoop Distributed File System (HDFS) can utilize multiple servers to provide mass storage spaces in a distributed manner. Based on the use of Apache HBase, which provides Bigtable-like structured storage for HDFS, this study proposes database schema for storing the information from massive BIMs in two bigtables, named Object table and Property table respectively. In addition, Hadoop MapReduce, a Hadoop component for the parallel processing of large data sets, is utilized for model data acquisition by parsing the IFC files of uploaded models in parallel.

Aug 1, 2013

By R. C. Gilmore

Underground longwall coal mining sections may develop explosive mixtures of methane-air in the mined-out gobs. If the panel are operated as bleederless or sealed gobs, progressive sealing along the gate roads as the longwall face retreats limits the flow of fresh air into the gob and thus deprives potentially explosive atmospheres of oxygen. In a project sponsored by the National Institute for Occupational Safety and Health (NIOSH), researchers at the Colorado School of Mines have used computational fluid dynamics (CFD) modelling to simulate the flow of gases in longwall gobs. Modelling indicates that targeted injection of nitrogen through the seals along the gate roads inbye the face can be used to control the size and location of methane and air clouds within the gob and to minimize or eliminate the explosion hazard resulting from the formation of flammable methane-air mixtures in longwall gobs.

Aug 1, 2013

By Roderick C. McDonald

Great Bear lake, the fourth largest body of water on this continent, comprises an area of approximately 12,000 square miles, and is set astride the Arctic circle, with a large portion of it witnessing both the Arctic winter night, and the Arctic summer day with its midnight sun. The very name itself, Great Bear, suggests an Arctic region. The seasonal contrasts at Great Bear lake are very marked by the cold and darkness of winter, and the warmth and brightness of summer. Signs of winter such as low clouds, snow, sleet, fog, and night frosts, generally appear the latter part of August, while ice forming on bays during the last two weeks in September ends boat travel on the lake about September 30th.Early in June the ice leaves the river mouths, during the last ten days of the month it disappears from small bays, and at some time during the last two weeks of July the main body of the lake becomes navigable. In 1916, the ice disappeared earlier than usual, and the lake was navigable on July 5th. Great Bear river generally breaks up about June 1st, but, on account of ice cliffs and floes, it is not navigable with safety until early in July. Even then, the traveller is confronted with the Charles rapids, but these might be overcome by a wagon or motor road, such as the one from Fitzgerald to Fort Smith: However, in 1931, Mr. A. W. Boland, Fort Norman, N.W.T., carried with scow and motorboat practically all freight between Fort Norman and LaBine point and Hunter bay, at the east end of the lake. During July and August, two types of clothing are required, for, although the days are mainly ones of warm sunshine, the nights are cloudy and cold. In the winter season, fur clothing is used exclusively. Considerable timber, mainly white spruce, suitable for fuel and building purposes, borders the lake and extends eastward to the Coppermine river. North of the lake, no timber is found except in the river valleys, but with oil and coal possibilities near Fort Norman, the fuel situation might be solved.

Jan 1, 1932

By Minerals Refining Company, Gerald Luttrell, Biao Li, Robert Bratton, Roe-Hoan Yoon, Stan Suboleski, Nikhil Gupta

Flotation is regarded as the best available method of upgrading coal and mineral fines in the mining industry. However, its efficiency deteriorates rapidly with decreasing particle size. Furthermore, ultrafine concentrates are difficult to be dewatered economically. Due to these technological problems, some operators are forced to discard at least part of the ultrafine materials to tailings (or refuse) ponds, causing significant losses of valuable resources and creating environmental concerns. To address these technological issues, a new separation process named hydrophobic-hydrophilic separation has been developed on the basis of the recent advances in the science of hydrophobic interactions. The results obtained to date show that the process can recover and dewater ultrafine particles simultaneously with high separation efficiencies. Following a series of extensive laboratory tests, the process has been scaled up to proof-of-concept and pilot-scale continuous tests. The results obtained with desliming cyclone overflows, screenbowl effluents, and by-zero coal flotation feeds can be cleaned to less than 4% ash and moisture with over 97% organic matter (or coal) recoveries. The results obtained with mineral fines also showed encouraging results.

Jan 1, 2016

By Ken J. Brouwer

Stillwater Mining Company commenced construction and development of the East Boulder underground mine in 1998. This new PGM mine is situated adjacent to the East Boulder River approximately 35 miles south of Big Timber, Montana. Project planning and development incorporated detailed collaboration between the regulatory agencies, concerned citizens and mine personnel. A unique ?good neighbour agreement? was established with a local environmental group who have become actively involved in the review of ongoing site development and the implementation of environmental and compliance monitoring. Environmental management systems allow for integrated management of tailings, waste rock and water in order to minimize surface disturbances and to prevent adverse impacts to the East Boulder River. Long-term site development plans contemplate implementation of comingled waste rock and paste tailings. Water management capabilities allow biological treatment of all excess mine water in order to reduce nitrogen loadings prior to land application disposal by means of spray evaporation, snow making and land application. The comprehensive waste and water management plans have also been integrated with staged mine development and interim reclamation requirements.

May 1, 2002