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By L. B. Pankratz

Heat contents were measured for Na2CaSi04 and Na2Ca2S02 between 298° and 1,300° K, for Na2Ca2Si309 between 298° and 1,500° K, and for Na4CaSi3O9 between 298° and 1,350° K. Copper-block drop calorimetry was employed. Reversible, first-order transitions were found for Na2CaSi04 and Na2Ca2Si309. The transition for Na2CaSi04 is at 830° K with a heat absorption of 160 cal/mole; that for Na2CagSi309 occurs at 750° K with a heat absorption of 1,550 cal/mole. Results for the other two silicates showed no irregularities. A table of heat content and entropy increments above 298.15° K and heat con-tent equations are included for use in thermodynamic calculations.

Jan 1, 1968

By Jack A. Touseull

The Bureau of Mines has developed a simple stereographic method of analyzing the orientation of single and intersecting planes of weakness in vertical pillars of parallel symmetry. From this method, it can be determined if planes of weakness transect the full horizontal cross section of a pillar. A major finding resulting from this method was that intersecting planes of weakness can transect the full horizontal cross section of a pillar even though the individual planes do not. This paper provides step-by-step instructions for using this method.

Jan 1, 1977

By G. R. Friggens

A nuclear method for continuously monitoring the coalbed and ash levels and void formation in commercial-scale, fixed-bed, pressurized gas producers is proposed. Measurement of gamma ray transmission through the coalbed is the basis of the method. The coalbed level is monitored by detecting the trans-mission of gamma rays from a 1 to 2 Ci Co-60 source positioned on the outside wall of the vessel. Coal bridging or, alternatively, ash level is monitored by a 10 Ci Co-60 source at the center of the coalbed. Source activities and geometries are calculated for a 12-foot-ID producer designed to operate at 350 psi. Source capsule and detector specifications and operational safety are also discussed.

Jan 1, 1973

By John C. Machisak

THIS CHAPTER of the Minerals Yearbook (Volume III) contains overall employment and injury experience for coal mines-bituminous, lignite, and anthracite; coke, petroleum and natural gas; and peat and slag plants; metal and nonmetal mines; sand and gravel operations; stone quarries; metallurgical plants, including metal mills and smelters; and nonmetal mills for 1959. Volume I of the yearbook contains injury experience and employment data in the metal, non-metal, sand and gravel, slag, and quarrying industries, and the milling operations and related plants. Volume II contains the injury experience and employment data in the fuel industries--coal, coke, petroleum and natural gas, and peat. Surveys conducted by the Bureau of Mines were the source of injury and employment data used to compile the tables and furnish information for the accompanying text. Response to the surveys was voluntary except that for coal mines. The Coal Mine Safety Act requires operators of coal mines to furnish the information requested.

Jan 1, 1960

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

4. Preliminary Study - Remote Seal Checker 4.1 Introduction Determination of the completeness of each individual seal at the time of its emplacement is essential for an effective remote sealing system. A satisfactory seal checking technique should provide a signal which: (1) indicates percentage completion as the seal is emplaced (2) provides a definite indication of a complete seal (3) indicates the size of the unsealed area if a complete seal is not feasible This information is required to establish the need for additional seal material, the need for additional seals, and the risk likely involved in entering the mine., In many situations it is as important to know the quality of a seal as it is to build an effective one. It is likely that with repeated use the remote sealing technique developed by Foster-Miller Associates will be sufficiently reliable and predictable to preclude the seal checking requirement. It is recommended, however, that each seal be checked during construction to insure its completeness and increase the level of confidence so necessary in reopening the mine. 4.2 Description of General Problem Several characteristics of remote mine seals are important in considering techniques for evaluating the effectiveness of these seals. These include:

