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By O N. Antzutkin, W Forsling, K J. Pike an

The adsorption mechanism of three different O,OÆ-di-alkyl-dithiophosphate (dtp) collectors, K[S2P(OR)2] with R = Et, i-Bu and i-Amyl, on the surface of synthetic chalcocite (Cu2S) was studied by means of solid-state 31P CP/MAS NMR spectroscopy. The morphology changes on the conditioned Cu2S surfaces, in the collector concentration range 0.1 - 10 mM, were also monitored with scanning electron microscope (SEM). In order to assign Cu(I)-dtp species on the surface of Cu2S, the corresponding bulk Cu(I)-dtp compounds, which are clusters of the monovalent copper containing either Cu6(antiprismatic) or Cu8(cubic) cores, were synthesised, and characterised by means of solid-state 31P CP/MAS and static 65Cu NMR. Further investigations on the crystal habits of the bulk systems were carried out by powder x-ray diffraction and SEM. A comparative analysis of the 31P chemical shift and chemical shift anisotropy (CSA) data estimated from the experimental NMR spectra of the polycrystalline bulk Cu(I) dialkyldithiophosphate complexes was used for assigning the 31P resonance lines in the NMR spectra of the collector treated Cu2S powder samples. The species formed on the synthetic Cu2S surfaces were assigned to polycrystalline phases of: Cu6L6 with L = Et2dtpû, Cu6L6 and Cu8L6(S) with L = i-Bu2dtpû, and Cu8L6(S) with L = i-Amyl2dtpû. A heterophase autocatalytic step process of both formation and growth of solid CuxLy (L = R2dtp, x = 6 or 8 and y = 6) complexes on the collector treated Cu2S surface is proposed. A possible role of the oxidised form of dithiophosphate collectors, bis[di-alkyl-thiophosphoryl]-disulfane (disulfide), is discussed in terms of a specific self-redox reaction. The second order quadrupolar lineshapes in 65Cu NMR spectra were simulated and the interaction parameters, CQ and hQ, for the bulk dialkyldithiophosphato-copper(I) complexes were obtained.

Jan 1, 2005

By H Zahiri

Utilisation of the InSAR technique for monitoring of subsidence in mining areas, employing open pit and underground mining methods, has large potential due to sensitivity and safety issues associated with usage of the classical surveying techniques. InSAR can also be very competitive concerning the cost of provided results. However, there are a few issues that may significantly limit InSAR applicability for subsidence monitoring in mining areas. The altered terrain topography, involving steep slopes and deep pits, may lead to the layover of radar signal for specific satellite and pit geometry. Also, the highly dynamic character of subsidence induced by mining, especially using mass mining methods, may lead to issues such as apparent heave and ambiguous results. In this paper the authors analyse the above-mentioned issues and demonstrate how InSAR technology was applied, as a supporting system, to monitor large scale and highly dynamic subsidence for a real case study in Western Australia.

Jan 1, 2008

By G Billing a, D Gribble, E Hall, D Varga

The theoretical benefits of electronic detonators have been reasonably well documented. To support this, a practical comparison was made between the performance of the standard shock tube system, NONEL, and a high precision electronic system, HotShotÖ, at the Sunrise Dam Gold Mine. The expected benefits from electronic detonators to Sunrise Dam were identified prior to the trial. Based on these, a number of objectives were set to demonstrate the value of the HotShot system. These are an improvement in fragmentation leading to an increase in productivity, less oversize rehandling, increased throughput and more uniformity in muck pile movement. To maintain the integrity of the trial, the nominal timing of the shots was kept exactly the same, thereby restricting any performance improvements to the precision of the electronics. Accordingly, adjacent shots were chosen with consistent geology. Video footage was taken of the blasts and vibration monitoring was carried out by fixed geophones throughout the mine. Spot heights of the muck pile swell were taken immediately after the blast and heave profile graphs were generated for comparison. Video footage was taken for a period of three hours for both shots to analyse cycle times of the excavator and trucks. PITRAM data was also collected for analysis. As far as practicable, the ore was taken to the same finger on the run-of-mine (ROM) pad to assist in single sourcing for the crusher and to allow oversize to be separated out. From specific metrics taken during the trials, it was shown that the expected improvements due to the high precision timing of electronics were realised in all areas.

