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By B. J. Clauzier

"The Falconbridge Limited approach to employing communication equipment is first, to determine what is required in a given situation, second, to evaluate the possible alternatives, third, to select the most suitable hardware and, fourth, to determine what modifications, if any, are required to ensure not only successful implementation but continued low-cost reliability. Two examples are examined.The first situation required remote video monitoring of an acid loadout station. Several alternatives for linking to theremote site were investigated, including hard-wired, slow-scan and microwave. A comparison of these alternatives is shown and an appraisal of the performance of the selected microwave link is presented.The second situation required direct voice contact between the two members of an underground tram crew. Alternative solutions are described and an evaluation of the selected system- SHF portable radios - is presented.ObjectivesIn general, projects must have four main objectives: (1) to improve the safety of its operations; (2) to reduce its operating and capital costs; (3) to increase the efficiency of its work force; and (4) to increase its productivity. ScopeCommunication, when used wisely, can be a good tool to achieve these objectives. Projects can be kept simple using existing technology and adapting it to a particular task. To ensure the success of the project, it was necessary: to determine the project objectives; to evaluate the possible alternatives; to select the most suitable hardware; to adapt the hardware to the application, if required; and not to provide more than is necessary.Application at FalconbridgeTo illustrate this approach, two examples of actual installations at the Sudbury Operations are presented, sulphuric acid loadout, and the Falconbridge Mine haulage system."

Jan 1, 1987

By C. F. Gleeson, D. G. Sheehan

"The results of humus and overburden geochemical surveys over the Doyon, Bousquet and Page-Williams gold ore deposits are presented.These studies show that humus sampling for gold gives negative results over the Doyon deposit. The lack of response is probably caused by the presence of 1 m of relatively impermeable glaciolacustrine clay and silt that overlies 1 m to 2 m of till over the surface expression of the ore zone. By contrast, positive responses for gold occur in humus samples over the Page Williams A and C gold deposits. The ""A"" ore zone is covered by several metres of exotic calcareous till over 0.5 m to 1 m of older, locally derived till. Anomalous values for gold in humus range from 10 to 35 ppb over the orebody. Overburden over the ""C"" ore zones is much thinner, generally it consists of less than 2 m of sandy till. Trenching humus anomalies that range from 10 to 1360ppb Au uncovered the gold mineralization. The geochemical dispersal trains in till from the Doyon orebody and the Page-Williams ""A"" zone are relatively short (i.e. less than 200 m) because both deposits occur in the lee of bedrock highs that shielded them from extensive glacial quarrying. Dispersal trains from all three pyritic gold deposits can be defined using either the fine fraction or heavy mineral fraction of the till.The intensity of the gold in till anomalies over the ore zones is variable. Therefore, it would be misleading to attach rigid significant threshold gold values to overburden drilling results. Each case must be evaluated based on bedrock topography, sample density, overburden type, thickness of till, as well as size, type and orientation of the target exposed to glacial erosion."

Jan 1, 1987

By M. Lahtinen, P. Latostenmaa, I. Kojo, E. Peuraniemi, M. Lindgren, S. Jyrkönen, M. Jåfs

The year 2019 marks the 70th anniversary of Flash Smelting. The technology was operated on industrial scale for the first time at the Outokumpu Harjavalta copper smelter in Finland in 1949. Since then Flash Smelting technology, now owned and developed by Outotec Oyj and the first plant, now owned by Boliden Harjavalta Oy, have been evolving throughout history by optimizing the process for various feeds and raw-materials, as well as through developing the equipment and operating practices. Even though sustainability was not a popular theme during the first days of Flash Smelting, it has still been the key principle in guiding the development. This is well proven by the wide adoption of Flash Smelting for the processing of copper and nickel concentrates, mostly due to its ability to fulfil the economic and resource efficiency criteria demanded by its operators. This paper describes the history and improvements of the Outotec® Flash Smelting process by looking into the early days of operation and how the development of the process and equipment has taken place over time as a joint effort between the technology provider and the users of the technology. INTRODUCTION In the 1940s, Outokumpu Oy refined the concentrate produced in the Outokumpu mine into metallic copper initially in Imatra, and later from 1945 to 1949 in Harjavalta, based on the most modern electrical melting process of the world at that time. After the war, Finland lost a significant part of its hydropower production, and due to the increasing use of electricity, the availability of electricity weakened, and the price rose. To maintain Outokumpu's profitability, it was forced to look for a melting solution that was not based on electricity.

