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By Yasuo Iizuka

We have had studied CO oxidation on unsupported Au powder (mean particle size, ca.100nm) manufactured by evaporating ultra high purity gold metal (>99.99%) in inert gas and reported that it showed some activity after oxidizing pretreatment in O2 at 423 K?453 K. However, recent XPS analysis of the Au powder revealed that it contains much amount of impurity metals such as Ag and In at levels which far exceed those expected from the impurity level of raw gold metal in the bulk. Several samples of Au powder containing different amount of impurity metals were prepared to examine whether the activity depends upon the existence of surface impurity or not. Activity measurements were performed at 273 K after undergoing the powder under various pretreatment conditions. Although the activity of Au powder varied to some extent according to the pretreatment condition, it is strongly correlated to the surface concentration of Ag. Such dependence was not found for In, indicating that the activity of unsupported Au powder is mainly due to the existence of Ag in the surface layer. The activity attributable to ?particle size effect? was not recognized for Au powder with a mean particle size larger than 80 nm.

Oct 1, 2003

By M. A. Vos

"Aggregates are the low-cost mineral raw material of building construction. Large volumes of aggregate are consumed each year. The availability of aggregates in southern Ontario is discussed in the context of the geological formations in which they occur. Sand and gravel are abundant in glacial deposits and in recent sediments. A knowledge of the glacial history is important for their discovery. Bedrock formations provide a variety of aggregates in Ontario. Knowledge of the rock types involved and of the depth of overburden are important for evaluation of the aggregate potential of bedrock resources in an area. Utilization of available resources intensifies as the population increases. Urban development makes it progressively more difficult to satisfy the demands of the construction industry. The effects of urban development on the aggregate resource base of an area are illustrated by developments and consumption statistics in the Toronto- centred region. There is an obvious need for a comprehensive survey of available resources in urban areas to serve as a guide in land-use planning. To fill this need, staff members of the Industrial Minerals Section, Geological Branch, Ontario Department of Mines and Northern Affairs, are engaged in mapping projects and mineral resource studies in southern Ontario as well as in some urban areas of northern Ontario."

Jan 1, 1972

By Roger Potvin

Abstract The demand for pure zirconium and titanium metals in Germany increased considerably during the war. Pure zirconium was used in flash bulbs, in vacuum tubes, and in time fuses for bombs, where it has a decided advantage because it gives no gas in burning. Under the form of alloy, it was used with other rare elements for making substitutes for platinum; it was also used as a scavenging agent in high-grade steels. Metallic titanium was mainly used in connection with the manufacturing of special alloys. The authors were sent to Germany by the Department of Reconstruction and have investigated the German process developed for producing these rare metals. They describe the procedure and special equipment used for their commercial production in Germany during the war. General Metallic zirconium and titanium were .produced on a commercial scale in Germany by the thermal reduction, with metallic sodium, of potassium fluozirconate and titanium chloride, respectively, using a mixed potassium and sodium chloride flux. According to the information gathered, the sole German producer of these rare metals in pure form was the Deutsche Gold und Silber Scheideanstalt (commonly called Degussa), at their Werk II, 215 Gutleutstrasse, Frankfurt/Main, which was visited by the authors on September 18th, 1945. As far back as 1934, Degussa was carrying on active research on the manufacture of zirconium, and nearly one ton of the pure metal had been produced before September, 1939. Concurrently, a quite similar process was worked out for the recovery of titanium and it was in commercial operation in the year 1938, during which the production totalled about half a ton (metric). The demand, especially for pure zirconium, increased considerably during the war, attaining a total of about 48 tons during the period October, 1939, to the end of 1944, and reaching a peak of more than 15 tons in 1943. In 1944, the plant was slowed down due to the frequent and disastrous bombing by the Allies, especially in March and September.

Jan 1, 1946

By S. Fabich

Since the very beginning of Polish copper mining, special consideration of sink shaft techniques through highly saturated Cenozoic rocks was required. Shaft freezing has been chosen as a method to consolidate these rocks. Due to the rock mass structure and water inflow potential, shaft sinking without freezing was considered dangerous. In the course of time, rock mass freezing technology and experience were evolved and this technology became safer and more reliable. New techniques appeared not only in the technical method of freezing, but also in the matter of designing. Computer aided techniques allow engineers to make a detailed analysis and view of freeze wall development. Nevertheless it is important to determine basic thermal rock properties. In this paper, the evolution of knowledge and engineering experience taken in Polish copper mines and current knowledge level in that matter were shown.

