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By H. Henao, E. Kohnenkamp, L. Rojas

The slags generated in the copper conversion process are mainly composed of Cu2O-Fe2O3-SiO2 with the compounds CaO and Al2O3 in concentrations up to 10 wt%. The present work contributes to the knowledge of the conversion process, generating experimental data for the diagrams of phases Cu2O-Fe2O3- SiO2-Al2O3 and Cu2O-Fe2O3-SiO2-CaO. The experiments were carried out in a tubular furnace at temperatures of 1150°C and 1200°C under a condition of saturation with tridymite. Once the equilibrium was reached, the samples were fast quenched in water. The phases in the samples were observed in a Scanning Electron Microscope (SEM) and the elemental composition of the phases analyzed by means of Energy-dispersive X-ray spectroscopy (EDS) detectors. The addition of Al2O3 and CaO into the Cu2O-Fe2O3- SiO2 system resulted in an appreciable displacement of the liquidus lines, corresponding to an expansion of the liquid in the tridymite primary phase field. INTRODUCTION The conversion process of copper consists of oxidizing Fe and S present in mattes with 60 to 65wt% Cu (up to 16wt% Fe). This process is separated into two stages: 1- Slag blowing: Fe is oxidized, the addition of a flux such as SiO2 (silica) forms a second liquid phase called slag, this phase is removed from the furnace; 2-Copper blowing: in this stage, the matte with low concentration of Fe (<1% w/w) is again oxidized to remove S as SO2 in the exhaust gases. The product of these two processes is the formation of Copper Blister (> 98wt% Cu) (Schlesinger et al., 2011). Unlike the aforementioned conventional processes, in most Chilean smelters, conversion Peirce- Smith Furnaces are loaded with high copper matte (70–75wt% Cu) (Henao & Moyano, 2016). Due to the low concentration of iron in these matte (up to 5wt%), it is considered that separating the conversion process in two stages is neither operational nor environmentally convenient. Therefore, the process is carried out in a single stage (Pradena et al., 2006), generating a slag phase with a high percentage of Cu2O (wt%Cu>40).

Jan 1, 2019

By F. Rosenblum, P. Spira

"Self-heating of broken sulphide ore or waste rock underground can lead to ignition and cause serious problems in a mine operation. An extensive study has demonstrated that it is caused by oxidation of certain species of pyrrhotite. Self-heating was found to take place in two stages, first progressing from ambient temperature to 1000C with exothermic formation of elemental sulphur in the presence of moisture and oxygen, and proceeding to a second stage in which the sulphur oxidizes to SO2. Ignition may eventually follow. An apparatus was developed to assess the propensity of sulphide rock to self-heating and the potential for hazardous behaviour. The effect of temperature, time, rock size, and surface treatment with chemicals is presented. On the basis of these results, possible approaches for preventing a runaway reaction are suggested for further investigation.IntroductionThe oxidation of sulphide ore, waste rock or tailings backfill, which may cause hazardous conditions underground through heating, oxygen depletion and, in some cases, fire, is well documented (Farnsworth, 1977; Ninteman, 1978; Rosenblum et al., 1982; Reimers, 1987). The self-heating mechanism, nevertheless, has not been satisfactorily explained. The onset of heating from ambient temperature, in particular, has not drawn the attention of researchers. In the course of a previous study (Rosenblum et al., 1982) aimed at finding a method to assess the hazard from using sulphide tailings as backfill, the authors developed an apparatus to measure self-heating rate under controlled, near ambient conditions. This has since provided decisive information in backfill investigations in the Noranda Group.The test methodology devised for tailings failed to predict self-heating in a broken waste rock known to be active. Upon repeated testing, however, a freshly crushed sample began to exhibit appreciable heating and oxygen uptake (Fig. I). After 14 tests, the self-heating rate reached a plateau of about 4O°C/h and then fell progressively to < 5°C/h after 30 tests. It was hypothesized that weathering in the presence of moisture and oxygen during testing had caused the onset of self-heating. Active tailings, on the other hand, are exposed to natural surface oxidation and need not be weathered to show heating. Based on this finding, a new apparatus was developed capable of simultaneously weathering a sample of rock and monitoring its self-heating behaviour."