Jan 1, 1973

This chapter presents MSHA data on mine employment and active mining operations during 1986-1995. Figures 3-1 through 3-10 show, for each commodity, the location of mine operations in 1995, and employee hours and active mining operations by year during 1986-1995 for mine operators. For coal and nonmetal operators, the number of active mining operations and the number of employee hours decreased over the 10-year period. For metal operators, the number of active operations decreased, while the number of employee hours increased. For stone and sand and gravel operators, the number of active operations and the number of employee hours remained about the same. Figures 3-11 and 3-12 show that over the 10-year period, there was an increase in the proportion of hours worked by contractors in coal mining, while the overall employment decreased. For metal, nonmetal, stone, and sand and gravel combined, the proportion of contractor hours increased, with overall employment also increasing. Table 3-1 shows the distribution of hours worked during 1986-1995 by commodity and type of operation. For coal, the majority of hours worked were in underground mines. For metal, nonmetal, and stone, the largest number of hours worked were in mills and preparation plants. For sand and gravel, all work hours other than office were in surface mines. [ ]

Jan 5, 2000

By Launa G. Mallett, Charles Vaught, Michael J. Brnich

Beginning in 1991, scientists at the Pittsburgh Research Laboratory recorded interviews with individuals who are recognized as experts in mine emergency response. These 30 veterans related stories and observations from events experienced during as many as 47 years of response activities. Overall, the response veterans averaged 29 years of mine emergency response experience and 35 years of mining experience. Interviewees included representatives from mining companies, the United Mine Workers of America, and State and Federal agencies. Most of their comments dealt not so much with technical aspects of particular mine emergency responses, but rather the human side of more general topics, including preparedness, experience, people on-site, mine rescue teams, and decision-making. An analysis of their interviews provides an overview of lessons learned on-site at some of the largest mine disasters since the mid-1940s. This knowledge was gathered so that it could be provided to today's miners and to tomorrow's emergency response personnel. It is expected that the collective wisdom obtained can be used to help train new responders and guide those decisions that will have to be made on the scenes of future events.

Jan 4, 2004

By Fred N. Kissell

Experimental work by the Bureau of Mines indicates that when a coalbed is degassed by boreholes, the flow of methane may actually increase with time. This phenomenon appears to be the result of a relative-permeability effect; that is, the coalbed permeability to the gas increases sharply with decreasing water saturation. This report reviews the background of experimental evidence indicating a relative-permeability effect, and presents the results of a computer simulation of two-phase flow in coal.

Jan 1, 1975

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

1. Introduction This document represents Part II of our final report on the development of a "Remote Sealing System for Extinguishing Coal Mine Fires. " It is a technical report which summarizes the results of system development and field demonstration. Part I of this two - part final report is an Operator's Manual for the application of the Remote Sealing System to a coal mine fire. 1.1 Background When coal mine fires go out of control and can no longer be fought directly, the standard fire fighting technique is to construct air-tight seals in the mine passages leading to the fire area so'--,that the oxygen supply to the fire is". cut off. Ultimately, it is desirable to isolate the fire zone in such a way that normal operations can resume in the remainder of the mine. The construction of seals in the- mine causes the atmosphere to pass through a toxic and explosive phase. Explosions, if they occur, are not only hazardous to the men working at the sealing operation, but can also undo much of the sealing work which has already been accomplished. Sealing of passageways surrounding the fire zone from within the mine is extremely difficult and dangerous. Methods for direct sealing are detailed in "Control of Mine Fires'. 1 An alternative to this approach is the technique of remote sealing. This involves drilling boreholes which intersect the mine passages at the locations where the desired seals are to be constructed. The seals are then constructed by pouring material down the borehole and filling a segment of the passage from bottom to top. During this operation, there are no personnel in the mine, all operations taking place on the ground surface.

Jan 1, 1973

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

A. 4 Illustrative Simulations The capabilities of the program are demonstrated by simulating various evacuation cases in different situations for a particular mine. The mine selected for the illustrative simulations is the mine I C' , as described in Section 2, chosen particularly because of availability of mine characteristic data and mine evacuation results for test drills. These evacuation results can be used to verify validity of the predictions made by the program A.4 1 Mine Characteristics A schematic diagram of the mine is shown in Figure 19. The figure shows all the major shafts, drifts, raises and stopes of the mine in the form of a network. There are four hoists, Hoist No. 1 and Hoist No. 2 are assumed to be single drum hoists and Hoists Nos. 3 and 4 form part of a double drum hoist, with Hoist No. 4 being the main hoist (master hoist) The positions of the 133 miners, typically working in a day shift of the mine, are also shown in the figure. The miners are identified by a miner number, and their total number on each level is chosen from the data on the fire drill simulated as Case No. 1 in the illustrative simulations.

