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By J. J. Kellar, W. M. Cross, H. Du, C. D. Struckman, D. A. Boyles

Silane coupling agents have been used in the filler industry for years. One particularly unique feature is the ability of the coupling agents to enhance the adhesion between filler and polymer matrices. This paper will review the use of coupling agents for polymer matrix composite applications and discuss a new approach to coupling agent chemistry, namely, direct formation of a silicon-carbon non-hydrolyzable linkage between glass and coupling agent. The grafted silane monolayers were evaluated by infrared spectroscopy to ascertain their surface coverage and relative stability. Finally, composite specimens were fabricated and their mechanical properties were compared with traditional silane coupling agent treatment.

Jan 1, 2003

By James P. Cooney

The global mining industry is in the process of redefining its activity and purpose in terms of sustainable development. This process is impelling a growing number of companies to engage their stakeholders on environmental and social issues. Nongovernmental organizations (NGOs) have customarily acted as critics of the mining industry's performance. A new relationship between mining companies and NGOs is emerging in the context of sustainable development, ranging from dialogue to joint action. If positive interaction among mining companies and NGOs is to succeed, clear terms of engagement must be articulated, and measurable progress toward achieving both corporate and NW objectives must be demonstrated. The experience of Placer Dome is illustrative of the rewards and challenges of engaging with NGOs.

Jan 1, 2001

By D. Denton, C. Peppin, D. Tesarik, D. Bayer, J. B. Seymour

Hecla Mining Company and NIOSH cooperated in a study to document the safety of rock support supplied by reinforced cemented paste backfill at the Lucky Friday Mine. Data are presented on backfill modulus values from laboratory tests and compared with modulus values from in-mine wall closure on the backfill. It is theorized that a compressive zone is created in the backfill between the upper and lower bearing plates on the reinforcing bolts, and that the backfill remains stable as long as the compressive zones from adjacent bolts overlap.

Jan 1, 2001

By Jin Anshi, Wang Dai, Wang Zingshen

Both fire and gas problems in Fully Mechanized Sublevel Caving Coat Face are quite different from those in common fully mechanized coal face. Pouring N2into the goaf would be the best method to prevent fire in the goaf. In this paper how to determine parameters of pouring N2 is discussed. Comparing distributions of gases and temperature before pouring N2into the goaf with those after pouring N2 into the goaf, the effectivenesses of preventing the fire by pouring N2 into the goaf are testified. Some special gas problems appear in Fully Mechanized Sublevel Caving Coal Face, which are proved to be serious and interrelated with pouring N2 into goaf. Finally, a few methods adopted to deal with gas problems are described simply.

Jan 1, 1991

By S. M. Hsiung, Wen H. Su, Syd S. Peng

This paper examines the interaction problems of multiple seam mining by combining underground investigation, laboratory testings, and numerical modeling. One case of multiple seam interaction that occurred recently in West Virginia was carefully studied. Causes for the interaction problems were identified and the corresponding mining recommendations were proposed. The principle of pillar columnization and the effect of a remnant pillar on mining operations in the underlying and over- lying seams were also carefully examined. Considerable attention was given to the effect the pillar size, the pillar width, the coal stiffness, the extraction ratio, the degree of inhomogeneity in the interburden, the overburden thickness, the mechanical properties of the interburden rocks, the strata inclination, the interburden thickness, and the in-situ horizontal stresses have on the pillar load transfer mechanism.

Jan 1, 1986

By Lei Zhang, P. Somasundara

The beneficiation of phosphate is complicated due to its sparingly soluble nature. The surface proper- ties of phosphate and associated minerals are determined, in addition to the ionic composition of the solution, by the dissolution of the lattice ions of the minerals and subsequent complexation, hydrolysis, adsorption, and precipitation of the dissolved species. These, in turn, are influenced by the pretreatment of the mineral. These complex interactions determine the interfacial properties of phosphate and associated minerals and thereby the efficiency of beneficiation processes such as flotation and flocculation. Under- standing of the chemistry involved in such systems is helpful to develop the optimum beneficiation schemes. It is shown that desired selectivity can be achieved by controlling the chemistry of the systems. More important, the need to conduct development tests under plant conditions is clearly demonstrated.

Jan 1, 1999

By I. Stavrakas

This work studies the variations of the electric current caused by the application of an electric field on marble samples when they are subjected to continuously increasing mechanical stress at a constant rate up to fracture. The external electric field is applied in a direction perpendicular to the applied mechanical stress. An increase of the level of the electric current was observed when micro-damages started to occur in the samples. The increase of the electric current was approximately 14%. Consequently, the current started to decay abruptly and the sample failed. This electric current recording is compared with the corresponding electric recording without applying the external electric field (Pressure Stimulated Current technique). Both recordings show similar qualitative characteristics. The most obvious of these characteristics are that the electric current starts to develop when microcrack structures start to form due to the externally applied stress. Both recordings show a maximum in the vicinity of fracture.

