Search Documents

By M. Kawata, T. Amano, T. Miyamoto, K. Shibayama

"The High Pressure Acid Leach (HPAL) plant of Taganito HPAL Nickel Corporation (THPAL), located in Taganito, Philippines, with a nameplate capacity of 30,000 Ni-t/year started commercial operation on October 2013. The plant load was smoothly ramped up and it achieved monthly production equivalent to 33,000 Ni-t/year in 2016. Partial improvement of the plant capacity for the achievement of 36,000 Ni-t/year, as evaluated from the current operation progress of each system is planned for 2017. In this paper, aside from presenting the progress of the plant ramp-up, research and development activities such as the reduction of nickel loss and the improvement of filtration capacity which was achieved by particle size control of ZnS precipitates in the Zinc Removal system are also discussed.INTRODUCTION Taganito HPAL Plant Project History of THPAL Taganito HPAL Nickel Corporation (THPAL) was incorporated in August 2008, as a joint venture of three (3) companies, namely Mitsui Corporation with 15% share, Nickel Asia Corporation (NAC) with 10% share and Sumitomo Metal Mining Corporation (SMM) with a controlling stake of 75%. Aside from its capital share, NAC’s Taganito Mining Corporation (TMC) supplies the ore for the HPAL plant located in Taganito, Claver, Mindanao, Philippines. The objective of THPAL is to produce 30,000 MT of nickel and 2,600 MT of cobalt as mixed (Ni/Co) sulfide by treating nickel laterite ore in the Philippines and exporting to Japan as raw material for SMM’s Niihama Nickel Refinery (NNR) for the next 30 years. In other words, 1.15 wt% of nickel in ore is refined to 99.99 wt% nickel in electrolytic nickel. The mixed (Ni/Co) sulfide is shipped to NNR and SMM provides the technology and management personnel to THPAL plant as well as sulfuric acid which is the main reagent for HPAL process. Figure 1 shows the location of THPAL and current relationship between the stake holders.The Characteristics of THPAL Plant In terms of plant design, a 2-train system is applied for the HPAL circuit considering the reliability of the process, facility and avoidance of whole plant shutdown due to HPAL troubles. The technical data, operation know-how and improvements gained from the successful operation of Coral Bay Nickel Corporation (CBNC) which was established in April 2002 were reflected in THPAL’s plant design. As for the H2S plant, a more economical design was considered which is different from CBNC."

Jan 1, 2017

By D. L. Mckay

"Texasgulf's 25-foot-diameter Kidd Creek No. 2 Shaft is situated next to the company's No .1 Shaft, so that both shafts can share common surface and underground facilities. Shaft construction, covering a span of five years from collaring to commissioning , started by freezing the 50 feet of grey varved clay covering the bedrock. After first completing the concrete headframe, sinking to the 5/00-foot horizon utilized two different shaft construction methods. The top 2800 feet was excavated by slashing a 6-foot-diameter borehole and hoisting the broken material up the 3OO0-foot-deep No.1 Shaft; the remaining 2300 feet was excavated by conventional benching methods. Prior to installing the 5100 tons of galvanized shaft steel on the completion of the sinking operation, the sinker was able to install all thirteen armoured electrical cables in one pass with his modified galloway stage. All loading and lip pockets were installed along with the steel guides and bun tons during the equipping operation.IntroductionOn November 21,1978, Texasgulf completed the No.2 Shaft at Kidd Creek Mine. This shaft is the largest shaft (volumewise) in North America and is unique in many respects . The purpose of this paper is to outline some of the unique features of this shaft as well as to record how this facility was constructed.Soon after sinking No.1 Shaft, Texasgulf started a program of exploratory diamond drilling from the 2800 level in No. 1 Mine. The drilling outlined sufficient ore below that level to justify a second mine. Feasibility studies demonstrated that production could be increased by one-third exclusively from this deep ore . The study called for a 25-foot-diameter shaft to the 5100-foot horizon to service a mine producing 5,000 tons of ore per working day.The site chosen for No.2 Shaft and head frame is 350 feet southwest of No.1 Shaft. This, along with No.1 Shaft, will be away from the influence of ground subsidence when mining at depth. The collar and head frame foundations are located on a flat rock ledge some 70 feet below surface. This flat ledge was found by test holing through the overburden by diamond drilling. It is fortunate that this location best satisfied the surface layout and logistics for both surface and underground ore and waste handling."