Jan 1, 1995

By John O. Marsden

Technology development and innovation has played a crucial role in the copper industry throughout history. The effective development and implementation of new technologies allows mankind to produce copper at progressively lower cost of production at a given feed grade and mineral type. This progress serves to counteract cost escalation over time and, depending on the magnitude of the cost benefit, allows ore cut off grades to be reduced thereby improving the availability, accessibility and utilization of mineral resources. The development of step change technologies that can offer >$0.15/lb total cost benefits provides a significant opportunity for producers to achieve competitive advantage, but it has been argued that rapid dissemination of technology makes such competitive advantage unsustainable over time. This paper presents the results of a recent study that evaluates a number of historical and emerging step change technology case studies in the copper industry and quantifies the associated cost benefits for users, the impact on the production cost curve, and the duration of such cost benefits for various categories of implementers: first mover, fast follower, conservative followers and laggards. The results provide a compelling case for major, mid-tier and emerging copper producers to invest in technology development initiatives if they wish to achieve and sustain competitive advantage over the long term. INTRODUCTION AND BACKGROUND A key issue for mining companies is how much time, effort and cost to spend on research and technology development (R&TD). The economic drivers for technology development and implementation are poorly understood in our industry and the business case is clouded by some notable and well-publicized failures (McNulty, 1998). Mining companies are in business to deliver financial returns to investors. This means delivering short term results on a quarter-by-quarter reporting basis as well as sustaining and growing the company to retain and reward a sustainable longer term investor base. The cyclical nature of the commodity metal markets makes it challenging to maintain investment in research and step change technology development: Mining companies must manage through the highs and the lows of price cycles, typically ranging from 5-15 years in length. The discounted cash flow approach to investment evaluation results in weak financial justification for R&TD expenditures. A clear and compelling rationale to support longer term investment in research and step change technology implementation is required.

Jan 1, 2019

By Alain Tshilombo, Vijay Reddy, Chowdary Meenavilli, Kelvin Buban, Cory Kosinski, Sriraj Meenavilli, Siddhartha Tirumalaraju

The use of artificial intelligence (AI) for process optimization is expected to play an increasingly important role in the future of the mining industry. The objective of AI is to develop a data driven soft (virtual) sensor using historical data that can estimate unmeasurable characteristics of the process and provide appropriate recommendations during operation to optimize the process through continuous learning. The application of AI to a hydrometallurgical process was evaluated by Sherritt Technologies in coordination with NTWIST. Historical operating data obtained from the Ambatovy facility’s High Pressure Acid Leach (HPAL) circuit was used to develop models to predict autoclave discharge parameters based on operating conditions and ore mineralogy. The prediction models were developed in such a way to also allow the user to simulate and test different operating conditions. A second set of models (AI model) were developed based on the prediction models, economic data and operating constraints for a given process unit to identify optimal reagent and steam dosages across the HPAL circuit. The development of these models was significantly complex due to the dynamic and interactive nature of the HPAL process. Despite the complexity of the models, the models were able to predict, with accuracy, the relationship between ore composition, leach autoclaves retention time, acid addition and steam addition with metal extractions as well as levels of impurities in the autoclave discharge slurry. The study showed that AI has the potential to improve the overall operation of a facility through providing tools to assist with training, troubleshooting and process optimization. INTRODUCTION The Ambatovy project, located in Madagascar, is one of the world’s largest nickel and cobalt mining and processing operation, with a design capacity of 60.000 tonnes of nickel and 5,600 tonnes of cobalt per year (Collins et al., 2016). Commissioning and start-up of the Ambatovy mine and plant facilities were completed in 2012, with acid first introduced to the ore leach in March 2012. Commercial production (defined as 70% of design capacity) was achieved in January 2014 and the production level required to achieve financial completion (90% of design capacity for 90 days) was achieved in March 2015 (Valle et al., 2016). Figure 1 shows a simplified flowsheet of the hydrometallurgical pressure acid leach (PAL) process employed by Ambatovy.

Jan 1, 2019

By Ata Akcil, Z. B. Karshigina, Ye. G. Bochevskaya, Z. S. Abisheva

"Phosphorus slag is the most heavy-tonnage waste of yellow phosphorus production, which is stored in the dump fields for many years creating ecological problems in the regions. Despite of the actions taken to utilize the slags, most of them remain in the slag disposal area. One of the relevant and priority directions is rare-earth metals production (REMs), presence of which in the phosphorus slags allows considering the latter as an acceptable raw material source. Phosphorus slags contain about 30–40 wt% of silicon dioxide, therefore they can serve as a source of production of precipitated silicon dioxide highly required in different industries.The purpose of this work is the most complete REMs recovery in the solution while leaching and subsequent processing of siliceous cake. The work shows results of researches on establishment of the chemical and phase compositions of phosphorus slags, determination of the forms of presence therein of REMs compounds, processes of phosphorus slag leaching by nitric acid and processing of produced siliceous cake by NaOH solution.Based on the data of the instrumental and chemical methods of phosphorus slag analysis, it was established that it consists of pseudowollastonite a-CaSiO3 for 90–92%. It was found out that REMs are present in it in the form of carbonate apatite Ca10(PO4)6CO3 or rare earth apatite, and La2S3 compound inclusions.Optimum parameters of phosphorus slag leaching process were selected: HNO3 concentration 7- 7.5 mol/L; L/S ratio = 2.6–3 mL/g; temperature – 50–80o?; duration – 1 h; pulp stirring – 500 rpm. Recovery of SREMs, CaO, Al2O3 and Fe2O3 into the solution were achieved at 98.0, 99.1, 99.0 and 18.8%, respectively. Presence of 10 elements of the rare earths group in the phosphorus slag was established. It was found out that recovery of almost all REMs is within ~92–99%, except for Sc and Lu – ~39% and ~28%, respectively.For the purpose of optimization of siliceous cake leaching by NaOH solution, influence of some physical and chemical parameters was studied: N?O? concentration, L/S ratio, temperature, and duration. Results of the experimental data will serve as a basis for development of the technology of complex processing of the technological waste of phosphorus industry with production of REMs concentrate and precipitated silicon dioxide."

