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By H. F. Niemand, C. J. Postma, P. L. Crouse

"SynopsisThe separation of zirconium and hafnium is essential in the nuclear industry, since zirconium alloys for this application require hafnium concentrations of less than 100 ppm. The separation is, however, very difficult due to the numerous similarities in the chemical and physical properties of these two elements.Traditional methods for separation of zirconium and hafnium rely predominantly on wet chemical techniques, e.g. solvent extraction. In contrast to the traditional aqueous chloride systems, the AMI zirconium metal process developed by Necsa focuses on dry fluoride-based processes. Dry processes have the advantage of producing much less hazardous chemical waste.In the proposed AMI process, separation is effected by selective sublimation of the two tetrafluorides in an inert atmosphere under controlled conditions, and subsequent selective desublimation. Estimates are made for the sublimation rates of the two tetrafluorides based on the equilibrium vapour pressures. A sublimation model, based on the sublimation rates, was developed to determine if the concept of separation by sublimation and subsequent desublimation is theoretically possible.IntroductionZirconium requires several purification steps to conform to nuclear-grade specifications. Little information is available on the sublimation separation of Zr and Hf compounds, especially in the fluoride form, the majority of which deals with sublimation under vacuum conditions. On the industrial scale, only vacuum sublimation of ZrF4 has been reported. No records were found for the sublimation of ZrF4 in an inert atmosphere. Information on the sublimation rate of ZrF4 or HfF4 in an inert atmosphere is also limited. The rate is assumed to be dependent on several factors, of which temperature, area, and composition are considered the most important."

Jan 1, 2015

By Ken Wood

"A reliable source of water of an acceptable quality is vital to the success of any mineral processing plant using wet methods. For Cerro Verde, a new 108,000 t/d copper mill in southern Peru, the main source of raw water is the Chili River. The Chili River is heavily contaminated with raw sewage, industrial wastewater and agricultural runoff, and can also receive high sediment loads during the rainy season. The initial water treatment plant could not supply design flows of water due to the exceptionally poor water quality. Problems with treated water quality caused significant difficulties with water consuming equipment, such as the plant cooling systems. This paper details the Cerro Verde water system and changes from design through to start up from a mineral processing perspective.INTRODUCTIONMining, and mineral processing in particular, is a water intensive activity. Improving water system design and practice are key strategic requirements in moving toward a more sustainable mining industry. This case study forms a basis for ongoing research into water use and reuse at mines and mineral process plants, conducted by AJ Gunson, under the supervision of Dr. Bern Klein and Dr. Marcello Veiga at the University of British Columbia. The case study material was gathered through involvement with the design, startup, and redesign of the Cerro Verde water system.Cerro Verde is a low-grade copper porphyry mine, located near the city of Arequipa in southern Peru, at an elevation approaching 2,800 m. In 1972, one of the world’s first copper Solvent Extraction – Electrowinning (SX/EW) facilities was built on the site, processing oxide ore from two main open pits. In 2004, the operator, Sociedad Minera Cerro Verde S.A.A. (SMCV), approved a 108,000 t/d expansion project to process sulfide ore reserves through a new concentrator plant. The plant was designed under extremely tight schedule and capital constraints, with a mandate to intentionally avoid any overdesign."

Jan 1, 2008

By C. Wen

In Huoqiu region of Anhui Province, Fe2O3 occurs mainly in the form of specularite. Besides quartz, the gangue minerals include iron-bearing silicates such as chlorite and sericite which account for about 10% of the total gangue. The separation effect of conventional collectors is poor in the flotation of the minerals, that is, the average grade of iron concentrates is only 60-62%. Using the developed amphoteric collector can successfully realize not only the separation of specularite from various gangue minerals with results of iron concentrate grade above 65% and iron recovery of above 80% but also low temperature flotation at 15°C.

