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By D Lau

Traditionally X-ray diffraction (XRD) has not been significantly used by the cultural heritage sector, as the most commonly used technique, X-ray powder diffraction (XRPD), requires sample removal from the artwork or artefact, followed by grinding of the sample to a fine powder. With the development of micro-X-ray diffraction (micro-XRD) and other associated advances, non-destructive, in situ analysis of crystalline pigments on micro-areas of paintings and artefacts has become possible. This is illustrated with the application of this technique to the in situ analysis of propriety paints, paint cross-sections and small paintings. However, workers have noted that XRD can be insufficiently sensitive with pigment mixtures, due to matrix effects. This study obtained X-ray diffractograms of 17 single pigment preparations and determined relative amounts of crystalline content. The purity of single pigments was compared with Joint Committee on Powder Diffraction Standards (JCPDS) database diffractograms. The impact of pigments with high X-ray absorption coefficients on the detection limits of pigments with low X-ray absorption coefficients was further investigated by building on work done with the chromium oxide-zinc oxide series with the preparation of a second series of binary mixtures of zinc oxide (which has a high absorption coefficient and is almost fully crystalline) and ultramarine blue, which has a lower absorption coefficient but which is more crystalline. Semi-quantitative analysis, where baseline and absorption factor corrections are made, confirm detection limits as low as five per cent for chromium oxide and ultramarine blue when in a binary matrix with zinc oxide. However, this type of analysis is very time consuming. So in order to theoretically simulate issues that will be encountered with binary pigment mixtures, the single phase diffractograms were used to theoretically investigate the matrix effects of the three white pigments with the various coloured pigments. This illustrated that detection limits can be as low as five per cent or in non-ideal conditions, such as with partial peak clashes or where there are large differences in relative peak intensity, as high as 50 per cent. These results have significant implications for the analysis of painted surfaces on artworks or artefacts. It has been demonstrated that ideally this method is more suited to the investigation of surfaces where there is minimal mixing of pigments or where there is not a significant difference between the absorption coefficients of the mixed pigments.

Jan 1, 2008

The foundation of our industrial welfare lies in the success of our primary industries, and, so far as mining is concerned, it is hoped that for many years it will be a most important primary industry in Western Australia.

Jan 1, 1927

A survey of derelict and active alluvial tin and sapphire mines in the Emmaville area of northern N.S.W. as the first step in a pro- gramme of similar surveys to be undertaken throughout the State by the State Pollution Control Commission is presented. Thirty nine individual mine sites in the study area were included in the survey and an assessment made of the current level of impact on the environment at each site by assigning values of "magnitude" and "importance" to a number of impacting factors. Results are pre- sented in matrix form and mine sites ranked in order of impact "importance". Examples of alluvial tin, underground tin/arsenic and alluvial sapphire operations are discussed in detail and rehabilitation programmes proposed for implementation.

Jan 1, 1976

The Permian coal in the Muja Coal Measures of Collie Basin of Western Australia has a subdued lustre because of the fine laminations of lithotypes, and the dominance of dull and dull banded lithotypes with minor bright, bright banded and fusinous types. The maceral composition of the coal is variable, however the macerals of vitrinite and inertinite groups dominate and the exinite and mineral matter contents are low. The lithotypes have low concentrations of trace elements and the boron concentration is between 10 - 100 ppm recorded only from the dull lithotypes. On the basis of organic petrology, the inter-seam sediments, flora and the very low concentration of boron, the depositional environment postulated for the coal is braided, fluvial and fluvio-lacustrine with marked fluctuations in the water table. The low water table in the environment accounts for fusain and inertodetrinite in the coal.

Jan 1, 1996

By Ritchie I, Fleay J

The key issues in the conceptualisation and testing of treatment options for gold and base metals mineral processing projects are discussed. A prerequisite of this process is the need for close interaction between geologists, mining engineers and metallurgists to facilitate an understanding of the orebody based on the parameters impacting on each discipline. Typical testwork programs for unit operations, including comminution, flotation and gold processing are Described.

Jan 1, 1997

By Evans R, McCallum P

Modem blast initiation systems allow users many options for connection and application in the field, and have resulted in more innovative and complex uses of sequencing to influence blast outcomes. However, no tool existed which allowed the blaster to easily and quickly assess the effect of different options. The original requirement was for a computer program which allowed the easy input of blast patterns and the associated initiation sequence, and then permitted the evaluation of different options with respect to established criteria such as the number of holes per delay and angle of initiation. The implementation of this goal saw the development of the SHOTPIan blast sequence design software, with particular emphasis on an easy-to-use menu driven interface and visualisation of the blast sequence. Extensive trialling during development saw the incorporation of additional features requested by industry such as the ability to import from established mine design software packages, and further features such as the calculation of burden relief times. Case studies of the use of the program are provided, where the rapid evaluation of a number of options has enabled blast results to be optimised. Examples are also given of cases involving two-path initiation