Jan 1, 2016

By B. Adams, T. Angelov, G. Sasov, D. Steinhilber, A. L. Tsekov, S. Neufeind

A complementary ion exchange/solvent extraction process for the recovery of copper from low- grade ores is described. It has successfully been implemented on a full-scale plant level at the Buchim Copper Mine in Macedonia, yielding a maximum copper cathode production of 2400 tons per year. Compared with conventional SX/EW operations, this technology makes the exploitation of low-grade copper ores economically attractive, due to reduced operational and capital expenditures. Furthermore, the additional Lewatit® ion-exchange installations diminish the volumes of harmful organic substances in the following SX step and minimise the risks associated with the handling and usage of these chemicals, such as environmental pollution or fires. Finally, the significantly diminished quantities of liquids for the SX operation have a tremendous effect on the footprint of the plant (ca. 50% less) thereby leading to a reduction of capital expenditures. This paper reviews the main stages of the combined IX/SX process, the applications for metal recovery and introduces projects where the process is applied. Key findings of the process are also presented. A comprehensive technical comparison between processes has been carried out. This paper also evaluates the advantages of using combined IX/SX technology as a purification and separation step in copper production process, with the aim of further increasing the overall copper recovery and to ensure that a suitable copper concentration in the advanced electrolyte is achieved. The implementation of a Ion Exchange (IX) process in the classic Solvent Extraction-Electrowinning process(SX/EW) is found to be beneficial for processing of pregnant leach solutions both from spent and new copper heaps and dumps, acid mine drainage and other industrial streams without any preconditioning as well as in terms of achieving improved recoveries and copper cathode quality. INTRODUCTION The concentration and separation of copper from primary leachates is one of the key operations in the hydrometallurgical processing of oxide ores (Langner, 2011). Conventionally, this basic operation is conducted by submitting the pregnant leach solution (PLS), with a 1–5 g/L Cu content, from the initial sulfuric acid leach to a solvent-extraction (SX) process in which copper reports to the organic phase. After phase separation, the metal is stripped from the extractant/diluent mixture employing sulfuric acid to furnish a concentrated metal solution, usually containing 40–50 g Cu/L. The final products of the overall process are copper cathodes, which are obtained from a terminal electrowinning step.

Jan 1, 2019

By G. Danha, S. Wabula, D. Glasser, D. Hildebrandt, N. Hlabangana

"Impact tests on single particles or a bed of particles are used to determine the fracture characteristics of particles. Many different techniques have been adopted in comminution in order to find ways of optimizing energy consumption in the size reduction process. In this paper, we apply one such method called the Attainable Region (AR) analysis technique to optimize the impact energy on a bed of silica particles. The attainable region is a fundamental approach that is equipment-independent and can be used to analyze breakage processes. The AR is defined as a set of all possible outcomes, for the system under consideration that can be achieved using fundamental processes operating within the system.INTRODUCTIONThe energy crisis in Southern African has reached such critical levels, that most cities in countries like Zambia, Zimbabwe, Lesotho, Swaziland and even South Africa are experiencing load shedding challenges lasting sometimes up to 18 hrs a day. Southern Africa is well known for its riches in mineral resources, and the economies of most states in this region are driven by the mining & mineral processing sector. With the emergence of small scale miners due to government empowerment policies, national energy providers have had to resort to power cuts mainly to domestic users in a bid to cope up with the huge industrial electricity demands.It has been estimated that about 4% of the total energy used in the world is consumed by the mineral processing sector (Fuerstenau & Lutch, 1999). Tomanec and Milovanovic (1994) estimated that milling alone accounts for more than 50% of the total power used in mineral processing, but this can rise to as high as 70% for hard or finely dispersed and inter-grown ores. Today, the greatest challenge in mineral processing is how to optimize energy input to the size reduction process (Dey & Das, 2013; Nomura & Tanaka, 2011), where it has been observed that only a small percentage (1.5%) of the total energy input really does the breaking (Khumalo et al., 2008) while the rest is consumed by the equipment concerned and lost to contacts that do not result in breakage. The immediate benefits of focusing research on the optimization of energy in size reduction operations in the mineral processing sector lies in potential savings on industrial electricity usage that may then be directed towards domestic users."