Jan 1, 2012

By C. J. Van Treeck

PGE concentrations of 18 g/t occur in the pyroxene rich rocks at the Union Bay Alaskantype complex. This PGE enrichment is hosted in magnetite veins. These veins cross magmatic layering and have an irregular morphology in both outcrop and thin section. Fe-Ti oxide geothermometry suggests that this mineralization took place between ~700-400°C. A variation in the amount of ilmenite and Mg- Al spinel exsolution in magnetite correlates with temperature estimates, lower temperature magnetite has less exsolution. Hydrous silicates form an alteration envelope around magnetite veins with a formation temperature of <575oC, vary with temperature, and contain appreciable amounts of Cl. Interaction of a PGE-Fe-Cl rich fluid with clinopyroxene increased the fluids pH and decreased PGE and Fe solubility depositing a PGE enriched magnetite within the Pyroxenites and Olivine Pyroxenites of the Union Bay complex.

May 1, 2003

By Gerald Verbeek, Erick Baziw

Downhole Seismic Testing (DST) is a very popular applied seismology site characterizing tool within geotechnical engineering. A challenging aspect of DST is to characterize the acquired seismic data sets to determine the analysis method that will result in the most accurate interval velocity values. BCE has invested considerable resources into developing Seismic Trace Characterization (STC), which uses various independent parameters of the acquired data at a particular depth. Initial work in this area resulted in the selection of the linearity estimate from the polarization analysis, the cross correlation coefficient of the full waveforms at the particular depth and the preceding depth and a uniquely developed parameter referred to as the signal shape parameter for this characterization. Subsequent analysis in STC identified two other parameters: the Signal-Noise-Ratio (SNR) and the Peak Symmetry Differential (PSD). The paper briefly describes these parameters and then outlines how they can guide the data analysis to derive more accurate results, especially near surface, which is especially important to assess the liquefaction potential in areas prone to earthquakes, such as California. The process will be illustrated with actual data from another area prone to earthquakes, namely New Zealand. 1. INTRODUCTION The near surface characterization of low strain in-situ shear wave velocities (VS) has proven critical for liquefaction assessment. Liquefaction is a phenomenon in which dynamic loading of saturated soil results in the material properties to change suddenly from a solid state to a liquefied state. VS is an important parameter for evaluating liquefaction potential due to fact that it is influenced by many of the variables that influence liquefaction (e.g., void ratio, soil density, confining stress, stress history, and geologic age (Andrus et al., 1997)). Aki and Richards (2002) also outline that the amplitude of ground motion should depend on the density and shear wave velocity of near surface soils and rocks according to the theory of wave propagation. Since the change in density with the increase in depth is relative minor compared to that of the shear wave velocity, the latter is a very useful parameter to represent site conditions (Stewart et al., 1997). Bray (2014) and his colleagues carried out an extensive geotechnical analysis of the catastrophic liquefaction that occurred in Christchurch, New Zealand in 2010 and 2011 and found that near surface rather than deep liquefaction resulted in extensive foundation damage.

Jan 1, 2018

P&H MinePro Services Canada is supplying Syncrude Canada three more of its model4100BOSS electric mining shovels. The shovels will be delivered during 2003. Syncrude’s oil sands operations already use five P&H shovels. The first 4100BOSS shovel was commissioned at Syncrude’s operation in northern Alberta, Canada in October 2001. The unit loads more than 9 kt/hr (10,000 stph) of unblasted oil sands. Since it began operation, the 4100BOSS has shown a 28% production increase over the four P&H 4100TS shovels also on site.

Jan 1, 2003

A study of drilling data at various stages of development of an orebody show that the semi-variogram, used for calculating the accuracy of block estimates can be ill-defined if too few data are available. The consequencesin this case are to have blocks supposedly more accurately known than is possible at the early drilling stage; such a result being potentially dangerous. However, as the amount of data increases the recalculated, semi-variograms approach the underlying semi-variogram of the deposit and the calculations made using them become more reliable and robust.

