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By H. R. Beard

The citrate process for sulfur dioxide emission control was developed in pursuit of the Bureau of Mines goal of minimizing the adverse environmental impact of mineral-processing operations. This publication describes the gas analysis procedures used during development of the process. The research required the capability to analyze SO2, H2S, CO, CO2, COS, volatile hydrocarbons, NO, NO2, O2, N2, and H2. The methods described include gas chromatography, electrochemical detection, infrared spectroscopy, and the use of a computer program to predict the product composition in complex reactions. Laboratory and pilot plant applications are discussed.

Jan 1, 1979

By R. L. Grayson, S. S. Peng

"Research has been conducted during the past year on a study to correlate respirable coal mine dust characteristics with worker positions and coal seams. The first characteristic of respirable coal mine dust which has been addressed in the correlation study is respirable dust mass concentration. In fulfillment of this objective, two mines operating in different coal seams have been selected for respirable dust mass sampling on both longwall panels and continuous mining sections. At present, sampling has been completed on the longwall panel operating in the first mine, and one half of the planned sampling has been accomplished on the continuous mining section.The first mine sampled is operating in the Pittsburgh coal seam. The average mining height is approximately 78"" with an average of 8"" of bottom shale being mined. The mine is primarily a longwall mine, and continuous mining machines are used to support the longwall.Figure 1 shows the layout of the longwall panel which was sampled. Intake air is coursed via the track heading up to the headgate area. The air splits at the headgate. Approximately 20,000-30,000 cubic feet of air per minute (CFM) is used to ventilate the longwall face and about 5,000-10,000 CFM is routed down the belt entry. Substantial leakage across the gob was noted during the sampling period. An average of 1800 CFM per 100 feet of face leaked through the shields into the gob from #1 shield to #112 shield. A substantial amount of leakage also occurred between the #1 shield and the solid rib of the headgate development panel. The path of the air used to ventilate the panel is shown with arrows in Figure 1. Direction of air flow was opposite to the coal moving direction on the armored face conveyor.A double-drum ranging shearer is used on the face to cut a 30-inch web of coal. Normal practice is to cut from the tailgate to headgate with the leading drum raised and the tail drum lowered for cutting bottom. After reaching the headgate, the shearer is reversed and both drums are lowered for a clean-up pass. The last 40 feet of face on the tailgate is cut on the clean-up pass.The shearer is equipped with 2 banks of 4 water sprays each and 2 large sprays on the headgate end and 1 bank of 4 sprays on the tailgate end. Additionally, sprays are located above bits on the cutting drums. Actual cutting speed was approximately 14-18 feet per minute, depending on conditions.The cross sectional area for air flow on the face was approximately 60 square feet before a pass was mined and 80 square feet after a pass was mined but before the shields were advanced. The cross sectional area at the shearer was about 35 square feet.The condition of both the tailgate and headgate of the panel was good with no signs of significant roof problems. The roof conditions along the face during the sampling period were variable. At times, as much as 3 feet of drawslate fell from the roof for a span of as much as 40 shields. Generally, however, relatively local areas of falling roof were encoun-tered, usually limited to a 10-20 shield span when appearing.Ten days were spent gathering respirable dust samples on the longwall panel. Mine Safety Appliance (MSA) sampling units equipped with 10-mm nylon cyclones, pre-weighed MSA PVC filters, and constant-flow DuPont pumps were used to obtain thesamples. The pumps were calibrated at a 2 liters-per-minute flow rate. The 10-mm cyclone was selected for classifying total dust into the desired respirable fraction in order to obtain ""legally defined"" respirable dust samples for detailed physical characterization."

Jan 1, 1988

By J. E. Zeilinger

The technical feasibility of using energy from explosive ignitions of coal dust to pump water was .demonstrated in an exploratory investigation. Ignition of small amounts of pulverized coal that were dispersed in air over columns of water pumped up to 5.3 gallons of water per cycle when operated against a head of 30.75 feet. Water displacement was accomplished by either manual or automatic operation through a single cycle, and by automatic operation through a continuous series of cycles of I-minute duration. Operating through single cycles, slurries containing up to 3 pounds of coal and 4.6 gallons of water were also pumped. Possible uses of an efficient coal-fired pump would include pumping water for irrigation purposes, removing water from mines, transporting coal from mines in the form of a slurry, and pumping water to elevated reservoirs at electric powerplants so that it could be used to generate electricity during peak periods of demand.

