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By Barry K. Johnston, Norman W. Bainbridge, Neville C. Lockhart

CSIRO and its collaborators have developed a major R & D project on dewatering of coal. This involves sub-projects on (i) the fundamentals of coal-water associations; (ii) reducing the variability of product moisture levels from small coal centrifuges; (iii) process mechanisms and optimisation for fine coal dewatering; (iv) pilot scale testing, engineering development and innovation. Results from each of these sub-projects are presented, and the pilot facility incorporating a vacuum filter, belt press, membrane press, hyperbaric filters and centrifuges, is discussed. The vacuum filter and membrane press can be configured for electric-field assisted dewatering, which provides substantial enhancements in the rate and degree of dewatering for fine coal, coal tailings, and other suspensions.

Jan 1, 1995

By R. D. Hansen, R. R. Klimpel

Previous papers by these authors on slurry rheology control grinding aids have emphasized the end-use results and application methodology involved. This paper emphasizes the chemical principles and the influence of various chemical structures behind slurry rheology control chemicals. Particular examples are shown which correlate chemical structure modifications to environmental factors involved in grinding such as pH, shear, ore type, water chemistry, and particle size.

Jan 1, 1990

By P. E. Snoek, R. L. Gandhi, C. S. Miller

Slurry operations are an integral part of mineral processing. There is therefore reason to consider using slurry pipelines for long distance mineral transportation. This paper reviews the current state-of-the art of such systems and, in particular, the design factors which must be addressed. It also discusses the selection of major components such as pipe, pumps, valves and storage facilities. Finally, the major steps required to determine the economic feasibility of a slurry system are listed and the major advantages and disadvantages of slurry pipelines compared with other forms of land transport are summarized. SLURRY PIPELINES: GENERAL OVERVIEW Minerals Transported Long distance slurry pipelines have been successfully used for transporting coal, iron concentrate, copper concentrate, limestone and phosphate. Additionally, several tailings disposal pipelines of considerable size and length have been built, but these generally are not categorized as long distance commercial mineral transportation systems. Table 1 lists selected examples of commercial slurry pipelines.

Jan 1, 1986

By Jim M. Johnson

INTRODUCTION The facility water balance and maintenance of sufficient excess storage volume in the solution control system are often amongst the most critical facets of design and operation of heap leach facilities in cold, snowy climates. The purpose of this paper is to summarize and discuss climatic and operational factors which have a significant impact on heap leach water balance evaluations in high snowfall climates. Example water balance simulations are presented for proposed heap leach projects located in areas subject to high snowfall in the northwestern United States. The climatic data input to these simulations represent both net evaporative and net precipitation climates. FACTORS AFFECTING WATER BALANCE EVALUATIONS The combined effects of seasonal operations, re1atively low evaporative losses, and potentially large inflows to the solution control system from snowpack and spring storms require an enhanced awareness of the factors which impact facility water balance. Unlike operations at mines in more arid climates, seasonal excess water rather than a shortage of make-up water is the rule. A thorough understanding of a number of factors, including regulatory constraints, climatic influences, and impact of operating philosophy and techniques, is critical to successful development of an incident-free heap leach operation under high snowfall climatic conditions. A process water circuit schematic for a typical heap leach operation is shown on Figure 1.

Jan 1, 1988

By Keith G. Wallace, Justus B. Deen, Daniel J. Brunner

This paper describes the impact of natural ventilation pressure (NVP) on the Nuclear Waste Isolation Pilot Plant in New Mexico (WIPP). The WIPP site is a U.S. Department of Energy underground facility for the disposal of low level radioactive transuranic defense generated waste. Because the facility is designed for the storage of nuclear waste, special design considerations are necessary to ensure containment of potential radioactive releases. The main design considerations which influence the ventilation system are the requirements of separate air splits for mining and storage operations and of air filtering before atmospheric discharge in the event of a radioactive release. The leakage between the two air splits must always be from the mining area to the storage area. The transient effects of natural ventilation pressures, caused by seasonal and diurnal surface temperature changes, impact the ventilation characteristics throughout the facility. This paper discusses the measurements taken to quantify the changes in NVP and the engineered systems designed to mitigate against the effects of NVP.

