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By Louise Pearce

?Environmental and social impact assessments (ESIAs) are: ??process-driven and scientific processes ??The process entails a number of steps and procedures which result in obtaining a licenceto operate ?and moving more towards a social license to cooperate. ?However, the primary premise of ESIA is to facilitate the consideration of environment and the communities in planning and decision-making which would ultimately make it possible to arrive at decisions that are ?sustainable?. ?Hence, ensuring the development of the mining sector on a sustainable basis is a critical challenge that needs to be addressed by the global community.

May 1, 2011

By W. L. Thayer, K. A. Jonasson, R. D. Coleman, J. D. Hazlett, C. E. Capes

"Loss of coal fines in reject slurries limits the yield of coal cleaning operations. Difficulties in handling fines also limit the extent of physical cleaning in treating coals with finely-disseminated impurities. Selective oil agglomeration allows even extreme fines to be processed and offers some novel approaches for coal cleaning and utilization.The oil agglomeration process for the recovery and beneficiation of fine and ultrafine coal has now been commercialized by the Chemical Engineering Section/Chemistry Division of the National Research Council (NRC). This paper describes these activities to apply oil agglomeration and related fine coal technologies on an industrial scale. Pilot plant and large scale results are described, as well as aspects of agglomerate utilization in both wet and dry form."

Jan 1, 1988

By R. Amelunxen

"The molybdenite associated with copper porphyry ores is generally treated in a flotation circuit consisting of a separation and a cleaning section. In the last few years column flotation cells have replaced the numerous counter-current stages that were previously used in the cleaning section. Despite this, little has been published regarding the number of column cleaning stages required. Therefore a Moly flotation database is assembled with the objective of verifying the existence of a common upgrading profile. This can then be used as a guide in the prediction of the number of stages required to achieve a given concentrate grade.INTRODUCTIONAlthough the first use of Column Flotation was on copper flotation products, the popularity and understanding of their operation was not really achieved until they were widely implemented in Moly circuits in early 1983. The use of columns in Moly plants has since left a legacy of information, both published and unpublished. The data collected since that time has been used primarily used to establish column operating parameters and to determine upgrading potential within the circuit.Byproduct Moly generally occurs with porphyritic copper ores in concentrations less than 0.1% MoS2. As such, piloting a new moly ore to produce, say 5 Kg/Hr MoS2, in a slurry approximately 1 Lt/min (at 10% solids), requires a moly plant feed of about 570 Kg/Hr, which translates to a mill feed rate of 200 to 800 Tonnes per day (depending whether you deal with Chilean or Canadian ores). Piloting Moly for any lower tonnage would reduce the accuracy of the testwork.Thus a need exists to collect operating data in order to establish the existence of process relationships that could be used for feasibility and design purposes.The object of this paper is to expose a preliminary relationship that could be used for the purposes described above and to apply the findings to a preliminary design of a moly cleaning circuit flowsheet."

Jan 1, 1990

By John G. Payne

The Pebble deposit contains three contiguous zones. In the Pebble West zone, granodiorite stocks intrude gently warped volcanosedimentary rocks that had been intruded by diorite sills and two felsic intrusion breccias. In the Central zone, volcanosedimentary rocks are cut by diorite and granodiorite sills; the latter are genetically associated with the granodiorite stocks. In these zones, widespread potassic alteration consists of brown biotite and K-feldspar, with abundant quartz-carbonate-sulphide vein stockworks. Chalcopyrite/pyrite ratios range from 2/1 to 1/20. Diorite hosts the highest-grade mineralization, with much of it being disseminated. Patchy, later phyllic alteration is moderate and commonly depleted in copper. The Pebble East zone occupies a granodiorite stock and intruded host rocks below an eastwardly thickening wedge of barren Tertiary volcanic and sedimentary rocks up to 600 m thick. Brown biotite alteration and copper mineralization are strong, with chalcopyrite/pyrite ratios commonly over 1/1. The zone extends to a depth of at least 1200 m below surface; some drill holes bottomed in strong mineralization. Later, weak to moderate sericitic alteration removed some chalcopyrite and locally remobilized gold. The Pebble deposit has a Measured/Indicated resource of 3 billion tonnes grading 0.28% Cu, 0.32 g/t Au and 0.015% Mo (= 0.5% copper-equivalent) and an Inferred resource of 1.13 billion tonnes grading 0.30 g/t Au, 0.27% Cu and 0.015% Mo (0.55% copper-equivalent). The Pebble East zone has an Inferred resource of 2.13 billion tonnes grading 0.55% Cu, 0.34 g/t Au, and 0.037% Mo (0.97% copper-equivalent). The Pebble East zone is open to the east and to a lesser extent to the north, south, and to depth.