Jan 1, 1995

By M Kilburn, A Edenton, M Adam, A Dehghan-Manshadi, R Smyth, L Lu

The blast furnace is a counter current reactor. The counter current principle of the furnace makes it very efficient in transferring the heat and mass required to drive the reduction reactions inside the furnace. However, this does impose a stringent requirement on the permeability of burden material in the furnace. Lump ore is one of the key ferrous feeds used in the blast furnace ironmaking process, often accounting for ten to 20 per cent of the blast furnace ferrous burden. As the lump ore descends through the blast furnace, it is dried, heated and reduced by the ascending hot reducing gas. To ensure good furnace permeability, generation of fines from burden materials including lump ore due to mechanical, thermal and chemical processes needs to be minimised. Unlike sinter and pellets, lump ore is subject to thermal degradation. To assess this behaviour of lump, the ISO decrepitation test (ISO 8371, 2007) is often conducted, and the result is calculated as a decrepitation index (DI). However, the DI values obtained from the existing ISO decrepitation test vary considerably between test portions and between laboratories, which makes meaningful comparison very difficult. In order to identify the sources responsible for the unacceptable repeatability, the effect of various testing conditions, such as particle size, heating rate, sample preparation and loading method, on the mean DI value was studied. The mechanisms contributing to thermal degradation in the top of the blast furnace and during the standardised decrepitation test are also discussed.CITATION:Lu, L, Kilburn, M, Dehghan-Manshadi, A, Adam, M, Edenton, A and Smyth, R, 2013. Thermal degradation of lump ore in the top shaft of blast furnaces, in Proceedings Iron Ore 2013 , pp 421-426 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By D E. Langberg, D R. Swinbourne

The past century has seen the development and commercialisation of many new pyrometallurgical processes based on gas injection. The driving force behind this trend in smelting and refining technology was the increased productivity and resulting increase in capital utilisation achievable. However, measurement of system variables is not easy and their effect on the rate of the reactions involved is not well characterised. One of the critical parameters is the gas-liquid interfacial area produced by gas injection. Related variables such as bubble size and velocity, and gas hold-up fractions in aqueous systems have been measured using combinations of physical (visual, audio and electrical) and chemical techniques. Models have been developed relating interfacial area to physical properties and operating variables and attempts made to extrapolate these to high temperature, liquid metal systems. The only attempts at validation of these models have used either low temperature liquid metals, such as mercury or WoodÆs Metal, or operating plant data. This paper reviews existing knowledge of the effects of system variables on total interfacial area in gas injection systems. Interfacial area is calculated from a range of published experimental aqueous and liquid metal systems and used to assess existing models. An operating region diagram was developed to assess dynamic similarity between experimental and industrial systems. It highlights areas where further research into both measurement techniques and experimental system variables is required in order to extend knowledge and guide further technical and design advances into the 21st century.

Jan 1, 2000

By Miovski P, Hooft P. V

In the majority of recently commissioned gold mines granular activated carbon is used to adsorb gold from alkaline cyanide pulps or solutions. At the same time the carbon also adsorbs many other inorganic and organic species, most of which lower the activity of the carbon. Removal of these foulants is necessary before the carbon is reactivated and recycled. Standard practice for re- storing carbon activity involves high temperature treatment in a kiln - an apparently straightforward unit operation which is not always satisfactorily carried out. This paper presents the results of some fundamental work carried out on the thermal reactivation of carbon in a laboratory rotating pot kiln. The effects of temperature and steam addition on carbon activity were examined and compared with the activity of carbons obtained from a number of commercial kilns. Carbon was also reactivated using a small-scale Rintoul Furnace in which carbon was resistively heated by the direct passage of an alternating electric current. It was established that both elevated temperatures and the addition of steam to hot carbon generally enhanced its activity although peat-based extruded carbons responded a little differently to coconut shell types. Other measurements made included the weight loss and the hardness of carbons as a function of reactivation conditions.

Jan 1, 1987

The application of modern sciences prior to nineteenseventies have resulted in the placing of Continental Drift theory into broader concept of Plate Tectonics. The concept is applied to explain the Cenozoic Tectonics of North Sumatera.Oceanic crust flooring the Indian Ocean is moving northeasterly and being obliquely subducted at a Benioff zone along the western margin of Asian Plate, marked by the Sunda Trench in the west coast of Sumatera. This phenomenon was generated since late Mesozoic, continued during Cenozoic era up to present day, resulted an exellent example of arc-trench system which can be traced along SW - NE transect of North Sumatera.The oblique-subducting plate of Indian Ocean beneath Asian Plate, together with spreading of Andaman seafloor beginning in Pliocen epoch, have led to the origin of Sumateran Fault System; the System extends throughout the length of Sumatera island. In the region under review it comprises almost contiguous set of broadly SE-trending. Evidences for transcurent-dextral displacement have been observed.

Jan 1, 1990

By Corbett GJ

Epithermal gold-silver deposits occur in young volcanic terrains where post-mineral cover commonly impedes the search for mineralisation. At the Togi Project in Honshu, Japan, a complex mineralised system is largely covered by post mineral volcaniclastics. A combination of high resolution electrical resistivity surveying and detailed airphoto interpretation has, with close geological control, enabled synthesis of structural and alteration characteristics of the Togi geothermal system, in turn permitting ranking of the prospects for drill testing.