Jan 1, 1966

By EINAR M. ARENTZEN

This information circular. deais primarily with an engineering descrip- tion of a type of longwall cutting and loading machine developed by Eick- hoff Maschinenfabrik, Bochum, Germany..: This machine is supposed to have been developed and tested during the latter part of 1941 and early 1942. The only source of information is con- tained in certain literature and engineering data, with drawings which were acquired by the Allied Military Authorities when Germany was occupied; and the information will have to be limited because the writer has not seen the machine in the factory or in operation. However, the information may be of interest to the coal-mining industry in this country, and for this reason our Government has decided to publish the data procured so far. The Eickhoff cutting and loading machine is particularly suitable for the longwall mining system. It can only be used under that type of mining system and is not suitable for the more common type known in this country as room-and-pillar work. The material for the description of the machine and its operation was compiled and translated from German drawings and operating instructions. These detailed drawings and instructions are on file with the Bureau of Mines and are available for inspection by any responsible person interested in the details of the construction of the machine.

Dec 1, 1946

By R. L. Grayson, W. E. Wallace, M. D. Attfield, A. Q. Wearden, P. Bolsaitis, R. D. Kennedy, M. J. Keane, J. C. Harrison

"Respirable high-silica particles from four coal mines. a clay mine and a tunnelling site were analysed for silicon vs aluminum composition by performing scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDS) at electron accelerating voltages of 20 kiloelectron volts (keV). The same particles were analysed at 5 keV to determine possible differences in surface vs bulk composition. In some cases high-silica particles exhibited a decrease in the ratio of silicon to aluminium K-alpha line intensities with decreasing electron beam accelerating voltage. This behaviour is consistent with aluminosilicate surface contamination or occlusion of a silica particle. Some 20 high-silica particles were analysed from each of 10 samples. Powdered aluminosilicate glass was used as a control for the behaviour of silica with a homogeneous distribution of aluminium in the particle. Significant differences were found between the control and sample means for an Illinois bituminous coal mine dust, two western and one central Pennsylvania bituminous coal mine dust low-temperature ashes. and a clay mine and mill dust sample, but not for an anthracite coal mine dust and two central Pennsylvania bituminous coal mine dust low-temperature ashes. INTRODUCTIONRESPIRABLE dust quartz content commonly is measured on bulk samples by using i.r. spectroscopy or X-ray diffraction. For research purposes, individual particle-by particle SEM-EDS analysis at 20-30 keV electron beam accelerating potential may be used also. Such measurements have not provided an unambiguous association of quartz content with occupational pulmonary disease prevalence in exposed workers (WALTON et al., 1977). Rather, there is evidence that coal rank modifies the relationship between dust exposure and pneumoconiosis development (WAL TON et al., 1977; ROBOCK and BAUER, 1990; ATTFIELD and MORRING, in press). SEM-EDS analysis was performed to measure the silicon fraction, Si/(Si +Ai), at 20 and at 5 keV on high-silica particles to determine if some respirable quartz particles generated by mining exhibit heterogenous composition with depth (WALLACE et al., 1990), which might affect the bioavailability of the quartz surface."

Dec 1, 1995

By Oliver Bowles

Calcareous rocks, of which the principal varieties are marble and lime¬stone, are used extensively for building and ornamental purposes. Onyx and travertine, subdivisions of these groups, are sufficiently distinctive in origin and use to merit separate classification. The purpose of this paper is to define the terms "onyx" and "travertine" and to describe the occurrences and uses of the materials bearing these names. ORIGIN AND CHARACTER Confusion exists in the use of the word "onyx." True onyx is a banded chalcedony, a form of silicon dioxide related to jasper, agate, and flint. Calcium carbonate is commonly deposited from solution in successive layers of varying color closely resembling onyx, and for this reason such calcareous rock is also called "onyx." To distinguish the calcareous from the siliceous

Jan 1, 1940

By Daryl E. Radcliffe

This report describes an instrument system developed by the Bureau of Mines to continuously monitor and record changes in roof displacement during underground mining activity. The instrument consists of a single-wire extensometer coupled to a mechanical-drive chart recorder mounted in an aluminum frame installed in the roof. The unit is small and simple to install and meets safety requirements for use in underground coal mines.