Jan 1, 2007

By P Hanna

In an effort to improve returns to shareholders, the Australian Mining Industry has consolidated considerably over the past decade or so. Technical services at mines have been re-structured, whilst those at corporate offices have been all but eliminated. A recent study of the role of the geologist in BM Alliance Coal Operations Pty Ltd (BMA), showed the adverse impact on the companyÆs performance due to a lack of geologists. With an education campaign, to demonstrate the contribution of geologists to the æbottom lineÆ and in increasing the options available to the company, the value of the geology role became better understood. The implications of the loss of invaluable corporate knowledge, when long serving geologists left the company, also became clear. Steps have since been taken to increase the numbers of company geologists, particularly on mine sites. In common with other sectors of the mining industry, the Australian coal industry is experiencing a critical shortage of experienced coal geologists, as companies have found in recent recruitment efforts. This is further evidence that the recommendations from the recent study by World Competitive Practices, commissioned by The Australasian Institute of Mining and Metallurgy, æRising to the ChallengeÆ have not been adopted. People, and the mineral resource base, are the assets from which mining companies gain a sustainable competitive advantage. Geologists, as the nexus between the resource base and people, are in a unique position to enhance the profitability of their companies. To maximise their contribution to the industry, and ensure that they receive due recognition, geologists must adopt a more commercial approach in their work and take a front foot stance in promoting their value to management. Geology is a core competency for all mining companies. The tendency for companies to outsource this function, to the detriment of the company geologist role, is not sustainable in the longer term. TodayÆs geologists need to work closely with management, technical and human resource professionals, universities and schools to ensure their significant value is well understood, and that the industry can attract, train and retain new recruits through the implementation of graduate programs and company career paths.

Jan 1, 2003

A pilot plant has been constructed for the low temperature carboni-zation of Wallarah (N,S,W6) coal at the rate of 300 pounds per hour. The plant was built and tested at Australian Mineral Development Laboratories for Broken Hill Pty, Ltd. Char product was required within the specifi-cation 15.5 `S' 1 per cent volatile matter. The design was based c atz an entrained state carbonizer developed by Parry and U.S. Bureau of Mines co-workers at Denver, U.S.A. The method involved the carbonizatioan of fine coal by entrainment with air in an externally heated reactor.. The heat required for carbonization of tits coal was supplied to the be, both through the reactor walls and also by internal cambustion of products .

Jan 1, 1963

By Lee G, Stitt P

The term "industrial minerals" covers a vary wide field. However in Australia this field tends to be characterised by the follow- ing: (1) Relatively low unit values. (2) Product specifications can be exacting compared to the metalliferous field. (3) Product specifications often have to be tailored to the needs of the end user. (4) Beneficiation plants tend to involve low capital outlays relative to the metalliferous field. However they often have to produce products'to a range of specifications. (5) Technology often influences what can be considered as reserves. (6) Because of low unit values industrial minerals tend to be relatively cost sensitive. This is particularly the case in regard to transport. (7) Location of deposits near to major urban areas (markets) dictates a greater pressure on ecological aspects. (8) In Australia there has been a tendency to vertical integration largely due to the restricted market available. Reserves assessment is shown to be critically dependent upon the above Factors.

Jan 1, 1979

By Corrans I. J, Yan D. S

The CIP process for gold recovery has enjoyed widespread application in most gold-producing countries. The development of a mathematical model of the CIP process has value for use in process design, process optimisation, and process control. Mathematical model development through laboratory experimentation is an important step in the design and optimisation of the CIP process. For this purpose, data has been generated through small scale laboratory leaching and adsorption tests both in batch and continuous mode. This test program has been carried out on specific ores of various types prior to the application of the models to production CIP plants utilising these ores. The applicability of leaching models derived from batch experiments was tested in a continuous five stage CIP pilot plant. The models were then adapted to scale-up the batch to the small scale continuous operation.

Jan 1, 1991

Blasting in Norwegian mines is often carried out by contractors who tend to look for the cheapest solution, without concern about fragment quality. The requirementsfor a contractor are usually only related to the maximum size of boulders and the quantity per month. Even when the owners of the mine are responsible for blasting, very little effort is made to optimise the blasting process. This paper presents test methods which were used and results from small-scale and full-scale blasting tests. In the small-scale tests, cubes 500 x 500 x 500 mm of four different rock types were blasted in a chamber, using two types of dynamite explosive. The velocity of detonation (VOD) for the dynamite explosives was 3000 m/s and 6000 m/s respectively. Three cubes of each rock type were blasted with each type of explosive, and a total of six cubes of each rock type was used. The entire muckpile (approximately 350 kg) was- sieved and weighed after each blast and fragments between 8-16 mm were tested for impact values and flakiness. The results of these tests clearly showed improvement in fragmentation the closer the acoustic impedance ratio of the explosive (VOD x density) over the rock (Cp density) was equal to one. The results also showed that the quality of the fragments (in terms of impact values) tends to be better when the cubes are blasted with the high velocity dynamite.

