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By George P. Demopoulos

In this paper the author will provide an overview of over 20 years of research & developments in the area of hydrometallurgical arsenic immobilization that culminated recently in the industrial implementation of the atmospheric scorodite process. The paper will consider various aspects of arsenic fixation in the non-ferrous metal industry from the iron-arsenic co-precipitation process employed to arsenic-bearing effluent solutions; to autoclave processing of arsenical copper and gold feedstocks and the fate of the in-situ formed iron sulphato-arsenate precipitate phases; the precipitation and stability of scorodite; the possible stabilizing role of mineral phases like yukonite, and the development of "scoroditeplus" processes employing novel encapsulation strategies. Emphasis is placed on the characterization and long-term stability of the various forms of arsenic-immobilized phases under either oxic or anoxic conditions over a wide pH range and the establishment of critical links between process parameters and hazardous material stability, contributing thus to advancement of new generation safe and sustainable waste management technologies.

Jan 1, 2014

By Y. Miyabayashi, K. Nishikawa, H. Nagai

JX Nippon Mining & Metals Group recovers valuable metals from end-of-life electronic products in an economical and environmentally-benign way, based on technologies that have been acquired in mining, smelting, and refining operations over time. End-of-life electronic products contain halogens and hydrocarbons. When such materials are treated in the copper smelting process, corrosion of equipment and discoloration of sulfuric acid occur. As a countermeasure to these problems, we have developed pretreatment processes that include an incinerator, exhaust gas washing towers, and a defluorination facility. By implementing these improvements, we have been able to treat a large volume of end-of-life electronic products efficiently in the copper smelting process.

Jan 1, 2014

By Ron Bradburn, Derek Perkins

"The Brenda mine is located in south central British Columbia, 22 km north west of Peachland, in the heart of the Okanagan Valley. Situated at an elevation of 1500 metres, the mine area straddles the divide between the headwaters of Trepanier Creek and Peachland Creek. These flow into Okanagan Lake, the chief valley water resource located 1100 metres below. The creeks are of great significance to the water management of the area as they constitute the water supply for the Municipality of Peachland, a thriving retirement community with a population of 5000. A location map is shown in Figure 1.The history of the Brenda Mine operation has been well documented previously. After twenty years of operation, the open pit mine shut down in June 1990 due to the depletion of its ore reserves. During the course of its life, it produced 109 million tonnes of waste rock which is thought to contain approximately 0.10% copper as chalcopyrite and 0.015% molybdenum as molybdenite stored in four rock piles around the pit. Similarly, approximately 200 million tonnes of tailings were produced grading 0.015% copper and 0.005% molybdenum. During operation, tailings were hydrocycloned to produce a coarse sand for dam building with the fine slime stored behind the dam. It is estimated that 40% of the tailings were used for the dam construction. The layout of the mine site is shown in Figure 2.The mine was operated under a zero discharge permit. This was achieved by diverting practically all surface water flowing towards the mine area around the site. Water affected by mine operations, was discharged to the tailings impoundment, and recycled to the mill for reuse. The recycle rate was 90% and seepage from the tailings embankment and saddle dam was pumped back to the tailings pond. Because acid drainage was not a problem with the low grade Brenda rock, runoff from the rockpiles was initially released to the local environment. However, due to the alkaline nature of the waste rock, dissolution of low concentrations of molybdenum in the site runoff waters became evident by the late 1970's. The molybdenum content of Peachland Lake, the water reservoir for the municipality of Peachland, approached the Canadian Drinking Water Standard of 0.25 ppm. By 1979, a series of diversion and collection ditches was completed to direct all runoff water from the rockpiles to the tailings impoundment area. This had a significant detrimental effect on the site water balance causing it to go into a considerable surplus condition. During normal operation, this oversupply was contained by the rate of tailings dam building. An economic shutdown of the mine during 1984 forced a limited discharge from the site to protect the integrity of the tailings dam."

