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By Ken-ichi Miyazawa

A Center of Excellence (COE) titled the Creation of Nature-Guided Materials Processing, called Nature COE, has been established at Nagoya University. In the Nature COE, a new field of material research is being developed through learning the laws of nature, namely, methods of attaining ?appearance of the maximum function under the minimum substance and energy consumption?, which the nature and living organisms have acquired through their evolution in long period. As one of the specific features, an ?Open Cluster Program? was originated for promoting the researches conducted by young researchers and Ph.D. students with those in and out of the university and also for fostering them, together with such educational programs for Ph.D. students as the research incentive, the oversea training and the international lodging seminar programs. The Open Cluster Program has been found to be effective for fostering of young researchers and students, for promoting their researches, for gathering researchers and knowledge from the world and for propagating the research fruits. Through conducting these programs, world-highest intelligent fruits and a gathering of young minds to lead the new field are expected. In this COE, the researches are conducted on (1) materials used for living bodies, (2) mimicking structures which nature or living bodies are forming and (3) materials processing by mimicking processes to form the structures observed in the nature or the living bodies. These researches are conducted by four groups to extend the processes observed in the natural world to a new type of processing that is thoroughly rationalized by plunging a scalpel of engineering, and to establish a new academic field of materials science and engineering.

Jan 1, 2006

By K. E. Gonsalves, G. M. Chow

"Nanostructured powders (particle diameter of 1 - 100 nm) have uses in electronic, magnetic, structural, thermal applications as well as advanced processing of materials. Among many methods of making nanostructured powders, chemical routes offer many attractive features such as feasibility of cost-effective bulk quantity production, design of chemistry at the molecular scale, and chemical homogeneity of the powders. In this talk, two systems of chemically synthesized nanocomposite powders are presented, namely, granular magnetic materials of Fe-Cu and Co-Cu, and thermal-structural materials of AIN-BN. Synthesis and processing, characterization and properties of these materials are discussed.IntroductionNanostructured powders (particle diameter of 1 - 100 nm) are attractive materials because of many useful properties (e.g. catalytic, optical, magnetic etc.) and processing advantages (e.g. lower sintering temperature) [1]. There are many methods of making nanostructured powders, for example, physical and chemical vapor deposition, mechanical attrition, and solution chemistry [1, 2]. A common method of making composite powders involves the grinding, mixing and blending of constituents powders, but it has the limitation of inhomogeneous mixing. Chemical routes have many useful features. Using solution chemistry, precursors can be molecularly tailored and homogeneously mixed at the molecular level. The chemical approach may result in better properties of the final product. Compared to vapor-phase fabrication techniques, chemical routes are more cost-effective in producing large quantity of material. In addition, control of particle size, size distribution and stabilization of the nanoscale particles against agglomeration can be more effectively manipulated via solution chemistry.In this paper, we present an overview of some of our work in nanocomposite powders prepared by solution chemistry. Metallic systems of FeCu and Co-Cu, and ceramic system of AIN-BN are discussed. The powders were characterized using x-ray diffraction (XRD) , scanning electron microscopy (SEM), conventional and high resolution transmission electron microscopy (TEM, HRTEM), vibrating sample magnetometry (VSM), inductively coupled plasmaatomic emission spectroscopy (ICP-AES)."