Jan 1, 1976

By Maria I. De Rosa

The U.S. Department of Energy Pittsburgh Research Center2 conducted experiments with mine conveyor belt samples in a 20-L furnace and in a laboratory fire tunnel to measure and compare the major toxic gas concentrations evolved during the combustion of the materials. The toxic gas concentrations, measured simultaneously through a multiport sampling device and treated as yield values, included hydrogen chloride (HO), hydrogen cyanide (HeN), oxides of nitrogen (NO, treated as NO), and carbon monoxide (CO). The data obtained from the two experimental systems were in good agreement. Correlations were developed for the toxic gas yields as a function of the percentage of chlorine (for HO gas), nitrogen (for HCN and NO, gases), and carbon (for CO gas) contained in the original materials. The toxic gas yields were also used to calculate a toxicity index (TI) parameter to assess the potential gas toxicity of belt materials during a fire. Furthermore, the TI and the mass loss burning rate values were used to calculate a toxicity hazard (TH) parameter to estimate the toxic gas hazard produced by a burning belt in a ventilated system. Results show that polyvinyl chloride (PVC) belts released higher HC1 concentrations because of the higher chlorine content; styrene-butadiene rubber (SBR) belts released higher CO, HCN, and NOz concentrations because of the higher carbon and nitrogen contents. The TI's, however, were greater for the PVC belts due primarily to the higher levels of HC1 produced. The fire tunnel data indicate that the SBR belts can bum with higher mass loss rates than the PVC belts, resulting in a potentially higher toxic hazard (higher TH values) even though their TI values were lower than those of the PVC belts.

Assist in controlling or extinguishing fires that occur in abandoned mine lands (AML) by providing a compilation of information on past fire control projects, the estimated extent of the current problem, and factors affecting the occurrence, propagation, and extinguishment of AML tires. Conventional fire control methods and their probable effectiveness are evaluated. Background Fires that occur in abandoned coal mines, waste banks, and coal outcrops constitute a serious health, safety, and environmental hazard from toxic fumes, deterioration of air quality, and subsidence. Although fires on AML occur in every coal-producing State, the severity of the problem varies, with most underground fires occurring in Kentucky, Pennsylvania, and Wyoming. Surface fires are prevalent in Kentucky, Pennsylvania, and West Virginia. Methods to extinguish or control AML fires, including excavation, fire barriers, and scaling, are generally expensive and have a relatively low probability of success (see figures 1 and 2). Bureau of Mines Study The Bureau compiled information from a variety of sources and found that the problem of AML fires is a serious one. Such fires can involve a high degree of hazard and can be difficult and costly to control. AML fires usually involve smoldering combustion in outcrops, waste banks, or abandoned mines. Given the nature of these fires, it is unlikely that the extent of the problem or the cost of solutions will decrease in the near future.

Jan 1, 1992

Provide reasonably priced, reliable fire protection for loading shovels. Approach An automatic fire, sensing and suppression system using both dry chemical and Halon 1301 was developed. It is more rugged than similar industrial-type fire protection systems. How It Works Temperature sensors detect heat from a fire, and trigger the system. These sensors are located inside the machinery house and under the house and shovel frame where it rotates around the crawler chassis ring gear. An alarm is sounded, and extinguishing agents are released either in the machinery house or in the ring gear area. The system can also be triggered by a manual control. If the fire Is detected in the machinery house, all power is shut down to the motor-generator sets, ventilation fan, and all electrical controls. Doors are automatically closed. After a delay to allow time for the ventilation fan to stop, Halon 1301, a gaseous fire extinguishing agent, is released inside the machinery house until it reaches a concentration of about 7 percent. This concentration is sufficient to extinguish a fire, but isn't toxic to personnel

Jan 1, 1980

Objective To develop and evaluate the effectiveness of safety training tools specific to the underground hard-rock mining industry. Background Scaling, the removal of loose rock from the roofs and walls of a mine by manual or mechanized means, may be necessary during any stage of mining. Manual scaling is very labor intensive, and mechanical methods can be too powerful and actually produce a less stable roof.