Jan 1, 1977

By H. Warren Newcomen

Assessments of the stability performance of open pit highwalls have traditionally been based on consideration of surface movement rates. Although generally accepted in industry, this approach presents challenges for establishing appropriate threshold values to allow for safe mining operations and does not address the issue of total strain. Surface movement monitoring data from a limited number of open pit mining operations in North and South America has been evaluated in terms of highwall strain, rock mass quality and inferred mechanism of instability. Threshold strain levels for key stages of highwall stability proposed from previous work have been reviewed and are generally endorsed based on evaluation of additional data. An empirical highwall strain criteria for the assessment of highwall stability performance is postulated based on the observed trends in highwall strain data from the case histories presented.

May 1, 2004

Although bismuth mineralization is spread widely through the Lachlan Fold Belt in New South Wales, broad grouping of the various deposits can be effected on the basis of geographical and geological (age and type of associated rocks) affinities. As a result, significant concentrations of bismuth can be recognized in the Mid-Western granites, Cobar-type ore, the Yass Silurian acid volcanic belt, and the Albury, Bega, Braidwoodand Bathurst districts.In these deposits bismuth generally occurs in minor amounts associated with molybdenite, wolframite, scheelite, cassiterite, chalcopyrite, galena, magnetite, pyrite, arsenopyrite, and native gold. From this group of minerals three broadly defined associations can be recognized.I. Bi-Sn-W-Mo2. Bi-Au( -Te)3. Bi-Pb-Cu(-Au)There may be some interchangeability of these metals, as instanced by occasional Bi-Cu-W-Mo mirleralization, but pyrite and/ or arsenopyrite are usually prominent in all associations.The first two of these associations occur mainly in the form of narrow quartz veins rarely averaging more than O&#183; 3 per cent Bi, although there is often a marked enrichment in ferruginous material in the oxidized zone.Most of these veins occur within or adjacent to granitic rocks of varying ages (principally Silurian or Devonian), although Bi-Au mineralization tends to be related to more basic igneous activity than the Bi-Sn-W-Mo association.The latter is also occasionally developed in pipes, usually coarse-grained and richer in bismuth (as at Whipstick, the principal mine in New South Wales with a production of 343 tonnes of the metal), or in lower grade, but probably larger tonnage skarn deposits. The bismuth-base metal association occurs mainly in Silurian acid volcanic sequences and may also form low grade but large tonnage deposits, such as is possibly developed at Cobar.

Jan 1, 1973

By Maurizio Siepi, Fabio Santillan, Lyndon Bedford, Carlo Crippa

"Abstract: Wolf Creek dam, on the Cumberland River in Kentucky, US, operated and maintained by the Nashville District of the USACE, is the Corps' largest reservoir east of the Mississippi river. The 1748 m (5,736 ft) long Wolf Creek dam combines earthfill and concrete gravity sections. Construction began in 1941 and was completed in 1950. The dam showed signs of instability in the 1960’s, and in the late 70’s an in-depth project of rehabilitation was undertaken, using both grouting and secant piles. The works saved the dam, but in the late 90’s further signs of distress worried the Nashville district of USACE which, after a study conducted on the water seepage, concluded that construction of a new concrete barrier cut-off wall was needed. In 2009, the $341.4 USD million contract was awarded to TREVIICOS-SOLETANCHE JV.The new wall, located upstream of the concrete monoliths, has a minimum thickness of 60 cm (24 in.), and runs the length of the embankment, into the right abutment, for about 4,200 feet. The founding depth reaches 84 m (275 feet), well below the zone of solutioning. With a total surface approaching 92,903 sq.m (1,000,000 sq.ft), the Wolf Creek barrier wall is unlike any other project in the world.The construction of the cut-off wall followed a complicated but logical sequence of several operations, involving a variety of technologies: grouting, hydromill, directional drilling, and secant piles with reverse circulation. The intensive rock grouting program was aimed to minimize the risk of slurry loss and extend the positive cut-off further deep. Subsequently, an Encasement Concrete wall was installed with hydromill, toeing into the rock, to protect the embankment during the following phases. Smart holes were then drilled into the Encasement wall down to the final depth. Eventually, the holes were used to install the secant piles by employing the reverse circulation piling method.An extensive verification campaign has confirmed the superior quality of the cutoff wall consisting of 1200 secant piles, exceeding by far USACE’s requirements. The main project was substantially completed in early 2013. A small portion of secant piles wall will be installed downstream of the dam, to close the switchyard, finishing the project in the early months of 2014.IntroductionWolf Creek Dam is located on the Cumberland River in south-central Kentucky. The Nashville District of USACE operates this multipurpose dam to provide hydropower, flood control, water supply, and water quality benefits for the Cumberland River system and surrounding region. Lake Cumberland, created by the dam, impounds 7,400 million cu.m (6 million acre foot) at its maximum pool elevation of 232 m (760 ft) above sea level. This lake is the largest reservoir east of the Mississippi and the ninth largest in the United States, and attracts 4.89 million visitors, more than Yellowstone National Park (2.87 million).This paper describes the recently completed works for the rehabilitation of the dam, accomplished by TreviICOS-Soletanche JV with the construction of a new Barrier Wall."