Jan 1, 1991

By J. E. Gebhardt, P. E. Richardson

External control of the electrochemical potential of a bed of mineral particles was investigated by the US Bureau of Mines as a method for controlling particle interaction with organic collectors and, thus, flotation response. A cylindrically shaped, 200- to 300-g bed of sulfide mineral particles was used as the working electrode in an electrochemical-flotation cell. In a pH 9.2 sodium tetraborate buffer, chalcocite floated with ethylxanthate at applied potentials [=] - 0.25 V (versus the standard hydrogen electrode) ; pyrite floated at potentials [=] 0.15 V. Differential separation of a chalcocite-pyrite mineral mixture was obtained by controlling the potential, but the flotation response of the mixture did not follow the behavior predicted from measurements on the individual mineral beds. Chalcocite dissolution products had a deleterious effect on chalcocite-pyrite separation by activating pyrite so that it floated below the potential (~ 0.13 V) at which xanthate is oxidized to dixanthogen. A pyrite bed activated with a copper(II) sulfate solution exhibited a flotation response with a potential dependence between that of chalcocite and pyrite. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1988

By J. D. Miller

Fluid flow phenomena and therefore the flotation efficiency of air-sparged hydrocyclone (ASH) flotation are strongly dependent on operating and design variables such as air and slurry flow rates, underflow and overflow opening areas, percent solids of the feed, reagent levels, particle size and ASH length. Time-averaged multiphase flow characteristics, as determined by X-ray CT (described in a previous publication), are used to understand and explain the steady-state ASH flotation of quartz. A detailed parametric study of quartz flotation by a nominal 2in. diam. air-sparged hydrocyclone (ASH-2C) revealed the influence of these variables on the flotation response, which is discussed in terms of the multiphase flow characteristics. Thus, a phenomenological description of quartz flotation has been established to assist in the further development and utilization of the ASH technology.

Jan 1, 1996

By P. C. Kapur

The hierarchical relationship between three broad kinds of grinding models for a spatially homogeneous, linear, time-invariant batch grinding system are first established. Limiting and asymptotic arguments for arriving at approximate but simpler models are employed in all three cases. These parsimonious models -provide alternate and, in some respects, more incisive and convenient tools for the analyses of grinding processes and simulation of comminution circuits. In the discrete-size, discrete- time class of models, a reduced mill matrix is derived, which is seemingly adequate for those grinding circuits whose identification otherwise is difficult because of limitations on the quantity of data and its quality. In discrete-size, continuous-time types of models, parameter lumping has been employed for obtaining a G-H solution which is quite accurate and exceptionally useful for graphical display of data, model verification, and parameter estimation and simulation. In continuous-size, continuous-time models, a similarity transformation is used for solving the integrodifferential equation of grinding. This solution provides a unified framework for a number of apparently diverse empirical grinding phenomena such as self-preserving behavior of ground particle size distributions and energy laws.

Jan 1, 1987

By R. E. Johnson, J. E. Dutrizac, B. R. Palmer

Silver sulphide (acanthite) and lead sulphide (galena) dissolve relatively rapidly in FeCl3 media with the formation of elemental sulphur and soluble silver and lead chlorides. Parabolic kinetics are observed, and the leaching rates are controlled by the outward diffusion of the AgCl and PbCl2 reaction products through the constantly thickening elemental sulphur layer formed on the sulphide. Hence, both leaching rates are strongly dependent on those variables which affect the solubility of AgCl or PbCl2 at the reaction interface. The rates therefore increase with increasing temperature and total chloride ion concentration, but decrease in the presence of elevated concentrations of AgCl or PbCl2. By contrast, neither sulphide is significantly attacked by ferric sulphate media, even at high Eh values. Although the reasons for the refractory behaviour of Ag2S in sulphate media remain unknown, the low rate of PbS attack is attributable to the passivating layer of PbSO4 and elemental sulphur formed on the surface of the galena.