Jan 1, 2019

By Jacek Paraszczak

Application of teleoperated and automated mobile equipment in underground metal mines represents a promising avenue to overcome some of the challenges facing the industry. This paper addresses the issues of overall effectiveness of the autonomous loading and haulage equipment in comparison with conventional man-operated machines. It overviews and discusses the factors affecting availability, utilization and production rate. It puts an emphasis on some problems and risks not present in conventional man-operated systems, as well as their character and criticality. It stresses the need to analyze the factors affecting OEE of the autonomous equipment more in-depth than it has been done up to date and to take them into consideration at the stage of feasibility studies. The paper concludes with some recommendations and indicates the directions of the future research in this field.

Oct 1, 2009

By Dave Stefanuto

Voisey?s Bay Project Components ? Mine/Mill Port In Labrador ? Mini Plant in Mississauga ? Demonstration Plant in Argentia ? Supply Vessel (Umiak1) ? Transshipment Facility (Quebec) ? Concentrate Handling & Transport to Sudbury/Thompson ? Cobalt Refinery Upgrade (Thompson) Project Setting ? The Project is on the traditional lands of the Labrador Inuit and the Labrador Innu ? Canadian courts have held that Aboriginal peoples in Canada possess special rights to traditional Aboriginal lands Those rights can include requiring resource developers to enter into Impacts and Benefits Agreements (IBAs) on traditional lands to set forth how lands can be used and benefits to be received by Aboriginal people

May 1, 2006

By D. M. Doyle, P. J. Hannon

"The Canada/Nova Scotia Mineral Development Agreement (M.D.A.) is a subsidiary of a five-year Economic and Regional Development Agreement, signed on June 11, 1984. The objectives of the M.D.A. are to strengthen and diversify the Nova Scotian mineral industry and to coordinate federal and provincial policies and programs. The agreement outlines the activities and responsibilities of each government, including the division of the cost (60:40, federal: provincial) between governments. The agreement established a framework for joint planning to avoid overlap or duplication of programs.The M.D.A. programs are broadly divided into five sectors (Table 1 and Fig. 1): Geoscience, Minerals Technology, Development, Firm Specific and Public Information. Each sector is administered by a subcommittee composed of one federal member and one provincial member. The subcommittees report to a Management Committee. The Canada/Nova Scotia Mineral Development Agreement (M.D.A.) Management Committee is made up of Dr. Jack Reeves from EMR and Dr. Richard Potter from the NSDME.The Geoscience subcommittee, co-chaired by Peter Giles (NSDME) and William Poole (EMR), manages the regional geologic, geochemical and geophysical studies in the province. Included in this sector are studies into mineral deposits and the basic geological relationships between mineral deposits.The Mineral Technology sector is co-chaired by the authors, Don Doyle (CANMET) and Pat Hannon (NSDME). This sector of the M.D.A. conducts studies into mineral processing, sampling, deposit byproduct commodities and project feasibility analysis."