Jan 1, 1995

By W. C. Ferguson

"This paper could be more appropriately titled ""The Application of Vacuum Filters to Underground Minewater Treatment. in a previous paper co-authored by the writer (1) the history and development of minewater treatment at the Sudbury District Operations of the International Nickel Company was outlined. It is the intention of this paper to dwell more specifically WIth the the application of the vacuum filter to a problem found in most, if not all, underground mining operations. In the preparation of this paper the writer has made liberal use of the illustrations and text of the paper previously noted.Last year we heard Mr. Nemeth discuss the basic mechanisms involved in vacuum filtration (2), and today Yr. Cunliff has exposed us to the selection of the filter media (3). I will now briefly review the various vacuum filter designs that generally lend themselves to metallurgical dewatering applications.DRUM FILTERSThe revolving drum-type which filters on its outside periphery is illustrated in Fig. 1. This is the Oliver or Drum filter and represents the first commercially available continuous vacuum filter. The original design dates back more than 50 years, but with the exception of the method of discharge, is identical to the units being marketed today. This filter is generally applied to slow filtering slurries. The cake may be discharged in several ways; strings, scraper blades, rolls or by passing the filter cloth over a small diameter discharge roller (belt discharge).THE DORRCO FILTERThe revolving drum type which filters on its inside periphery is illustrated in Fig. 2. Here the slurry lies in the drum and the cake discharges through a chute or conveyor. This type of filter is most often applied to fast-filtering slurries.THE DISC FILTERThe revolving filter which filters on the vertical plane of the disc is referred to as the Disc or American-type filter. This represents the most inexpensive design in terms of cost per square foot of filter area. This filter is widely applied, but is probably more suitable for slower draining pulps."

Jan 1, 1971

By C. Lara-Valenzuela, R. Perez-Garibay, F. López-Saucedo, A. Uribe-Salas, L. Magallanes-Hernandez

A relationship between gas dispersion parameters, namely gas rate (Jg), gas holdup (Eg), average bubble size (db) and bubble surface area flux (Sb), with the metallurgical performance (e.g., grade and recovery) has been established.. Results of eleven columns operating at five concentrators of Grupo Pefioles (Mexico), ranging between 1.52 to 3.35 min diameter and performing in the cleaning stages of lead and zinc circuits, are presented and discussed. The results showed that the effect of gas dispersion parameters was consistent and that both, Sb and Eg, correlate well with recovery particularly when the influence of feed pulp density is also considered.

Jan 1, 2009

By S. Fox, Y. Fujita

Increasing demand for rare earth elements (REE) is expected to lead to new development and expansion in industries processing and or recycling REE. For some industrial operators, sending aqueous waste streams to a municipal wastewater treatment plant, or publicly owned treatment works (POTW), may be a cost effective disposal option. However, wastewaters that adversely affect the performance of biological wastewater treatment at the POTW will not be accepted. The objective of our research is to assess the effects of wastewaters that might be generated by new rare earth element (REE) beneficiation or recycling processes on biological wastewater treatment systems. We have been investigating the impact of yttrium and europium on the biological activity of activated sludge collected from an operating municipal wastewater treatment plant. We have also examined the effect of an organic complexant that is commonly used in REE extraction and separations; similar compounds may be a component of newly developed REE recycling processes. Our preliminary results indicate that in the presence of Eu, respiration rates for the activated sludge decrease relative to the no-Eu controls, at Eu concentrations ranging from <10 to 660 µM. Yttrium appears to inhibit respiration as well, although negative impacts have been observed only at the highest Y amendment level tested (660 µM). The organic complexant appears to have a negative impact on activated sludge activity as well, although results are variable. Ultimately the intent of this research is to help REE industries to develop environmentally friendly and economically sustainable beneficiation and recycling processes.

Jan 1, 2016

By Wei Zhang, Jinhong Zhang

"The adsorption of ethyl xanthate on copper sulfides, i.e., chalcopyrite, chalcocite and bornite, has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). AFM images show that xanthate, such as potassium ethyl xanthate (KEX), adsorbs strongly on chalcocite and bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is totally different from the one obtained with chalcopyrite/xanthate system, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The findings obtained from the present AFM study suggest that an AFM image analysis is a powerful tool for the study of the collector’s adsorption on mineral surface and as well the development of novel collector for copper sulfide flotation.INTRODUCTIONIn mining industry, copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite, are usually separated selectively from non-valuable gangue by froth flotation, which treats the highest throughput and produces the maximum economic outcome of any surface chemistry process. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineralbubble attachment and thus a high flotation recovery.The adsorption of collector on mineral surface, therefore, is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2016

By S. Ghafarnejad Parto, Å. Rasmuson, A. Fredriksson, M. Mohammadi, K. M. Forsberg, J. Martinez De La Cruz

The present study aims at recovering rare earth elements (REE) in conjunction with the production of fertilizers from an apatite concentrate. Apatite is one of the REE rich minerals ending up in the tailings pond when Luossarvaara-Kiirunavaara AB (LKAB) in Sweden processes Malmberget’s iron ore deposit. Leaching with nitric acid, hydrochloric acid, and sulphuric acid respectively have been studied. The nitric acid route was chosen for further investigations and the optimum acid concentration for leaching of the REE were determined. The leached REE are recovered by solvent extraction using di-(2-ethylhexyl) phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid-mono-2-ethylhexyl ester (EHEHPA).