Aug 1, 2013

By L. Sun

Recently, micro-tubular solid oxide fuel cells (SOFCs) have attracted the attention of many researchers because of their numerous advantages over larger tubular and planar SOFCs. These include excellent thermal shock properties giving rapid startup/shutdown capability, a high volumetric power density compared to larger tubular SOFCs, and reduced sealing problem compared to planar SOFCs. In order to screen cathode materials for micro-tubular SOFCs, the perovskite cathodes were deposited, using a variety of methods, on 10.5 mol % yttria-stabilized zirconia (YSZ) tubes. Their electrochemical properties were then evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods, based on a three electrode configuration, and with the reference electrode position carefully optimized. The oxygen reduction reaction kinetics at the cathode/electrolyte half cell were then investigated in detail.

Jan 1, 2005

By M. R. Julien

"The geomechanical behavior of rocksalt shows very distinctive features. The response of this most ductile of all low porosity rocks is dominated by inelastic processes that are strongly time- and historydependent. These characteristics must be taken into account when analyzing underground openings. Different constitutive models have been proposed and used for this purpose, and this paper presents the general formulation and applications of one of these. The SUVIC model relies on a unified approach with internal state variables producing mixed hardening to represent the inelastic behavior, which lead to specific solutions for plasticity and creep. The model equations have been implemented into a finite element code to perform numerical analyses. Simulations results are presented to show that this model captures essential aspects of rocksalt behavior under simple and complex laboratory testing conditions. Simulations are also conducted to analyze the response of underground openings. INTRODUCTIONPredicting the response of man-made excavations in rocksalt can be quite a challenge as it requires a reliable constitutive model to represent the material behavior. This softest of all low porosity rocks shows a highly non-linear inelastic behavior, very sensitive to history and rate effects (e.g. Senseny et al., 1993; Cristescu & Hunsche, 1997; Julien, 1999; Wittdke, 2014). The many deformation (micro) mechanisms acting locally in rocksalt make the construction of appropriate constitutive equations quite complex. Nonetheless, there have been significant progresses made over the last two decades or so; many of these developments have been included in a series of specialized Conferences Proceedings (Ghoreychi et al., 1996; Aubertin & Hardy, 1998; Cristescu et al., 2002; Wallner et al., 2007; Bérest et al., 2012)."

Jan 1, 2015

By F. S. Thurner

This paper, a description of the new ore-unloading and stockpiling facilities at the Sydney Works of DOSCO Steel Limited, deals with a new approach to arrive at the most economical solution to combine ore unloading facilities for common bulk carriers and for different types of self-unloading vessels. Also discussed is the design and installation of a 1-mile-long steel-cord belt conveyor sys-tem with a most modern type of mobile belt conveyor stacker, along with automatic and semi-automatic controls for the entire ship-unloading and stockpiling operations.

Jan 1, 1968

By J. H. Douglas, A. F. Matheson

"The Hard Rock is the most easterly producing mine in the Little Long Lac area. The Company was formed in 1934 to develop a surface showing of gold in quartz made by a prospector, W. W. Smith, in 1931. Although some ore was eventually produced from this discovery, the principal orebody, hidden below 10 feet of muskeg, was found about 1,000 feet to the north by exploratory diamond drilling early in 1938 from the No. 2 shaft workings at the 250-foot level.Production started in 1938 and to January 1, 1947, 201,000 oz. gold had been obtained from 1,165,282 tons of ore mined and 869,397 tons milled. Of this ore about 15 per cent came from the development and mining of the original orebodies discovered at the surface. The remainder came from the ore found by the underground diamond drilling done in 1938. Of the latter ore, the Company estimated, at January 1st, 1947, only 140,000 tons remained. The orebody, therefore, contained approximately 1,100,000 tons.OREBODIES AND GENERAL GEOLOGYThe orebodies of the Hard Rock mine are of two main types: the quartz ore of the south and No. 1 shaft zones, and the sulphide ore of the north zone. The quartz ore consists of white quartz veins mineralized with sparse, fine, light-coloured pyrite, or, less commonly, nests of coarse, crystalline, light pyrite. A little tourmaline, scheelite, pyrrhotite, chalcopyrite, arsenopyrite, and native gold are also present. Native gold occurs in a few places in quartz veins in exceedingly rich cemcentrations, apparently where there are large, light-coloured, pyrite crystals of imperfect form. The ore of the north zone is massive pyrite with arsenopyrite and in places pyrrhotite. Many short irregular quartz veins, from a few inches to 2 feet in width, are also present, but the quartz forms a very small percentage of the whole. The veins may be flat to vertical, and sulphides on one or both sides replace the host rocks. The gold is closely associated with the sulphides . The quartz is commonly barren except where it contains sulphides or along the borders of the sulphide ore zone where native gold is not uncommon in quartz stringers."

