Search Documents

By T. R. Strombotne

The purpose of this report k to document a contract undertaken by TSA Systems, Incorporated for the United States Bureau of Mines to develop a commercially available source of a continuous, working,, level detector for the measurement of radon daughter products in various working environments. The basic radon measuring technique was devised by Robert Droullard and Robert Holub and has been applied here. For further details or purchasing information contact: TSA Systems, Incorporated 4919 North Broadway Boulder, Colorado 80302

Jan 1, 1982

By Frank J. Wiebelt

The Carbonate King zinc mine is on the west slope of Kokoweef Peak, Ivanpah Mountains, San Bernardino County, Calif. It has produced more-than 10,000 tons of ore with a 39-percent?zinc content since mining operations began in 1940. The ore, consisting principally of calamine and smithsonite, occurs in replacements of the YellowPine limestone. Milling, has been done from the surface to a depth of 275 feet. Eight holes, aggregating 2,121, feet were drilled by the Bureau of Mines in an endeavor to establish extensions of the worked-out ore bodies and to develop new ones. Although indication of mineralization was found in several of the holes, no new ore bodies were developed.

Jan 1, 1949

By N. S. Dalal, X. Shi

"Electron spin resonance measurements provide evidence for the formation of long-lived Cr(V) intermediates in the reduction of Cr(Vl) by glutathione redtuctase in the presence of NADPH and for the hydroxyl radical formation during the glutathione reductase catalyzed reduction of Cr(Vl). Hydrogen peroxide suppresses Cr(V) and enhances the formation of hydroxyl radicals. Thus Cr(V) intermediates catalyze generation of hydroxyl radicals from hydrogen peroxide through a Fenton-like reaction. Thus the mechanism of Cr(VI) toxicity might involve the interaction between macromolecules and the hydroxyl radicals.C(Vl) compounds have been found to exert serious toxic and carcinogenic effects on humans and animals (1-3). In contrast, most Cr(III) compounds are relatively nontoxic, noncarcinogenic, and nonmutagenic (1,4). Cr(VI) and Cr(III) oxidation states are different in their metabolic pathways: Cr(VI) , ions are rapidly transported across cellular membrane (1,4,5), while Cr[III) moieties do not easily penetrate cells and are not oxidized by cellular constituents (!). Since it is known that the reduction of Cr(VI) ion is required for its reaction with DNA (1), the molecular mechanisms for the intracellular Cr(Vl) reduction has been the focus of current studies but the details are still not understood.Earlier studies on the mechanism of Cr(Vl) reduction include those on the reduction of Cr(VIJ by glutathione (GSH) .0,6-8), ascorbic acid (9), glucose (10), lactose (IO), galacturonic acid (11), microsome (12), and mitochondrial electron transport chain complexes (13). These studies have shown that the Cr(VI) reduction involves the formation of Cr(V)-containing species which are often considered to be the toxic form of chromium. Thus far, however, no information is· available on the subsequent fate of those biologically formed Cr(V) species, in particular employing well defined biochemical systems. In this context, we report here our investigations of the reduction of Cr(VI) by glutathione reductase (GSSG-R). This enzyme was selected because it is ubiquitously present in cellular systems and it has been postulated to be involved in the Cr(VI) reduction (14-17) but the underlying mechanism has not been clarified. We find that the reduction proces·s involves not only Cr(V) but also ·OH radicals. We further investigate the reactivity of Cr(V) and find that it catalyzes generation of OH radical from H2O 2 through a Fenton-like reaction. The role of ·OH in Cr(VI) carcinogenicity is suggested from this study."