Jan 1, 2016

By G. Sedelnikova, D. Kim, N. Ibragimova

"The object of this study was three samples of sulfide old tailings, which were obtained after Cu- Zn ores processing. Fine metal dissemination in sulfides as well as fine mineral intergrowth determine the refractory nature of material and low metal extraction using simple methods: gravitation 1-6%, flotation 32-48%, cyanidation 10-37%, and cause the need to use sulfide bio-oxidation to liberate gold and to recover it by heap leaching. The gold is the main valuable metal in the tailings with content 1-1.5 g/t. Heap bio-oxidation with mesophilic and moderately thermophilic bacteria was used for pre-treatment of tailings before gold heap leaching from bio-oxidation solid residues. The tailings have a low permeability < 0.3-1.2 m/day, which is caused by migration of fine particles, decreases recovery rates, and is poorly suited to heap bacterial leaching. Therefore, preliminary gold sulfide tailings with permeability < 0.3 m/day were pelletized using copper containing flotation tailings of converter slags and calcium oxide. The most gold extraction was obtained for pelletized tailings. The base metals (copper and zinc) were precipitated from bacterial solutions. Experiments have demonstrated effective bio-oxidation of all third gold sulfide tailings samples and enough high gold extraction 60-82%.INTRODUCTIONIn Russia, as everywhere, there is a trend toward deterioration in the quality of mineral resources, including non-ferrous and precious metals, manifested in lower grade and higher complexity of ores. The proportion of refractory ores is increasing, characterized by fine dissemination of metals in sulfides, intergrowth, and poor liberation of minerals during concentration, resulting in loss of base and precious metals to flotation tailings.Over the operation period, huge reserves (hundreds of million tons) of ore processing waste have been accumulated at mining and concentration operations. Because of the imperfections of the previously used ore concentration technologies, the content of precious and base metals in flotation tailings is comparable with the grades of the ores being currently processed. Therefore, old tailings can be viewed as an additional reserve of non-ferrous and precious metals. The works (DEN, 1997; Lyman, Johnson, & Guerney, 2000) demonstrate that, tailings containing sulfides (sulfur, copper, zinc, and other metals) are a potential environmental hazard since they produce acid drainage water containing toxic components. Processing those tailings would require designing an effective technology for recovering useful components and protecting the environment."

Jan 1, 2016

By S. Eckert, M. Reuter, D. Obiso, S. Kriebitzsch, M. Akashi

The present paper focuses the application of CFD techniques to investigate the Top-Submerged- Lance (TSL) gas injection in liquid metal. Previous works of the authors have shown that up- and down- scaling procedures based on the modified Froude number have some shortcomings, as this approach does not take into account the interfacial and viscous forces. Indeed, surface tension and dynamic viscosity of the smelting slags (σ = 0.4-0.5 N/m, μ = 0.2 Pa·s) are higher than the operating fluids that have been used in literature (water, paraffin oil) to study TSL injection in down-scaled furnaces. In order to get closer to real systems, the authors study the TSL injection of Argon in a liquid metal. An experimental campaign was carried out in the X-ray lab at Helmholtz-Zentrum Dresden-Rossendorf (HZDR), where the eutectic alloy GaInSn was used as liquid phase. The alloy is liquid at room temperature, and X-Ray imaging is used to picture the multiphase flow in a quasi-2D vessel. The aim of the present work is to demonstrate the applicability of CFD techniques to model multiphase flows involving liquid metals, and validate the model using the data produced at HZDR. The commercial software ANSYS Fluent® was used together with the Volume of Fluid model to directly resolve the gas-liquid interphase. Some features of the flow, such as the void fraction distribution and bubble detachment frequency are tracked with CFD and compared to the experimental data. INTRODUCTION In the last thirty years the TSL smelting technology has increasingly been used for industrial non- ferrous smelting processes and is now one of the significant pyrometallurgical processes. Developed in the early 1970’s at CSIRO, the furnace is nowadays commercialized in different market sectors, including copper and lead smelting, zinc fuming, waste treatment and slag recovery (Floyd, 2005). Despite the wide application of these reactors in the pyrometallurgical market, some aspects of the process are still not fully clarified, since in-situ measurements and optical accesses are prohibitive because of the high temperatures and aggressive conditions. Phenomena such as the bubbling regime, the slag solidification and the submerged combustion still need a deeper scientific investigation to obtain a better understanding of the process.

Jan 1, 2019

By R. D. Livingstone

"THE LETHBRIDGE COAL FIELD lies mainly .to the north and west of the city of Lethbridge. Mining carried on in this area for over eighty years until 1965. Before the building of a railway the coal was carried by bullock wagon to Montana for use in smelting, and for a while by river boat to Medicine Hat for railway use. The single, almost flat, worked seam is designated the ""Galt"" seam and is about 1.5 metres thick. It belongs to the Belly River formation and is under cover of 80 to 180 metres of weakly stratified sediments. A complex system of cross faults adds to the mining difficulties. Close timbering required in the entries and rooms reflected in a high timber cost and lower output per man shift. The coal is High Volatile"" C"" bituminous in rank with maximum gross calorific value of 11,200 Btu per pound and with a well defined cleavage. Roof conditions in the field range from very tender and very heavy on the south end of the field and west of the Oldman River to a more stable character to the north. Relatively speaking, the whole field would earn a rather tender rating and definitely so in relation to many U.S. fields. Floor conditions are characterized by a bentonitic type heaving in the south end of the field west of the Oldman river to a more stable situation in the north, which can tolerate shuttle car operation if kept drained. Water problems are minimal, except paralleling the Oldman River, where the seam dips below the river level. While vigilance is necessary to prevent accumulations of gas, the volume is rather limited. The seam was entered by shafts, except where small mines were located along the Oldman river banks and gained access by drifts. The coal seam was developed by driving either 3 or 4 Face entries 2 1/2 metres (8 ft) wide on 18-metre ( 60-ft) centres. Sets of dual butt entries driven at right angles to the Face entries completed development work. Normally rooms up to 8 metres wide were turned off the butt entries on up to 11 - metre centres. These were worked in groups of three to five, depending on the roof conditions, and normally advanced 60 m (200 ft). In some areas rooms had to be abandoned short of their objectives due to roof pressure, heaving floor and intermittent work."

