Search Documents

By G R. Hancock, W D. D P Welivitiya

is placed in a waste rock dump, which is usually later reshaped to be erosionally stable, initiate and sustain vegetation and ultimately integrate with the surrounding undisturbed landscape. However, it is unclear how this exhumed material will weather and evolve for most sites. Also, there is a lack of data on the weathering of post-mining materials. If weathering is better understood, then there is the potential to improve rehabilitation outcomes. To improve predictions of the evolution of soil properties and weathering-limited erosion, estimating the rate at which fine, transportable material is produced from the weathering of larger, non-transportable particles and the resultant fragment size distribution and how that distribution evolves over time is necessary. This study examines the weathering process for four different coalmine waste rock materials for a Bowen Basin, Queensland site. Materials obtained from various areas of the coalmine were subjected to cyclic wetting and drying and heating and cooling. Particle size distribution and other material properties were explored after each experimental cycle to ascertain how the material changes during the experimental cycles. The particle size distribution data of wet and dry cycles were used as input data in a numerical weathering model to explore the dynamics of the weathering process for each material sample. A Monte Carlo framework was employed to assess the geometry of the weathering products, weathering rate and the number of daughter particles produced within a weathering cycle. Then the SSSPAM Landscape Evolution Model was used to evaluate the influence of weathering on erosion and landscape evolution of a post mining landform. SSSPAM simulations with: (i) active weathering and (ii) without weathering were run for each material. The erosion rate and the overall landform structure were then compared between weathering and non-weathering simulations.

Aug 2, 2023

Batterham and Algie began their paper on: `The role of technology in the minerals industry' (1995) by noting that while: it is often stated that innovation is central to the economic survival of mining and minerals processing in the face of global competition, .. . technology is often far from a core strategy in our industry. This point is correct. Throughout the world, as a broad generalisation, mining companies do not value technology development as a principal means of gaining competitive advantage. It is important to understand why this is the case. Batterham and Algie address this question by making distinctions between innovation, technology and research. They note that while: all successful (mining) companies are good at innovation . . . that innovation can proceed without any research and development and that it is innovation that generates the competitive advantage, not research and development per se. In this paper we accept these arguments. However, our focus is somewhat different. Whereas Batterham and Algie took a mining company's perspective on the technologies of mining and processing, we take a broader view of the opportunities for technology development for company Australia but, in order to focus the argument, we restrict our discussion to the area of mining (rather than processing); we focus particularly on mining systems and mining equipment. We begin by looking at the motivation of companies operating in any industrial sector to invest in research and development. Figure 1 recognises four levels of industrial maturity. For companies in the embryonic and growth stages R&D often is essential to initiating and developing the business. Mining, on the other hand, is a mature industry. In mature industries the conventional roles for R&D are to reduce costs, to extend product differentiation, or to develop new technology with the aim of rejuvenating the business. Next we ask whether these general-industry arguments apply to the mining industry. If they do then the mining industry should value R&D more highly; after all cost reductions and business rejuvenation are goals that are worth achieving. On the other hand if, for whatever reason, these general arguments do not apply to mining then this may lead the mining industry to invest only modestly, or not at all, in R&D. In this event, while this may be a rational decision for the mining industry, it may not be in the best interest of a nation like Australia where revenues from the sale of mineral products represent an important part of the country's economy.

Jan 1, 1997

Renison Limited produces high and low grade tin concentrates at an annual rate of 5000 tonnes of contained tin metal. In spite of the fine average cassiterite grain size, emphasis is placed on gravity concentration methods to produce a high grade final product. Cassiterite flotation is considered and operated as a gravity circuit scavenger responsible for approximately 15 percent of recovered tin metal as a fine grained low grade concentrate. Metallurgical problems mainly result from ore-type variations which may be aggravated by a number of circulating loads. The rationalisation of circuitry is being studied to provide more effective control by operators and to allow exploitation of current control and modelling techniques.