Jan 1, 1989

By Bernard Porter

The rate of the heterogeneous reaction between reactor-grade yttrium and lithium fluoride in lithium fluoride-yttrium fluoride mixtures was measured using a quartz spring balance. At 950° C the magnitude of the rate of reaction is 10-5 grams of yttrium/cm2-sec. The heat of activation for the reaction is 38.3 kilocalories per mole of LiF. A surface-controlled mechanism is proposed in which LiF is adsorbed on the yttrium metal surface. An activated complex is formed when additional LiF reacts with the adsorbed LiF-metal site. The activated complex then decomposes to the products) which are lithium metal and YF3. The importance of the reaction in the electrowinning of yttrium metal from fluoride electrolytes is discussed.

Jan 1, 1967

By James S. Browning

The Bureau of Mines conducted laboratory batch and pilot plant flotation tests to determine the technical feasibility of recovering commercial-grade mica from a California micaceous schist. Best results in the laboratory batch tests were obtained using sodium carbonate and sodium silicate for pH control and quartz depression, and a combination of fatty acid and cationic reagents as the mica collector. In continuous pilot plant flotation tests, an alkaline fatty acid-cationic method recovered about 70 percent of the mica in a concentrate analyzing 95.6 percent mica.

Jan 1, 1965

By Nick Derick

The continued growth of steel production in the Western States is contingent upon the development of new iron ore sources. Recent development of economical techniques for concentrating and agglomerating taconites has focused attention on the low-grade magnetite deposits near Atlantic City, Wyo., as potentially important sources of iron ore for blast furnace smelting. Therefore, the Federal Bureau of Mines has made comparative evaluations of blast furnace burdens that incorporate pellets produced from Atlantic City concentrates. The Bureau also has evaluated the relative effect of Utah coke on blast furnace performance, using a high-quality Eastern coke as a basis for comparison. This work was done in the Bureau's experimental blast furnace at Bruceton, Pa. Tests determined the maximum wind rate that could be used while a continuous stock movement was maintained in the furnace. The furnace was operated at wind rates ranging from 800 to 1,400 std. c.f.m., them maximum limit of the blowers for the 1.75 in.-diameter tuyeres used. Using a normal Utah ore burden and Utah coke, the furnace went into a tight hanging condition with a wind rate above 950 std, c.f.m. Using the experimental pellet burden again with Utah coke, the wind rate could be increased to 1,000 std, c.f.m. and probably to 1,050 std. c.f.m, before tight hanging occurs. This represents an increase of 5 to 10 pct. in the wind rate. The experimental results indicate an accompanying increase of iron production, as much as 8 pct.

Jan 1, 1961

By E. S. Leaver

The mineral value in the ores from the Mother Lode mining districts of California is almost entirely gold, Although many mines have produced extremely high-grade ore the usual mill grade averages approximately $7.00 gold per ton. Fully 80 per cent of the gold has been and is now being recovered by amalgamation. Various methods have been introduced to recover the gold that was not obtained by the amalgamation processes. They include vari¬ous kinds of gravity concentration which in some cases were followed by chlorination or cyanidation. The usual practice includes only stamp battery, plate-amalgamation, and vanner concentration. In the very early practice the tails were run to waste through the main drainage streams of the different mining districts. During later years very large storage dumps have been impounded. These old tails, together with those being saved from present mills, furnish the problem discussed in this article. The clean sand portion of these mill tails is amenable to the usual cyanidation. The slime portion contains the major amount of the gold lost, but it also contains 1-1/2 to 3 per cent carbon, which precludes direct cyanidation of this part of these low-grade waste tails. The black carbonaceous slime portion is the particular problem considered in this report.

Jan 1, 1930

By Homer J. Ballinger

The Rex mine is one of several zinc deposits in Ozark and Howell Counties, Mo. It is the second of these deposits investigated by the Bureau of Mines in an effort to demonstrate reserves of sulfide ore underlying the shallow carbonate ores from which the district's major production has come. The initial investigation was made during 1945-46 on the Alice mine, Ozark County, Mo.21 The investigation reported herein was conducted during 1947. The Rex open pit is about 250 feet long, 100 feet wide, and about 25 feet deep (average). Three caved shafts are evident in the bottom of the pit, but the extent of the workings from these shafts is not known. The Bureau of Mines drilled five churn-drill holes in and around the Rex pit to test the grade and the vertical and lateral extent of the deposit. Two of the holes indicate notable zinc mineralization ranging from less than 1 to more than 10 percent metallic zinc, but largely in the oxidized condition.