Jan 1, 1987

By Ken Dyck, Chuck Edwards

"Cameco's McArthur River is the world's largest high grade uranium mine. Production started in late 1999. Cameco carried out the engineering design and construction management for the McArthur River project, including all aspects of mining, ore handling and ore transportation. The ore composition was expected to vary dramatically (0 to 30% U3O8; 0 to 25% clay; etc). To cope with the composition swings, sizing screens were selected to provide classification in the grinding circuit. The grinding circuit started up close to the design to provide minus 500 micron slurry. The 50% solids (wt) ground ore slurry proved to be difficult to transport to and process at the Key Lake Mill. Slurry containing high concentrations of high density pitchblende (about spgr 8.0) and low concentration of stabilizing clays, would settle in containers. Ore transport efficiency to Key Lake was found to be unacceptable.A test classification cyclone was installed in the grinding circuit at McArthur River early in 2002. The cyclone operating parameters were not typical, but the cyclone was made to work very successfully. Transportation efficiency to Key Lake increased due to more stable slurry. Preferentially ground (fine) pitchblende particles were easier to leach at Key Lake. The radiation exposure for operators and maintenance personnel to handle the more stable slurry was also reduced.The classification sizing screens were removed from the McArthur River grinding circuit and replaced by permanent classification cyclones late in 2002.INTRODUCTIONThe McArthur River mine and Key Lake mill operations are located in northern Saskatchewan, approximately 650 and 720 kilometres from Saskatoon, respectively. Figure 1 is a location map. McArthur River is the world's largest, high-grade uranium mine, with a production capacity of 18.7 million pounds U3O8 annually. (Rosner and Edwards 1998, Dyck 2000, Jamrozek 2000, Rodgers 2001) Proven and probable reserves are more than 473 million pounds U3O8. McArthur River ore, grading on average 21% U3O8, is milled at Cameco's Key Lake operation, 80 kilometres southwest by road. McArthur River production began in December 1999."

Jan 1, 2004

By Michel R. Julien, Michel Lemieux, Jean Cayouette, Daniel Talbot

"The Louvicourt Mine located near Val d’Or, Quebec has been in operation since 1994. It produces copper and zinc concentrates. The tailings generated from the ore processing operations have a strong net acid generating potential. Louvicourt Mine, a grass root project, was designed for closure with the best available technology at the time of design. In order to inhibit short and long time acid potential generation, sub-aqueous disposal was selected at the design stage. Given the fact that disposal in a natural lake was ruled out up front for obvious reasons related to loss of natural habitat and risks of permitting delays, a man made facility built with dams was planned. This mine includes therefore the first fully man-made sub-aqueous tailings disposal facility built in Canada. The requirement of using sub-aqueous disposal had serious implications on the placement of tailings. This tailings facility located about 9 km from the mine site has been selected based on the available natural confinement, the favorable foundation and hydrogeological conditions. This paper describes the site and the design criteria that were used. A presentation is also made on the placement technique to maximize storage and its impact on the operation of the basin. The performance of the basin, the dams and the decant structures is reviewed.Résumé : La mine Louvicourt, située près de Val d’Or, Québec est opérationnelle depuis 1994. Elle produit des concentrés de cuivre et de zinc. Les résidus générés par les opérations de traitement du minerai possèdent un fort potentiel net de génération d’acide. Le parc à résidus de la mine Louvicourt, implanté dans un milieu naturel intact, fut doté dès sa conception initiale de la meilleure technologie de fermeture disponible à l’époque, soit la déposition sous couverture aqueuse et ce, dans le but de bloquer le potentiel de génération d’acide à court et à long terme des résidus. Etant donné que la déposition dans un lac naturel fut mise de côté dès le départ pour des raisons évidentes reliées à la perte d’habitats naturels et au risque d’introduire des délais dans l’émission des permis, un étang artificiel délimité par des digues a été conçu. Cette mine fut donc la première au Canada à être dotée d’une installation anthropique de disposition des résidus sous une pleine couverture aqueuse. L’exigence d’une déposition sous couverture aqueuse a eu des implications sur le mode de mise en place des résidus. L’emplacement de l’installation de gestion des résidus a été choisi en un lieu situé à environ 9 km du concentrateur sur la base du confinement naturel disponible et des conditions hydrogéologiques et géotechniques favorables. Cet article décrit le site et les critères de conception utilisés. Une présentation est faite sur la technique de mise en place utilisée pour maximiser l’entreposage et son impact sur l’opération du bassin. La performance du bassin, des digues et des structures de décantation est également revue."

Jan 1, 2004

By Brigitte Lacouture, Yeen Shien Hwang, David Lin

"A baseline survey of the partially open lead regrind circuit at Red Dog Mine indicated poor regrind efficiencies for the three parallel 450 HP tower mills. Driven by the high energy cost and the potential metallurgical gain brought by improved mineral liberation, the Red Dog lead regrind circuit was optimized in two stages.In the first optimization stage, different circuit layouts were evaluated in two plant trials. In June 2003, the regrind circuit was changed to a fully closed circuit. This reduced the tower mill requirement from three to two mills. The circuit modification payback was 11 days through power savings alone.The second stage of optimization was the evaluation of reagent addition. To improve pyrite depression, sodium cyanide was added to the feed of the lead regrind tower mills and tested in a series of plant trials over several mill feed stockpiles. Galena selectivity against pyrite was found to improve in these plant trials. Due to environmental sensitivities, no net increase in cyanide addition to the plant occurred and thus no increase in the cyanide concentrations in the tailings pond or the environment will result.The lead regrind optimization work improved the overall lead metallurgical performance and reduced energy and reagent costs. Economic analysis showed that annual profit increased by as much as US$3.0 M."