Jan 1, 1995

By L Faulkner

The Tarnagulla Gold Project in Central Victoria, Australia, was developed and operated by Reef Mining NL between 1994 and early 2000, producing 53 000 ounces of gold from the Nick OÆTime Shoot, a single narrow vein shoot structure within part of the larger Poverty Reef, with a strike length ranging from 30 m to 60 m. The ore shoot was developed over a vertical interval of 190 m, using a small cross-section decline and small, mechanised equipment. Various stoping methods were employed including mechanised cut-and-fill with a single boom jumbo, hand-held mining using airleg drills and rope scrapers, and small uphole retreat stopes using a line of sight remote operated LHD to recover a crown pillar. Experience during stoping showed that airleg drilling and rope scrapers gave much better dilution control than diesel equipment. Innovations included a low-cost hydraulic fill system. Due to the small scale of the deposit, the feasibility studies, planning and permitting for the mine were based on very limited drilling information; however, the mine was brought into production within two years of the discovery. While the mine made an operating profit, it failed to fully repay capital at the low gold price then prevailing. Applying the lessons learned from the operation to optimise the access and stoping method, the project is re-examined at todayÆs gold price and operating costs. Central Victoria has the potential to host many similar small deposits. The authors were respectively Non-Executive Director and Resident Manager for Reef Mining NL when the mine was operating.

Jan 1, 2008

Strata bolting/dowelling reinforcement techniques are being reintroduced into the mines of the National Coal Board. There are strong reasons for the selection of the full hole anchorage principle of bolting and for the development of the wood/resin dowel. There are strong reasons also for the measurement of strata bed separation as the method of assessing the effectiveness of a roof bolting system. There are several designs of bolts. Instruments have been developed for investigation and control purposes. Different drilling and bolting machines have been employed in trial sites. In addition comparative laboratory model work has been conducted on simple non-bolted and bolted systems.

Jan 1, 1971

By J Austin, R Bitencourt

Differences between the long-term model (LTM) and mine geology system (MGS) grade control block-outs on a blast block scale can impose difficulties to planning crusher feed grade and tonnes on a monthly to weekly blend basis. Detailed geological input to short-term planning has been integral to improve the performance and reduce risk in six-week to three-month production schedules and local variability in tonnage and grades is often not accurately represented in the LTM. The challenge of producing to combined target specifications from different mine sites in an integrated mine to ship business has been reduced with the creation of blast blockout-based short-term model. These short-term blast block models (STBBM or STM) are robust predictive tools created for upcoming benches of current mining areas by firstly collecting data from the pit in the form of bench and face mapping and projecting the structure and stratigraphy down to the next bench. A wire-frame of the projected contacts based on material destination from production blockouts is created and then checked against the LTM. Blast block data from the bench above including assay results and material logging is extracted and validated according to the projected wire-frames (geozones). Individual blast blocks and a full block model are created for each bench production defined by the STP (bench plans). Data output from the STM is in a compatible format for import into scheduling specific software packages. Additional information is incorporated into the STM to allow querying of drill penetration rates, predicted powder factors, material hardness and feed type to further aid in the production planning process and cost forecasting. To date, reconciliation of the STM has been pleasing and certainly an improvement on the LTM, especially in areas where variability is higher due to geological complexity. Short-term predictions derived from in-pit geological observations allow mine planners to more confidently decide on mining block sizes and schedule tonnages and grades, reducing the risk component attached to developing production schedules based directly upon long-term orebody models and mine plans.

Jan 1, 2005

Currently, mining in Australia underpins the economic vitality of the nation, generating massive revenue from commodity exports and providing substantial infrastructure and employment. In addition, it is predicted that mining related services will in the future develop a global market of their own that could eventually grow to rival, in value, the export trade in mineral commodities. There is however little room for complacency. In the short- to medium-term, escalating, vigorous competition can be expected from many previously underdeveloped countries that are reforming their own mining and mineral export industries. In addition, most mining companies are facing a modem-day renaissance in terms of new expectations, changing social norms, evolving employee relations and statutory obligations. Thus, along with whatever promise the future might hold, the mining industry is currently being subjected to a growing number of largely unprecedented problems and pressures, both economic and social, that are both highly complex and demanding. In particular, it remains a matter of on-going concern that relations between mining companies and their employees still, in spite of recent reforms, continue to constrain productivity, perpetuate inefficiencies, affect quality of work life and retard progress towards mutually beneficial goals and achievements. If mining in Australia is to attain and hold on to a commanding position on the global scene, then further changes will clearly need to be made. Realisation of this appears to be growing, with most mining companies having attempted in recent years to improve workplace culture. Based on a wide ranging study, this paper presents an overview of what has been learned to-date with regard to the `people factor' when it comes to implementing and progressing positive change and reform in mining. From this, a number of practical suggestions, arising from hard won lessons and experiences in the field, are offered. Attention to the nine `key principles' given should help to ensure that many of the common problems encountered to-date with change and reform in the mining industry are in future avoided or at least minimised.