Jan 1, 1985

By S. Torres, J. Álvarez, R. Castillo, R. Fuentes, C. Sandoval, R. Parra, Myakalwar A. K., M. Velázquez, J. Yáñez, D. Sbarbaro

Rapid analytical assessment in copper mining industry is a limiting factor for operational purposes and for the improvement of processes. The present work aims to review the analytical assessment in the copper industry utilizing emerging spectrochemical techniques such as laser induced breakdown spectroscopy (LIBS) and UV-Vis-IR Hyperspectral Sensing. LIBS is a plasma based spectroscopic method where the sample surface is irradiated by high power laser. The light emitted from the plasma contains atomic -molecular spectral information and can be detected using a simple CCD based spectrometer. UV-Vis-IR Hyperspectral Sensing is produced by the reflection of light from the sample’s rough surface in all directions and it can be collected by using an ellipsoid or paraboloid mirror arrangement. The electromagnetic radiation emitted by the samples in the UV-Vis, NIR and MIR region can be used for molecular characterization. The spectrometer splits different wavelengths through a CCD arrangement in 2D spatial and spectral dimensions, thus a hyperspectral cube of data is generated. Chemometric techniques such as principal component analysis (PCA), K- nearest neighbors (KNN), support vector machine (SVM) among others, can be applied to LIBS and Hyperspectral data for better classification and quantification purposes in copper ores. Real- time determination of elemental and mineral species used for online processing control will help to achieve the copper industry 4.0. INTRODUCTION The demand for copper mineral resources is intensely growing with the increase in population, per capita GDP, the development of new technologies and the increase in global living standard. With the rise in consumption of copper, it is important to optimize mining and metallurgical processes tending to the copper industry 4.0 (Ge, Song, Ding, & Huang, 2017). The real-time analytical assessment in the mining and metallurgical processes is a crucial part for allowing the global improvement in mining industry. The features considered for better analytical assessment are the instrumental automation and interconnection, real time results, low cost, quality in terms of accuracy and precision. Furthermore, improving recovery (extraction), timing and quality of final products avoiding environmental impacts. Some elements such as Cu, Fe, Ag, Au, Mo, S, As, Pb, Zn are important to be determined in the process control. Additionally, rapid mineral identification of few species such as CuFeS2, Cu4FeS5, FeS2, CuS, Cu2S, MoS2, Cu3AsS4, FeAsS, among other can be challenging.

Jan 1, 2019

By G. Vibert Douglas

IN a previous paper by Douglas and Gillies (1), a simple field test was given for gold. Later work by the present writers, and by others who have kindly written to us, shows that the test is not as satisfactory as it was hoped. In many cases, the gold mirror is completely obscured by a dense precipitate which, up to the present, it has been found impossible to remove. After many attempts, we have temporarily given up the iodine test and have been working on a simple pyridine reaction based on the work of Putnam, Roberts, and Selchow (2): The ore to be tested is ground to a fine flour. Place half a gram of this powdered ore (an amount that will cover a Canadian ten-cent piece, not heaped) in a six-inch test-tube and add 5 c.c. of aqua regia. The aqua regia. should be made up on each occasion, using four parts of hydrochloric acid and one part of nitric acid, both concentrated. Shake the solution in the test-tube for about one minute and allow to settle until dear. The rime to settle may be 30 to 60 minutes. When dear, a drop of the solution is with-drawn with a fine, dean eye-dropper or capillary tube and placed on à small glass plate. A slide such as is used for mounting rock sections is suitable. Now place an equal sized drop of pyridine solution on the plate beside that of the aqua regia solution to be tested. The pyridine solution, containing nine volumes of hydrogen bromide to one volume of pyridine, can be made up in advance and carried in a glass-stoppered bottle. Join the two drops with a glass thread or fine, dean stick, and allow the merged drops to stand undisturbed. I t is well to place the slide on a piece of white paper so that the presence of the crystals which may form can be easily seen. The time for their formation will vary with the amount of gold present, but the slide should be allowed to stand for at least 30 minutes before negative results are reported. A hand lens of at !east ten magnifications is essential. If gold is present, minute red crystals will form around the margin of the drops as these drops slowly evaporate.