Jan 1, 2005

By L. van Hijfte, A. Piché

"Drilling and blasting are fundamental operations in the mining cycle and constitute an important component of the mining costs. Problems associated with improper drilling and blasting practices can create losses of several millions of dollars per year. For this reason, a Blasting Technology program was initiated in 1984 at the Noranda Technology Centre (NTC). In this paper, advances made at NTC in drill and blast technology are reviewed. Impacts of drilling and basting for Noranda are assessed in terms of dilution and ore losses. Future challenges are addressed. IntroductionUp to 1997, Noranda was a diversified natural resources company that operated in three sectors: mining and metallurgy, forest products, and oil and gas. The company employs more than 33 000 people in operations and sales offices around the world. Today, Noranda has returned to its roots in mining and metallurgy. The new vision of Noranda is to be dedicated to the responsible and profitable development of mineral resources around the world for the benefit of its shareholders. In so doing, Noranda will continue to be deeply committed to the environment, health, workplace safety, cost competitiveness and return on capital. Technology is an integral part of Noranda’s success strategies. For this reason, the Noranda Technology Centre, formerly known as Noranda Research Centre, was founded in 1963. Since then, it has undergone four expansion phases to keep up with the increasing needs of the businesses. Today, NTC employs more than 220 specialists who work in partnership with different Noranda companies to identify, develop, and transfer technology to the operations, as well as to explore new sectors of activity."

Jan 1, 2000

By Luis A. Tondo

The Paracatu Expansion Project III in Brazil was implemented between 2006 and 2008 to increase the existing capacity from 20 to 61 Million tons per year of gold ore treatment. This expansion led the Brazilian subsidiary of the Canadian Kinross Gold Corporation to become the single largest gold producer in Brazil and the largest single gold concentrator in the world, with a nominal capacity to treat around 167,000 tons per day of ore. This paper describes the Project Development areas for the Paracatu Expansion, using the approach proposed by the Project Management Institute (PMI) and the methodology included in the PMBOK (Project Management Book of Knowledge). The author has more than 20 years of experience in the gold mining industry, having worked as a plant metallurgist, mill superintendent and development manager for RPM until he took the position as the Project Manager of the Paracatu Expansion III in 2005. Luis Tondo has a BSc in Mining Engineering from UFRGS-Brazil, an MScEng from the University of Queensland - Australia and an MBA degree from FDC-Brazil. Luis is currently based in Santiago-Chile, acting as the Project Director for developing projects in Latin America for the Kinross Gold Corporation.

May 1, 2009

By John D. Godfrey

Geological mapping on the Canadian Shield in northeastern Alberta outlined severalgranitoid rock massespotentially suitable as building stone. A particularly attractive prospect, the Chipewyan Red Granite, was subjected to an aerial survey and ground check. The petrologic and fracture characteristics critical for quarrying and use as a building stone were assessed in the course of detailed mapping at two of the most favourable sites. The extension of good rock was tested to shallow depths at one site by shallow diamond-drill coring. , The Chipewyan Red Granite displays a warm red colour, medium grain size and fairly massive texture, and takes a good polish. Deleterious geologic features studied in outcrop and subjected to structural analysis included regular joint systems, quartz veins, pegmatite dykes, basic shear zones and fault zones. Many of these key geologic features are systematic and hence predictable for stone quarrying purposes; other features, such as irregular fracelM tures, are non-systematic and arefar less predictable. The megascopic structural features studied show similar preferred orientations which appear to be collectively related to the tectonic history.