May 1, 2006

By Andréa Lagacé

"The milling of sulphide ores inherently generates “thiosalts”, a series of partially oxidized sulphur oxyanions (S2O3 2-, S3O6 2-, S4O6 2- etc.), which make control of effluent treatment systems difficult because their natural oxidation produces acid with the potential to lower the pH within the treatment system and/or receiving environment.At the Xstrata Copper Kidd Metallurgical Site, thiosalt oxidation in the Tailings Management Area continues after buffer storage Ponds A and C where lime is added to precipitate metals and elevate the pH to within the required range for discharge. If the additional acidity generated during the continued process of thiosalt oxidation is not neutralized there is a risk that the final effluent will be non-compliant with regulated standards.To mitigate this risk, in 2007 a full scale pilot trial was conducted with hydrogen peroxide in order to force the complete oxidation of thiosalts prior to the lime treatment stations. This method of chemical oxidation had been shown to be effective at Xstrata Zinc’s Brunswick Mine. The pilot results indicated that a maximum of 50% of the stoichiometric quantity of hydrogen peroxide is required to reduce the thiosalt concentration in the No. 2 thickener overflow stream (feed to buffer storage Ponds A and C) to less than detection (10 mg/L); however, treatment was only effective in the presence of a 20 mg/L iron (Fe) catalyst. Since the hydrogen peroxide addition point at the No. 2 tailings thickener overflow typically contains <1 mg/L total Fe, a second reagent, ferric sulphate, was used to increase the total Fe concentration to the required level. This paper describes the set-up and results of the pilot trial which were used in the design of the full-scale plant.INTRODUCTIONTailings Management Area OverviewXstrata Copper’s Kidd Metallurgical Site, located in Timmins, Ontario, is an integrated metal refining facility producing copper, zinc, cadmium, indium, liquid sulfur dioxide, and sulfuric acid from third party custom feeds, and mineral concentrates recovered from its 7,800 tonne per day mill."

Jan 1, 2010

By M. F. Almeida

"Due to the randomness of all factors influencing the sintering operation, a two-stepped procedure is proposed to find the best way of using stocked fines at a plant producing Fe-Mn alloys for the steelmaking industry. The approach is based on the following: (1) predict the result of the sintering operation by establishing the best multilinear regression model using some of the characteristics of the loaded material; and (2) find the best solution under a minimizing cost criteria by solving a linear optimization problem using the regression equation plus constraints on the feed and product. IntroductionSome tests carried out using 20% to 30% of sinter in the material loaded into a 60 000 KVA Tysland-Hole electric furnace producing Fe-Mn alloys for the steelmaking industry indicated: (1) a meaningful decrease in the off-gas temperature and, consequently, a better energy use due to the material higher porosity; (2) more uniform heat distribution as a consequence of the electrode reaction zone enlargement; (3) an improved furnace control resulting in a smoother operation; and (4) a decrease in gas production facilitating the off-gas treatment. For some years, this plant used only the coarse fraction of the Mn ores, thus stocking all the received and own-generated fine particles. In view of the mentioned results, a strategy for increasing the use of stocked fines was formulated, including a step where it was necessary to decide which components and respective quantities should be used in the blends to be sintered (Almeida, 1984).It is well known that several factors affect productivity and energy consumption in sinter production, also influencing the product quality. Raw materials characteristics, namely chemical and size composition, affect permeability to gases and may or may not allow a deeper bed. In general, finer ores decrease permeability, increasing electricity consumption by fans, but due to their higher specific surface area, react more completely with other components in the mixture. For coke granulometry, a compromise must be obtained in order not to burn it too quickly nor to widen the flame front, therefore decreasing productivity. Decreasing coke in the blend also acts in sinter bonding, decreasing its consistency and increasing crushing and return fines. Moisture addition also influences components mixing, pre-agglomeration, bed permeability and, consequently, sintering productivity. Therefore, optimum conditions must be established for both a given sintering plant and the components in the feed (Dawson, 1993)."