Jan 1, 2014

By Holla L, Tyminski A

Stowing has been successfully used in many countries as a means of controlling surface subsidence, minimi ing incidences of spontaneous combustion, maintaining gate road stability and maximising coal recovery.Australian experience in stowing is limited but in the future increased extraction of thicker and/or multiple seams by longwall operations and resolution of conflict of alternative land u&apos;ses may necessitate the use of stowing in coal mining. At present there is little incentive for mining companies to introduce and operate a stowing system because costs have to be borne by the individual companies and benefits spill over to society and the State. Cost sharing by the industry and State incentives may overcome the problem of cost disincentive.

Jan 1, 1987

By K. W. Lee, C. Pound, J. Carmody, L. Petersen, C. Nelson, J. G. Cai

The feasibility of developing the Underground Science City below the Kent Ridge Park has been investigated. The primary aim of the study has been to explore the possibility of creating underground space to house a new community of research laboratories and offices. The investigation represents the first such study undertaken in Singapore for a non-military underground facility. The paper describes the geology of the Underground Science City site and illustrates the layout and plan of the Underground Science City. The geology and rock mass below the Kent Ridge Park is generally favorable for the development of an underground cavern complex. Underground Science City can be potentially developed housed in a cavern complex. Several potential development schemes are studied; with various combination of deep/shallow mined caverns of different span sizes and access options. The preferred scheme is shallow, mined room-and-pillar caverns with large spans and shaft accesses at both existing surface Science Park 1 and Science Park 2. The scheme can be potentially expanded laterally to create more underground space for new Underground Science Cities at Kent Ridge area.

Jan 1, 2001

Drill cores from Section 62, New Broken Hill Consolidated Ltd., were used to study the petrology of rocks associated with the zinc lode. The distribution of the rock types in relation to the lode structure was determined. The distribution of the gahnite-bearing rocks was shown to be only partly conformable with the structure.It was concluded that large scale metasomatism was not widespread, that the rocks associated with the lode (except, perhaps, the quartz-gahnite-garnet rocks) were formed by metamorphism of sediments, and that rocks and lode were contemporaneously metamorphosed.INTRODUCTIONThis investigation was undertaken in order to study the rock types associated with the zinc lode of the Broken Hill orebody, and their relationship to the structure of the ore horizons. The work was confined almost entirely to the laboratory, and is therefore limited in its scope. It is hoped, however, that the information gained may throw some new light on the genesis of the lode.Certain inferences which are drawn from this work are at variance with the ideas of a number of earlier workers.In particular, the idea of large scale metasomatism developing many of the rocks associated with the lode, especially those containing manganese, is questioned. On the contrary, the rocks associated with the lode are more simply explained as highly metamorphosed sediments, in some cases modified by water introduced from surrounding rocks into zones of strong folding and faulting. As a corollary, a metamorphicsedimentary origin for the lode material, either as a concentrated sulphide deposit, or somewhat disseminated...