Jan 1, 1997

By J Andrina, D Richards

The Grasberg is a large copper and gold open pit mine operated by PT Freeport Indonesia and located in the high equatorial mountains of Papua Province, Indonesia. The climate is alpine/sub-alpine with little seasonal variation in temperature and rainfall. The annual precipitation varies from about 3000 to 5000 mm over short distances around the Grasberg, but in general, an average daily precipitation of 10 mm per day applies and leaching of the overburden is continuous throughout the year. Mining commenced in 1988, and almost all of the overburden mined up to 2003 was potentially acid forming. The current acid drainage from this overburden is being collected and treated. From 2004 to the end of the Grasberg pit operation in 2014, approximately 70 per cent of the overburden will be potentially acid forming and 30 per cent limestone. A program of laboratory leach columns, field test pads and an instrumented full-scale dump was developed with the objective of defining scale up factors to quantify the acid and metal leaching rates and to evaluate the stockpile geochemistry and control options. The results of an ongoing seven year program have demonstrated feasible scale up between laboratory columns, field test pads and the trial dump in relation to material geochemistry and ARD evolution trends at Grasberg. The potentially acid forming waste types are highly reactive and maximum acid generation rate occurs within two to three years and that maximum copper release occurs within one to two years of exposure. The results also show that the net acid generation (NAG) test provides a good estimate for the potential acid load from overburden types. The chemistry, temperature and oxygen data from the trial dump suggest that oxidation and acid generation is occurring throughout the dump but at a decreasing mass rate with increasing distance from the toe of the dump. It is apparent that convection and/or advection are important mechanisms for the transport of oxygen into and within the dump. Key results and findings of the investigations carried out are presented and the implications of the findings for long-term ARD management at the Grasberg mine are outlined.

Jan 1, 2003

The scope of this paper has been restricted to the manufacture in Australia of seamless steel tubing, as the subject of buttweld tubing has already been dealt with by A. N. Hamilton in a paper delivered before the Institute in 1935.The earliest attempts to produce seamless steel tubes were based on the extrusion of lead piping, a process developed by Thomas Burr in 1820. However, the problems associated with the extrusion of white hot steel had to await the metallurgical knowledge of the twentieth century, and these early attempts were unsuccessful.The years 1840 and 1845 were noteworthy for the introduction of the first practical methods of making seamless steel tubes. In one process, a large circular plate was 'cupped' in a vertical press; in the other, a round steel billet was pierced for its entire length.The product from both these methods was then elongated by repeated reheating and rolling over an internal mandrel, in a circular pass mill.At this juncture, it should be noted that every process developed for the manufacture of seamless steel tubing can be divided into two parts. In the first part of the process, attention is centred on the conversion of the heated bloom into a short, thick-walled, hollow cylindrical forging; this product is then elongated in the second section of the process. It will be noted that these two sections are actually quite distinct, and in practice numerous methods exist for carrying out both functions. The first stage is generally referred to as 'piercing', the second stage being termed 'elongating.' In this paper, the author proposes to outline the various methods adopted for piercing and elongating; the reader is asked to note that although certain methods of piercing are almost invariably associated with only one method of elongating, the distinction between the two functions is, nevertheless, a vital one and should be noted accordingly.

Jan 1, 1947

By Wright S, Rogers L. J, Precious T. H

Brown coal and its char were investigated as substitutes for petroleum coke in the manufacture of anodes for Hall-Heroult cells. The char, which had been densified by several techniques, was made into compacts with various binders and the anodic consumption determined during electrolysis. The results were an improvement on previous work, but the anodes still fell short of acceptability for use in aluminium smelters because of intractable microporosity. Some options for future development have been discounted.