Jan 1, 2014

By Louise Laverdure

Outline ?Background ?Issues and considerations ?Why do we need to innovate ?Green Mining Initiative ?Footprint reduction ?Innovation in waste management ?Ecosystem risk management ?Mine closure and rehabilitation ?The Future

May 1, 2011

By S. McCarthy, K. E. Waters, A. Jordens

The beneficiation of rare earth (RE) element bearing minerals has become an active area of research as applications for these elements grow while the supply to non-Chinese consumers is restricted by export quotas. One of the most interesting beneficiation techniques for RE minerals is froth flotation as their unique chemistry suggests that collectors with a specific affinity for RE cations should be able to selectively recover these minerals. Existing literature, focusing mainly on bastnäsite flotation, identifies hydroxamic acids as excellent collectors for RE minerals. The high stability of hydroxamate-RE cation complexes is the explanation most often offered for the observed selectivity of these reagents in bastnäsite flotation however some research has also suggested that mineral solubility plays a crucial role in the success of hydroxamic acid flotation of RE minerals. This work investigates the interaction of allanite, a relatively insoluble RE-silicate mineral, with benzohydroxamic acid using zeta potential measurements and microflotation. The effects of Fe(III) and Fe(II) ions as potential activating ions (cations that form stable hydroxamate complexes) on benzohydroxamic adsorption to the allanite surface are investigated as a potential solution to promote hydroxamic acid adsorption. The results indicate that the optimum conditions for separation of allanite from quartz occur at pH 4 using FeCl2 as an activator for benzohydroxamic acid adsorption.

Jan 1, 2014

By Jun Shan

The preparation of poly(N-isopropylacrylamide)-monolayer-protected clusters (PNIPAM-MPC) of gold nanoparticles was carried out in a homogeneous phase using three ways, in which three types of PNIPAM ligands were employed. The first type comprised of PNIPAMs with narrow molar mass distributions, synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and thus, bearing a dithiobenzoate at the chain end. These polymers were used directly to passivate the gold nanoparticles upon the Schiffrin reaction in a one-pot synthesis. The second type of ligands was derived from the first one through hydrazinolysis, and they therefore contained a thiol end group. The third type of ligands was PNIPAMs obtained through conventional radical polymerization, post-modified to contain thiol end groups. The PNIPAM-MPCs were characterized by high-resolution transmission electron microscopy, and by dynamic light scattering. The one-pot synthesis utilizing the ligands of the first type turned out to be a simple and facile method, compared with the other two ways, with which the size of the gold nanoparticles can be easily manipulated mainly by adjusting the molar ratios of PNIPAM / HAuCl4. PNIPAM is a more efficient ligand to stabilize the gold nanoparticles in water and in organic solvents than alkanethiols. The surface density of PNIPAM chains ranged from 1.8 to 3.6 chain/nm2, which is much lower than that typical for alkanethiols. The thickness of a PNIPAM monolayer bound to the gold core is somewhat larger than the size of the random coil of corresponding free PNIPAM in aqueous solution, which suggests that the conformation of a PNIPAM chain bound to the gold core is to extended.

Oct 1, 2003

"This paper discusses the use of risk assessment and risk management techniques within the Australian underground coal mining industry, within the context of geotechnical risk. The industry works within a pro-active, “enabling” legislative framework, where companies and management apply a range of risk assessment tools as part of their everyday management processes. Different geotechnical risk factors and approaches are reviewed, together with application examples – ranging from mine planning and design, operations, and accident investigations.A particularly powerful resource in each of the above stages of geotechnical management is the RISKGATE system. RISKGATE is an assembled “body of knowledge” structured under different topics across the Australian coal industry, of which three topic areas address rock mechanics issues for both the underground and surface mining sector. This paper will provide an overview of RISKGATE in the context of risk-based rock mechanics applications in underground coal mining."