Jan 1, 1998

By Éric Poulin, Simon Gariépy, Mario Paredes Malca

"While the design of a control strategy depends on the available process knowledge, its implementation depends on the available process information. On-line chemical analyzers are today widely spread in the mineral processing industry. A real-time concentration measurement of chemical components is valuable information that could bring control strategies to whole new levels. However, the use of these measures rarely reaches anything more than process monitoring. The reason is simple: the on-line chemical measurements quality is most of the time insufficient to be directly included in control strategies. The choice is then made to let the critical eye of the engineer or the operator appreciates the measurements before making any decision based on it.Data reconciliation through mass balance is a technique today widely used in the mineral processing industry to increase the accuracy and the reliability of plant data, mainly for accounting and survey analysis purposes. Real-time data reconciliation of on-line measurements appears as a natural coupling of technologies that could bring new process optimization trends. Once overcome the technical difficulties, full valorization of the instrumentation investment could be reached.This paper presents the application of real-time data reconciliation for process control and performance monitoring. It proposes a general approach, discusses challenges and illustrates concepts with industry experiences."

Jan 1, 2006

By D. A. Trotter, G. J. Goddard

"This paper describes a method of deciding on various design parameters for a sublevel caving layout. Layout design curves are obtained from the output of a computer optimization program. The program uses mathematical relationships derived from the theory of gravity flow of material to optimize the large number of interdependent design variables which are involved.IntroductionIn the design of an efficient sublevel caving mining system, a large number of interrelated variables need to be considered. Although many papers discuss individual variables, very little exists in the literature to show how these variables interact to achieve optimum results. This can lead to trial and error in sublevel caving design, which can prove costly, particularly because sublevel caving is a mining method which requires integration with sublevels above and below. With no pillars being left, experimental stopes cannot be isolated for study. Unfortunately, the complexity of layout design and the costs associated with trial and error have caused many planning engineers to choose more tried and tested mining methods.Sublevel caving works best to extract low-value ore surrounded by incompetent rock. All phases of the mining method can be highly mechanized, allowing low operating costs and high production rates. Good safety records are achieved, as workers are always in &apos;good&apos; ground and the method is regular, making it comparable to an industrial process."

Jan 1, 1981

By Michael Young, Peter Allum, Mingwei Gao

"Tough economical conditions and high grade but fine-grained ore processing have forced the mining industry to look for more efficient processes. Isa Mill Technology for ultra-fine and fine grinding is one such process employed at several mining operations in Australia including Mount Isa Mines Limited in Australia. Mount Isa Mines is a business unit of MIM Holdings Limited. MIM is an Australian-based international mining and mineral processing company with around 8000 employees worldwide. Major products include copper, gold, zinc-lead-silver, coal and technology sales.The Isa Mill is a horizontal stirred mill with sizes up to 3 m3 chamber net volume and 1 120 kW installed motor. It was jointly invented by Mount Isa Mines of Australia and Netzsch Feinmahltecknik GmbH of Germany for ultra-fine and fine grinding duties in the minerals industry. Isa Mill operations started in 1994 at the Mount Isa Mines Leadzinc Concentrator and then at MIM’s McArthur River Mine in 1995. These Isa Mills have been used to liberate sphalerite and galena at Mount Isa and silica at McArthur River by grinding to less than 7 micron.This paper discusses the Isa Mill Technology and reports on the metallurgical performance of the Isa Mills at Mount Isa Mines, including work done over the last 9 years to improve mill design, process efficiency and maintenance, which has resulted in the current state-of-the-art Isa Mill Technology.INTRODUCTIONThe current leadzinc deposits at Mount Isa Mines (George Fisher, Hilton and Isa) have an average grade of 10.5% zinc, 7.2% lead and 165g/t silver. Fine grinding, in particular in the zinc retreatment circuit requiring a milled product P80 of 7 micron, is essential to treat the ores from the Mount Isa Mines deposits. Every one micron size reduction in the zinc retreatment circuit below a P80 of 10 micron improves the overall plant zinc recovery by 1%, resulting in an increase in revenue of about 1 million dollars per annum."