Jan 1, 1977

By L. C. IlsLey

Figure 1 is a reproduction of a chart recently prepared by the Bureau of Mines at its Pittsburgh Laboratory to show the Bureau's approval work in connection with electrically operated mining equipment. Nearly 27 years of approval work, covering 346 approved units, are shown on this chart. These approvals are arranged according to year of approval and the manufacturer to whom approval was granted. Forty-five manufacturers are represented, and a scheme of using various colored tabs permits the following subdivision of the equipment: Cutting machines, loading machines, conveyors, battery-operated locomotives, battery-operated power trucks, drills and drilling machines, rock-lusting machines, pumps, room hoists, air compressors,, and miscellaneous, The greatest number of approvals granted to a single manufacturer is 80; the next highest is 65, and the third is 49. Several manufacturers have been granted only a single approval. The chart shows all approvals granted for, motored equipment. Some of these units have since become obsolete, and a few are used to a very limited, extent if at all.

Jan 1, 1941

By G. J. Slavens

The Bureau of Mines has devised technology to recover cobalt, nickel, and byproduct copper from domestic lateritic material using an oxidative, ammoniacal ammonium sulfate leach. Nickel, cobalt, and copper were recovered by solvent extraction and electrowinning. To reduce the cost and complexity of cobalt recovery, an alternate method using lig-nite to extract Co3+ was investigated as reported herein. In the first 25 BV (bed volumes) of solution contacted with lignite, 97 wt pct of the Co3+ was extracted in & downflow column at pH 9.3. After 85 BV, the lignite was loaded to 1.5 wt pct Co3+ and further ex-traction was minimal. The lignite extracted cobaltic ammine complexes rather than cobalt ions and was nonselective as to other -metal cations and ammonium ions. Deleterious cations and 80 wt pct of the nonammine ammonium ions were removed prior to acid elution of the lignite. The removal of the ammines prior to elution to produce an ammonium-ion-freeCo3+ eluate was only partially successful. Thus Co3+ removal from ammoniacal solutions by lignite is technically difficult and economically unfeasible. It was also determined that reduction of Co3+ to Co2+ occurred during the extraction-elution process.

Jan 1, 1984

By M. J. Reasor, M. DiMatteo, J. M. Antonini, K. Van Dyke, Z. Ye

"The inhalation of silica has been shown to produce a dramatic inflammatory and toxic response within the lungs of humans and laboratory animals. A variety of cellular and biochemical parameters are used to assess the silica-induced lung injury. The purpose of this paper is to introduce the use of luminok:Jependent chemiluminescence as a new method to study inflammation in both phagocytic cells and lung tissue recovered from silicaexposed animals. Chemiluminescence, or the emission of light, accompanies the release of reactive forms of oxygen when phagocytic cells are challenged. In this study, male Fischer 344 rats were intratracheally instilled with either silica (10 mg/100 g bw) or saline vehicle. One day after the instillations. a marked increase in the chemiluminescence was observed in the lung tissue and bronchoalveolar lavage cells recovered from the silica- treated animals when compared with the saline controls. The light reaction was markedly decreased by either superoxide dismutase or N-nitro-Larginine methyl ester hydrochloride. Superoxide dismutase is involved in the enzymatic breakdown of superoxide anion. while N-nitro-L-arginine methyl ester hydrocholoride, a nitric oxide synthase inhibitor, prevents the formation of nitric oxide. When superoxide anion and nitric oxide react. they form the highly oxidizing substance peroxynitrite. This study then implicates peroxynitrite as an agent that may be responsible for some of the oxidant lung injury that is associated with silica exposure. The use of luminol-dependent chemiluminescence may prove valuable as a method to measure the earliest events in the inflammatory process. and may be an adjunct in studying the mechanisms that produce inflammation. - Environ Health Perspect 102(Suppl 10):37-42 (1994) IntroductionResearch on inflammation has not produced a method that links the initial events of the process to the controlling events. Rather, a variety of parameters are measured that are the result of and not the basis of the inflammatory reaction. Parameters such as tissue weight, edema, blood flow, enzyme and protein release, or production of metabolites (prostaglandins, leukotrienes) have been used extensively. A method is needed that could be applied to cells of a particular type, groups of cells of different types, and even tissue, in an attempt to study the kinetics of the inflammation as well as being sensitive enough to monitor the early events of the process . Since inflammation is so complicated, the relationship between the control of the initial events and the oxidation process has never been explained nor studied in any derail."