Jan 1, 1977

Politicians and economists talk glibly about the so-called knowledge revolution. The reality is that knowledge is fundamental to economic progress. Consequently there have been many technological revolutions. The global impacts of the invention of the steam engine and the development of the frozen meat industry are well known. Another less publicised technological advance occurred in Central Otago late in the nineteenth century. This was the adaptation of the bucketladder dredge to the mining of placer deposits. A product of over 30 years experimentation and innovation, New Zealand dredging technology was taken to the Risdon Iron and Locomotive Works, San Francisco by R H Postlethwaite, a Dunedin based mining engineer. New Zealand-style dredges built by Risdon operated successfully in California, Alaska and the Yukon. Californian engineers assimilated the best features of the New Zealand dredges with American (Bucyrus) designs to produce a standard for the worldwide placer mining industry.

Jan 1, 2003

By I R. F MacCulloch, K Jones

Pintail Systems, Inc, a Colorado USA based company has developed and commercially applied bioremediation processes for biological detoxification of cyanide compounds in mine waste. Site-specific microorganisms are isolated from spent ore, tailings or process solutions and augmented in the laboratory for cyanide oxidation, denitrification and metal biomineralisation. Biological processes typically treat complex contaminants (cyanide compounds, soluble metals and nitrates) in a fraction of the time of conventional remediation processes. Cyanide is used in microbial metabolic processes as a carbon or a nitrogen source. Biological detoxification processes applied at the end of mine life can end long-term liability and perpetual monitoring and containment. Case studies from commercial application and demonstration programs for the US Environmental Protection Agency will be presented in this paper.

Jan 1, 2004

By S Hapugoda, M Peterson, A Haileslassie, A Poliakov, E Donskoi, L Lu

Most metallic iron in the world is produced in blast furnaces from different feed stocks – sinter, lump ore and pellets. Sinter is the main iron-containing feed to the blast furnace and can constitute up to 70–85 per cent of the total ferrous burden. As sinter quality is a key element for stable blast furnace operation, the textural, chemical and physical characteristics of the sinter are very important. Two major factors that affect sinter strength are mineralogy and porosity. This study utilised optical image analysis (OIA) to characterise sinter mineralogy, and the results were compared to those obtained by manual point counting under the optical microscope.Two major mineral characteristics of iron ore sinter are the presence of primary (unreacted) and secondary (derived from melt) hematite. Standard OIA, which is based on RGB thresholding, is not able to distinguish them as they have the same reflectivity; however, primary and secondary hematite in iron ore sinter have a different morphology. The CSIRO-developed OIA software Mineral4/Recognition4 has a unique feature to identify various textures/morphologies of the same mineral. Together with other capabilities of the Mineral4/Recognition4 software, this feature was used to identify different types of hematite and silico-ferrite of calcium and aluminium and other common sinter phases, such as magnetite, larnite, glass and remnant aluminosilicates.A visual comparison of the sinter mineralogy present in optical photomicrographs and that present in the mineral maps created automatically by the Mineral4 module of the CSIRO software confirmed the accuracy of the automated mineral identification.CITATION:Donskoi, E, Hapugoda, S, Lu, L, Poliakov, A, Peterson, M and Haileslassie, A, 2015. Advances in optical image analysis of iron ore sinter, in Proceedings Iron Ore 2015, pp 543–548 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

When the new No. 3 Shaft is in full operation, the main hoisting duties will be in connection with the raising of: (a) ore from the various mining operations, and (b) mullock, or broken country rock, from development work in extending access to existing levels, opening up new levels, exploratory work, or sinking the shaft to greater depths.

Jan 1, 1957

By N Donnellan

The Palaeoproterozoic Warramunga Formation is notable as the host to the enigmatic, so-called 'Tennant Creek style' mineralisation. These polymetallic (but mainly Au-Cu-Bi) ore deposits typically have a close spatial association with massive ironstone bodies, and frequently also with banded ironstone, known locally as 'haematite shale'. The Warramunga Formation is a polydeformed, turbiditic succession. Partial, or complete Bouma sequences variously comprising lithic arenite, wacke, siltstone, and mudstone constitute a classic flysch sequence deposited as a proximal (sandstone lithofacies) to distal (siltstone lithofacies) fan association. The Warramunga Formation has a substantial component of volcanic detritus and has generally been attributed to an essentially contemporaneous volcanic provenance. However, lithostratigraphic revision (Donnellan, Hussey and Morrison, in press) apparently precludes outcropping volcanic rocks of the Tennant Creek Block, or indeed Inlier, as the source of detritus. Warramunga Formation geochemistry indicates rapid derivation from a fractionated, predominately felsic igneous source (Palaeoproterozoic upper crust) with a minimum of chemical weathering; together with an admixture of mafic material. Warramunga Formation geochemistry cannot, however, be reconciled with that of the Bemborough Formation, which is here taken to be representative of Flynn Subgroup felsic volcanic rocks. Similarly, the Warramunga Formation is geochemically distinct from Flynn Subgroup sedimentary rocks. Geochemistry of the banded ironstone is consistent with its interpretation as Dine-grained turbidites.