Jan 1, 1986

By M Ewart

The securing of a reliable water supply for a prospective mine in the North West Queensland Mineral Province is usually one of the most influential factors in determining the mine's feasibility. The Ernest Henry Mine required a reliable water supply to serve a demand estimated at feasibility stage to be up to 20 ML/day. Numerous options were considered before a decision was made to construct a 113 km long pipeline from Lake Julius as this was the most cost effective, reliable source of supply. The North West Queensland Water Pipeline is a multi-user, Queensland government funded project initially supplying up to 7000 ML/year of water from Lake Julius to Ernest Henry Mine, with provision made for expansion to serve future users in the region. This paper discusses the history of the pipelineÆs development, together with a summary of the scheme's design features. Environmental and licensing requirements, construction and operational issues are also discussed.

Jan 1, 1998

Prior to 1975, most geochemical drainage surveys for gold were based on analyses for pathfinder elements, such as As and Cu, rather than direct analysis for gold, for two reasons. Firstly, analytical methods lacked the required sensitivity and precision to determine gold abundance at background levels in stream sediments (usually in the range 1 - 10 ppb). Direct analysis was also inhibited by concern about the potential for gross sampling error, brought about by the dispersion of gold as rare discrete particles of the extremely dense native metal. This sampling error, commonly termed the 'nugget effect' has two components: erratic distribution of the element within the stream environment, related to hydraulic factors, and the difficulty in taking representative samples, both in the field and later in sub-sampling for analysis. In more recent years the collection of very large samples was commonly advocated to overcome the sampling problem (Hams, 1982; Nichol, 1986).Two methods have been widely used to evaluate the gold content of bulk samples (Elliott and Towsey, 1989). The preparation and analysis of heavy mineral concentrates has in recent years been largely superseded by the leaching of gold contained in bulk samples by cyanide, commonly termed the BLEG (Bulk Leach Extractable Gold) or BCL (Bulk Cyanide Leach) methods. The terms BLEG and BCL are essentially interchangeable and the latter will be adopted for the remainder of this paper. The strengths and weaknesses of these two techniques were compared with conventional total gold analysis on fine fraction (

Jan 1, 1976

Distal rhyolitic tephras from the Taupo Volcanic Zone are widespread in the Auckland urban region. Some are primary air fall or flow deposits but most are reworked. Their presence indicates potential hazard for the Auckland urban region from future eruptions of central North Island volcanoes and associated secondary effects. Geotechnical problems occur as a result of weathering of the tephras yielding sensitive materials.

Jan 1, 1990

By S Jeon, K Aikawa, M Ito, A Kusano, I Park, N Hiroyoshi

In mineral processing of complex sulfide ores containing copper (Cu), lead (Pb), and zinc (Zn), flotation has been commonly used. Typical Pb mineral in the ores is galena (PbS), while some types of the ores contain anglesite (PbSO4). This article reviews our recent studies on the effects of coexisting PbSO4 on the flotation of complex sulfide ores, and a method to suppress the floatability of sphalerite (ZnS) in the presence of PbSO4 was proposed. Comparison of flotation experiments for different types of model samples showed that PbSO4 makes the separation of Zn from Cu difficult; that is, for the model sample containing PbS without PbSO4, Zn could be separated from Cu, while when the model sample containing PbSO4, Zn was recovered together with Cu as froth. Solution analysis and thermodynamic calculation suggested that Pb2+ was released from PbSO4 and reacted with ZnS to form PbS, acting as an adsorption site for the flotation collector, xanthate. This would be the main reason for high floatability of ZnS in the presence of PbSO4. As a method to suppress ZnS floatability for the ores containing PbSO4, a pre-treatment of the ores to remove PbSO4 prior to flotation was proposed. The results of model experiments using mixture of ZnS and PbSO4 showed that ~97 per cent of PbSO4 was dissolved within 30 minutes of pretreatment using ethylenediaminetetraacetic acid (EDTA) as extractant, and thus ZnS floatability was markedly suppressed. Moreover, Pb2+ extracted from PbSO4 during the pre-treatment could be recovered as zero-valent Pb by the cementation using zero-valent Fe as a reductant. The details of ZnS flotation in the presence of PbSO4 and the effects of the pre-treatment are discussed based on the results of surface analysis like XPS.

Aug 24, 2022

Longwalling has reached a high standard both in Germany and Australia and most improvements should be expected in planning, monitoring and control. Double drum shearer have electric drives to 1000 kW and automatic height control is under development. Conveyor pans to 40mm thickness and chains to 2300 kN breaking load are in use with controls for pretension and load compensation under test.Trends in support are towards two leg shields with loads to 3850 kN per leg and electrohydraulic controls. Expert systems have been devised for planning and diagnosis tasks. With increases in technical standards, staff qualification standards at rising too, drawing attention to training requirements for modem personnel.

Jan 1, 1991