Jan 1, 1979

By Laura Mottola

This paper outlines a framework for ensuring the success of the implementation phase that follows research and development of new mining technologies and systems. It is based upon recent and past lessons learned that have demonstrated the critical challenges to effective technology transfer, which frequently receive inadequate attention within the culture of the mining business. The paper focuses on mining automation implementation challenges and then outlines a Roadmap which is proposed as an integrated framework to deal with the key aspects of people, process and technology. This framework is built upon: assembly of a Strategic Team to develop a Roadmap; fully understanding the business requirements of the technology initiative; defining Key Performance Indicators in a Balanced Score Card; performing a Stakeholder Analysis to identify the affected groups; and finally developing a master Project Plan to execute the Roadmap.

Oct 1, 2009

By Sibabrata Patnayak

A major problem during shovel excavation in oil sand mining is the variability of material diggability resulting in varying mechanical energy input, cycle time, energy consumption, wear, and stress loading of shovel dipper-andtooth assembly. This variability greatly influences the mining equipment performance. Different approaches such as empirical ground classification systems, analytical methods, and performance monitoring that are used to determine diggability of groundmass are reviewed. It is concluded that the existing empirical diggability classification systems are site specific and mostly based on rock and therefore, cannot be used for shovel excavation in oil sands. The O&K wedge test is a simple and useful index test for establishing correlations between cutting resistance and geotechnical properties of coal and other soft rock overburden material. But this test, when performed on small size unconfined oil sand samples, may not give reliable indication of diggability because of the boundary conditions on the specimens. Digging predictions made using analytical and laboratory digging models need to be verified with performance monitoring data to better understand the digging effort in oil sands.

Apr 1, 2005

By Michel Brissette

"To recover more valuable ore and considering the complexity of minerals, the needs to grind finer is increasing. To reach the desired fine grinding targets, using the existing grinding media size, the energy consumption is increasing exponentially. As already proved at this conference, small grinding media represents the best potential to improve grinding efficiency. How do the small grinding media perform in industrial grinding mills?The use of small grinding media in regrind mills proved that finer grinding can be achieved at lower energy consumption. In ball mills, smaller grinding media versus 25 mm media generate a power saving from 10% to 44%. In vertical stirred mills, the power saving increases from 20% to 60%. More potential savings have been identified.For the same operating conditions, how a vertical stirred mill is performing compared to ball milling? In regrind application, a vertical stirred mill with small media (5-12 mm Millpebs) will require at least 62% less energy than a ball mill charged with 25 mm grinding media.INTRODUCTIONIn some mining applications, fine grinding is needed to liberate further the valuable ore. The purpose of regrind mills is to achieve the last stage of grinding before final flotation stage: the cleaners. In part because of high prices of small grinding media as well as availability, the most widely used size of grinding media is 25 mm.When calculating the recommended ball top size from Bond’s formula (Bond, 1961), the size for regrind applications is much lower than 25 mm. Today, the barrier for small grinding media is broken. They are best suited in regrind application. The size of grinding media is one of the most important variables affecting the mill efficiency (McIvor, R., 1997; Nesset, J.E., Radziszewski, P., Hardie, C. & Leroux, D.P., 2006).Conventional ball milling was discarded for fine grinding because of its very poor energy efficiency (Zheng, J., Harris, C.C. & Somasundaran, P., 1994; Yan, D.S., Freeman, M. & Dunne, R., 1995). Therefore, new technologies as stirred mills were developed to grind finer more effectively. Three fundamental questions should be asked. What is the best fine grinding technology? What should be the best media size to use? Is it possible to grind finer by using less energy with the existing regrind equipment?"