Jan 1, 1994

By D J. Williams, A Shokouhi, A Naderian

Extracting alumina from bauxite involves the production of fine-grained waste known as red mud. The highly alkaline red mud is usually neutralised by applying sea water, thickened to between 25% and 30% solids by mass, before disposal to a Tailing Storage Facility (TSF). Hydraulic sorting, settling, self-weight consolidation, and desiccation are the processes contributing to the overall volume change of the red mud after deposition. Investigating the effect of these processes on the volume change behaviour of the fine-grained red mud is an important step in the estimation of the required storage volume of the storage facilities. This paper presents the results of a series of laboratory consolidation tests in a slurry consolidometer, and comparisons are made with field testing and observations.CITATION:Shokouhi, A, Naderian, A and Williams, D J, 2018. Assessing the volume change behaviour of red mud through laboratory and field testing, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 309–316 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

The present stage of economic development of the Broken Hill lode, attained after 40 years of active exploitation, leaves little opportunity for the study of the zone of secondary sulphides.Little remains of the oxidised zone, and the observations of the secondary sulphides of copper and silver can rarely be made on specimens collected in situ. A few specimens containing secondary...

Jan 1, 1927

Recent and on-going studies on the leaching of gold, the properties and activity of carbon, developments in the elution of gold from carbon, and methods of recovering gold from solution are reviewed. Emphasis is placed on Australian contributions, and their impact on gold metallurgy. Consideration is given to the future development of selective solvent extractants, ion exchange resins or alternative reagents for cyanide.

Jan 1, 1987

By M Saghaeian, A H. Baladastian, A Dehghani Ahmadabadi, V Sheikhzadeh, R Hejazi

This research was done to reduce silica from mixed hematite concentrate of Barfkar Iron Ore Sample and increase Fe grade using reverse flotation method (Depressing Hematite and floating Silica). The used sample in the reverse flotation tests was a mixture containing two types of hematite concentrates (Spiral cleaner concentrate and Slon-VPHGMS cleaner concentrate) with the percentage of 16 per cent and 84 per cent, respectively. Fe grade of two samples was 59.31 per cent and 57.52 per cent and SiO2 grade was 5.83 per cent and 6.71 per cent, respectively. After mixing, the Fe and SiO2 grade of the mixed sample was measured at 58.10 per cent and 6.20 per cent. For flotation tests, effect of variable operational parameters including feed size distribution (d80 = 130 microns and d80 = 53 microns), pulp solidity (25 per cent and 30 per cent w/w), pH (9.70, 10.20 and 11), Sodium silicate as a dispersant (500, 1000 and 2000 g/ton), Starch as a depressant (500, 1000, 2000 and 3000 g/ton) and EDA as a collector (180, 300, 400 and 500 g/ton) were investigated. For evaluating the influence of Sodium silicate and Starch dosage, initial flotation tests were performed on the main sample (d80 = 130 microns). These two parameters had no significant effects on the yield, Fe, and SiO2 grade of flotation concentrate based on test results. In the next step, screen analysis was carried out on the main sample for mineralogical studies. Accordingly, the suitable size distribution for releasing Fe and SiO2 particles was smaller than 53 microns. Therefore, the sample was crushed until d80 = 53 microns. Then, supplementary tests were performed on the crushed sample for studying the pH range, pulp solidity, and EDA collector dosage. After doing silica removal flotation tests based on the designed pattern and comparison of the results, the conditions consisting of size distribution d80 = 53 microns, pulp solidity 25 per cent, pH 10.20, Sodium silicate 1000 g/ton, Starch 1000 g/ton, and EDA 500 g/ton was selected as optimum values. In the last test, Fe and SiO2 grade was measured at 60.00 per cent and 3.93 per cent, respectively, and Fe recovery was obtained at 74.93 per cent.