Jan 1, 1993

By Nora M. Hutt, Kevin A. Morin

Geochemical static tests are a basic component of geochemical assessments and predictions for acidic drainage, and include acid-base accounting and total-metal contents. A key database for such information is the International Static Database (ISD), which currently contains more than 45,000 static-test analyses from over 200 minesites. Such large databases are useful in identifying general trends and, just as important, the percentage of exceptions. General trends and significant exceptions can be seen in the ISD by comparing one parameter against another. This paper shows that bulk neutralization potential (bulk NP) obtained from acid titration is often a good indicator of neutralizing capacity above values of 10 t CaCO3/1000 t. Other types of calculated neutralizing capacity are then compared to bulk NP to determine if they, in fact, reliably represent actual neutralizing capacity and if they can substitute for the more time-consuming and expensive bulk NP. For example, bulk NP correlates better with Carbonate NP (from carbonate analyses) and Total-carbon NP (from total-carbon analyses) than with (Ca+Mg) CaNP (from solid-phase analyses of calcium and magnesium). This means that, in general, (Ca+Mg) CaNP is a less accurate substitute for bulk NP than the other types, and thus requires intensive site-specific justification if a substitution is attempted. This also means that measurement of the frequently less-expensive parameters of total carbon and carbonate can often substitute, within site-specific error bars, for the bulk-NP titration. However, the ISD also shows that non-carbonate minerals make the primary contribution to neutralization in up to 20% of samples, so Carbonate CaNP and Total-carbon CaNP do not always reveal the full neutralizing capacity of a sample.

Jan 1, 2000

By Richard Keith Corbin

Canadian junior mining companies whose gold exploration and exploitation programs take them across the border into the western United States should be prepared to deal with the myriad of title issues involved in acquiring unpatented gold mining claims. The purpose of this paper is to serve as an introductory outline for Canadian junior mining companies to mining laws of the United States, as well as to relevant laws of some of the western gold mining states. Topics will include the five w's (who, where, what, why and when) of Canadian junior mining companies1 rights and responsibilities in acquiring interests in U.S. gold mining properties by claim staking, lease or purchase. Historic terms of common parlance among U.S. miners, such as "claimjumping" are defined and discussed. Various legal doctrines, such as "pedis possessio" and "good faith" in the location of claims are covered as well. Controversial subjects of contemporary interest are addressed in some detail, such as whether to locate a bulk-mineable disseminated gold deposit with placer claims or lode claims, and whether lodes may be staked over placers. By thus heightening the awareness of Canadian junior mining companies, it is hoped that they can be properly prepared to avoid title disputes, and to win lawsuits when they are unavoidable.

Jan 1, 1988

By Mark G. Aylmore, Eric J. Grimsey

Anenopyrite, both pure and in some cases associated with pyrite, was laboratory roasted either isothermally or at a constant heating rate, at temperatures mainly between 723 and 923 K and under environments of air, sulfur dioxide, oxygen and argon, as well as S02/02/H20/N2 mixtures. The mineralogy, arsenic contents and in some cases surface areas of the calcines were evaluated so as to provide an enhanced understanding particularly of the conditions under which the important transformations to pyrrhotite and magnetite occur. A thermodynamic analysis is also undertaken to rationalize the observations and provide some guidance for the operation of commercial roasters.

Jan 1, 1990

By John A. Rajala

The water chemistry of the froth flotation pulp is one of many parameters which can affect the flotation process. The fluid may contain certain inorganic salts which, along with increased ionic strength, can produce undesirable flotation depression or activation. A source of a salt could be the use of calcium chloride to prevent freezing in ore cars, chutes, and bins (Anon., 1980). Alternately, the salt or salts could be initially contained in the water as in the case of sea water and some brackish waters. These salts may become more concentrated because of the need for recycling of plant water due to environmental regulations and/or economic considerations (Davis, F.T., et. al., 1976). The presence of inorganic salts in flotation pulps and their effects upon the recoveries and surface chemistries of different oxide minerals have been the object of various studies. Some researchers (Fuerstenau, D. W. and Raghavan, 1976; Fuerstenau, D. W. and Modi, H. J. 1960; Kulkarni, R. D. and Somasundaran, P., 1977) have reported that addition of a salt can increase or decrease flotation recovery depending upon the particular system.