Jan 1, 2009

By Ahmad Ghahreman, Lin Li

Silver and cupric ions have been proven to play the roles of catalysts to promote the oxidation kinetics of chalcopyrite in acid solution. In this study, the interaction between silver ions and cupric ions during ferric leaching of chalcopyrite in sulfuric acid solution has been investigated. The electrochemical study by Tafel analysis showed a significant boost of dissolution rate for chalcopyrite dissolution in Fe3+- Cu2+ containing sulfuric acid solution after Ag+ was added in the solution. For 10 ppm Ag addition, the dissolution rate of chalcopyrite increased to 7.94 ×10-6 A/cm2 from 3.2 ×10-7 A/cm2, when Ag+ was absent. On the other hand, the effect of Cu2+ on the dissolution of chalcopyrite in Fe3+-Ag+ containing sulfuric acid solution was not obvious from electrochemical measurements. The chalcopyrite leaching tests in different acid solutions showed that silver addition had an obvious catalytic effect on promoting chalcopyrite dissolution. Comparing the leaching rates of chalcopyrite leached in Fe3+ containing, Fe3+-Ag+ containing, Fe3+-Cu2+ containing and Fe3+-Cu2+-Ag+ containing sulfuric acid solutions, it was found in Ag+-Fe3+-Cu2+ containing sulfuric acid solution, the leaching rate was highest among all the aqueous acid systems. Further leaching tests suggested that with increase of the Ag+ concentration from 0 to 20 ppm, the leaching rate of chalcopyrite in Ag+-Fe3+-Cu2+ containing sulfuric acid solution also increased and reached 57.62% with 20 ppm Ag+ addition after 24 h. INTRODUCTION Chalcopyrite is the most important copper mineral in copper hydrometallurgy and it accounts for nearly 80% of the universal copper resource (Olvera, Rebolledo, Mora, Dixon, & Asselin, 2018). The hydrometallurgy of chalcopyrite has been intensively studied with emphasis on solving the slow dissolution kinetics of chalcopyrite in acid environment. A variety of aqueous systems, such as sulfate (Hiroyoshi, Miki, Hirajima, & Tsunekawa, 2001), chlorides (Liu, Chen, & Yang, 2017), and ammonia (Hua et al., 2018) have been studied to improve copper leaching. From another perspective, chalcopyrite leaching studies have indicated that the mechanism of chalcopyrite dissolution in acid solution is essentially electrochemical (Li, Kawashima, Li, Chandra, & Gerson, 2013). Therefore, extensive studies have recently been carried out to explain the dissolution kinetics of chalcopyrite in different media by various electrochemical techniques.

Jan 1, 2019

By Pierre Gauthier

Is the hydrogen economy of the future just another fish story? Absolutely not! There have been many changes affecting the energy equation over the last 10 years and conditions have changed. In this presentation, we will examine the reasons why, in the very near future, hydrogen production and distribution will be increasingly visible on many industries? radar screens.

May 1, 2007

By Tony Lipiec, Greg Gosson

"When it comes to new mines being developed, there is a general industry consensus that most low-hanging fruit has been picked. Many projects currently in the mine development pipeline have been around for decades, but were held back because of technical challenges. Future development of these deposits will likely require access to the public capital markets, and in Canada that means providing scientific and technical disclosure on these deposits in compliance with NI 43-101. As many of these “challenged” projects have metallurgical issues, the companies that own the projects need to ensure their metallurgical Qualified Persons provide transparent disclosure regarding proposed solutions to those issues.This paper provides an overview of the disclosure requirements under NI 43-101 that are pertinent to metallurgists, and other Qualified Persons who prepare technical disclosure regarding the metallurgical characteristics of a mineral project. It lists the triggers for a technical report under NI 43-101 and Canadian stock exchange policies, and identifies the sections of the report that should involve input from a metallurgist or process engineer. It briefly outlines new civil liabilities under Canadian securities laws that increase the possible consequences for not complying with the technical disclosure standards.These materials are provided for general information purposes only and do not constitute legal advice. Readers are advised to seek specific legal advice from their own legal counsel in relation to any decision or course of action contemplated."

Jan 1, 2010

"In mineral exploration and mining applications, it is sometimes necessary to reduce sampling error in order to improve representivity of individual sample assays. Historic efforts to reduce sampling error have relied on the belief that larger samples exhibit less sampling error. Justifications for this belief traditionally have coupled the binomial theorem with an ideal geological material consisting of ore and gangue particles of equal size and shape (an equant grain model) and empirical tests of geological materials, to illustrate an inverse relationship between sample size and sampling variance. To date, no proof exists of this sample size-sampling variance relationship in real geological materials exhibiting variations in grain size, shape, composition, and degree of liberation.Using first principles calculus and the formula for the mean, sample mass and sampling variance are proven to be inversely proportional in all geological materials. Distribution assumptions and physically ideal geological models are not used in this proof. Furthermore, algebraic manipulations of expressions describing the variances of equant grain models consistent with binomial, hypergeometric, and Poisson distributions reveal that these models also exhibit an inverse sample size-sampling variance relationship. Thus, the sampling behaviors of these models are numerically consistent with the sampling behaviors of real geological materials, and these models can be used to estimate sampling errors in real geological materials using simple sampling parameters."