Jan 1, 2015

By William H. Pomroy, Kenneth E. Hjelmstad

An underground mine fire can seriously threaten the lives of all personnel in the mine. This fact makes fire emergency planning a high priority in the mining industry. A fire emergency plan includes a means of warning miners of the existence of a fire, and the need to evacuate or retreat to a place of refuge. The warning alarm must be fast and must reach all miners, regardless of their location or work activity. Means of fire warning are varied, and include such methods as stench, flashing lights, telephones, and word-of-mouth (messengers). Unfortunately, none of these methods are entirely satisfactory. Stench can be slow and seldom achieves total mine coverage, especially in high-back room-and-pillar mines with low ventilation velocity. Telephones are effective only where personnel are close enough to hear the phone ring. A novel fire warning alarm system has been developed by the U.S. Bureau of Mines which enables instantaneous warning of all underground personnel. The warning alarm is sent by an electromagnetic signal which penetrates through mine rock from a transmitter to small person-wearable receivers. Each miner&apos;s cap lamp battery could be equipped with a small receiver and when a fire or other emergency occurs the miner could be alerted to the danger by a blinking of the cap lamp. Testing of prototype equipment has demonstrated that the transmitted signal is capable of penetrating through over a mile of mine rock and activating the receiver. This paper describes the theoretical basis for through-the-rock ultra-low frequency electromagnetic transmission, design of the prototype transmitter and receiver, test results, and status of commercial development of systems utilizing this technology.

Jan 1, 1994

By S. Hobo, M. Yagisawa, T. Uchida, C. Tokoro, T. Kato

In this study, quantitative modeling was carried out for the treatment of simulated waste water containing As(V), Zn(II) and Hg(II) as toxic elements, and Fe(III), Na(I) and sulfate as coaxing ions. The objective was to predict the pH and residual concentrations of all the elements in solution after the neutralization/co-precipitation treatment. To accomplish this, the removal mechanism for As(V) and Hg(II) by ferrihydrite precipitation was first investigated for simulated waste water containing only As(V) or Hg(II). From the experimental results, it was confirmed that the removal mechanism involves not only surface complexation but also surface precipitation. However, surface complexation is the main mechanism for As(V) and Hg(II) removal to meet the target levels regulated in Japan. Next, the surface complexation model was constructed for the removal of As(V) and Hg(II) by ferrihydrite. The specific surface area and site density were determined from reference values proposed by Dzombak and Morel (1990). By comparing the experimental and calculated results, it was confirmed that our constructed model could successfully represent the experimental results. Furthermore, the surface complexation model was coupled with chemical equilibrium calculations and applied to the neutralization of simulated waste water containing As(V), Hg(II), Zn(II), Na(I), Fe(III) and sulfate. The constructed model could successfully represent the pH edge for As(V), Hg(II), Zn(II), Fe(III) and SO42- removal. In addition, the constructed model could represent the ion balance. Thus, our constructed model is useful to estimate the amount of neutralizer that is needed to achieve a target pH.

Jan 1, 2016

By Nicolas Gatelier, Sophie Laurent, Thierry You

Hard-rock caverns for hydrocarbon storage are a very particular type of underground facility controlled not only by local administrative and regulatory constraints that can be very specific, but also by the possible risks of geotechnical or geomechanical failure. Each such facility throughout the world is a prototype that needs to be adapted to very different site conditions. The straight forward application of design methodologies from relatively similar fields (mines, tunnels) can be very useful, but risks holding back the scientific and technical improvements needed by an engineering industry in full development. Here we look at various case histories and at problems that have been raised where recent attempts at standardization would appear to have been ill adapted, and where storage designers, through experience and judgment, may still provide innovative engineering solutions.

Jan 1, 2015

By Qidong Xu

Abstract - The metavolcanic rocks of the Dahongshan area have been subjected to both widespread hydrothermal alteration from circulating seawater and to regional metamorphism, such that their mineralogic and chemical compositions have been changed significantly. Studies of immobile elements show that these rocks were originally tholeiitic basalts with geochemical characteristics of T-type MORB formed in a mid-ocean ridge environment. The accompanying Cu-Fe-rich VMS mineralization is in keeping with the original petrology and tectonic setting of these metavolcanic rocks. Regional alteration evident in K-Mg enrichment is related to sericitization and chloritization. Local alteration associated with Cu-Fe mineralization appears to have been accompanied by Si enrichment and Na depletion. P enrichment identifies metasomatism related to Cu-Fe reconcentration in the mineralized zone.