Jan 1, 2001

A primary objective of the Surface Mining Control and Reclamation Act is to establish uniform national regulatory standards to protect the environment during mining and for reclaiming land after it is disturbed by current and future surface coal mining. In recognition of the wide range of climatic and geologic conditions in coal-producing areas, Congress provided that individual states may establish their own programs for regulating surface and underground coal mining and reclamation on private land. The standards for state programs must be at least as effective as the federal standards. Initial and Permanent Regulatory Programs Congress recognized the importance of establishing regulations to implement the Act as quickly as possible, while recognizing that the preparation of such complex regulations would be a lengthy process. Consequently, a two-phase schedule was established. An abbreviated initial program was put in place immediately, followed by a more extensive and detailed permanent regulatory program. The initial program regulations were published in December 1977, and mine permits issued by states after February 1978 were required to conform with those regulations. Regulatory provisions contained in the initial program included 12 basic performance standards, continuation of existing state permitting, bonding, and enforcement processes (although if those features did not already exist, they did not have to be added), a federal inspection frequency of once every six months, joint state and federal inspection and enforcement in states that had existing programs, and the prohibition of mining in the specific areas listed in the Act. Permanent program regulations were published in March 1979, following extensive review and comment from the public, including the coal industry and organized environmental groups. The regula¬tory provisions in the permanent program expanded those in the interim program by including the implementation of all performance standards contained in SMCRA, a new permitting process, a requirement for performance bonds, an increased inspection frequency (one per month), a new enforcement process, and a process for designating lands unsuitable for surface mining. The regulations for the permanent program have been revised several times since 1979; more revisions can be made as new mining and reclamation tech¬niques are developed. Such changes were anticipated by Congress; in fact, a provision in SMCRA for experimental practices encourages advances in mining and reclamation techniques.

Jan 1, 1992

By Travis Q. Lyday

Gold continued to dominate mineral production in the group of volcanic islands and atolls of Melanesia in the southern Pacific Ocean, which comprise the British Commonwealth nation of Fiji. The Fijian mineral sector, however, remained of minor importance in terms of export earnings, Government revenues, and employment to the economy of the country, which was primarily agrarian with sugar as its mainstay. The Vatukoula gold-silver mine on the north side of the main island of Viti Levu remained the largest and most important mining operation, as well as Fiji's only operating metalliferous mine. In October, Western Mining Corp. (Fiji) Ltd. (WMCF), a wholly owned subsidiary of Australian-registered Western Mining Corp. Holdings Ltd., increased its interest in the Vatukoula joint venture from 10% to 20% by exercising its option with Emperor Gold Mining Co. Ltd., also of Australia. The assumption of mine management operations at Vatukoula in 1983, with its attendant influx of additional capital and technological expertise, enabled WMCF to increase both efficiency and output at the mine during 1984. Higher output was obtained owing to an increase in underground ore production, which was partly offset by a reduction in opencut tonnage, as well as to modifications in the recovery circuit. Rate of recovery increased from about 15% to over 82% of the gold contained in the ore and from about 40% to 45% of the contained silver.

Jan 1, 1986

By Karl R. Becker

Detonators representing a sampling of various domestic commercial delay detonators were fired at various direct-current (dc) firing levels. Results of firings using well-below-recommended firing levels showed marked increases in delay times above the nominal values. There was also a marked increase in variation, to the extent that out-of-sequence firings would be essentially assured in any typical blasting round at these low firing levels. Within the range of recommended levels the effects of current increases were not considered to be of great importance relative to other overriding effects, such as the significant difference noted in average values of detonators from different lots having the same nominal delay. This effect, when combined with the normal variation noted among members from the same lot, would cause out-of-sequence firings with detonators from a neighboring delay period. Where comparisons with results from another study were possible, it was found that both studies observed quite similar variations in delay times about the average values, and a lower probability of out-of-sequence firings for the shorter delay period groups. The criterion of the previous study for assessing the likelihood of observing out-of-sequence firings, when applied to the Bureau of Mines data, properly identified two neighboring delay period groups where out-of-sequence firings would occur.