Jan 1, 1982

The design of solvent extraction plants has been generally based on the assumption of steady operating conditions in both the settler and the mixer units. However, recent experience in both large and small plants has shown this not to be the case. Mixer transients include start up aqueous locking and partial phase separation in secondary mixers, which both lead to reduced plant capacity or overflow of upstream mixers. Analysis of the hydraulic pressure profiles has generated new design methods to eliminate the effects of the partial or complete phase separation. Changes to the method of specification and selection of primary and secondary mixers have been made to eliminate the onset of partial separation during operation. The observation of settler operation has shown that it is also a dynamic process, even under "steady-state" conditions. Four transient phenomena have been identified that lead to internal circulating flows, poor disengagement of fine secondary haze and erratic and high entrainment levels in the discharges. A, first approximation analysis has shown that there are significant pressure differentials within settlers, and these change along the length and with the phase separation rates. A technique to control the effects of these transients was developed that allows plant performance to be improved beyond "standard" expectations. The design and selection of the settler internals is described. Key words: Solvent extraction, Mixer-settlers, Phase separation, Entrainment, Mixer transients

Jan 1, 2003

By E. C. Grunsky

Spatial auto- and crosscorrelation assessment of variables can be carried out using quadratic function estimates. From the function estimates, multivariate relationships of the variables can be determined in the form of spatial factors. The calculation of the spatial factors requires computation of the corresponding amplitude vectors from the eigenvalue solution. This vector reflects the relative amplitudes by which the variables follow the spatial factors. Instability of some of the eigenvalue solutions requires that caution be used in interpreting the resulting factor pat- terns. A measure of the predictive power of the spatial factors can be determined from the auto- correlation coefficients and squared multiple correlation co-efficients which indicate which of the variables are significant in any given factor. The use of unconditional simulations provides a basis by which geological variables of varying spatial ranges can be modelled using the spatial factor technique. Simulations were generated for a variety of ranges and variables were created that form single or multiple combinations of the spatial patterns. The success of the spatial factor technique depends on the amount of associated noise, and the size of the neighbourhood relative to the spatial range of the variable. The predictive power of the components is dependent on these two factors. Problems with collinearity of variables can result in unrealistic eigenvalues and result in the failure of the method. Application of this method to spatial data in mineral exploration can assist in outlining spatially continuous zones of alteration associated with mineralization.

Jan 1, 1989

By Bernard J. Scheiner, R. J. Wesely, Cy E. Jordan, A. D. Zunkel, Gary M. Wilemon

The U.S. Bureau of Mines has investigated leaching of off-grade western United States phosphate deposits using sulfuric acid (H2SO4) in the presence of methanol. A combination of ore grinding followed by sulfuric acid in methanol leaching extracted over 80 pct of the phosphate. This leaching technique significantly limited the dissolution of iron, aluminum, and magnesium impurities and produced a phosphoric acid that was well within the desired limits for these impurities. The dissolution rate of phosphate rock in the sulfuric acid methanol system was significantly slower than the conventional aqueous sulfuric acid dissolution. Initially dissolution of the phosphate particle was controlled by the amount of surface area available to the sulfuric acid reactant. After about an hour of leaching, phosphate dissolution was slowed almost to a stop, limited by the rate of ion diffusion through the calcium sulfate barrier layer surrounding the unreacted phosphate particle. Consequently, the ore was ground below 38-pm to increase the particle surface area available and improve the overall dissolution kinetics and extraction. In addition, the sulfuric acid was slowly metered into the reactor to prevent any excess heat from the mixing of acid with the methanol from simulating the formation of methyl sulfates. The formation of methyl sulfate ultimately lowered the overall phosphate extraction by exhausting the supply of available sulfate ions for the dissolution reaction. Subsequent evaporation of the methanol from the product acid decomposed the methyl sulfates leaving undesirable sulfate ions in the product acid. Slow acid addition to the reactor provided high phosphate extraction and limited the amount of sulfate in the final product acid.