Jan 1, 2002

By J. E. Nesset

"I had been requested earlier this year by MetSoc, our sister society of CIM, to contribute a chapter on technical developments in Canadian mineral processing over the past 50 years to their 50th Anniversary volume. Accepting the challenge of assembling such a chapter seemed at first a reasonably straightforward task, until one realises that the list of contributions by Canadians to mineral processing over this period has been more than just significant. It turns out to have been an extraordinarily fertile time for innovation and impact for Canadian-based technology. The list is necessarily a subjective one, however I had no trouble identifying twenty technology developments that are clearly outstanding, and there are undoubtedly others. As much as possible, I approached the individuals themselves who played key roles in each technology and asked that they tell the “story”. Without exception, all who were invited accepted eagerly and delivered more than I had hoped for. The technologies have been grouped into those that are truly Canadian innovations, such as the Knelson gravity concentrator and the McGill gas dispersion sensors in flotation, and technologies where Canadians and Canada played a very significant role in their success and implementation, such as AG/SAG grinding and ion-beam surface analysis. Also included are what may be termed technology transfer initiatives and institutions that have risen to a world class level, such as SGS Lakefield and the Canadian Mineral Processors Society of CIM. The challenge is now for the coming generation to continue this record of innovation and contribution to the industry, and that includes the (mostly) Canadian mining and metallurgical companies who have taken the longer term view and supported many of these initiatives, through their critical early years, with both financing and project sites for these ideas. Let us hope that the current trend of mining company globalization will not dampen their enthusiasm to participate. This plenary presentation will highlight many of these technologies, the individuals behind them, and their significance to the mineral processing industry."

Jan 1, 2012

By M. J. Fairweather, Keith Lee, Naseem Mian

"The initial metallurgical response of the lead flotation circuit at Cominco Alaska's Red Dog Mine was substantially below feasibility expectations. A program of diagnostic mineralogical analysis pointed the way to a number of process improvements, including simplification of the flow sheet and installation of a large flotation column as a lead cleaner. A diagnostic mineralogical analysis of the improved circuit shows that inadvertent activation of both sphalerite and pyrite has been substantially reduced, resulting in significant improvements in metallurgical performance. Directions for further improvements to the circuit performance are suggested by the recent analysis.IntroductionRed Dog is a high-grade, sedimentary exhalative (sedex) deposit with relatively simple mineralogy. The primary non-sulphide gangue minerals are quartz and barite, with minor barium carbonate (witherite). The iron sulphate minerals, siderotil, rosenite and copiapite occur variably throughout the deposit. Mineral texture is variable ranging from liberated sphalerite grains visible to the naked eye to intergrowths, particularly between sphalerite and galena, to less than ten microns. Both pyrite and marcasite are present. To date no enhanced reactivity of marcasite has been observed. For this discussion, ""pyrite"" will be used to refer to both iron sulphide minerals. In common with other sedex deposits, Red Dog contains organic and sulphur impurities."

Jan 1, 1997

By Cz. Mora, A. Pawelczyk, D. Hreniak, P. Nowak, A. Dyonizy, S. Strek, W. Strek, K. Grabas, A. Ostrowski

Globalization and a growing demand for limited raw material resources have forced changes in the approach to the supply chain. This is particularly true in the case of rare earths, which are regarded as one of the most important development indicators of modern technologies. To ensure a secure supply of commodities, the European economies have been prompted to investigate REE recovery from sources which until recently, for technical or economic reasons, were considered not sufficiently attractive. An interesting example is apatite phosphogypsum waste dumps. The REE content in these waste dumps averages around 0.5-1 %. One of the most important phosphogypsum locations in Poland is the Lower Silesia region where a phosphoric acid Chemical Plant "Wizów" operated for several dozen years. In this work, rare earths are leached from the phosphogypsum crystalline structure by a chemical treatment and can then be separated into individual chemical compounds. The technology used in these recovery tests, matches up to a coherent European raw materials policy supporting effective management of resources and promoting waste materials recycling.

Jan 1, 2014

By R. Simonson

Agenda ? Need and Introduction ? Interface Management Programs ? Outcomes of Successful Interface Management ? Key Success Factors ? Lessons Learned ? Concluding Remarks Need for Interface Management ? Complex projects ? Larger in scale ? Physically dispersed and delivered remotely ? Involved with several stakeholders ? Risks thus imposed due to: ? Iterative and dynamic nature ? Large information flow ? Document revisions and information updates ? Related sources of Risk: ? Ineffective communication ? Poor work relationships ? Person to job mismatches ? Failure to clarify expectations