Jan 1, 1948

By John S. Dunning

This is one of a. series of papers being prepared for and published by the United States Bureau of Mines, describing raining and milling methods at crushed-stone plants throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total production costs. It is recognized that publication of total production costs might in man; instances cause embarrassment to individual producers as well as to the industry as a whole. However, operating costs are essential to technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that the scope of the cost tabulations shall not be misunderstood. This paper deals with the quarrying and crushing methods used at the Avon Mountain trap-rock quarry of the Atlas Sand, Gravel & Stone Co., in West Hartford, Conn.

Jan 1, 1936

By H. Kenworthy

The investigations described in this report were undertaken to demonstrate, on a laboratory scale, the possibility of recovering several million pounds of tin plus tungsten contained in stockpiled and currently rejected slags from the Longhorn tin smelter at Texas City, Tex. At the same time, it was anticipated that the treatment procedures developed might be applicable to slags from other tin-smelting operations. Results of the laboratory work show that it is possible, by pyrometallurgical means, to separate the tin and tungsten into products of intermediate grade that may be returned to the smelter circuits for further upgrading. Several methods of treatment were investigated. The methods that proved effective were: Fusion reduction, chloride volatilization, sulfide volatilization, and carbide formation. Over 90 percent of the tin and tungsten could be removed from the slat by any of these methods. Each type of treatment has advantages and disadvantages, and it could not be determined from the small-scale work which method was the more meritorious. Tungsten and (in some types of treatment) tin-bearing products were diluted by iron, the separation of which will require additional studies. Prevention of a portion of the iron from reporting with the tin or tungsten is a distinct advantage and possibility that will require inure laboratory work to develop the needed techniques for its accomplishment. Tin products from single treatments of stag ranged up to 75 percent in tin content but were more generally under 35 percent. Tungsten products were usually under 15 percent; but segregated portions could be selected, at a sacrifice in recovery, that contained up to 50 percent tungstic oxide equivalent.

Jan 1, 1957

By B. W. Naugle

This report describes the carbonizing properties of coals from the principal beds in Cambria County, Pa. Samples of coals from Upper and Lower Freeport and Upper and Lower Kittanning beds having estimated minable reserves of 50-million tons or more were studied by the Bureau of Mines. Cambria County coals rank either as medium-or low-volatile bituminous. A preparation study indicated that all coals tested in this county, except one sample from the Lower Freeport bed, were responsive to cleaning and would yield a product with satisfactory chemical properties for metallurgical coal. All coals tested from Cambria County yielded strong coke; however, they expand excessively when carbonized singly, and should be used only as minor constituents in metallurgical coking blends when carbonized in slot-type ovens.

Jan 1, 1959

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

Comprehensive ventilation surveys are made to review the adequacy of the mine system with regard to both statutory requirements and/or company policy, to evaluate improvements to the current ventilation system and to plan for £stun expansion. If computer simulation is to be used for these purposes, accurate quantity and pressure measurements become an absolute necessity since the validity of the computer generated output is heavily dependent on the accuracy of the input data. Consequently ventilation surveys that are run to generate input data for computer simu¬lation must use the best data collection procedures to guarantee as accurate results as are possible. These requirements have led to modifications in procedures that are used for routine ventilation surveying. McElroy and Kingery (1957) have recommended that pressures be measured independent of quantities since minor changes in mine conditions have a greater effect on absolute pressure measurements than on quantity measure¬ments. They estimate that, for large mines, a pressure survey may take only 1 to 3 days while the corresponding quantity survey would require 1 to 3 weeks. Although this procedure would undoubtedly lead to more ac¬curate pressure measurements, its use for the development of computer input data is not recommended for the following reasons. Atkinson's equation, H = RQ2, is used in computer oriented analysis to develop the airway resistance, R, based on quantity and pressure loss measure¬ments. It can easily be seen that since R a 1/Q2 and R a H, the effect of errors in quantity measurement is, in fact, more significant than those in pressure measurement. If the quantity and pressure measure¬ments are made at different times another problem results. Minor changes in quantity that may occur in the time between the pressure and quantity