Jan 1, 1981

By H. C. Boydell

Those connected with mining, prospecting, or mining geology in northern Ontario are familiar with the fact that it is a comparatively unusual thing to have assayed a sample for which the assay report shows no gold. Values of 20 cents to 80 cents per ton, or even higher, are extremely common. Whilst contamination by fluxes, faulty manipulation, or a desire, on the part of the assayer, to sugar-coat the pill for the client, may account for 20 to 40 cent values at times, it is un1ikely that they would a1ways do so. Exonerating the assayer from being necessarily at fault, what can be the cause of such a widespread distribution of gold (and silver) in minute quantities- of a dissemination .that, in the writer's experience, and so far as he is? aware, is not met with on a simi1ar scale in other parts of the world? Explanations that suggest themselves are, that the dissemination is due: 1. To a very widespread auriferous minera1ization, post-dating (epigenetic) the formation of the rocks in which it occurs. 2. To a general syngenetic distribution of gold in the volcanic rocks of Keewatin age that form so large a part of the sections of northern Ontario that have been prospected.

Jan 1, 1928

By W. Hawker, A. M. Ivana

"Pressure oxidation is used to liberate gold from refractory sulphide ore and concentrates with over fifteen autoclaves in operation. Despite the importance of pressure oxidation, the autoclave chemistry and chemical thermodynamics are not well established. For example, there is no consensus on aqueous iron speciation or stability of jarosite phases. Additionally, there remains questions about basic ferric sulphate formation and stability. In addition to a review of the current state of knowledge, a methodology to study the ferric precipitation reaction and relate the results to chemical thermodynamic predictions is presented which will be used to accurately define the phase boundaries of the iron precipitates in the future (hematite, jarosite and basic ferric sulphate).INTRODUCTION With declining availability of orebodies that respond to simple leaching conditions, pressure oxidation has become a prevalent technology to liberate gold locked in sulphide mineral matrices. Gold pressure oxidation was established 32 years ago, with McLaughlin being the first facility in 1985 (Thomas & Pearson, 2016). Pressure oxidation is carried out at elevated temperatures ranging from 180 to 240°C as shown in the summary of operations in Table 1 (Ruonala et al., 2016; Fleming, 2010).A considerable amount of research has been done to study iron solubility and precipitation under autoclave conditions (Tozawa & Sasaki, 1986; Umetsu et al., 1977; Sasaki et al., 1993; Fleuriault, 2016; Cheng & Demopoulos, 2004; Papangelakis et al., 1994; Yue et al., 2003). These reports provide a description of the process chemistry and iron behaviour in the autoclave. However, there remain questions about the type and stability of aqueous species and solid phases. This detailed information is required to build a robust chemical thermodynamic model of the system, allowing for equilibrium and kinetic reaction limitations to be discerned."

Jan 1, 2017

By Jack F. McQuat, Ross D. Lawrence

"Most geologists and mining engineers, in the course of their professional careers, frequently become involved with the appraisal of metalliferous mineral deposits and develop a familiarity with and standard approach to the evaluation of these deposits. When the same individuals approach the industrial mineral field, however, their usual approach pattern can be rudely disturbed.This paper highlights the difference in appraisal approach and outlines the factors common to both but which have entirely different emphasis. These comprise geological appraisal, analytical requirements, the importance of transportation, marketing requirements and standards, including appropriate allowances for product development, and marketing penetration.Out of these ""different"" considerations, however, a pat-tern or standard approach emerges which is as common to the industrial mineral field as that used either consciously or subconsciously in the metallic field.The paper reviews the different factors and points of emphasis and offers an outline of the common pattern of appraisal for industrial minerals."