Aug 24, 2022

By C Woodfull, S Munroe

Geological uncertainty is reduced by improved understanding of the relationship between regional-scale geological basement features (structure, composition, depth) and known local structural risk (such as recognised structural hazards at the mine). Coal mining and exploration entities can be more efficient and effective in managing geological risk at a range of scales. A more efficient and effective performance in forward interpreting and managing geological risk will result in a more efficient and effective exploration and also incremental or even significant mining cost improvements. In order to improve the understanding of basement features, a new 4D regional structural/basin framework for the Sydney Basin and the eastern part of the Gunnedah Basin has been constructed to provide primarily coal exploration and mining with a more integrated geological framework for ongoing subregional to mine-scale geological risk based studies. The model has been developed from a range of available regional geophysical and geological datasets, of variable detail and reliability, which have been brought together to generate a more robust structural and tectonic model than could be generated with any one single dataset. An initial regional structural model for the Sydney Basin was constructed in 2003 and an update to the model was released in 2005 (SRK Consulting, 2003; 2005). The development and ongoing refinement of the model was undertaken with financial and data support from a number of coal mining industry, gas exploration and government organisations. Prior to, and following the development of the regional structural/basin model and associated Information Base, a number of more area-specific studies have been completed, using the æbasement upÆ assessment approach. The methodology for developing comprehensive structural models, from the basement up, is outlined. The approach can be applied at a country-wide, regional or lease area scale. Case examples of where this approach has been used as an effective and efficient method in improving geological certainty and as a predictive tool to help manage geological risk are also presented.

Jan 1, 2006

By M Darvall And R Fare, D Dormer

The Argo Archaean lode gold deposit is hosted within a structurally complex shear zone system, 70 km south of Kalgoorlie, and 3 km west of the crustal-scale Boulder û Lefroy Fault. Argo is an active underground mine currently producing at a rate of 120 koz pa with a Probable and Proven Reserve as at December 2005 of 2.19 Mt at 5.94 g/t Au (419 koz), a reduction on the December 2004 Probable and Proven Reserve of 4.58 Mt at 5.74 g/t Au (845 koz). This Reserve is hosted in six separate gold bearing lodes within the Argo shear system. Presently, a further six subeconomic shears are recognised. The 2005 Reserve figure represents a reduction of 426 koz compared to the 2004 Reserve as a result of a thorough review of the geological interpretation/resource model, and engineering factors applied to the Resource/Reserve, and depletion due to mining. Year on year Resource/Reserve figures at Argo had gradually increased as additional information on the system became available and mining methods were increasingly resolved with early production. The portal for Argo underground mine was cut in June 2002 within the highly profitable Argo open pit. The proposed æAvocaÆ bottom-up mining method required extensive lead time between development and the commencement of stoping in April 2004. During development considerable additional complexity in the Resource was encountered. Additional structures were identified, and complex splay interactions affecting the geology impacted on development. Intensive concurrent exploration in the footwall to the main lode during this period was the main cause of the increase in the Resource/Reserve figures during early development. As development progressed, lower grade continuity was observed than was previously interpreted. At the same time, drilling of deeper portions of the deposit and subsequent reinterpretation of the geological model significantly reduced strike lengths of economic mineralisation. Radical changes to the mining methods were required to improve productivities and to satisfy geotechnical considerations. The changes altered the engineering factors applied, which resulted in a reduction in the Reserve figures.