Jan 1, 1994

By Hande Cavus, Ibrahim Yusufoglu, Cem Kahruman

"In this study, ammonium tetramolybdate (ATM) was obtained as the intermediate product of ammonium heptamolybdate tetrahydrate (AHM). The thermal decomposition mechanism of ATM was investigated under nonisothermal and isothermal conditions in air and inert gas atmospheres. Nonisothermal experiments were carried out by TGA/DTA/MS while TG was used for isothermal conditions. Characterization of the decomposition products were carried out by XRD and FT-IR. The thermal decomposition of ATM in air proceeds in a single step and forms M0O3 while [(ÍÇ4)2è]ïïï83Ìïè3 and molybdenum suboxide (Ìïè3.÷, ÷=0.025) were obtained in the first and the second steps of thermal decomposition in He, respectively. Activation energies, frequency factors and kinetic model equations were determined for thermal decomposition reactions. Fractional conversion-time diagrams were compared with diagrams drawn according to kinetic model equation.IntroductionM0O3 is usually used as catalyst in industry [1]. AHM is the basic source to produce molybdenum containing catalysts used in petrochemistry [2]. The oxides of Li, V, W, Te, Bi and Sn are doped in M0O3 to produce catalysts, which find commercial applications in the industry. The properties of M0O3 are affected by dissolution, settling, calcination, drying and thermal decomposition processes [1]. There are several studies in the literature about the thermal decomposition of AHM and the characterization of the decomposition products in different gas atmospheres and at various heating rates [3-19]."

Jan 1, 2012

By Shi Yuan

Molten copper was deoxidized using a one-end-closed yttria-stabilized zirconia (YSZ) tube. A thin layer of porous Ni-Zr02 cermet electrode was deposited on the inner wall of the YSZ tube. The outer surface of the tube was in contact with the melt and the inner surface with a flowing reducing gas. Without applying external EMF, the melt was deoxidized by short-circuiting the melt with the cermet electrode. The deoxidation process was analyzed and the rate controlling steps were identified. These experiments were also conducted at different temperatures to evaluate the effect of temperature on the deoxidation kinetics.

Jan 1, 1994

By D. Zhao

High temperature deformation characteristics of austenitic 304L, and martensitic 410 and 416 stainless steels were investigated by conducting compression tests over a wide range of temperatures and strain rates (950-1250 C and 0.001-20 s-1). Flow behaviors of the three alloys were characterized. Optical metallography was performed to determine the as-deformed microstructures. The flow behaviors were related to microstructural phenomena during high temperature deformation. Dynamic recrystallization was responsible for the flow softening. Both dynamic and static recrystallization were operating, and the recrystallized grain size increased with increasing temperature and decreasing strain rate. Strain rate sensitivity was found to increased with increasing temperature and decreasing strain rate. No defects such as cracking and shear bands were observed at those test conditions. Preferred processing conditions can be selected by considering as-deformed microstructure and strain rate sensitivity.

Jan 1, 1994

By Bekir Karasu

Boron raw materials are amongst the most important natural sources for many industrial branches and their values become increasingly raised with the discovery of boron usage in many new technological fields. All the countries in the world are unfortunately not as lucky as Turkiye and USA where major boron deposits are mainly located. It is widely known fact that on one side, boron is very precious component with its technological importance, on the other; only its limited sources are available. Therefore, even its wastes have to be evaluated and regained. In the present work wastes of Etibor Kirka Borax Company of Turkiye were used in the production of opaque frits which was suitable for floor tile glazes. Standard and newly produced frit based glazes were applied on the pre-engobed floor tile bodies and single firing was employed. Final products were examined according to the certain standard tests and their microstructures were also investigated. All the results confirmed the evaluation of boron wastes in opaque floor tile glazes.

Jan 1, 2006

By Ricardo Badilla-Ohlbaum

Copper has been used by man for a very long time and unlike certain other metals, it is an essential element for life. Its toxicity arises both from a deficit and excess copper exposure/intake. The focus of the current discussions in countries of the European Union (EU) and in some USA States, is based on the concerns, independent of the scientific facts and the economic status of these claims, of the negative influence of copper and other metals on health and the environment. These discussions have influenced the new regulations of copper in drinking water, and the approach to regulate the appropriate levels of copper in surface water, soils and sediments. To illustrate the challenges ahead for copper, the evidence by which the current US Environmental Protection Agency (USEPA), the World Health Organization (WHO) and EU recommendation and regulations regarding copper in drinking water have been derived is presented and discussed. The gaps between the demands for new standards of health and the environment and the practical scientific tools to achieve these goals are presented, and the need to develop new regulating paradigms is also illustrated. The introduction of methodologies for the regulation of essential elements and acute inorganic substances in drinking water is discussed, as well as the status of the present approach contained in the International Program of Chemical Safety Environmental Health Criteria, (EHC) N° 170. The impact of the possible restrictions on the use of copper in the EU because of health and environmental concerns in terms of the world market for copper is discussed.