Jan 1, 1954

By T. L. Tanton

Introduction Sturgeon River area, on the east side of lake Nipigon, Ontario, was the scene of a gold rush in 1934. According to press reports, the active staking during the latter part of the summer spread out rapidly from the early holdings until it embraced practically all of the lower basin of Sturgeon river in a belt up to ten miles wide extending west from Kinghorn for 35 miles to lake Nipigon. And, before winter set in, active prospecting and claim staking reached beyond lake Nipigon to areas where belts of ancient schists were known, notably west of Obonga lake. The writer's familiarity in past years with the areas to which attention has been directed admits of some observations on means of access in the field, the general geology, and the progress that has been made in identifying formations favourable for the occurrence of gold. Canoe Routes From the writer's observations in Sturgeon River area in 1917 and in the Obonga Lake area in 1933, it is recalled that there is, locally, a striking dif~ ference in the accessibility of the two areas by travel along canoe routes. Sturgeon River area is easily accessible from Kinghorn or Jellicoe stations on the Canadian National railways. Many small lakes, commonly of the linear type and with elongations east and west, occur among the forested rocky ridges near Jellicoe (Figure 1) and to the east and west along, or adjacent to, Sturgeon river. This stream has long stretches with gentle current between the falls and rapids. The drainage system provides excellent canoe routes (Figure 2), and the interruptions to travel (Figure 3) are remembered .as scenic features that were passed by portages with firm footing. West of Obonga lake, the streams flowing easterly to lake Nipigon may be followed through scenic canyons to a plateau of law relief characterized by extensive muskegs and shallow, brown-water lakes; and along small streams, where beaver dams have been destroyed, there are muck ponds where the usual alternatives of paddling or portaging can be dismissed in favour of the 'moosing' method of progress with the canoe (Figure 4).

Jan 1, 1935

By J. Palarski

Hard coal, mined in Silesia Region as well as in the eastern part of Poland, is a key national resource. In Polish underground coal industry, modern mining technologies have been successfully tested and used in the last 50 years. More than 98% of the coal produced underground is extracted by longwall mining method. Current underground coal mining expands into increasing depths. The use of conventional coal extraction methods ? room and pillar and longwall with caving - is becoming increasingly difficult. The coal mining is modifying existing methods and is testing innovative technologies. Backfill is an important component of modern underground mining operations. In Polish underground mines, backfill is recognized as an integral component for extraction of coal from greater depths in a densely populated environment. The modifying and innovative methods require the use of backfill or grouting of caving to provide structural support in underground excavations and to ensure that the mining operations are safe. Depending on the geological structure, mining conditions and environmental requirements there are several variations of longwall methods used in underground coal mining in Poland, in particular: longwall with caving, longwall with backfill, longwall with grouting of caving area. This paper will discuss the different components of an effective longwall production and filling process of caving area. The paper will give a overview of the current application of backfill technology, focusing on Polish coal mining operations. This paper will also briefly describe how backfill contributes to an innovative method ? underground coal gasification. The paper discusses specific requirements for fill materials and the technology of backfilling for underground coal gasification (UCG) operations and problems of implementation and correlation of backfill parameters with other processes that occur during thermal processing of coal.