Jan 1, 1971

By Martin Bouchard, Bruno Paillard, Jean-Claude Dubé, André L’Espérance

"A precise analysis of the noise emitted by an aluminum plant has shown that one of the main sources of noise is the noise emitted by an exhaust stack 40 m high and 1.8 m diametre, emitting a pure tone at 320 Hz. Because a classical cost effective solution is not available for this source, active noise control (ANC) solution was investigated.Commonly available ANC systems, how-ever, are not applicable to the chimney considered because the diameter of the stack (f) is too important compared to the wave length(?)of the frequency to control. In fact, until now, active noise control (ANC) has been successfully used to reduce the acoustical energy emitted at the end of ducts in the case of plane wave propagation, i.e. ?/f< 1.7 [1,4].When f> ?/1.7, high order modes propagate in the duct and a single canal active noise control system is not sufficient.This paper presents an ANC system developed to control higher modes in a circular duct. The controller used is based on a multiple-input, multiple-output adaptive filtered X-LMS and allows up to 11 error micro-phones and controls sources. The system has been used in a laboratory on a finite duct of3.5 m long and 0.30 m diameter which corresponds to the same ratio ?/f for the real stack. The efficiency of the system with different numbers and location of control sources and errors sensors has been analyzed. Noise reduction of 15 dB(A) could be obtained with some configurations. Actually, the system is being considered for installation on the real chimney stack."

Jan 1, 1997

By BRIAN HITCHON

Calcium, magnesium, bromide and iodide extraction from formation waters for use as industrial minerals has occurred in several countries, but not yet in Canada. Potential commercial brine fields exist in th e Upper Devonian Beaverhill Lake Formation of so uthern Alberta, and the Middle Devonian Elk Point Subgroup of north-central Alberta, f rom which calcium, magnesium and bromide are potential products. Iodide contents in fo rmation waters f rom the Upper Cretaceous Belly River Formation and the Lower Cretaceous Viking and Bow Island fo rmations in central and southern Alberta are at the lower range limit of commercial iodide-bearing formation waters elsewhere in the world. Available information is insufficient 10 outline potentially commercial areas in Alberta, but such info rmation can be most easily obtained f rom test borings for shallow natural gas. Lithium is not now produced commercially f rom formation waters but its content should be monitored in view of f uture increased demand for this metal.

Jan 1, 1984

By P. R. Brito-Parada, A. Norori-McCormac

Positron emission particle tracking (PEPT) has become an important tool for flotation research, as it is able to resolve directly the behaviour of particles in laboratory scale flotation vessels. The first applications of PEPT to flotation showed only the motion of an individual particle in the pulp and the froth, but nonetheless allowed interpretations of behaviour not previously possible. Since then, PEPT measurement and data analysis techniques have improved significantly and now ensure a high level of confidence in the particle behaviour obtained. In particular, statistical analysis of long-duration experiments allows time-averaged data to be collated, ensuring spatial accuracy and allowing rigorous comparison of different conditions. It will be shown that these PEPT techniques can be used to compare directly the effect of operating conditions and particle properties in a laboratory flotation system. Particle tracks will be illustrated, as well as analyses of particle speeds, average flow streamlines and occupancy that show marked differences in behaviour near the interface and impeller.

Jan 1, 2015

By Antonius Prayoga

PT Smelting adopted the Mitsubishi Continuous Technology for its copper smelter plant which has been operating since 1998. Through a series of expansion projects, the plant annual production capacity increased gradually from 200,000 to 300,000 tons of copper. There were no significant modifications for the smelter to reach the 50% additional capacity. It was mostly achieved by intensifying the operation of the furnaces by increasing the oxygen content in the furnaces blowing air. Intensive smelting furnace operation caused shorter campaign life of some furnace refractory, especially the melt zone wall on furnace outlet. During each furnace relining, which is done once every two years, severe wall erosion was found. The worst condition occurred in 2007 when the smelting furnace experienced a melt leak through the eroded wall beneath the bath-line coolers. During the 2008 furnace relining, a modification was performed by installing vertical coolers behind the melt zone wall. Additional vertical coolers were installed during the 2012 furnace relining to extend the coverage area. The modification improved melt zone wall integrity significantly by keeping them safely within the two year campaign life. Recently a modeling study was done to estimate the influences of molten waves on furnace wall erosion. The aim of the study was to predict the impact of blowing parameters, such as blowing air velocity, on the melt wave character and wall erosion.