Jan 1, 1999

Lance based copper-nickel matte converters have become an established technology in the field of base metal sulphide smelting and converting. An Ausmmelt® converter is currently being constructed at Anglo Platinum in South Africa to convert a nickel-copper rich matte containing platinum group metals (PGM's). The accurate prediction of the matte chemistry is required to control the composition at the endpoint which influences segregation of PGM's during the subsequent slow cooling and magnetic separation processes. A hybrid modelling approach is introduced in this paper that incorporates both the effect of thermochemistry and system dynamics. It will be shown how the model relates to fundamental conservation laws, while still providing enough flexibility to adapt to changing operating conditions. It will also show how off-line modelling can be incorporated into a robust on-line model. Based on the data from many pilot plant trials, the model prediction performance is shown to be within the accuracy requirement set by industry and therefore constitutes a reliable basis for model based control. The final generic model structure takes on the form of an thermodynamically integrated ARMAX hybrid model. The final model has the advantages of being dynamic, adaptive, robust and it can be related to thermochemical fundamentals.

Jan 1, 2002

By Robert D. Pehlke

"The evolution of oxygen steelmaking is reviewed and new operating processes are described. The developments which could impact this technology are summarized. Staged and continuous steelmaking are considered in the light of new technologies. The future opportunities for oxygen steelmaking processes are overviewed. IntroductionThe use of oxygen in steelmaking was originally brought on the scene by the development of pneumatic steelmaking. Sir Henry Bessemer in England originally conceptualized the use of gaseous oxygen in steelmaking, and then he and William Kelly in Eddyville, Kentucky independently developed the original pneumatic process which involved blowing air through a bath of molten pig iron to oxidize the carbon and silicon and produce steel. This process and many following processes, including those which would use pure oxygen gas, have been proposed.Beginning with the first commercial oxygen steelmaking vessels at Linz, Austria in 1952, the world steelmaking industry has adopted this style of processing. In general, the process has involved the use of steel scrap in amounts from 20 to 35% of the metallic charge with molten pig iron produced in blast furnaces making up the remainder. The impurities in the charge are oxidized through the use of oxygen gas injected into the steelmaking vessel.However, currently being adopted into commerical practice and on the horizon are a number of advances in this process which include the use of iron ores as a source of iron and oxygen, the use of an all scrap charge, incorporation of pre-reduced iron, the use of auxillary fuels to change the balance of cold and liquid iron-base charge materials and numerous refining techniques."

Jan 1, 1988

By Tatiana Pereira Moreno, Priscilla Aki Mori de Hanashiro, Viviane Tavares de Moraes, Denise Crocce Romano Espinosa, Hugo Hashimoto

"Nowadays, End-of-Life (EoL) Liquid Crystal Displays (LCDs) are traditionally disposed in landfills. The increasing access to LCD technology over the last years by Brazilian consumers has intensified LCD' s disposal as an environmental and economic issue. This study aims to characterize used LCDs to identify the main components for recycling. Characterization was performed through scrap disassembly and its components were identified, separated, and weighted. LCDs were disassembled and the following divisions were applied: screen, metal frame, polymeric frame, polymeric sheets and electronic part. Some techniques were used to determine the concentration of Indium in the LCD, the glass/plastic ratio and the different kinds of polymers that compose the screen. The techniques used for characterization included inductively coupled plasma optical emission spectrometry (ICP-OES), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). This method, when applied to a wide range of LCDs, can allow the development or improvement of an EoL management of LCD.IntroductionWaste Electrical Electronic Equipments (WEEEs) are waste from discarded equipment, such as computers, monitors and cellphones [1]. Over the past years, treatment of WEEE has been emphasized. It occurs due to the technology's advancement that leads to an even larger increase of WEEES [2].Among WEEEs, there are the liquid crystal displays (LCD). LCD technology is applied in cell phones, tablets, computers and monitors. Nowadays, it's the most well known technology when it refers to monitors, due to its advantages over the Cathode Ray Tube (CRT) technology. Some of them are energy saving, smaller size and no radiation emission [3].This feature in the LCD's global market along with the speed at which electronic equipment becomes obsolete affects society economically and ambiently.This issue becomes even more serious when considering the final destination of the liquid crystal displays. LCDs are lead to landfills as other WEEEs. Besides the different materials long degradation time, the environment is damaged by the disposal of the potentially reusable and hazardous materials [ 4]."