Dec 1, 1995

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

By J. A. Herdlick

"INTRODUCTION The Bureau of Mines began a broad program of exploration of various proportion in the Pine Creek area of the Coeur d'Alene mining region in the fall of 1943. As a part of this project, exploring was done at theLittle Pittsburg property in 1945. The work included driving a 500-foot crosscut from the No, 6 level and drilling four diamond core drill holes to test the behavior of the Little Pittsburg vein at depth. This report presents the data obtained by the Bureau.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources, to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyses samples and performs beneficiation tests.The Bureau's exploration of the Little Pittsburg vein was one of the activities of the Albany Division of the Mining Branch, S. H. Lorain, chief. The project was started by R. M. Gammell, mining engineer, and was continued by the author and J. R. Reynolds, assistant mining engineer.The chemical analyses included in this report were made at Reno, Nov., under the direction of A.C, Rice, acting engineer in charge, Rare and Precious Metals Experiment Station, Bureau of Mines.The cooperation and assistance of the management of the Denver Development Co. is gratefully acknowledged, in particular that of C. E. Nugent, who made available much of the operational data included in this report."

Jan 1, 1947

By E. D. Gardner, Edmund Stein

"IntroductionMassive sulphides occurring in metal mines are inflammable and furnish the fuel for many mine fires. Actual sampling has shown that dangerous amounts of sulphur dioxide and hydrogen sulphide may occur in mine atmospheres after blasting in massive sulphides. Probably some .of the finer sulphide in the material being blasted burns while it is in contact with the flame from the explosion. It’s also possible that oxygen of the explosive enters into the reaction.That sulphide dusts are explosive under some conditions has long been suspected, but the theory has not been generally accepted as having been proved. Evidence now at hand appears to be conclusive that such explosions do occasionally occur in mine workings in massive sulphides. Information from several mines working in heavy sulphides shows that occasionally, sulphur dioxide in larger amounts than could be expected from the blasting alone are occasionally thrown out into the mine atmosphere during blasting. Accidents have occurred and lives have been lost by men being caught in such gases. Also it appears in a few cases that damage done to timber in stopes by concussions has been greater than could 112.ve been expected from the regular blasts. In most of these cases the unusually large amounts of Sulphur dioxide could only be accounted for by an explosion or by an ignition of sulphide dusts. When this occurs it is probable that the settled dust is stirred up by the first shot of a round, then the dust cloud is ignited by this or a succeeding shot.In one instance, the senior author, while wearing breathing apparatus, returned to a station to take a gas sample immediately after a raise round had been blasted, and encountered a heavy white fume or smoke that was corrosive to the skin and which forced a retreat. The sample, which was taken farther back in a greatly diluted atmosphere, showed a high percentage (0.18) of sulphur dioxide. The station and the raise which was just being started were very dry and the walls and floor of the station contained settled sulphide dust which apparently was ignited by the blast."

Mar 1, 1928

By Deno M. Pappas

The objective of this Bureau of Mines investigation was to identlfy and evaluate alternative binder materials for use in stabilizing and consolidating highly fractured roof along longwall faces and gate roads. The desirable characteristics of a stabilization material were defined, and an extensive search was conducted to find materials satisfying these characteristics. Of 20 materials originally scrutinized, 9 were chosen for laboratory analyses. The laboratory tests evaluated bond strength and tensile strength under both dry and wet conditions. An optimum material was not found. The laboratory analyses indicated two possible candidate materials for longwall stabilization: high-aluminous cement and two-component epoxy; however, the tensile strength of the high-aluminous cement was mediocre, and the epoxy cement is toxic, flammable, and fairly expensive. The potential market demand for an effective and economical stabilization macerial is discussed in the appendix.