Jan 1, 1977

By Don M. Coulter

"INTRODUCTION The district comprising Union, Lafayette, Pontotoc and Calhoun Counties, Miss. (fig. 1), was examined in October 1941 by R. W. Smith of the Bureau of Mines, accompanied by J. W. Adams of the Mississippi Bauxite Co. 3/ Subsequently, geologists of the Federal Geological Survey made a more detailed study of the area. 4/Bauxite had been reported as present in several localities in Pontot. County, and large deposits of kaolin are known in Pontotoc, Union, Calhoun, and Lafayette Counties. Many of the bauxite deposits, such as those on Big Hill, Second Hill, and Third Hill, in Pontotoc County, form the caps on hills and are outliers of Wilcox deposits on the Midway formation. Such deposits could have no extensions because of erosion and were not examined, as they were investigated by the Mississippi Geological Survey. 5/ Most of the bauxite was known to be low-grade, with a high iron content. However, Pontotoc County in particular presented possibilities of finding high-grade bauxite with a low iron content by drilling down the dip from the Wilcox-Midway contact. Consequently, with few exceptions the investigation was confined to drilling in this direction.Headquarters were established in Tupelo, Miss., on July 13, 1943, and mineral agreements were obtained covering 8,367 acres of land, with 62 land-owners in Pontotoc and Union Counties. Holes were drilled on properties of three of the landowners in Union County and 36 in Pontotoc County."

Apr 1, 1948

By R. J. Bielicki

A sorption apparatus for measuring the equilibrium sorption isotherm and the rate of diffusion of methane from fine-sized coal was designed and constructed. Preliminary work that used Pittsburgh and Pocahontas No. 3 coal shows that the diffusion coefficient varies with pressure and that the fracture spacing in these two coals is substantially different.

Jan 1, 1972

By C. M. Mason

The current Bureau of Mines active list of permissible explosives includes 95 brands. Twelve are gelatinous and the rest are the more commonly used granular ammonium nitrate type. The list of permissible blasting devices comprises five Cardox models.

Jan 1, 1968

By J. A. Stampe

In connection with its investigations of strategic minerals in the United States, the Bureau of Mines ran magnetic surveys totaling more than 533,000 linear feet at 30 deposits of magnetite in northern New Jersey. These deposits occur in a belt of granitic gneiss and in limited areas of limestone. The ore consists of magnetite accompanied by score of the following minerals: Hornblende, augite, apatite, feldspar, biotite, calcite, garnet and pyrolusite. Results of these investigations are being presented in two reports of which this is the second. The first paper, Certain. Magnetite Deposits in New Jersey, by A. L. Neumann and McHenry Mosier, was issued in April 1948 as Report of Investigations 4225.

Jan 1, 1949

By R. Havens, B. K. Shilber

"INTRODUCTION In the course of the investigation of the occurrence of manganese deposits in the western United States, ore-dressing tests were made on three samples procured by Bureau of Mines engineers from two properties in southeastern Juah County, Utah, each of which is known by the name Black Jack. To avoid confusion, the tests will be described under the names of the owners Kendall-Duvall and the Empire Mines.None of the samples were amenable to ore dressing for the production of high-grade manganese sinter.Ores from the Kendall-Duvall deposit represent an interesting metallurgical phase of low-grade manganese occurrence, as the occurrence of manganese as silicate (braunite) automatically governs the extent to which they can be beneficiated by mechanical methods of treatment. As less than 50 percent of the total manganese was recoverable by complex methods of treatment in a 40- percent-manganese sinter, attempts were made to recover most of the manganese in a low-calcite, intermediate-grade product that might be acceptable for subsequent metallurgical treatment. By selective flotation of calcite and manganese, up to 68 percent recoveries were obtained in plus 20-percent manganese products..No encouragement can be given for successful ore-dressing of Empire ores as represented by samples received for testing, as no products were obtained that would meet minimum marketing specifications. Empire ore contained only 1 percent lime and might be high enough in grade (19 percent manganese) for direct hydrometallurgical treatment."