Jan 1, 1981

By C. W. Davis

"A copper-palladium-gold-silver ore is being mined at Salt Chuck, Prince of Wales Island, Alaska, from which a concentrate is produced that contains 40 to 50 per cent copper, and considerable amounts of palladium, gold and silver. There has been much difficulty in obtaining assays for palladium, gold and silver from the mine, smelter, sampler, and umpire that check within reasonable limits. While the results for copper content have not been unusual, the results for palladium have varied as much as 0c8 oz. on 3 oz. material, results for gold differed by 0.1 oz. on 1.6 oz. materials, and for a silver content of 7 oz., results differed by as much as 4.0 oz.The Bureau of Mines was requested to determine the causes of variation in the results of the different assayers, and to develop a satisfactory procedure for analyzing such ore.Three samples of concentrate were received for analysis, two small lots that had previously been assayed by the various laboratories, and one large sample. The large sample was dried and ground in a ball mill, put through a 150-mesh screen, and then returned to the ball mill for thorough mixing. The small samples were ground to pass a 150-mesh screen and then mixed on a mixing wheel.The large sample (No. 1) was analyzed by five different procedures, one of the small samples (No.2) by three procedures, and the other (No. 3) by two procedures (the two small samples being too small for further tests). The different procedures tried and the results obtained arc presented below. The samples of concentrate were from ore mimed and milled by the Alaska palladium Co. at Salt Chuck."

Feb 1, 1926

By John M. Devine

The oxygen bomb-is used extensively for determining sulphur in petroleum, although it has been suspected that the results obtained with this method are somewhat lower than the true varies. In this paper are compared the results given by the oxygen-bomb and Carius methods, the latter being generally accepted as the standard procedure for the determination of sulphur in organic compounds. The Carius determinations given hero were made in connection with a special study of this method.4 Only petroleum oils of the less-volatile type are covered in the present work. Summary and Conclusions. When used with oils containing 2.3 to 0.15 per cent of sulphur the oxygen-bomb method gives results that are consistenly if slightly lower than those obtained with the Carius method. This variation, for the oils used, amounts to 3.1 per cent (on tae basis of sulphur present) for the sample containing 2.47 per cent of sulphur, and gradually increases (as the percentage of sulphur in the oils decreases) to 7.3 per cent for the oil containing 0.15 per cent of sulphur. With the oils studied the presence of ammonium nitrate in the bomb does not influence the results materially.

Jan 1, 1928

By Martin Harper

This paper concludes a five year program on research into the use of a portable X ray fluorescence (XRF) analyzer for analyzing lead in air sampling filters from different industrial environments, including mining, manufacturing and recycling. The results from four of these environments have already been reported. The results from two additional metal processes are presented here. At both of these sites, lead was a minor component of the total airborne metals and interferences from other elements were minimal. Nevertheless, only results from the three sites where lead was the most abundant metal were used in the overall calculation of method accuracy. The XRF analyzer was used to interrogate the filters, which were then subjected to acid digestion and analysis by inductively coupled plasma optical emission spectroscopy (ICP OES). The filter samples were collected using different filter holders or "samplers" where the size (diameter), depth and homogeneity of aerosol deposit varied from sampler to sampler. The aerosol collection efficiencies of the samplers were expected to differ, especially for larger particles. The distribution of particles once having entered the sampler was also expected to differ between samplers. Samplers were paired to allow the between sampler variability to be addressed, and, in some cases, internal sampler wall deposits were evaluated and compared to the filter catch. It was found, rather surprisingly, that analysis of the filter deposits (by ICP OES) of all the samplers gave equivalent results. It was also found that deposits on some of the sampler walls, which in some protocols are considered part of the sample, could be significant in comparison to the filter deposit. If it is concluded that wall deposits should be analyzed, then XRF analysis of the filter can only give a minimum estimate of the concentration. Techniques for the statistical analysis of field data were also developed as part of this program and have been reported elsewhere. The results, based on data from the three workplaces where lead was the major element present in the samples, are summarized here. A limit of detection and a limit of quantitation are provided. Analysis of some samples using a second analyzer with a different X ray source technology indicated reasonable agreement for some metals (but this was not evaluated for lead). Provided it is only necessary to analyze the filters, most personal samplers will provide acceptable results when used with portable XRF analysis for lead around applicable limit values.

Jan 1, 2007