Jan 1, 1999

By Mike D. Riley, Alan V. Bell, Ernest K. Yanful

Acid mine drainage (AMD) research under the MEND program has been ongoing since 1988 at the Heath Steele Mines waste rock piles including sulphide material, outside Newcastle, NB. In 1989 approximately 10,000 mt of waste rock was placed on a prepared sand base with an underlying impermeable membrane. The waste rock pile was heavily instrumented for measuring oxygen concentrations and temperatures. In September 1991, a composite soil cover designed for the Heath Steele climatic conditions, using local soils, was placed over the pile, creating a totally enclosed system. Moisture content and oxygen probes were installed within the composite soil cover to monitor changes within the soils over time, while two large-size lysimeters were installed below the cover to monitor the hydraulic conductivity of the cover. The waste rock site has been monitored on a monthly basis since installation of the cover, for performance of both cover and waste rock. The monitoring shows very clearly that the placement of the composite soil cover has had a major impact on the generation of AMD. Major reductions in temperature and oxygen concentrations within the waste rock pile indicate that the cover has significantly inhibited the oxidation reaction that generates the AMD. Performance data have shown that the cover has maintained its integrity under the climatic conditions of the area.

Jan 1, 1995

By S. Suzuki, C. Tokoro, S. Owada, T. Sakakibara

Acid mine drainage (AMD) has been actively treated by neutralization from about 80 abandoned or closed mines in Japan. More efficient and cost effective treatment processes has been demanded for AMD due to the government investment of billions of yen every year to protect the environment from these discharges. In this study, quantitative modeling was conducted for actual AMD to predict pH or residual concentration of toxic elements after neutralization/co-precipitation process. Simple chemical equilibrium calculation was not adequate for quantitative prediction of pH after neutralization, because residual concentration of major elements of AMD, such as Fe or Si, could not be quantitatively calculated. When oxidation rate of Fe(II) to Fe(III) and precipitation rate of kaolinite were added to the model, quantitative prediction of pH and Fe or Si concentration was achieved. Surface complexation at the interface between hydroxide such as ferrihydrite or aluminum hydroxide and AMD was the most important mechanism for removal of dilute toxic ions. When surface complexation model at the interface of ferrihydrite was added to the model, residual As (V) and Pb (II) concentration after neutralization/coprecipitation process was successfully calculated. On the other hand, surface complezation model of aluminum hydroxide was also necessary for quantitative prediction of residual Zn(II) concentration after neutralization/co-precipitation process.

Jan 1, 2014

By David W. Mogk, Tamara Darsow, Macgregor L. Fogelsong, Robert M. Hunter, Frank M. Stewart, Edwin H. Abbott, Courtney A. Young

Abstract: Development of cost-effective techniques for recovering precious metals from their ores has been the goal of metallurgists for hundreds of years. Today, metallurgists are increasingly called upon to design processes for ores that are refractory to conventional recovery techniques. These challenges and the addition of environmental costs (including site remediation) to the total cost of mining have stimulated a search for alternatives to conventional processes, such as cyanidation. This paper describes the progress made to date in development of an innovative alternative to cyanidation, termed bisulfide leaching, for extracting gold, silver and platinum-group elements from refractory ores and concentrates. While bisulfide leaching can be implemented abiotically, significant benefits accrue from its practice as a bioprocess that integrates the steps of precious-metals liberation and extraction. In many applications, bisulfide leaching appears to offer significant advantages over the traditional cyanidation process. Dissolved bisulfide and hydrogen sulfide are much less toxic than dissolved cyanide and hydrogen cyanide. Recommended workspace exposure limits and harmful concentrations for hydrogen sulfide gas are higher than those for hydrogen cyanide gas. While the facilities required to practice the bioprocess on an industrial scale would be similar to that of cyanidation plants, chemical reagent costs could be 80 percent less. The bioprocess may also offer advantages in the leaching of ores and concentrates that are not amenable to cyanidation. For example, bisulfide leaching of ores containing carbonaceous material may produce higher gold recoveries if the "preg-robbing" characteristic of the material can be controlled biologically or with dissolved sulfide binding. Moreover, in that precious metals are much more soluble than base metals in bisulfide solutions, bisulfide leaching offers distinct advantages over cyanidation for selective dissolution of precious metals from base-metal concentrates. Thus, the bioprocess uses the natural sulfur cycle to mitigate pollutant production and to enhance precious-metals recovery.

Jan 1, 1998

By Stephen Hardcastle

Personnel Heat Exposure Issues In Canada?s Deep Mechanized Mines ?Project developed in 2004 ?Base/precious metal industry identified heat stress/management as a major challenge affecting productivity and operating costs ?Project started in 2005 ?Current research nearing completion ?Guidelines, further data analysis and ?Communicating the Science? will continue into 2011 Managing Heat Exposure Control?. The cost implications ?Controlling the environment ?Ventilation already a major expenses/energy user ?Large Canadian mines are currently delivering massive volumes of air 15-20 tons of air/ton ore ?Large investments in ventilation upgrades, mechanical cooling

May 1, 2010