Nov 1, 1947

By James P. Bennett

The Bureau of Mines investigated the effect of refractory oxide additions, introduced in soluble form, on the high-temperature properties of 90- and 98-pct-MgO brick. Brick samples were soaked in solutions containing Al, Ca, Cr, Co, Fe, Mg, Mn, Mo, Ni, Si, Sr, Sn, Ti, or Zr ions. Additions to 98-pct-MgO brick did not generally result in statistically significant property improvements. Statistically significant improvements were noted in hot modulus of rupture (MOR), slag resistance, and spalling resistance of the 90-pct-MgO brick for additions of Al, Mg, or Sn. High-temperature performance of treated 90-pct-MgO refractories was equal to or approached that of 98-pct-MgO brick. The marked improvements due to tin were obtained with additions of only 1.14 wt pct Sn02.

Jan 1, 1985

By L. R. Willmott

An ethanolamine purification unit for removing carbon dioxide and hydrogen sulfide from Firscher-Tropsch synthesis gas was installed at the Bureau of Mines synthetic liquid fuels demonstration plant at Louisiana, Mo. The unit was a surplus Radford Girbotol unit from the Missouri Ordnance Works modified for a capacity of 90,000 std. cu. ft per hour of synthesis gas at 450 p.s.i.g., operating pressure. The hydrogen sulfide loading of the feed gas was specified at 500 grains per 100 cu. Ft. The unit was designed by the Girdler Corp. and installed by the Koppers Co. Initial operations were conducted far 11 days in May 1951. Thereafter 7 additional runs were made, varying lo duration from 8 to 54 days. The last run was terminated on May 29, 1953, the total time the Plant wars in operation being 219 days.

Jan 1, 1956

By W. H. Ode, W. A. Selvig

"INTR0DUCTIONAccording to the Standard Specifications for Classification of Coals by Rank of the American Society for Testing Materials (A.S.T.M. Designation: D388-38).1/ high-volatile bituminous coals, subbituminous coals, and lignites are classified on the basis of calorific values on the ""moist"", mineral-matter-free basis. The moist basis refers to coal containing its natural bed moisture but not including visible water on the surface of the coal. It is assumed that the natural bed moisture of coal in the ground represents the moisture-holding capacity of the coal when in equilibrium with air at approximately 100 percent relative humidity. This moisture is sometimes referred to as inherent moisture as opposed to extraneous moisture, which wets the surface of the coal.To simplify procedures for determining the moisture-holding capacity of coal it is assumed, for all practical purposes that the moisture content of coal when brought to a standard condition of moisture equilibrium in an atmosphere of 97 percent relative humidity and 300 C. represents the bed moisture of the coal. The A.3.T.M. specifications provide that this condition of moisture equilibrium shall be obtained by bringing the coal to a standard condition of moisture equilibrium at 300 C. in a vacuum desiccator containing a saturated solution of potassium sulfate (97 percent relative humidity) according to the procedure proposed by Stanfield and Gilbart. 4/ No mention is made in the specifications for bringing partly air-dried samples to their natural bed moisture condition probably because of the hysteresis effect that has been noted by various investigators. 5/ In this connection it has been found from sorption studies that the adsorption and desorption curves for lignite are not entirely reversible. The hysteresis effect has been explained by some investigators as resulting from shrinkage of the lignite during drying, which causes a collapse of some of the capillaries, so the dried lignite cannot take up as much water as it held originally."

Apr 1, 1953