Jan 1, 2007

By Weng Fu, James Vaughan, Stefan Lakemond

Uranium bearing copper sulphide flotation concentrates produced from iron oxide copper gold uranium (IOCG–U) ore contains radionuclides such as 238U, 230Th, 210Pb, 226Ra, 210Po, which have the potential to reduce their marketability, thus posing a challenge to the industry. Thus, a two–stage leach process has been proposed in this study. In first stage, a sulphuric acid leach process effectively dissolve most of the 238U and 230Th into solution, but other radionulclides (mainly 210Pb, 226Ra and 210Po) remain associated with copper sulphide minerals owing to their low solubilities in sulphuric acid solution. In the second leaching stage, the use of methanesulfonic acid (MSA, CH3SO3H) is investigated to selectively dissolve the 210Pb, 226Ra and 210Po from the residue of the first stage. The results indicate that 96% of 238U, 87% of 230Th, 90% of 210Pb, 86% of 226Ra and 17% of 210Po are dissolved using 3 mol/L MSA solution at 90°C for 3 hours, which represents a dramatic decrease in the radioactivity of the copper concentrate. INTRODUCTION Australia is host to one of the largest iron oxide copper–gold–uranium (IOCG–U) deposits in the world. Most of the value in these deposits is associated with copper. In mineral processing, the gangue minerals are separated from copper sulphide minerals that report to a copper flotation concentrate. However, due to the strong association of uranium with copper minerals and hematite, even clean copper concentrates can contain significant amounts of uranium (238U) and its radioactive decay elements, of which thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) are the long life radionuclides. These hazardous radionuclides negatively affect the marketability of the copper concentrates. Customer copper smelters in China, Japan and Europe may consider the radionuclides penalty elements or may not be able to process the feed. Therefore, there is a strong motivation to remove radionuclides from copper concentrates at the mine site before shipping to custom smelters in global market. Hydrometallurgical leaching has been widely employed to remove radionuclides from different kinds of minerals such as copper concentrates (Ragozzini & Sparrow, 1987), zircon concentrates (Aral, Sparrow, McDonald, & Norgate, 2007), and coal ash (Lei, Qi, Sun, Xu, & Wang, 2014). Leaching using sulphuric acid (H2SO4) solutions is the most widely used process for the extraction of uranium from uranium ores due to the relatively low cost and wide availability of the acid (Bhargava et al., 2015; Gilligan & Nikoloski, 2015). The leach process involves treating ground ore slurry with sulphuric acid at elevated temperatures (typically 60–90 °C) under oxidising conditions in order to convert the uranium in the minerals 2+ from the relatively insoluble tetravalent form (UO2) into water–soluble hexavalent state (UO2), which then complexes with SO42- and forms UO2(SO4)22- in solution. The uranium oxidation is generally carried out in the presence of ferric ion (Fe3+), regardless of the reagent and oxidant used. The most commonly used oxidants for uranium include sodium chlorate, pyrolusite and oxygen (Ring, 1980). These oxidants act indirectly by converting ferrous sulphate, formed by the oxidation reaction of UO2 in slurries, into ferric sulphate. The presence of Fe–containing gangue minerals such as hematite in the ore usually provides sufficient Fe required for the oxidation of UO2. After sulphuric acid leaching, the locked thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) elements are chemically liberated from hematite and uranium mineral grains (Ciobanu, Wade, Cook, Schmidt Mumm, & Giles, 2013). However, the extraction rate of radium (226Ra), lead (210Pb), and polonium (210Po) in sulphate solution is very low due to the limited solubilities of (Ra, Pb, Po)SO4 (Bagnall & Freeman, 1956; Liu & Papangelakis, 2006; Nikitin & Tolmachev, 1933).

Jan 1, 2019