Jan 1, 2006

By T Raynlyn, A Edenton, M Adam, R J. Holmes, J R. Manuel, N Ware, R Smyth

Due to ongoing demand and increasing depletion of high-grade iron ore resources from large deposits, Australian iron ore producers are developing smaller size deposits to maintain current export levels. The iron grade, mineralogy, chemical and physical characteristics of iron ore fines being mined from different deposits vary considerably. It is therefore imperative to develop long-term strategies to maintain the quality and consistency of iron ore fines while moving to a larger diversity of smaller deposits. Blending is a common practice in sinter plants as it is almost impossible to produce a high performance sinter mixture displaying the required characteristics from one single ore. Blending is also one of the most effective options being used by iron ore producers to ensure the long-term stability of their products while increasing production. When designing a blend, the blend components are selected to support each other to achieve the required overall balanced metallurgical performance of the final product at a relatively low cost. To do so, a fundamental understanding of the key characteristics of iron ore fines and their potential impacts on the iron ore sintering process and sinter quality are required. In this paper, the sintering process and sinter structure have been analysed and the key factors affecting the sintering performance of iron ore fines, including productivity and quality, identified. Under fixed sintering conditions, the granulation efficiency, nuclei stability and the volume and properties of the primary sinter melt are believed to have important impacts on both sintering productivity and sinter quality. Discussion is then focused on the effects of ore chemical, physical and mineralogical characteristics on the key factors identified and in turn the consequences for sintering productivity and sinter quality.

Jan 1, 2009

By J MacNeil, R Dimitrakopoulos

As open pit mining of a deposit deepens, the cost of extraction may increase up to a threshold where transitioning to mining through underground methods is more profitable. This paper provides an approach to identifying an optimal depth at which a mine should transition from open pit to underground mining. The value of a set of candidate transition depths is investigated by optimising the production schedules for each depth’s unique open pit and underground operations. By considering the sum of the open pit and underground mining portions’ value along with the cost of transitioning corresponding to each candidate transition depth, the optimal transition depth can be identified. The optimisation model presented is based on a stochastic integer program that integrates geological uncertainty. As an input, the stochastic integer program utilises a set of several stochastic simulations that represent equally probable scenarios of the mineral resource. This group of simulations describes the uncertainty in the deposit, while the optimiser aims to maximise value based on discounted profits of both the open pit and underground components of the deposit.CITATION:MacNeil, J and Dimitrakopoulos, R, 2014. A stochastic optimisation formulation for the transition from open pit to underground mining within the context of a mining complex, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 363–368 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By G M. Jeffress, D C. Arne

There are two discrete aspects to collecting portable X-ray fluorescence (pXRF) data to obtain reliable results and to comply with reporting requirements under the 2012 edition of the JORC Code (JORC, 2012) – sampling method and quality assurance. A robust sampling program is required to obtain representative material for analysis. The appropriate method should be established for a particular project using a small orientation study. A variety of approaches to sampling soils, drill cuttings, rock faces and diamond drill core are discussed. These include using multiple spot analyses, scanning using a single operating beam and the collection of cutting saw pulps. The operator must also be aware of the attenuating effects of analysing through sample bags of different material types for various elements as well as the limitations of current pXRF instruments in reporting reliable data for certain elements. The analysis of the samples must also be accompanied by a quality assurance program in order to generate data that are ‘fit for purpose’. This includes recording X-ray tube resolution on a routine basis, using matrix-appropriate standards for which total elemental concentrations are available, using silica blanks, capturing sufficient duplicate analyses to constrain data precision and obtaining check assays to calibrate pXRF data against laboratory data. Examples of quality control approaches and data are presented. Table 1 of the 2012 JORC Code also recommends that information on instrument make and model, reading times and calibration be provided in any reporting of pXRF data. To this should be added information on operating mode and temperature, software version and moisture content of the samples. A robust sampling methodology with a suitable quality assurance/quality control program should produce pXRF data of sufficient quality for public reporting purposes, provided that the data are presented using appropriate cautionary language and adequate supporting information.CITATION:Arne, D C and Jeffress, G M, 2014. Sampling and analysis for public reporting of portable x-ray fluorescence data under the 2012 edition of the JORC Code, in Proceedings Sampling 2014 , pp 57–64 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By K H. Esbensen

Sampling of grain, animal feeds (solid and liquid) including important mineral mixtures in the Danish agricultural sector is subject to an ongoing investigation with the objective of improving existing (suboptimal) sampling procedures. Results from the first six months are presented here; the project will continue for two more years and will include international collaborators (Australia and Canada). The Danish authorities have instituted a system of control analysis, which contains a set of mandated sampling and analysis methods. From a preliminary survey it was concluded that in fact all of the existing sampling procedures are not optimised in the light of Pierre GyÆs Theory of Sampling (TOS).