Aug 1, 2013

By Eugene Larochelle

The serpentine of the Eastern Townships of Quebec is more or less seamed and impregnated with chrysotile asbestos, of which we note two types: the cross-fibre and the disseminated fibre. The cross-fibre type always appears in fibres or crystals arranged parallel to one another, and disposed at right angles to the walls of the matrix serpentine. The length of fibre of these veins, which run in every conceivable direction, even crossing ?one another, varies from microscopie dimensions to three and sometimes four and even five inches. It is the principal form of asbestos found in the serpentine of Thetford Mines, Black Lake, Coleraine, and Asbestos. The disseminated-fibre type, which is the main product of the serpentine of Broughton township, in which ate located the mines at East Broughton, does not form veins, but occurs in the serpentine without any definite arrangement. There is a difference in the toughness and hardness of the rock of the two types, the Broughton serpentine being softer than that at Thetford. The disseminated-fibre section of the serpentine belt is probably more regular in its content than is the cross-fibre section. Nevertheless, it contains no 'crude,' which is the most valuable of asbestos, and the fibre is usually shorter than the cross-fibre average.

Jan 1, 1928

By Alan Bauer

IN RECENT PAST YEARS, the mining industry has expanded rapidly and mining engineers have not been generated in sufficient numbers to sustain this growth. Canada has not been alone with this problem, which has resulted in considerable soul-searching as to what the solution might be. Because of the unfavourable economics of running small departments such as mining, metallurgy, ceramic engineering, etc., one approach in some cases has been to put these departments together to form a department of mineral science which now has a broader base structure. Another solution has been the "conversion kit" program which has been conducted both at universities and in industry. At universities, such programs have consisted of converting graduates of other engineering disciplines into mining engineers. In some of the large mining corporations, extensive training programs have been used with the same aim.

Jan 1, 1972

By S. Razavialavi

In the planning phase of every construction project, layout of temporary facilities is a crucial task; site layout can affect safety, travel cost and time, construction productivity, and space utilization. However, site layout planning can be a complicated problem, due to the interdependency of influencing factors. Although interaction among activities is one of the major drivers of site layout planning, it has not been properly addressed in past research. In this study, simulation is presented as a promising tool to address this gap. The capability of simulation technology to model complex processes in construction projects makes use of simulation tools in site layout optimization problems effective, while existing methods are unable to perfectly model these problems, in some cases. Additionally, the advantages and challenges of implementing simulation are assessed and a generic framework for simulation application in site layout planning is proposed.

Aug 1, 2013

By F. Andrieux

"Extruded aluminum profiles are increasingly used for lightweight vehicle construction. Since fracture strains of aluminum profiles are relatively low, damage modeling is crucial for reliable crash simulation. For aluminum profiles, not only the stress state but also the orientation influenced both the deformation and damage behavior. For the material characterization smooth tensile tests were performed in six orientations, both stress-strain curves and r-values were registered. Moreover notched tensile and shear-tension tests were performed in three directions. Finally punch specimens were tested to investigate biaxial loading. Digital image correlation (DIC) analyses were performed to determine local strain values such as critical values at failure. Numerical investigations were conducted with the strain based damage model GISSMO, which is well suited and widely applied for crash simulation. For a strain based failure model the choice of the deformation model is crucial. Deformation models with increasing complexity were investigated to find the best compromise over all experiments. It was found that there is still a great requirement on development of a material model which describes the orientation dependence of the hardening behavior over all stress states in order to be able to use a strain based failure model reliably.INTRODUCTION Weight reduction is an important step for less energy consumption and as a consequence aluminium is increasingly used in automotive parts. An important field of application is the well-established aluminium extrusion which allows the realisation of quite complex shapes of profiles required for an innovative lightweight design with integrated functions. Typical applications are chassis parts, bumpers, crash elements, air bags, etc. Especially the Al–Mg–Si medium strength alloys of the 6000 series can be easily extruded to form complex profiles and prevail for extrusion. Since fracture strains of aluminum profiles are relatively low, damage modeling is crucial for reliable crash simulation. For aluminum profiles not only the influence of the stress state but also the orientation with respect to the extrusion direction have an influence on both the deformation and damage behavior and need to be characterized. The effect of orientation on deformation behavior has been intensively investigated in the last decades and material models haves been proposed (e.g. Barlat & Lian, 1989; Barlat, Lege, & Brem, 1991; Barlat et al., 2003) to describe accurately anisotropic behavior. However it can be noticed that the parameters of anisotropic material models often rely on the yield stress in different directions, which means that the effect of strain hardening is not automatically accounted for. The accuracy of the models at large deformation is not guaranteed and has to be verified. In contrast to deformation models both the characterisation and the modeling of anisotropic damage behavior are not systematically studied. Isotropic failure models based on a critical strain as function of stress triaxiality (ratio of the hydrostatic stress to von Mises equivalent stress) are widely used for crash application (e.g., Bai & Wierzbicki, 2010; Sun, Andrieux & Feucht, 2009; Sun et al., 2013). The mechanisms of failure are manifold and not fully understood; to develop an anisotropic failure model it is mandatory to also have experimental data in different orientations for loading scenarios other than uniaxial tension, e. g. shear, biaxial tension, which implies an extensive experiment plan. This makes the development of failure models more challenging than deformation models for which it is possible to develop a reasonable anisotropic model using the framework of yield function and calibrate the material parameters based on results of tensile tests in different directions. Moreover the development of deformation and failure models are intricate as the variables governing the damage evolution are predicted by the def"