Jan 1, 1938

By Ross Gilders, Leo Cheung, C. David Desjardins

"For the past twenty years significant progress has been made in bacterial leaching. In fact, a recent article in the Northern Miner has cited that nearly all new copper production is based on bioleaching. The bacteria that play the predominant role in bioleaching is an obligate chemolithoautotroph called thiobacillus ferrooxidans. These bacteria thrive in areas rich in sulphide and prefer low acid media. In the simplest sense, they metabolize sulphide converting it to sulphate either as acid or as soluble metal sulphates. This process is well known because these bacteria generate acid mine water. Over the last five( 5) years, we have been carrying out development work on creating optimum bioleach conditions for the extraction of metals from sulphide rich ores and concentrates. Recently, a study was carried out on a byproduct sulphide concentrate produced in a tin flowsheet developed for the Mt. Pleasant Mine of ADEX Mining Corp. The objective was to determine whether a bioleach process might successfully leach this sulphide material which contains copper, zinc, iron and, what is more important, trace metals such as Indium, Gallium, and Bismuth. The current work describes the successful recovery of these metals achieving extractions of more than 80% by applying bioleaching techniques. An overview of this technical program forms the basis of this paper.IntroductionBio-Oxidation of metal sulphides has emerged to be one of the leading edge hydrometallurgical processes for the economic extraction of metals from ore and concentrates. The fundamental process involves the bacterial assisted oxidation of sulphide to sulphate yielding metal sulphates which can be subsequently leached by conventional means. The bacteria that play the predominate role is an obligate chemolithoautotroph named thiobacillus ferrooxidans (TF). These bacteria thrive in areas rich in sulphide and occur naturally worldwide. In fact, TF is responsible for generating acid in water (acid mine water) from exposed sulphide surfaces primarily through the oxidation of pyrite. TF bacteria thrive under the proper conditions of temperature and oxygen supply in the presence of sulphides and populations in excess of a million per millilitre (ml) of solution are achievable. Typically, at room temperature, the bacteria will bio-oxidize in a pH range of 1.0 to 3.0. Today, bio-oxidation has been applied commercially with great success for the extraction of uranium, copper, and gold."

Jan 1, 1996

By J. P. Aiello

"INTRODUCTIONWhile this paper deals specifically with potential coal use at the Cold Lake Project of Esso Resources Canada Limited, a majority of the technical aspects of coal conversion could apply to any oil field and industrial boilers or stearn generators. In 1962, Imperial Oil Limited&apos;s production arm (the forerunner of Esso Resources), began examining methods of extracting bitumen from a 50 m thick layer of oil sand buried 450 m below the surface in the Cold Lake area. Almost two decades of research followed to develop an in situ oil sands recovery technology that made commercial production feasible.A $13 billion mega project that would have produced 22 000 m3/d (141 000 barrels/day) of synthetic crude oil (160 000 bpd of bitumen) was shelved in 1981, and ultimately replaced by a phased development strategy, involving smaller production units, to bring blended bitumen production on stream as markets and prices permit.The first two phases came into production in 1985. There are currently a total of six phases in production with four more in the construction stage. Each phase has 130to 140production wells (initially) and a central plant with water treatment, crude treatment and stearn generating facilities capable of producing 150 m3/d (9500 bpd of raw bitumen). The stearn generation section for each phase consists of three 180millionBtulhour oil fieldsteam generators.In its natural state, the bitumen is too thick to be recovered using conventional oil recovery techniques. At the Cold Lake Project, bitumen is recovered by a method called cyclic stearn stimulation. Water is pumped to the central plant where it is treated and heated to produce high pressure, high temperature steam. During the steam cycle, this steam is transported in insulated pipelines to the wells for injection into the oil sand formation. This cycle lasts from 30 to 50 days, heating the formation and causing the bitumen to flow. Following an initial flowback period, a surface based artificial lift system pumps the heated liquid bitumen, mixed with water and gas, out of the well and back to the central plant. The water and gas are separated from the bitumen, with the gas being used to provide some of the fuel for the stearn generators and the water being treated and recycled. Approximately 5% of the water cannot be recycled and is disposed of by injection into deep formations . The bitumen is blended with a diluent and shipped by pipeline to market."