Jan 1, 2015

By Alessandro Navarra, Kristian Waters

Mineral concentrators are designed from preliminary geological data, and are therefore subject to geological uncertainty. This uncertainty has a demonstrable impact on the mining lifecycle, and has motivated stochastic strategic mine planning algorithms. The current paper describes how these algorithms may be extended to consider mineral processing operations in conjunction with open-pit mining operations. In particular, the paper describes an effective way to incorporate variable concentrator feed grade into these algorithms, which is the first step toward more elaborate representations of mineral concentrators. The resulting framework will be able to connect geological data to alternate configurations of the downstream resources, hence comparing the benefit of each configuration, and the corresponding capital investments. Sample computations are presented, comparing the NPV and utilization for several different mineral processing capacities.

Jan 1, 2015

By M. L. Smith

"In the Phosporia formation of SE Idaho, ore quality varies by depth, seam and distance along strike; phosphorus recovery is sensitive to these variations. Plant ore feed can be blended over time to minimize this fluctuation by using a combination of mine production and inventory stockpile scheduling. Mixed-integer and goal programming has been used to optimize short-term mine production, but the seasonal nature of mine haulage requires the use of stockpiles both at the mill and the mine. The contents of the stockpiles can also be optimized as part of the production scheduling problem, but introducing inventory control introduces a nonlinear term into the formulation. A solution using a piecewise linear formulation is modelled and solved using AMPL/Cplex, and solution strategies are discussed for similar large-scale problems. IntroductionIdaho’s minable deposits of phosphate rock are found in the Meade Peak member of the Phosphoria Formation; two separate zones of this formation are mined with a combined thickness of 30 ft to 60 ft. A generalized stratigraphic section of the Phosphoria section is shown in Figure 1, illustrating the degree of complexity encountered when scheduling mine production. Alteration of the formation results in higher grade ore zones near the surface and variable in P2O5 levels between seams and along strike. This variability is seen as well in other quality characteristics critical to the production of acid and elemental phosphorus. Further, plant recovery and nodule quality are sensitive to variations in ore feed; variability in SiO2, carbonates, moisture, organics (carbon), P2O5 and other constituents of the ore can strongly affect plant recovery. Because ore quality characteristics can vary as a function of the alteration zone (or seam) being mined as well as the depth and distance along the strike of the formation, scheduling of mine production can have a highly significant effect on recovery in the plant. As illustrated in Figure 1, there are nine seams containing 20% to 35% P2O5. Phosphoric acid and elemental phosphorus production requires an ore content of 30% and 25% P2O5, respectively. Variability between numerous beds that are mined and quality variation within a seam due to alteration greatly complicates production scheduling with the result that erratic mill feed characteristics greatly decrease recovery."

Jan 1, 1999

By P. Chu, J. A. Finch

The formation of small bubbles in flotation is usually accomplished by the use of frothers, or sometimes is due to the presence of inorganic salts in the process water. The effective mechanism associated with the presence of these solutes is generally considered to be coalescence inhibition. However, recent work has demonstrated that the presence of frothers and salts also reduces the size of bubble at the initial formation stage. In this paper we adapt the same experimental setup to investigate the time that it takes for a bubble to form; for a known system power input, the energy to form a bubble can then be estimated from the time. The hypothesis is that the presence of frother and salt will reduce the time for a bubble to form, which can be interpreted as an added energy component being derived from the solute. Testing different types and concentrations of frothers and salts, the hypothesis is supported: the mechanical energy required to form a bubble decreases by about 10% in the presence of these solutes.

Jan 1, 2015

Current AG and SAG mill circuits have continued the trend to larger, fewer mills. These large mills place a significant additional load on the discharge systems and it has become imperative that the designs of these mill discharge systems are evaluated carefully to ensure maximum efficiency and have the capacity to be able to handle the increased mill discharge volumes. The current generation of multiphysics modeling tools allow a detailed analysis of AG and SAG mill discharge performance. The combination of Discrete Element Method modeling and Computational Fluid Dynamics allows the designer to model in detail all aspects of a mill discharge performance. This includes a detailed description of the build-up of solids and slurry in a mill discharge, the recycle of material back into the mill through the grates, the relative wear rates and the occurrence of overloading at the pinch points. These tools allow intelligent decisions to be made regarding the type of discharge arrangement, pan lifter geometry, and discharge cone design, so as to ensure that the discharge is capable of handling the duties required for a specific installation. This paper details the current state of the art in these modeling tools, and provides an overview of some recent applications.