Jan 1, 2018

By P. Molera

"In Catalonia, between the 10th century and 1878, some installations were developed which at first were called ""factories"" and later ""fargas"", since they manufactured iron and steel of low carbon content. Because of its excellent quality, the fame of this metal spread from Catalonia to many countries. Fargas were started in Corsica, the Low Countries, Germany, Oriental India, Madagascar, Finland and along the rivers Orinoco and Mississippi among others. The extractive process used in these fargas has passed into history as the ""Catalan Farga Process"", ""Catalan Process"", or just ""Farga Catalana"". With this technology, raw material was obtained for the fabrication of tools, nails, weapons, grilles, etc. to supply the national and export markets. Aside from meteorites and native iron, found as metallic nodules in basalts in Greenland and Palestine, the ancient civilizations, which had no means to reach the fusion temperature of iron (1535°C), obtained iron by a direct process. Similar processes were used until quite recently (1930s) by certain tribes in Central Africa; holes in the ground were filled with iron ore and coal, and combustion encouraged by blowing air by mouth or with bellows made of animal skins. Thus without melting the iron it is possible to reduce the mineral and obtain a porous and impure metallic mass, which is purified on forging by mechanical squeezing. With a process very likely similar, the famous column at Dehli weighing 6.4 m.t. was built about 300 B.C."

Jan 1, 1999

By S. H. Logan

The present discussions throughout the civilized world on the subject of gold for monetary purposes may seem due to general economic conditions during the past year. But for some years previously a small group of authorities had warned the world against the continued disregard of an equitable distribution of existing gold reserves, and had urged the necessity of keeping the supply of new gold equal to the monetary demand, which, according to world production and trade figures, increases on the average about 3 per cent per annum. In 1927, Sir John Aird, the President of The Canadian Bank of Commerce, stated that the United States could spare a billion dollars of the supply it then held, 4 ½ billion dollars. About a year and a half ago the Professor of Banking and Currency in the University of London, Mr. T. E. Gregory, said, "If the world finds it impossible to modify its habits so far as to make an organized effort to economize gold seem less Utopian, it must be prepared to pay for its bad habits, in this and other respects, by a possible loss of material welfare." These clear-cut statements were not heeded, perhaps for one reason because most countries were in the flush of prosperity, and making such great demands upon the mining fraternity for industrial materials as to distract attention, at least to some degree, from gold mining. Now the world knows it faces serious problems, first, of making? fully effective its present monetary reserves, which, although badly distributed, are as a whole ample for the needs of the present, and secondly, of preventing a shortage in the supply of new gold, one that may come within the next few years if the present sources of supply are not enlarged, and if there is no marked change in the technique of gold production.