Jan 1, 1993

By H. G. Fleshman

Thousands of years ago, Chinese water well drillers developed a technique for punching holes in the ground by lifting massive metal bits and letting them fall against the rock. With diligence, they could pound away about 2 feet a day. The Chinese drillers pounded holes in the ground this way for almost 2000 years. In the 1860's, French water well drillers developed a perforated bit moistened by fluids pumped into the hole through a hollow rod. The fluids carried the cuttings from the hole and spared the Frenchmen the task of bailing them out by hand.

Jan 1, 1986

By Jon P. Stone

The Automated Minerals Information System (AMIS) is an integrated data base system being developed to support the Bureau of Mines minerals information collection and analysis activities. The system facilitates cross-referencing and integration of domestic and foreign information from a variety of sources. The AMIS provides a central source of minerals information that is versatile and responsive to the needs of problem and policy analysts as well as supporting the needs of those involved in data collection and interpretation. As the AMIS becomes fully implemented, it will become an important tool in forecasting and assessing the impact of policy decisions that affect the supply and demand for minerals. The Bureau of Mines has long been the Federal Government's principal source of worldwide information on non-fuel minerals. Emphasis is placed on the analysis of mineral problems and policies as they affect the world's nonfuel mineral resources. To facilitate timely and accurate analysis, comprehensive data on 87 commodities are collected by various Bureau programs. Minerals information is made available through a number of periodic publications including the annual Minerals Yearbook and monthly Mineral Industry Surveys. These data collection and analysis activities have traditionally been supported by over 200 separate information processing systems. The Bureau of Mines has begun to implement a broad information strategy to provide a better response to the mineral problems and issues of the 1980's. The cornerstone of the Bureau of Mines information strategy is the development of the Automated Minerals Information System. When fully operational, we believe that the AMIS will provide the Bureau of Mines with the most comprehensive source of minerals information available anywhere in the world.

Jan 1, 1982

By S. Zendejas-Mendivil, E. Pérez-Segura

The Cananea porphyry copper-deposit is the site of the second largest mining operation in Mexico. Mineralization is related to quartz-monzonite Laramide stocks that intrude volcanic and volcaniclastic Mesozoic rocks. The ore deposit is a stockwork and breccia-pipes system with Cu-Mo sulfides and pervasive quartz-sericite hydrothermal alteration. A study was made of the arsenic distribution in the mine and the ore-dressing plants. The arsenic (As) in the mine is related to a feldspathic quartz-porphyry type rock associated mainly with the breccia pipe structures (100-700 ppm As in the Veta 7 Breccia). There is vertical zoning, with As decreasing in the deepest part of the breccias. This As mineralization corresponds to a later sulfide hydrothermal stage. The concentrates are made of Cu, Fe and Mo sulfides and some minor quantities of As minerals. The most important copper minerals are chalcocite-covellite, bornite and chalcopyrite. Some of these minerals have 390-880 ppm As. The main As mineral is enargite[ [Cu2.97Fe0.06(As0.90 Sb0.01Pb0 01 )0.92 S4 051 and there are traces of stibioluzonite-luzonite I Cu, .95(Aso.4vSbu.49)0.9rfS4.07-Cu2 93(Aso.H4Sba.10)0.94S4.13] and of another stibioluzonite mineral type with substitution of As by Bi[Cu,96(Ascr,,'Sb0ccrB'OJ3jI~6S] These minerals contribute 80% of the As in the concentrates.

Jan 1, 1992

By C. B. Cecil

The sulfur content of United States coal can be assessed by using a variety of approaches. The sulfur content may be expressed in terms of total sulfur in the coal, pounds of sulfur per million Btu, or sulfur remaining after reduction by coal preparation. In addition, the sulfur content may be applied to the demonstrated reserve base or to coal resource estimates. Unfortunately current data bases do not allow for an integrated assessment at the National level. Although classification of coal resources and reserves according to sulfur content is arbitrary, preferential production of low-sulfur reserves will positively skew the total sulfur of the remaining coal resource.

Jan 1, 1986