Jan 1, 1961

The pyrite-sphalerite-galena and barite orebodies at the Rosebery mine are concordant with the shale host rock and have been deformed into one system of folds with an associated axial plane cleavage. The folds are tight and overturned with east-dipping axial planes. Folds in the sulphide ore are commonly disharmonic, particularly between adjacent bands of different composition.Concentric style folds occur in the competent bands, e.g. pyrite-rich bands. Similar style folds are predominant in the less competent sphalerite-galena-rich bands and also in the shale of the host rock. The trends and plunges of the fold hinge-lines are variable but axial planes are of reasonably constant orientation throughout the mine area. The folds in the orebodies are of limited axial extent, approximating to conical folds, and are arranged in en echelon patterns. The fold system was possibly formed in one period of folding by heterogeneous strain that may have been caused by the presence of a mass of tectonically mobile sulphide ore. Lineations parallel to the ore/host rock contacts appear to reflect movement between the ore and the host rock during folding.

Jan 1, 1972

By G. P. Holmes

"IntroductionThe copper-molybdenum property of Brenda Mines Ltd. is located 18 miles north west of Peachland in the Okanagan Valley of the Southern Central interior of British Columbia. The actual site is 50 miles north of the international boundary and 150 air miles east of Vancouver at an elevation of 5000 feet above sea level. The earliest written mention of the prospect is found in the Geological Survey of Canada, Memoir No. 243, issued in 1947 by Dr. H.M.A. Rice. In 1954 the area was staked by a prospector, Bob Bechtel, who interested Bern Brynelsen of Noranda Exploration in examining the claims. A joint Noranda - Kennecott program resulted but since the grades were so low the property was not taken up until in 1964 a re-examination by Chapman, Wood and Griswold produced recommendations leading to the construction of the Brenda Mine as it is today.The rounded, timber covered mountains of the area are composed of the tuffs, argillites and limestones of the Upper Triassic Nicola Group, which is intruded by a Jurassic quartz diorite, called the Brenda stock0 The actual orebody occurs in a strongly fractured zone within the Brenda stock, approximately 1500 feet from the contact with the Nicola group0 The ore minerals, .chalcopyrite and molybdenite, associated with pyrite and magnetite of lesser importance, occur as fillings within the fractures 0 The grade of the ore decreases outwards from a central higher grade core and in January 1971 total reserves were estimated at 165 million tons assaying 0,182% Copper and 0,049% Mo."

Jan 1, 1972

By Brian Reid

"This paper studies the progress made by hydraulic shovel manufacturers over the last few years, particularly in the areas of productivity increase and operating cost reductions.Five years ago, it was widely considered that the unit production cost for a hydraulic shovel in a mining application was double that of a cable shovel in the same application. The hydraulic machine manufacturers have taken up this challenge, and modern improvements in design, coupled with changes in maintenance techniques, have narrowed the gap to the point where it is valid to ask the question ""will the cable shovel exist in ten years&apos; time?"".Historical BackgroundThe history of the cable shovel goes back to the early 19th century and the industrial revolution. Early machines were steam-powered and ran on rails.The ""power shovel"" and the ""dragline"" were the only mechanical means of mass excavation until the early 1950s. Rail-mounted units gave way to crawlers, which increased flexibility considerably. Some shovels were redesigned as backhoes, and some became extremely large when designed as stripping shovels primarily used in North American coal mines.In the early 1950s growth in hydraulic technology spawned the introduction of the hydraulic excavator, which soon began to replace the smaller cable shovels and backhoes used in the construction industry. They were completely self-contained with either a gasoline or diesel engine and, being much lighter, were more readily transportable.As the excavators grew in size from its early models of 0.5 m3 or less, many of the cable shovel models were discontinued. This was not surprising for several reasons, but the most obvious is that both were often made by the same manufacturer."