Jan 1, 1931

By G. M. Ritcey, K. E. Haque

"Laboratory-scale sulphuric acid leach tests were conducted on Elliot Lake and Rabbit Lake ores in the presence of various oxidants, namely: Fe2(SO4)3, CI2, H2O2, NaClO3, MnO2, H2SO5, HNO3, Oxon e, K2Cr2O7, KMnO4, O3 and O2. Uranium extraction is significantly accelerated when an oxidant is present in the leach slurry. Uranium extraction of 96-99% can be achieved by maintaining the oxidation potential of the leach slurry in the range of400 to 500 m V (S.H.E.). A rough cost comparison of all the oxidant s indicates that the use of Fe2(SO4)3, 02, O3, C12, HNO3 or MnO2 is far less expensive than NaClO3 and the uranium extraction rates are similar to or better than with NaCIO3. For uranium extraction, it is concluded that gaseous oxygen (i.e., air or oxygen) would be the most effective and economical oxidant for the 24- to 36-hour leach of Elliot Lake ore; whereas for the 8- to I2-hour leach of Rabbit Lake ore, a strong chemical oxidant (e.g. NaCIO3, H202, 03, K2Cr2O7, H2SO5 or HNO3) would be a logical choice.IntroductionThe common practice for the treatment of uranium o res is leaching with sulphuric acid or with a carbonate-bicarbonate mixture. Generally, the latter process is ad opted when an excess (> 18%) of acid-consuming components (e.g., carbonate) is present in the ore. Irrespective of the nature of the leachant, the addition of an oxidant to the leach mixture is necessary to obtain a high uranium extraction.The maximum extraction of uranium can only take place when all the uranium is in the highest oxidation state (i.e.,U +6-uranic ion) . Because a certain percentage of uranium present in the ore is invariably in the lower oxidation state (i.e.,U+4-uranous ion) , the addition of an oxidant to the leach slurry is necessary to oxidize uranous ion to the uranic state."

Jan 1, 1982

By G. M. Ritcey, S. H. Lucas

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."

Jan 1, 1980

By R. D. Brown

"AbstractOver the past five years, tax rates in the Canadian mining industry have skyrocketed upward across Canada, as both federal and provincial governments have sought to increase their share of mining revenues.However, the past few years have not only brought high tax rates to the industry, but also a number of important new federal and provincial tax incentives.In large part, these incentives ~ special credits or reduction in tax for carrying out specific exploration, processing or other activities - have helped to moderate the adverse effects of the higher tax rates and have provided inducements for exploration and processing activities which might not otherwise have been undertaken.However, the effectiveness of certain of these incentives can be questioned: our over-all tax structure now consists in large part of punitively high marginal rates with some extraordinarily generous but capricious tax reductions for specific activities and may not be in the best long-term interest of either the industry or the nation.A rational tax structure, with moderate and stable tax rates, together with reasonable incentives confined to activities specifically requiring them, could be a more effective spur to investment than the present tax and incentive jungleIntroductionIN THE YEARS since federal tax reform, the mining industry in Canada has faced a continued escalation in its tax burdens as federal and provincial governments have leapfrogged each other in imposing new and higher taxes on the industry. The result has been that marginal tax rates imposed on mining and processing activities throughout Canada have jumped to hitherto unparalleled levels."

Jan 1, 1977

By Peter A. Amelunxen, Richard LaDouceur, Courtney A. Young

"Many of the rare earth elements, the lanthanide series on the periodic table, are on the U.S. Department of Defense Strategic and Critical Materials list. In this regard, the U.S. Army Research Laboratory (ARL) has funded several projects at Montana Tech focusing on rare earth element recovery from natural resources. Current froth flotation operations utilize octyl hydroxamate for rare earth mineral extraction, however recovery is not ideal and flotation performance can be improved. Salicylhydroxamic acid (C7H7NO3) was identified as a novel collector due to similarities with n-octyl hydroxamate, notably the amine head group. Salicylhydroxamic acid is primarily used in the medical industry but due to the amine head group is ideally suited as a collector for rare earth mineral flotation.Parametric studies were performed for the flotation of rare earth minerals by modifying a wide range of variables. Mechanical variables of a 6L bench scale flotation cell, such as air inlet flow, rotor speed, and milling time for liberation were modified to elucidate energy input parameters for the desired minerals. Chemical parameters such as collector concentration and pH were varied to understand solution chemistry considerations of the salicylhydroxamic-rare earth mineral system. The study obtained a statistically significant experimental model for the flotation of rare earth minerals. A two stage compartmental model was also utilized for the determination of the first order flotation rate constants for each mineral. Optimized recovery of rare earth minerals was found to occur at near neutral pH ranges using salicylhydroxamic acid with maximum recoveries approaching ideal industrial standards although rare earth mineral grades were still not sufficient.INTRODUCTIONRare earth elements (REEs) are found in minerals that contain several REE which makes costeffective separation of the rare earths difficult. Significant scientific challenges have hindered mineral separation. The molecular similarity of rare earth elements results in minerals containing several REEs, such as bastnaesite [(Ce, La) CO3F]. This prevents efficient separation during concentration steps, for instance flotation, and has a direct impact on successive metallurgical processes. Consequently, concentration during flotation is of rare earth minerals (REM) as opposed to REE."

Jan 1, 2016