Jan 1, 2014

By Sadegh Safarzadeh, Anne-Marie Suriano, Stanley Howard

The electrodeposition of metal ions from aqueous electrolyte solutions has been a well-known process for the last half century. With numerous industrial applications such as electroplating, electrowinning and electrorefining, the kinetics of electrochemical reactions involved in the process has been extensively researched. Arrhenius-type rate equations, the Butler-Volmer equation, and the empirical Tafel equation are among the most important models to explain the rate of electrochemical reactions. The study of the kinetics of metal deposition is critical to understanding the underlying mechanisms through which a certain morphology of metal deposit is formed on the cathode. The purpose of this paper is to elucidate the influence of experimental parameters such as pH and additives on the rate and the reaction mechanism determining the rate limiting step of the electrodeposition reactions.

Jan 1, 2015

By Hubert Bril, Priscilla Pareuil, François Bordas, Emmanuel Joussein, Jean-Claude Bollinger

"According to the legislation, valorization type, origin and characteristics of waste material, various standard procedures are available to evaluate environmental impacts. A Mn-rich slag was sampled from a metallurgical plant. After its characterization (elementary analysis and mineralogy), five standard procedures were carried out (i.e. TCLP, EN 12457-1). Each fixed parameter of the standards was systematically studied in a large range: pH, Liquid/Solid ratio, contact time. For example, EN 12457-1 led to a low ME mobilization, increasing with the L/S ratio, the contact time and an acidic pH. As a conclusion, the representativeness of the considered parameters and their potential variations are predominant to assess of the real environmental impact during slag reuse. Introduction Recent studies have been carried out about environmental impacts of waste containing metallic elements (ME) because of their potential mobility [1-7]. Indeed, slags are either dumped or valorized in various activities such as building materials. In order to assess environmental risk, various standard procedures are used depending on country legislation, origin of waste and valorization way. Results of leaching tests are linked either to special legislation (e.g. Dumping: EC, Council Decision 2003/33/EC, Construction products: EC, Council Directive 89/106/EEC) or to legal levels used in drinking water (Directive 98/83/CE) when leachates could migrate to groundwater. If ME in leachates are lower than drinking water authorized levels, the waste will be considered as non-hazardous. On the contrary, if the leachable amounts exceed them, the question about the risk has to be posed. Beyond the abundance of leaching tests available, variety of operational conditions induced by these regulatory tests does not make the choice easier. According to operational conditions induced, ME release could vary from one test to another one. ME concentrations in leachates depend on pH, Liquid/Solid ratio, contact time and particle size [3]. To highlight the importance of these operational parameters, potential risk for valorization of a manganese-rich slag was assessed by comparing several standard leaching protocols [8-12] with a global study dealing with the influence of operational conditions. For each regulatory protocol, the most influential parameters (L/S ratio, pH, particle size and contact time) have been studied in a large range."

Jan 1, 2008

By Roberto Giovanardi, Isabella Lancellotti, Luisa Barbieri, Ercole Soragni, Fernanda Andreola