Jan 1, 2012

By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By S. W. Marcuson, P. J. Mackey

The 1973 Oil Embargo and succeeding disruptions in supply had a profound effect on energy costs and consumption patterns in the developed world. This was especially true in the USA where post World War II growth, fueled by low-cost imported oil, left the country dependent on uninterrupted oil shipments from the volatile Middle East. In this atmosphere, Professor H.H. Kellogg of Columbia University, convinced of the necessity of good environmental stewardship by the writings of the era’s leading environmentalists, developed a methodology for evaluating energy and process efficiency of metallurgical processes and wrote a series of papers describing and applying the techniques. One of these, "Energy Use in Sulfide Smelting of Copper" is recognized as a seminal work which both described the state of energy usage in copper smelting in the mid-1970’s and portended future developments. The background to these papers is examined and the current and past Cu-Ni matte smelting practices in Canada are examined in the context of the results. Data from early 20th century publications describing reverberatory and blast furnace operation is employed to show that energy consumption for much of the century was several multiples higher than that calculated for best reverberatory operation in the 1970’s.

Jan 1, 2015

By F. Rashchi, A. Ghahreman, J. Moghaddam, S. Karimi

"In this work, the kinetics of ferric-ferrous redox reaction on a passivated sphalerite electrode is studied by the application of chronoamperometry method in 0.5 mol L-1 H2SO4 solution. The electrochemical behaviour of ferric and ferrous couple was investigated on two sphalerite minerals acquired from two different geological regions (Iran and Canada). The carbon paste electrode (CPE) of sphalerite was initially prepared and passivated in 0.5 mol L-1 H2SO4 solution and after reaching the steady-state condition, ferric and ferrous sulfate solution was added. The registered current density differences between the current density of the passivated electrode and that of the electrode in the iron salts added solution were interpreted for kinetics of ferric-ferrous reduction-oxidation reaction. The equilibrium potential for ferric-ferrous couple on sphalerites surface was about 500 mV vs. Ag/AgCl. The exchange current density (i0) for ferric-ferrous redox reactions on the sphalerite samples had the same magnitude of 10–6 A cm–2. The electrochemical impedance spectroscopy (EIS) measurements at 550 mV vs. Ag/AgCl illustrated that sphalerite oxidation was controlled by two charge transfer process in both of Fe-free and Fe-containing solutions. The charge transfer resistance remarkably decreased when Fe salts added to the 0.5 mol L-1 H2SO4 solution, owing to the ferric-ferrous redox reactions being the predominant reactions on sphalerite surface.INTRODUCTION Direct atmospheric leaching processes for sphalerite concentrates are performed by reduction of an oxidant (e.g. ferric ion and oxygen) and oxidation of sphalerite to zinc ions. Oxygen could be an oxidizing agent as well, but the concentration of oxygen is very low in the solution. The role of ferric ions is predominate in this oxidation (Babu, Sahu, & Pandey, 2002). The oxidation reaction for sphalerite in the presence of ferric in can be presented as follows (Lampinen, Laari, & Turunen, 2015):"

Jan 1, 2017

By David Ulrich Furrer

Materials and manufacturing processing technologies have played an important role in the development and capabilities of nearly all manmade products. Market drivers for fuel efficient, low cost, environmentally friendly, more capable transportation has given rise to significant materials challenges and subsequent developments. The rate of improvement and implementation of new commercial products can be limited by the rate of new materials and process technology development and qualification. As many materials are being designed for unique requirements and even location-specific unique properties, the implementation of tools and methods to enable rapid characterization and validation of material definitions and design systems must also be accelerated. A review of new integrated material, manufacturing process and component designs, engineering processes and emerging tools and methods will be discussed. The linkage of computational materials science and engineering into component design will also be discussed along with the challenges and opportunities for further growth and application of integrated computational materials engineering (ICME).