Jan 1, 1988

By W. M. Myers

The U. S. Bureau of Mines conducted an investigation to determine the cause of the deterioration of Portland cement during storage and transportation , and to discover a means of preventing it . All available printed sources of information on this subject have been examined and a bibliography has been compiled . The subject has also been discussed with the leaders in the cement industry ; the present report is the result of their cooperation , and is based principally on information thus obtained . Deterioration of Portland cement during storage over any considerable period of time has long been noted ; closely related to it is deterioration of cement during transportation, which involves not only the time factor of storage but also exposure to varied climatic conditions . Deterioration in both cases is due to hydration of the cement by absorption of moisture from a humid atmosphere , or by exposure to actual rain-fall . After hydration cement possesses no cohesive power ; the degree of deterioration is directly proportional to the degree of hydration . The amount of deterioration of Portland cement during storage has been accurately determined in an investigation by the Structural Materials Research Laboratory , in cooperation with the Portland Cement Association . Cement stored in a shed in cloth sacks retained 80 per cent of its original strength after three months storage ; 71 per cent after six months ; 61 per cent after one year ; and 40 per cent after two years . The deterioration of Portland cement during storage and transportation was noted particularly in France during the World War . Information concerning cement used by the American Expeditionary Forces was furnished by Lt. Col. H. S. Spackman and Major E. C. Eckel , U. S. R. , who had charge of practically all matters concerning cement used by the A. E. F. The cement used by the A. E. F. came from the following sources : 42,000 tons was French , Swiss , and Spanish cements ; 120,000 tons was English cement ; 55,000 tons made in plants operated by the A.E.F .; 500 tons ( Not over) from America . Deterioration was most marked in cement from the first source .

Jun 1, 1922

By Clyde E. Williams

The Northwest experiment station of the Federal Bureau of Mines , at Seattle , Wash . , was established in December , 1916 , and is one of 13 mining experiment stations maintained by Act of Congress , under the direction of the bureau , in the various sections of the country . Under the terms of the organic Act (March 3 , 1915 ) , the province and duty of these experiment stations is to cake investigations and disseminate information with a view to decreasing waste and improving the efficiency in the production , treatment , and utilization of mineral substances . The investigations carried on at the Northwest experiment station attempt to cover the needs of the mineral industry of the States of the Pacific Northwest and of the coastal regions of Alaska . The most in ortant needs of this district are for work on coal washing , electrometallurgy , and ceramics . The electrometallurgical investigations are not necessarily limited to the Problems of the Northwest , but may be of general application . Problems other than those specified above are referred to other stations of the Bureau that specialize on the particular type of investigation required . The Northwest station closely cooperates with the State of Washington through the University of Washington and with the State of Oregon through the Oregon Bureau of Mines and Geology . The University of Washington at Seattle has donated the use of an entire building , which houses the station's administrative offices and chemical laboratory , and parts of two other buildings which are usea in conducting the experimental avestigations . Twenty-five thousand dollars is expended annually by the Federal Government , while the State of Washington each biennium appropriates $ 20,000 , and the State of Oregon from time to time appropriates various amounts for the conduct of work along cooperative lines . Also , the station cooperates with private organizations tht have problems similar to those in which the station is interested . For example , the Washington Electrochemical Co. is cooperating in the electrometallurgical research, and furnishes part of the supplies and technical assistance required .

Mar 1, 1922

By Thomas E. Marshall, Patrick A. Kinek, Gerald L. Finfinger

The purpose of this investigation was to evaluate the integrity of the existing shutoff valves and actuators used under high-temperature conditions in the Bureau of Mines' horizontal borehole methane drainage pipe- line system and to determine the potential for improvement in the system. In the field tests, both fire-safe ball valves and standard brass ball valves were initially subjected to a 30-min pan fire without thermal protection. Neither valve could maintain line pressure beyond 11 min in a fire that reached temperatures between 500° and 700° C. Based on the test results, it was concluded that the brass ball valve used in the Bureau's methane drainage pipeline system can be retrofitted with an inexpensive "fire bag" to substantially increase its integrity under mine fire conditions.