Aug 1, 2013

By David Stephenson, Hugo Granados, Steven Klohn

"HudBay’s Constancia project is a copper molybdenum concentrator located in southern Peru. In 2010 Ausenco was contracted to perform a feasibility study optimization review which resulted in an improved design with significantly increased throughput capacity at a minimal increase in capital cost. Construction began in 2012 with commercial operation commencing in May 2015. This paper outlines the process plant design as well as describing the plant’s major equipment selections, start-up and early operations experiences.IntroductionHudBay Mineral’s Constancia project is located at 4200 meters above sea level (masl) in southern Peru, approximately 630 km south-east of Lima, Peru. The property can be accessed by road from Cusco, Peru, (approximately 110 km to the north), or from Arequipa, Peru (approximately 215 km to the south). Matarani, accessed via Arequipa, is the closest port.Constancia is located within the Yauri-Andahuaylas metallogenic belt. The region contains several large copper-gold-molybdenum porphyry deposits such as Antapaccay (by Glencore) and Los Chancas (by Grupo Mexico), and copper skarn deposits such as Tintaya (by Glencore) and Las Bambas (by MMG). Constancia’s ore reserves contain copper and molybdenum with trace amounts of gold and silver.Ore is mined by an open-pit operation. The process plant recovers copper and molybdenum concentrates, storing tailings in a conventional tailings management facility. Infrastructure at the site includes a grid power supply (via a 70 km overhead transmission line from Tintaya), water supply, workshops and an accommodation camp. Mine life is 22 years.Site construction works began in 2012 with first copper concentrate produced in late 2014. The project was executed for approximately 1.75B$USD.Ausenco’s design approach focussed on developing a capital efficient copper molybdenum concentrator. This paper outlines key features incorporated in the concentrator design, plant layout and equipment selection, as well as start-up experiences and early operational results."

Jan 1, 2016

By R. Patrick

As a unique South African organisation, CSIR: Division of Mining Technology (Miningtek) strives to support the mining industry by improving health, safety and productivity through developing, adapting and transferring technology. Considerable effort is currently directed towards the development of potential non-explosive mining methods with the potential to allow continuous mining in narrow reef conditions. Besides improving productivity, continuous mining results in concentrated mining which has a significant impact on reducing infrastructural costs. Impact Ripping and Water Pulse Rock Breaking have been tried on gold mines, whereas Activation, Mini-Disc? cutting and the Plasma Holemaker are currently being tested on platinum mines. The organisation?s many years of experience in novel rockbreaking, together with its world-wide collaborator network, has placed it in a unique position to assist the mining industry and manufacturers in developing and/or adapting existing technologies for application underground. Currently a range of technologies are being investigated, which have reached different stages of maturity. The main technologies under investigation are; - Impact ripper system - Water pulse rock breaking - Activated undercutting rollers - Mini disc cutters - Electric rock breaking

Oct 1, 2001

Leadership "Organizing a group of people to achieve a common goal" Paradigms ? Rush to produce or cut costs. ? The most important thing after safety is production. ? We?ll take care of ??this?? once in production. ? I know what to do, 30 years of experience in mining. ? I want a 100% reliable operation.

Aug 1, 2013

By Richard Frentress, Dave Donelon, Robert Henderson, Mike Warnert

"The Round Mountain gold mine is an open-pit mining operation located 97 kilometres north of Tonopah in Nye County, Nevada. Gold has been produced from the property since 1906.Gold is currently recovered using a combination of four independent processing operations. These include a 10,000 ton per day mill, a 30,000 ton per day, crushed ore heap leach, a 150,000 ton per day, run-of-mine ore heap leach and a small high-grade gravity concentration circuit. In 2002, Round Mountain Gold Corporation produced 755,494 troy ounces of gold at a total direct operating cost of US$2.14 per ton ($193/oz).This paper presents a summary of the Round Mountain operations and discusses some of the processing innovations that have enabled the mine to profitably recover gold from a large low-grade ore body.INTRODUCTIONRound Mountain Gold Corporation is a 50/50 joint venture between Kinross Gold Corporation and Barrick Gold Corporation. Kinross acquired its ownership interest in the Round Mountain mine upon completion of combination with Echo Bay on January 31, 2003. The joint venture partners continue to support an aggressive exploration program in the vicinity of the mine in order to add reserves and extend the mine life.The Round Mountain mine currently operates a conventional open pit that is approximately 8,200 feet long, 4,900 feet wide and 980 feet deep. Mining is conducted on 34-metre benches by electric shovels and front-end loaders paired with 150, 190 and 240-ton haul trucks. Blasthole samples are collected and assayed and provide the control for ore segregation. Based upon these assays, blasted pit rock is determined to be run-of-mine Dedicated Pad ore, crushed Reusable Pad ore, high-grade ore or waste.Gold is recovered using a combination of four independent processing operations. These include run-of-mine ore heap leaching (Dedicated Pad), crushed ore heap leaching (Reusable Pad), milling and the gravity concentration circuit. Non-mineralised rock is delivered directly to the waste dumps. Low-grade ore is trucked directly to the Dedicated Pad and medium-grade ore is crushed and placed on the Reusable Pad. High-grade ore is handled in one of three ways: 1) leached on the Reusable Pad and offloaded to the mill; 2) sent directly to the gravity plant with tails reporting to the mill; or 3) sent directly to the mill or mill stockpile. The gold particle size distribution of highgrade ore determines the processing method."