"Recovery of precious metals (PMs) is a present topic, as they are used almost in every electronicelectric device. Gold is the second PM in order of consumption (following silver) and it is almost ubiquitary in electronics where it mainly finds application to produce bonding wires in integrated circuits and as a coating for contacts and connectors. Given this, discontinued electronic and, with a minor role, electric devices may represent a primary source of PMs as gold mines or jewelery wastes.At present the recovery of gold from such waste is generally accomplished by two strategies: by oxidative thermal treatment followed by metallurgical or chemical processes or by cyanide chemical etching; both techniques do not represent the optimum as the first one deserves a great amount of energy and non-combustible pollutant slag and fumes are produced, while the second procedure comports the use of a highly pollutant agent as cyanide.The aim of this work is the characterization of different electronics scraps to evaluate the gold concentration, and the selective recovery of this metal using enviromentally-friendly techniques. In particular, a new process was developed in order to overcome such environmental and efficiency issues. The process reaches the goal of detach the gold film from the substrate by selective leaching of the supporting metal.IntroductionThe treatment of waste from electrical and electronic equipments is a current topic as their role in modern life is increasing. The disposal of such waste represents both an environmental and an economical concern due to the vast amount of both precious and non precious metals.The use of precious metals (PM) in this field is of primary importance given PM’s unique properties, which give to each of them a specific and irreplaceable role. Silver is the most used, with a demand of over 5000 tonnes per year, mainly for switches and contacts in electric appliances. Gold is the second PM in order of consumption (over 250 tonnes per year and 8% of the total demand) and it is almost ubiquitous in electronics where it finds application to produce bonding wires in integrated circuits and as a coating for contacts and connectors. It is also used as solder in integrated circuits (in alloy with tin) or for wide coatings where it ensures protection against corrosion. Palladium, platinum, rhodium and iridium follow in order of consumption [1- 3]."

Jan 1, 2008

By R. C. Chaturvedi, S. B. Padwal

"Padwal and Chaturvedi have developed the model based on M-K theory, considering Hosford's yield criterion and critical thickness strain criterion"" to predict the sheet metal forming limits under simple (constant) strain ratio paths. This analysis has been extended in this paper to predict the sheet metal forming limits under complex strain paths. The effects of exponent ""a"" in Hosford's yield criterion and strain paths on the forming limits under complex strain paths are studied using this analysis. The predictions of the present analysis are compared, both for simple and complex strain paths, with experimental results of Ishigaki for A.K. steel and also with the predictions of Rao and Chaturvedi's model. The quantitative analysis of the error in predicting the forming limits has also been carried out using a method suggested by the authors earlier.1. INTRODUCTIONThe constant strain ratio condition has been assumed in the theories developed for prediction of forming limit diagrams (FLO). In actual forming operation, this condition is seldom satisfied. Even in the case of simple single stage press formed components, the strain path becomes curved and non-linear. In the case of pressings with complex shapes, or multiple stages of forming, the changes in strain path are more pronounced and even abrupt.Experimental study of the forming limits, under two stage strain paths, by Ishigaki [1], has shown that the forming limits are path dependent. It has been observed that the forming limits lower than that under simple strain paths, may be obtained under certain strain paths (when the first stage strain path is either equibiaxial tension or uniaxial tension, followed by the second stage strain path as plane strain). Rasmussen's work [2J, on the theoretical study of forming limits under curvilinear strains paths, has shown that a large drop in formability can result from very small changes in strain path. Thus if a deformation process gives rise to failures due to plastic instability, the failure is not necessarily due to insufficient formability of the material. In such cases, FLOs based on constant strain ratio path should not be used directly in predicting the success or failure of the forming operation. Thus the knowledge of forming limits under complex strain paths is of great importance to the interpretation of press-shop problems."

Jan 1, 1994

By C. L. Lin

Transformation of linear grade distribution to volumetric grade distribution has been used to estimate the actual mineral liberation during wet, batch, ball mill grinding of a copper ore. The degree of liberation based on the multicomponent-multisize grinding liberation model using volumetric grade is lower than the apparent degree of liberation estimated from using King's linear intercept model.

Jan 1, 1987

By Kazuaki Mita

There are various intermetallic compounds in the Zn-Fe system. We synthesized them at about 673K. A specimen was examined chemically and X-ray diffraction was applied to ensure the formation of intermetallic compounds. Material containing two phases was placed in a Knudsen type effusion cell and the mass spectrum studied to evaluate the vapor pressure of zinc. The thermodynamic properties of intermetallics was then evaluated through measured intensity.