Jan 1, 2015

By E. Henderson, L. K. Daneshmend

Drawpoint control is critical in determining the cutoff point for load-haul-dump mucking operations to minimize dilution. It is also necessary to ensure even mucking distribution and to prevent possible hang-up of material within a stope. A prototype production monitoring and reporting system has been developed for load-haul-dump operations in under-ground mines. The system generates accurate and timely information regarding mucked tonnages and drawpoint and ore/waste pass utilization. The monitoring system integrates a PLC-based load weighing system with a radio frequency identification (RFID) system for locating the vehicle. The system records the identification and time of entry and exit of each draw-point and ore/waste pass visited during a shift, as well as the weight of each bucket load. A trial of the system was conducted at the CAN-MET Experimental Mine near Val d’Or, Quebec. The monitoring and reporting system functioned as designed, with the exception that the maximum read range of the RFID tags under dynamic conditions was found to be a limitation. RFID systems with greater range capabilities have been identified for a second generation system. The system is the first of its type in North America to demonstrate that RFID tagscan be successfully applied to locate trackless underground equipment. Because of their ability to locate equipment and personnel within underground mines, RFID systems should be considered a key technology for future mine information and process control systems.

Jan 1, 1996

By E. Barnard, J. Tero, J. Rajala, N. Avenido, M. Fullam, A. Nashitati, S. Mbalamba

"The Otjikoto mining and milling complex is 90% owned by B2Gold Corporation, and began commercial operation on February 28, 2015. The milling circuit operates at a throughput 3.3 million tonnes per annum, with an average reserve gold grade of 1.28 g/t. The ore is high in Gravity Recoverable Gold (GRG), which varies between 73-91%, depending on ore type. Overall gold recovery since start-up is 98.2%, with about 63.5 % coming from the gravity circuit as doré. 2016 cash operating costs, and all in sustaining cost (“AISC”) were $361 and $604 per ounce, respectively.During design, three ore types were tested for GRG content, and based on the high GRG value of all three ore types, the decision was made to treat the full ball mill circulating load by gravity. Once operating, the gravity circuit performance was characterized by performing a detailed gravity audit, which included the ore, cyclone classification, Knelson concentrators, and the Consep Acacia intensive leach system. The deeper ores contain significant pyrrhotite, and this created some unusual challenges that had to be overcome. This paper presents the gravity circuit design process, the circuit commissioning, and the audit results and ongoing improvements.IntroductionHeadquartered in Vancouver, Canada, B2Gold Corp. was founded in 2007. Currently, B2Gold has five operating mines, and numerous exploration projects in various countries, including Nicaragua, the Philippines, Namibia, Mali and Burkina Faso. The Otjikoto Mine is located in the north-central part of the Republic of Namibia. It is situated approximately 300 kilometers north of Windhoek, the country’s capital, within the Province of Otjozondjupa. The Otjikoto mining and milling complex is 90% owned by B2Gold Corporation, and began commercial operation on February 28, 2015. The milling circuit operates at a throughput 3.3 million tonnes per annum. During design, a large emphasis was placed on gravity recovery, as the Otjikoto ores are unusually high in Gravity Recoverable Gold (GRG)."

Jan 1, 2018

By G. Minhas, M. Pule, Y. Laffitte, M. c. McGurn, T. Tzanetakis, Peacey. J., R. Susilo

Titanium (Ti) metal production from titanium tetrachloride (TiCl4) using magnesium (Mg) as a reducing agent is the well-known Kroll process. A chloride route is used to avoid oxidation of the titanium sponge. The sponge is consolidated into ingots and can then be made into powder by melting and atomizing or by hydriding/dehydriding. Attempts at direct powder production have met with difficulties, including low Ti yield and the formation of very fine particles (particles between 25-100 µm are desired). This paper discusses two methods to produce Ti powder in a molten salt medium using magnesium powder as a starting material instead of a pool of molten magnesium. The first method is a direct reduction of gaseous TiCl4 injected in the melt with the magnesium powder in suspension in the molten salt. The second method is a two stage TiCl4 reduction reaction where recycled Ti was used to form titanium dichloride (TiCl2) in the first stage followed by addition of magnesium powder into molten salt in the second stage. A correlation between Ti yield and processing variables such as TiCl4 to Mg ratio, Mg particle size, TiCl2 concentration in the melt, and reaction temperature was studied. The Ti powder formed was also analyzed for particle size distribution. Despite challenges and difficulties encountered, this paper shows some promising results which could provide guidance to others working on direct Ti powder production.

Jan 1, 2015