Jan 1, 2005

By J. Davis, M. G. Reading

"INTRODUCTIONInternational Minerals and Chemical Corporation (Canada) Limited operates two potash mine/refinery complexes near Esterhazy, Saskatchewan. Annual production of approximately 4.2 million tons is sold in the United States and overseas in five grades according to size and quality.Ore grading 25% K2 0 equivalent is mined from a horizontal bed by continuous boring machines, crushed, and hoisted at 8 inches. The refinery operation consists of the eight basic steps shown in Figure 1. Particle sizes handled are similar to those experienced in other forms of mineral beneficiation: 8 inches to 100 mesh. The ore is crystalline and particles are angular. Fortunately the major mineral constituents, sylvite (KCl) and halite (NaCl), demonstrate relatively low hardness at 2 to 2.5.Therefore, while simple abrasion must be acknowledged, it is not a major problem except, of course, in circuits carrying magnetite.Corrosion, as represented by the classic equations of Figure 2, occurs in all its various forms."

Jan 1, 1983

By Rodrigo Toro, Ivan Yutronic N

"The Copper Concentrator Plant of Compañía Minera Doña Inés de Collahuasi (CMDIC) is composed of three grinding lines, the third one being the largest. Due to the capacity feature of the third line, specially its SAG mill, it is a priority that the advanced process control team of the Company deploys a supervisory control strategy that allows this unit to operate in an optimal way, in order to achieve the maximum productivity at minimum cost. It is in this kind of tasks where advanced control applications play a key role in obtaining the best economic profit of the process.The advanced process control team, formed by people from Informatics, Automation and Operations of CMDIC have assumed the challenge of generating the transition from a manual SAG Mill 1011 operation (40 x 22 feet, the largest copper SAG mill of the world), to a fully automatic SAG Mill using a multivariable control strategy instead of a rule based on expert control system (widely used in industrial mining process control applications).Therefore, CMDIC decided to work together with Honeywell APC Team implementing an advanced automatic control strategy for the SAG Mill 1011, using for this purpose a technology called Model Based Predictive Control (MPC), based on a variety of control methods that uses dynamical models of the process, obtained from input/output data, in order to print the process knowledge into a group of mathematical relationships that links the constraints (controlled variables) with available commands (manipulated variables) and measured disturbances.The main objective of the advanced control strategy is to ensure process government, tending to throughput stability and optimization, by the execution of coordinated control actions, proactively avoiding measured disturbances effects and the SAG mill overloading.The most important benefits of using a multivariable control strategy are: the automated operation of SAG mill 1011 (that was manually operated before the implementation of this application), a safer, more coordinated and more stable process operation, achieving through this an increase of throughput and a decrease of specific energy consumption, controlling the amount of oversize material production, power consumption, mill loading, noise and torque. In addition to the operational results, this challenge has consolidated a control team, with the participation of engineers and operators, diminishing the typical implementation time and achieving a greater use of the application in a short time."

Jan 1, 2010

By Michael B. Cortie

Mesoporous gold sponge has the unique property of being both metallic and highly resistant to oxidation. It has potential application in catalysis, in bio-sensors, in optical coatings, in analytical chemistry and, as we show here, as the basis for a new kind of ultra-capacitor. Due to the cost of gold, the most probable niche for a gold-based ultra-capacitor would be in the high-power/high-energy regime, a region where gold would compete with devices based on RuO2. A high internal resistance limits the power that can be usefully drawn from existing carbon-based ultra-capacitors, and that this problem can potentially be overcome by gold-based devices. A simple proof-of-concept ultra-capacitor based on mesoporous gold is described and its behaviour during charge and discharge cycles examined. In this work a step change in the input or output voltage of the device was used as the controlling parameter. There was also a residual faradaic current resulting from traces of undissolved aluminium left over from the AuAl2 precursor used to make the sponge, and some charge storage due to polarization of the solution. Deconvolution of these three effects was not entirely accomplished, but an ostensible capacitance of about 7 to 14 mF/g Au was demonstrated. Further improvement from these early results seems likely.

Oct 1, 2003