Jan 1, 1988

The preeipitation of dissolved lead from a strong brine by metallic iron is a chemically controlled, first order reaction. The precipitation rate is sensitive to changes in chloride concentration and temperature. The precipitation of dissolved silver is a diffusion controlled, first order reaction. The precipitation rate is insensitive to changes in chloride concentration and temperature.INTRODUCTIONLead and silver sulphates can be extracted from electrolytic zinc plant tailings, or residues, by leaching with strong brine solutions, the lead and silver going into solution as complex chlorides. One of the methods which can then be used to recover the dissolved lead and silver is to precipitate them with metallic iron. The deposition reactions which take place are of the type Pb++ Fe - Fe++ Pb............ (a)To fit such a method of precipitation successfully into a practical flowsheet it is necessary to have some knowledge of the kinetics of the various reactions, Le. to know how the precipitation rates vary with temperature, brine and metal concentrations, and so on. Reaction rates are also needed to design suitable precipitation vessels. However, when examining the possibility of using a brine leaching process to extract the lead and silver from the residue produced at the Risdon plant of the Electrolytic Zinc Co. of Australasia, it was found that, although the use of metallic iron to recover lead and silver from the pregnant brine had been reported by Ralston (1924) and by TrumbulI, Hardiek and Lawford (1948), very little was known about the precipitation reactions. Consequently a laboratory investigation was undertaken, and this paper covers those aspects considered to be...

Jan 1, 1961

By D. Yu. Paleev, O. Yu. Lukashov, A. Yu. Krainov, E. R. Shrager, I. M. Vasenin

The gas-dynamic method is presented of calculation of explosion-proof distances during an explosion of the methane-air mixture in mine working. On the basis of this method is modelled of shock waves interaction with explosion protective parachute partitions, obstructions and water barriers. Calculations have been carried out of attenuation factors of shock waves during their interaction with explosion protective structures, arranged near conjugation zones of mine workings. Possibilities have been analysed of suppression of intensity of shock waves and of propagation of shock waves control in mine working network of coal mines by installation of explosion protective structures.

Jan 1, 2003

By G. L. Oldwright, F. K. Shelton, W. E. Keck

"INTRODUCTION Zinc must be of high grade to satisfy the present demand. Even when the amount of premium paid is small, the purer metal as the buyers' preference. The following specifications for spelter were taken from the American Society for Testing Materials for 1927, Part I, pane 524. (The specifications for 1930, p. 582, are tile same.)Another specification for zinc of a much higher grade than any of the above has been established lately by the same society. The committee on zinc die-casting (Proc. Am. Soc. Test. Mat., vol. 31, 1931, p. 263) reached the following, conclusions: I. ""That the purest of zinc is necessary to produce stable zinc-base die castings, and as a result requested specifications for zinc spelter .with total impurities not over 0.02 percent."" Their tests showed that the die castings made of the purest zinc had the least elongation and the greatest tensile strength, and exhibited the least changes with temperature.Still more far-reaching claims are made for the properties of zinc containing over 99.99 percent metal. Zinc foil, for instance, may someday be made as a common commercial product. It would seem likely that the demand for zinc of high grades rill continue and that even purer varieties may be desired. This demand fits in with the modern trend in manufacturing plants of reducing the number of variables to a minimum by using pure materials, and of controlling the processing of metals during their various stages of fabrication by mechanical means instead of by expert laborers."

Jun 1, 1933

The accompanying supply/demand flow diagrams and 10-year tables for mineral and fuel commodities present essential data required by government, industry, and others to formulate policies and programs that can help assure an adequate and continuing supply of mineral raw materials. The 10-year data base terminates with 1974 figures because adequate world information was not available beyond that date. The selected mineral supply/demand tables and flow diagrams comprise but one "output" from the massive body of information and data collected and com-piled by the Bureau of Mines on a continuing basis covering mineral production, consumption, prices, shipments, imports, exports, and stocks, as well as industry activities in all States and abroad.

Jan 1, 2012