Jan 1, 1999

By Yang Hong-ying, Yu Juan

Electrochemical behavior of natural chalcopyrite in electrolyte solution at pH value of 6.97 was studied by cyclic voltammetry, X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy. The results showed that the electrochemical processes occurred on electrode surface were controlled mainly by the growth of sulfur species at lower applied potentials (<0.35Vvs.SHE), and the oxidative dissolution of sulfur species and the hydroxylation of iron at higher applied potential (>0.45V). The EIS spectra of oxide product layers could be illustrated by the equivalent circuit of Re(QdlRct(QfRf)), and the degree of hydrophilicity for chalcopyrite was higher when the value of charge transfer resistance Rct. was greater. The optimum potential range for the floatation of chalcopyrite in collectorless solution at pH value of 6.97 was between OCP (0.165V) and 0.35V.`

Jan 1, 2015

By Kandipati Sreenivasarao

A promising method for removing heavy metal ions from dilute effluents is ion- or precipitate- flotation, in which a suitable collector is added to form hydrophobic metal-collector complexes or compounds that can be collected as foams. We have successfully removed Cu(II), Cd(II), and Pb(ll) from dilute solutions using sodium dodecylsulfate and ethanol as collector and frother respectively. However the process would not be economically viable unless the collector could be recycled, and the heavy metals recovered in a concentrated, preferably marketable, form from the foams. We investigated four different methods to decompose heavy metal-dodecylsulfate complexes, namely precipitation of hydroxides, precipitation of sulfides, chemical stripping, and electrolysis. We compare the performance of these methods. In each case the observed behavior is related to known thermodynamic data, and potential applications are discussed.

Jan 1, 1995

By K. Soldenhoff

The Bulong deposit, situated near Kalgoorlie in Western Australia and owned by Resolute Limited, is a lateritic deposit containing on average 1.1% nickel and 0.09% cobalt. A process has been developed and tested at the mini-plant scale for direct solvent extraction and separation of Co and Ni from solutions derived by acid pressure leaching of Bulong ore. In this paper, two solvent extraction processes are described. The first process uses Cyanex 272 to extract cobalt and reject nickel to the raffinate. The second process uses Versatic 10 to extract and purify nickel. The loaded strip nickel solution is suitable for electrowinning. Results of both batch laboratory tests and continuous mini-plant trials are presented. The selectivity of the solvents with respect to the major impurities such as Mn, Mg, Ca, and Zn is also discussed.

Jan 1, 1998

By Hiroshi Nakajima, Kotobu Nagai, Toshihiro Hanamura

"Low carbon ferritic steel bars with ultra-fine grain structure was developed through a warm rolling for the first time by the present authors. They show better low temperature toughness than conventionally hot-rolled plates. Hence, the brittle fracture surfaces in Charpy tests were examined in terms of the effective grain size of fracture, compared with those of conventional QT steels. The ductile-to-brittle transition temperatures were in good accordance with those for the QT steels if referred to the effective grain size of fracture: · However, the size was a few times that of the ferrite grain. This means the grain refining is not yet fully utilized from the viewpoint of low temperature toughness. The anisotropy of· the impact properties and the annealing effect of highly dislocated structure on the toughness are also discussed in the present paper.IntroductionFor structural materials, both high strength and good toughness are required. Well-known approaches for obtaining better toughness for steels are as follows:1) Grain refining2) Addition of Ni3) Thin plate effect by cracking parallel to the rolling direction prior to crack propagation4) Contribution of metastable austenite.Among them, only the grain refining can raise the strength and improve the toughness. And it is well known that the finer the ferrite grain size, the lower the ductile-to-brittle transition temperature. For example, in the case of 0.11 carbon steel, the transition temperature decreases linearly to in d 1/2 [1 ]. However, these have been told in the regime of coarse grain size that is larger than 10 µm in diameter. There ~as .been no study dealing with the low temperature toughness in the regime of ultra-fine grain size with a diameter in the order of 1 µm."

Jan 1, 2000