Jan 1, 1989

By F. W. Wellmer

"This paper discusses the changing nature of reserve/consumption ratios, using data from Canadian operations and focussing particularly on copper.IntroductionStudies in world metal consumption and world metal reserves are done regularly by the U.S. Bureau of Mines, the German Federal Institute of Geosciences and Raw Materials, and other institutions. Formerly, on the basis of these data, the following figures were calculated:• a static lifetime of reserves-reserves at year end divided by the consumption of the previous year;• a semidynamic lifetime of reserves-reserves at year assumed constant growth rate.These figures were severely criticized because they were purely theoretical and did not consider the availability of the raw materials.Recent practice is to calculate reserve/consumption ratios (R/C ratios) for periods(1) or for different years(2,3) and to interpret the trend. For base metals, these R/C ratios are increasing (Table 1). This had led to the conclusion that today the relative availability of base metal reserves has increased as compared to 10 or 15 years ago(4,5) As there are normally numerous deposits for each commodity, the anticipated production rates of deposits are irrelevant to this conclusion as long as the statistical distribution of possible production rates does not change significantly.The above conclusion is only justified if the quality and the nature of the data base remain the same. This is certainly the case for the consumption data. It is also assumed for the quality of the reserve figures, which usually take into account only proven and probable reserves. For the nature of the reserve figures, however, this does not seem to be true.Undoubtedly, the reserves increased in absolute terms between 1966 and 1978. To put the absolute reserve figures into perspective, it is common, as said above, to compare them with the mine production, which increased in the free world between 1966 and 1978; e.g. for copper by 40%, for Pb by 17% and for zinc by 36%. However, the reserves are also influenced by other factors, such as average size of the mines, changes in the grade of the mined ore, price-to-cost relationships and the like.The purpose of this paper is to examine the nature of the reserve figures in more detail. Because the completeness of mining data published in Canada is rather exceptional, Canadian .data serve as an example and it is assumed that the conclusions can be extrapolated to other mining countries or at least to those with free market systems."

Jan 1, 1981

By T. Crivits, I. Bellemans, V. Cnockaert, K. Verbeken

It is well known that slag foaming can significantly complicate copper smelting processes. This is especially true for unpredictable events that generate large amounts of slag foam during a small period of time. These events are here referred to as eruptions and are typical for certain types of liquid bath furnaces such as modern top submerged lance (TSL) furnaces. A few authors already made the link between over- oxidation of the slag phase and slag foaming. In this work, the mechanism is studied in more detail and explained using the smelter chemistry and the behaviour of dynamic foam formation. Finally, the most influential parameters on the foaming behaviour of the process are presented. INTRODUCTION Copper remains one of the most important metals used in our modern society. In 2017, the annual amount of copper produced worldwide was about 23.5 million metric tons. This makes copper the third most produced metal in the world after steel and aluminium. The majority of this copper was produced by copper smelting, about 19 million metric tons, both from primary concentrate and secondary feed material as reported in ICSG’s World Copper Factbook 2018. In the past, copper smelting was mainly performed using Flash smelting, a technology developed before 1949 (Kojo, Jokilaakso & Hanniala, 2000). Nowadays, this type of smelter is being complemented by other smelter types such as ISASMELT and Ausmelt technologies. These are two types op smelter furnaces, based on the concept of a top submerged lance (TSL) furnace. These two technologies were both commercialized around 1990 (Arthur & Hunt, 2005). It is estimated by Wang et al. (2016) that at this time, both flash and TSL smelters contribute equally to the total amount of annually smelted copper. Flash smelting stays the most important technology for extracting copper from primary sources. TSL furnaces, on the other hand, are more suited than Flash smelters for the recovery of copper from secondary materials. This is because of the different ways that the feed material is inserted in both furnaces. In Flash smelters, the ore and fluxes needs to be fine and completely dry in order to be able to blow the mixture inside the burner area of the furnace. The feed material for TSL smelters show less constrains concerning humidity and particle size. The material is dropped from the top inside the molten bath. As a result, a more complex and flexible feed stream can be processed using TSL smelting (Wood, Hoang & Hughes, 2017). This feature will become more important in the future as primary copper sources gets more scarce and the need for a fully sustainable material cycle increases.

Jan 1, 2019

By M. Oliazadeh, A. Vazirizadeh

"The inclusion of small amounts of silicon, phosphorus and sulphur in iron ores or concentrates can have a profound effect on the steel making process and thus on the final iron and steel products. In nature however, it is inevitable that iron deposits contain unwanted elements. Each element has its own distinct effect on the final steel product. The effect of high silicon is the formation of gray iron. Phosphorus mainly increases hardness and strength, lowers solidus temperature and increases fluidity and cold shortness. Finally sulphur contamination causes cracks in the iron texture when smelting and forms white iron when casting. Overall, the acceptable level of phosphorus, sulphur and silica in the iron concentrate should be less than 0.04%, 0.15 % and 1.5 % respectively.Scarcity of high grade iron ores necessitates using lower grade ores with higher amounts of impurities. The purpose of iron concentrators is to increase iron grades to an appropriate level suitable for steel making as well as removing impurities. Although many impurities can be traced in the ore, the most predominant impurities are limited to one or two elements. In this paper the beneficiation methods for removing SiO2, P and S are presented, including flotation, and the parameters that need to be considered in the design of beneficiation plants are discussed. Finally industrial cases are discussed along with their metallurgical performance.INTRODUCTIONIn metal sector, value of iron ores and concentrates is determined by iron percentage as well ascontent of:• Useful elements (Mn, Ni, Cr, V, Ti): natural alloying elements in steel• Deleterious impurities (S, P, As, Zn, Pb, K, Na): impair metal properties or complicate operational process in blast furnace• Fluxing components (Si, Ca, Mg,, Al)Sulphur and copper result in red-short, phosphorus is the cause of cold brittleness and arsenic and copper decrease welding characteristics. Sulphur should not exceed 0.15 in commercial ore. Acceptable sulphur content in ores and concentrates for producing sinter and pellets is 0.6%max, as sintering and heat hardening of pellets remove sulphur 60-90%. Phosphorous content in ores, sinter and pellets is limited to 0.07%-0.15%. 0.00.1% As max, 0.1-0.2% Zn max and up to 0.2% Cu are allowed in iron-ore part of the blast furnace burden for the production of standard conversion pig iron. Slag-forming components are divided into basic oxides (Ca, Mg) and acidic (Si, Al). Higher ratios of basic to acidic oxides are preferred since this reduces raw fluxing material."