Jan 1, 2008

By J. A. Brierley, C. L. Brierley

The history, current applications and future of biotechnical developments in the metals' extraction industry are reviewed. Bioleaching of copper minerals continues to be the most significant application. Uranium bioleaching was successfully demonstrated at industrial scale. Developments are now being made in biooxidative pretreatment of refractory gold concentrates, ores and low-grade materials. Advancements are forthcoming in water and solid mine waste bioreclamation, including metals' biosorption, wetland treatment of acid mine drainage, and biodegradation of cyanide in spent, heap-leach operations. Better understanding of the types and functions of microorganisms involved in metal interactions could advance genetic engineering applications in bioleaching and bioreclamation.

Jan 1, 1993

By J. K. Ahlness

The US Bureau of Mines investigated technologies for determining the integrity of in situ leach mining wells. A self-contained trailer-mounted well integrity testing system (WITS) was designed and built to enable rapid testing of well casings for leaks as required by environmental regulations. The WITS utilizes two inflatable packers to seal off the entire casing length or any portion thereof. Water pressure is built between the packers to the desired test pressure, and the presence or absence of casing leaks is determined by monitoring the pressure drop between the packers. A winch and steel cable are used to run the packers in and out of the well. The WITS underwent an industry field test at the Irigaray in situ uranium leaching mine near Buffalo, WY. A total of 37 wells with an average depth of 69 m (225 ft) were tested at an average rate of four wells per eight-hour shift with a two-person operating crew. This represents a 75% time savings and an 83% labor savings compared to the rigid-pipe method previously used at the mine, with which a three-person crew tested an average of one well per shift.

Jan 1, 1988

By R. Hogg, E. Kaya, H. Cho

Investigations were performed on fine grinding of bituminous coal in a laboratory-scale pulverizer. The results indicated that the breakage behavior at relatively coarse sizes (i.e., greater than about 20 µm) is essentially "normal." However, at fine sizes (i.e., less than about 10 m), there is clear evidence of reagglomeration. A simplified population-balance model for simultaneous growth and breakage is formulated. Breakage rates and breakage distributions were assumed to follow the patterns typically observed in simple grinding systems. It is recognized, however, that solid particles and agglomerates may exhibit different breakage behaviors. Agglomeration rates are assumed to be determined by contact probability, i.e., by the relative numbers of interacting particles. Based on comparisons between model simulations and experimental data, it appears that agglomerate rebreakage rates and fragment size distributions are quite different from those for solid particles. The result is that product size passes through a minimum and then increases with time as agglomeration begins to dominate.

Jan 1, 1998

By J. W. Wilson, Y. P. Wang, M. H. Erten

The use of water is still the most effective and economical means for dust control in underground coal mines today along with dilution by the ventilation current. Studies have shown that the dust capturing capacity of water is a result of a balance of many intermolecular forces. Surfactants are known to reduce such forces by affecting both the surface tension of the liquid and its interfacial tension against a solid. Surfactants can be added to the water sprays to facilitate the dust capturing capacity. A laboratory scale model has been developed in which surfactants were added to the spraying water and preliminary data indicates positive results.

Jan 1, 1991

By R. Poulin, A. Lamontagne, N. Tassé

This paper presents the results of a laboratory investigation aiming to verify the concept of co-mingling of waste rock with layers of compacted tailings. Overall, co-mingling is expected to delay the onset and reduce the magnitude of acid mine drainage (AMD) production in waste rock. To denionstrate the efficiency of the method proposed, five different column tests have been set-up. Columns were fed with deionized water at the top and drainage waters were collected and analyzed. Bacteria counts were done on the tailings and waste rock after the column tests. Permeability in saturated conditions and capillary parameters were measured for the tailings. The results obtained show that the co-mingling method would be effective in mitigating AMD by maintaining nearly water-saturated conditions in compacted tailings, thus reducing oxygen supply in waste rock by preventing thermal air convection and minimizing oxygen advection and diffusion.

Jan 1, 2000

By R. F. Kovar, R. N. Torbin

Foster-Miller has recently developed a new concept for a highly specialized shaft lining system. This innovative shaft lining system uses a continuous slip forming placement technique, lining the shaft from the bottom up such as in a raised bored shaft. Although this part is not unique, the concept is designed to use polyurethane foam instead of concrete for the liner material. Furthermore, the concept is designed to attain rates of advance of 30 m/h (98 fph). The polyurethane foam liner is designed to be thinner (100 mm or 4 in.) than a conventional concrete liner (300 mm or 12 in.). It will eliminate the high cost associated with the erection and operation of an on-site concrete batch plant. The system will be designed to operate remotely, requiring few personnel for its operation. This system (or parts of it) may be appropriate where fast construction speed is required or where a jointless liner is needed.

Jan 1, 1990

By F. G. Miller, M. Polat, S. Chander

Flotation was used to achieve improved separation of magnetite from the float and sink products obtained from heavy medium separation and to reduce the load of the medium cleaning circuit. The investigation was carried out in two successive phases. In the first phase, tests were performed on in-plant samples from the Homer City Coal Perdition plant to determine what effects variables such as medium density, particle size and magnetite source had on the efficiency of the process. In the second phase, the optimum conditions determined in the first phase were used to determine the applicability of the process to other selected coals from central Pennsylvania. It was observed that flotation was very effective in the separation of magnetite from coal. In most of the cases investigated, the magnetite recovery was approximately 99% with a magnetite grade ranging from 95 to 99%. The grade of the magnetite decreased as the ash content of the coal increased and the particle size of the magnetite decreased.