Jan 1, 1986

By X. Shi, V. Vallyathan, N. S. Dalai

"Electron spin resonance (ESR) measurements show that grinding of quartz particles in air produces silicon-based (Si- and SiO-) radicals which decay with aging in air. ESR spin trapping measurements provide evidence for the generation of hydroxyl and possibly superoxide radicals from a suspension of fresh quartz particles. The hydroxyl radical generation potential of the fresh quartz particles decreases on storing in ambient air and on the addition of catalase, superoxide dismutase, desferoxamine, or DMSO. Silica-induced lipid peroxidation also decreases on storing the fresh particles in ambient air. These findings suggest that oxygenated radicals play a role in the biochemical mechanism of pneumoconiosis in general and acute silicosis in particular.INTRODUCTIONThis communication summarizes our electron spin resonance (ESR) investigation of the formation of oxygenated radicals by freshly crushed quartz particles in a cell-free aqueous medium, and its potential role in the biochemical mechanism of acute silicosis. This study was undertaken because the mechanisms by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still not well understood. 1-3 It is generally believed, however, that the action of quartz particles on the cell membrane is the starting point of the silicotic process. 1,4 Since the first step must involve surface reactions, characterization of the chemical structure of the surface of quartz particles has been the subject of several recent studies!-' For example, we reported that mechanical crushing of quartz under normal atmosphere generates silicon-based (Si• and SiO•) radicals which decay with time, and that these radicals are associated with a higher cytotoxicity of fresh quartz dust as compared to that of an aged dust from the same stock. 6,8 Independently Fubini and coworkers' have also reported on the formation of Si• and SiO• -type of radicals from quartz particles crushed under atmospheric conditions. Gulumian and van Wyk9 have reported that quartz particles react with hydrogen peroxide (H202) to generate hydroxyl (•OH) radicals. These authors9 suggested that this process might contribute to quartz's pathogenicity but the mechanism of the -OH radical formation was not clarified. Earlier, Gabor and Anca10 had suggested that the cytotoxicity of quartz particles might be associated with the generation of some factor or factors possessing the properties of a free radical and hence capable of promoting the peroxidative chain cleavage of polyunsaturated fatty acid moieties of the phospholipids in the cell membrane. More recently, Weitzman and Graceffa 11 reported that asbestos is able to catalyze the generation of -OH radicals from H2O2. Their later work12 indicated that lipid peroxidation might be one of the mechanisms of tissue injury by asbestos."

Jan 1, 1989

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

CALCULATION OF MINE HEAD LOSSES FROM ALTIMETER SURVEY DATA USBM PENNSYLVANIA STATE UNIVERSITY - MINERAL ENGINEERING DEPARTMENT USBM USBM USBM THIS PROGRAM CALCULATES PRESSURE LOSSES USING THE USBM METHOD GIVEN USBM IN USBH IC 7809 BY MCELROY AND KINGERY.1957. THE MAJOR DIFFERENCE USBM BETWEEN THIS PROGRAM AND THE CITED REFERENCE IS THE TREATMENT OF AIR USBM

Jan 1, 1977

By J. E. Gebhardt

External control of the electrochemical potential of a bed of mineral particles has been investigated by the Bureau of Mines as a method for controlling particle inter-action with organic collectors and thus, flotation response. A cylindrically shaped, 200-to 300-g bed of sulfide mineral particles was used as the working electrode to examine the potential distribution in the bed. The dissolved oxygen concentration of the electrolyte had a significant effect on the potential profile across the mineral bed. Low oxygen levels were necessary to achieve uniform electrochemical potential distributions. Flotation separation of a chalcocite-pyrite mineral mixture by controlled potential was achieved using ethylxanthate, but the flotation behavior of chalcocite and pyrite from the mixture does not follow the flotation behavior of the individual minerals. That is, the presence of another sulfide mineral alters the flotation behavior with ethylxan-thate. Galvanic interaction due to mineral-to-mineral contact between chalcocite and pyrite contributes to differences in the recovery. Chalcocite dissolution products had a deleterious effect on pyrite flotation by activating flotation below -0.1 V (saturated calomel electrode) and depressing flotation above -0.1 V. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1985