Jan 1, 2016

By Liu Tao, Wang Wei, Liao Wenjiang, Yang Weiyan, Tang Bin

Side-blown Furnace technology is a developing technology and was developed very quickly in China in recent years, dozens of reference smelters can be found for the treatment of copper concentrate, copper slag, Lead slag, zinc leaching slag and different kinds of slurry. This paper introduces the working principle of the technology, displays the innovations and specifications of China Nerin's SBF technology, gives examples of the typical reference smelters, and looks ahead to future applications. INTRODUCTION Side-blowing furnace smelting process The side-blowing furnace smelting process (SBF process) is one of the bath smelting process with independent intellectual property rights of China Nerin. This process was originally applied to treat copper concentrate and high-lead slag. The SBF process includes two categories, i.e. to treat copper concentrate and to treat industrial solid waste. Up to now, the SBF process has been applied in around 5 million tons of copper concentrate processing capacity and 20+ plants with high-lead slag reduction process. In recent years, SBF process has been gradually used in zinc leaching slag, electroplating sludge, industrial solid waste (e.g., various metallurgical slag), and electronic waste disposal. The basic principle of SBF process is that the material to be treated is directly charged to bath through charging hole with crushed coal and flux, then, enriched oxygen air would be sent to slag level (Vanyukov/Jifeng style furnaces)or matte level (Baiyin style furnaces) via primary tuyere. In this case, the material completes matte/slag metallurgical reaction of gas-liquid-solid interaction under vigorous mixing, and separate matte and slag at the bottom of furnace hearth. With the help of secondary tuyere, the low-pressure air or enriched oxygen would be provided for secondary combustion in the freeboard. The core of SBF process is process parameter control and engineering design of SBF. Presented as a fixed rectangular type, the SBF is a metallurgical furnace consisting of copper water jackets and refractory material. The SBF is consisting of hearth, middle of furnace and furnace top with the sequence from bottom to top. The middle of furnace itself can be further divided into bath area and post-combustion area with primary tuyere and secondary tuyere at both sides. The furnace hearth is made of refractory bricks, which are fused and rebonded Mg-Cr brick, Mg-Cr brick and clay brick from inside to outside. The furnace top adopts a steel water jacket with charging hole and uptake shaft. The water-cooled partition wall is placed at uptake shaft and near charging hole.

Jan 1, 2019

By M. Silva, G. Olivares

In a leach pile, the drainage layer or commonly known as the cover layer has been a matter of discussion due to the multiple phenomena or events that occur within it which impacts negatively the leaching process. All these events are directly related to the loss of draining capacity and irregular flow net due to an excessive compaction and entrapment of fines reducing the flow velocity which in turn cause more fines to get trapped. Over time the problem will continue to worsen rapidly and accelerating continuously like a geometric progression. When the cover layer gets to a certain level of deterioration, the only alternative to continue operating safely is to replace the entire cover material, a huge cost for any mining operation. TESRA has developed a solution to counteract the accelerated advance of the deterioration of the drainage layer. The solution consists of using large agricultural tractors coupled to a proprietary design of a heavy- duty subsoiler-ripper for deep tillage for loosening and breaking up the ground at various depth and with different legs spacing from 0.4 m or above. Also, if the ground still requires additional breaking, TESRA proposes the use of a rototiller that breaks any lumps to homogenize the ground to a certain particle size. With the subsoiler-ripper/rototiller combination equipment a layer of 0.5 m deep is properly treated to match closely the original conditions of the ground thus regaining the flow net as close as to the original seepage condition. Once the ripping is completed the subsoiler-ripper tool is replaced with another that is similar to a plow and thus continue with the installation of drainage pipes. The tool digs a Y-type profile trench allowing the pipe to sit precisely at the bottom of the trench, contributing additional lateral and lower support. This tool controls the installation depth of the drainage pipe at different inclination grades and also eliminating any irregularities that may block the flow of the leaching solution. Sometimes the obstructions block completely the flow of the solution. The main result of this methodology is the reduction of groundwater levels and at least 2% less humidity in the leaching gravel due to an increase in the draining capacity of cover. The methodology developed by TESRA applied during a couple of cycles of a dynamic leach pile has proven to be a real alternative to remedy and recuperate the cover close to its original conditions. The methodology requires only one large tractor and two accessories operated in different stages while replacing the more traditional and less efficient machinery such as the Bulldozer, Motor-grader, and backhoes.

Jan 1, 2019

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019