Jan 1, 1994

By Z. F. Wang, W. K. Choi, A. E. Torma

The present study has investigated the bioleachability of low-grade and high-grade pyritic gold ores and the extraction of gold from the leach residues of bioleaching with thiourea solutions. Final gold extractions as high as 96% were obtained from the high-grade ore and above 93% from the low-grade ore. The gold extraction was found to follow the extent of pyrite biooxidation. Using a cyclic voltammetric technique and carbon-paste-FeS2 electrode it was found that the semiconductor pyrite oxidation involves many intermediate electrochemical reactions. Furthermore, the oxidation is solid-state diffusion controlled as suggested by chronoamperometric and chronopotentiometric measurements.Using Sand's approach, the activation energy of solid-state diffusion biooxidation of pyrite was determined to be AEa=22.4 kJ. A generalized model for the mechanisms of pyrite oxidation has been presented.

Jan 1, 1990

By R. K. Paramguru, K. Srinivasa Rao

This paper describes a new approach for examining the kinetics and mechanism of zinc dissolution from sphalerite concentrate in acidic ferric sulfate solution in the presence of manganese dioxide. A literature search was performed to access the possible action of the two oxidizing agents, i.e., ferric ion and manganese dioxide. The possibility of galvanic coupling between ZnS and MnO2 and the cyclic action of the redox couple, Fe2+/Fe3+, on these two minerals were theoretically examined based on corrosion principles. Expressions for the mixed potential (Em) and the mixed current (im) were derived for the relevant corrosion and galvanic couples. Leaching experiments were conducted to establish which of the above phenomena is operative during leaching. The results indicated that the dissolution mostly occurs by the action of ferric ion on ins producing ferrous ions. The presence of MnO2 enables a quick conversion of ferrous to ferric, which maintains the rate of in dissolution. The process has promising features for commercial exploitation.

Jan 1, 1999

By R. I. Pennington, J. L. Vanderbeek

Investigations have been conducted at Chino Mines Co. into the effect that SAG mill recycle material (critical size) exerts on SAG mill throughput and specific energy requirements. Tests were conducted on laboratory, pilot, and plant scales to evaluate the merits of alternative treatment options. Removing critical size material from the SAG mill circuit has been shown to improve new feed rates by 84% with a reduction in specific energy (kWh./t) of 88%. Test results obtained to date are presented.

Jan 1, 1987

By G. Barbery

A review is given of the present applications of random sets and integral geometry in fragmentation and liberation models of ores and minerals. Although attempts have been made in the past to apply such mathematical techniques to the comminution of solids, it is shown that it would not result in major progress. In liberation modeling, it is demonstrated that the approach can lead to fruitful results. Following a recent paper by Davy (1984), a model of liberation prediction is developed that can be calibrated for ore texture and breakage using image analyzers. The model is demonstrated for the case of a Poisson polyhedra ore texture and monodisperse fragment size. The model enables prediction of the complete composite particle distribution and thus is valuable for integration of ore breakage models with minerals separation models.

Jan 1, 1988

By Keith G. Wallace, Robert Wise, Ian J. Duckworth

This paper describes a case study for the ventilation planning at Utah Fuel Company's Skyline Mines which are located outside Price. Utah. The Skyline Mines are currently comprised of two longwall coal mining blocks located in two different mines. A third replacement longwall block is currently being developed. Future ventilation systems for the mines were determined by establishing ventilation models developed from data collected during a detailed ventilation survey. The paper discusses the challenge to coordinate immediate ventilation requirements with long-term demands. The continuous movement of the longwall, which frequently represented the only open split in the ventilation network, resulted in cyclic ventilation demands dependent upon the length of the tailgate. A series of system configuration changes were recommended based on the results of the network modeling exercise and an economic evaluation of the various options. The scope and cost of the configuration changes, and the mead improvement resulting from these changes is discussed.

Jan 1, 1995

By William H. Pomroy, Annie M. Carigiet

This U.S. Bureau of Mines report is an analysis of underground coal mine fire incidents occurring in the United States during the 15 years from 1978 through 1992. The fire data used in this analysis were obtained from Federal Mine Safety and Health Administration (MSHA) mine fire investigation reports. Fires were analyzed by year, state, coal bed thickness, mining method, evacuation measures taken, ignition source, burning substance, location, equipment involved, detection method, time of day, number of injuries and fatalities, and method of extinguishment. In all, 164 fires are reported, or an average of 10.8fires per year. The most common ignition source was electricity, the most common burning substance was coal, the most frequent fire location was the belt entry, belt conveyors were the most common equipment involved in fires, and water was the most common extinguishing agent.

Jan 1, 1995