Jan 1, 2005

By J Manuel, N Ware

Ideal iron ore sinter is produced by optimising the balance between coarse (+2 mm), stable ore nuclei and a reactive matrix consisting largely of fluxed -1 mm fines. The authors have previously published work evaluating the matrix melting behaviour of a number of fine ores, using techniques developed by CSIRO. The focus of that work was to demonstrate the contribution of the matrix to overall sinter quality, with the results showing a direct correlation between melting point, matrix porosity and strength. CSIRO has also developed a complementary test to study the behaviour of coarse ore nucleus particles in contact with the sinter matrix and provide an evaluation of their reaction and assimilation properties. This test provides valuable fundamental information that can be used to better understand the role of specific ore types and optimise blend composition.The CSIRO laboratory-scale assimilation test is carried out by embedding particles of ores of specific sizes into a fluxed matrix of known sinter blend composition, using real ores and fluxes, in a laboratory test that directly relates to pot-grate and plant sintering conditions. Samples are fired under controlled conditions in a tube furnace using a standard heating profile and a constant, low-oxygen potential atmosphere. These conditions simulate the actual sintering process while removing the effects of the many locally-variable parameters (eg temperature, oxidation potential and localised chemistry) that exist in the actual process, meaning that trends in behaviour can be more clearly seen. Designed as a compromise between the industry-standard pot-grate sintering test and a more fundamental test using chemical reagents, the aim is to isolate and evaluate the nucleus behaviour of an individual blend component to allow an improved understanding of the role that an individual ore plays in a specific blend. Measured cross-sections of the resulting fired samples provide a semi-quantitative measure of reactivity, while accompanying photomicrographs allow a qualitative assessment of assimilation properties (eg volume and distribution of secondary porosity generated during reaction).In this paper, to complement the previous work published on melting behaviour, nucleus particles were selected from hematite, hematite-goethite and goethite ores and embedded in a simulated plant sinter matrix. Drilled core particles of two sizes were tested at fixed temperatures simulating low- (<1300°C) and high-temperature (>1300°C) sintering conditions. The resulting assimilation properties are compared and discussed as a function of particle size, temperature and ore/sinter mineralogy. The implications for the contribution of each component to the prediction of blend sinter quality are also discussed.CITATION:Ware, N and Manuel, J, 2015. Fundamental nucleus assimilation behaviour of hematite- and goethite-containing ores in iron ore sintering, in Proceedings Iron Ore 2015, pp 77–82 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Alesse V, Belardi G

A new class of collectors, Mercapto-Benzo-Oxazoles (MBO), exerting selective action on copper sulphides in the presence of Pb, Zn and Fe sulphides (galena, sphalerite and pyrite), has been synthesised in co-operation with Enichem's Donegani Insitute. The collectors have a mixed aliphatic-aromatic structure and contain functional groups which form chelates with copper. Some reagents of this class having hydrocarbon chains of various lengths have been laboratory tested on a complex sulphide ore containing chalcopyrite, galena and sphalerite in pyritic gangue. Comparative flotation tests have permitted selection of the best collector for chalcopyrite, namely Methyl-Mercapto- Benzoxazole (MMBO). Systematic flotation tests have been performed with this reagent, varying collector concentration, grain size of the feed, pH and flotation time. The results obtained show that the synthesised collector is much better than potassium-amylxanthate (KAX) as regards selectivity towards Pb and Zn. Moreover, it is possible to work at natural pH (6-7) and the flotation rate is higher. In fact in the rougher stage with 80 g/t of collector at natural pH, a copper grade of 7.14 per cent was obtained with a recovery of 73.87 per cent, while the grade with KAX did not exceed 2.11 per cent for a recovery of 73.54 per cent. The amount of Pb and Zn reporting in the copper concentrate was eight per cent and ten per cent respectively, while with KAX it was no lower than 24.34 per cent and 22.71 per cent in that order. After two minutes flotation a copper grade of 5.2 per cent with 52 per cent recovery could be attained, against a grade of 2.5 per cent and a recovery of 44 per cent in the case of KAX. The efficiency of this new collector has been ascertained on two samples of complex sulphide ores of diverse mineralogical composition.

Jan 1, 1993