Jan 1, 1990

A methodology is described to integrate heap leaching into a CIP operation. The paper firstly describes what is meant by a 'systems approach'. A broad view of the objectives of integration of heap leaching into CIP is given, followed by the components of the system, and then a description of the methodology for integration. The seven stages of integration are given as determination of distribution of gold, sampling, metallurgical testwork, conceptual study, pilot heap operation, pit modelling and pit optimisation. The final result is a series of optimised curves which determine the maximum value of the orebody, and the optimum cut-over grade from CIP to heap leaching.

Jan 1, 1992

By Hansmire WH

The 14.7 km Mt. MacDonald Tunnel beneath Rogers Pass in Canada used both drill-and-blast and machine boring methods. A unique ventilation system provides for diesel operations. The design featured minimum construction support and an unrei.nforced poured concrete lining. The west heading was excavated in a single-stage drill-and-blast operation. The east heading used a TBM top heading with a drill-and-blast keyhole bench. The choice of methods was controlled by varying geology, with up to 1,700 m rock cover. Construction performance and progress are evaluated.

Jan 1, 1987

A number of mines in Australia have experienced premature detonations caused by bulk explosives reacting with the rock type being blasted. Premature detonations are extremely high risk events as they are unplanned, occurring at any place, at any time, potentially resulting in high loss (personnel and equipment). Many Australian mines have also experienced spontaneous combustion where spilt explosive reacts vigorously with the rock type. Premature detonation in these cases does not occur due to the lack of confinement and the volume of explosive present, but these reactions could impinge on the surface initiation system and provide an early warning of future premature detonations. The explosive ground reactivity phenomena is not restricted to Australia with similar incidents being reported in North and South America, South Africa, China and South East Asia. All reported incidents have two common denominators, being the presence of sulphide rock types and nitrate based explosives. Both premature detonation and spontaneous combustion result from the same series of reactions of partially weathered sulphides that ultimately result in the violent decomposition of the ammonium nitrate based explosive. A number of relatively easily observable indicators can be used to assess a particular minesiteÆs potential for explosive ground reactivity. The presence of two or more of these indicators means that minesite personnel should contact their explosives manufacturer for assistance in determining if a problem exists and if so then developing strategies to overcome the situation. The paper describes the indicators as well as discussing, via a case study, the holistic approach required to efficiently develop a relevant æSafe and Efficient Blasting ProcedureÆ to deal with explosive ground reactivity problems.

Jan 1, 1999

By Smith DM Jr

Silver deposits, in which silver forms at least fifty percent of the value of the ore, are abundant and large on the east side of the Pacific and are absent in the western Pacific. To determine if this uneven distribution is related to features of consuming plate tectonic boundaries which dominate the metallogeny of the Pacific Rim, the variation of Ag/Au in porphyry copper deposits was used to estimate the relative silver content of magma generated in subduction zones. Porphyry copper provinces with high Ag/Au occur in regions of the eastern Pacific where silver deposits are abundant, suggesting that the distribution of silver deposits is controlled by the relative abun- dance of silver in subducted ocean crust. Ocean crust being subducted in the eastern Pacific is mostly less than 50 million years old in contrast to most ocean crust in the western Pacific which is much older. Enrich- ment of silver in young ocean crust at spread- ing centers may reflect metallogenetic evolution over geologic time. Silver may be transported to the surface in volcanic rocks, and deposits are common where felsic varieties are abundant. The high ,solubility of silver in natural waters provides a natural storage mechanism for silver weath- ered from these rocks and ultimately circulated in near-surface hydrothermal systems where many silver deposits form. The regional distribution of silver deposits is not influenced by discoverability, vertical metal zoning, or regional tectonic style. The effect of igneous differentiation is unclear.

Jan 1, 1987

By S Hapugoda, A Edenton, M Adam, R J. Holmes, J R. Manuel, R Smyth

Lump ore is one of the key ferrous feeds used in the blast furnace ironmaking process, normally accounting for ten to 20 per cent of the blast furnace burden. Like other feeds, the characteristics of lump ore have an important impact on the stable operation and productivity of the blast furnace. Lump ore is usually assessed chemically, physically and mineralogically to establish its likely blast furnace performance. The physical characteristics of lump ore are strongly related to the chemistry, mineralogy and texture of the ore involved. In this paper, the blast furnace ironmaking process is reviewed, with particular emphasis on the key quality requirements for the ferrous burden material. A variety of key physical characteristics of lump ore measured using standard and non-standard methods are then described and subsequently correlated with the chemical and mineralogical characteristics of the ore wherever possible. Finally, the impact of these physical characteristics on blast furnace operation is assessed.

Jan 1, 2009

By Meyer T

Sunburst PCF (Penetrating Cone Fracture) technology has recently undergone extensive underground field trials at Leinster Nickel Operations, Western Australia. Trials with the Sunburst machine started in September 1994 and continued through to December 1994 during which approximately 130 metres of tunnel were developed. The Sunburst technology was used to excavate sub-levels through ultramafic nickel ore for future sub-level caving operations at the Perseverance nickel mine. The Sunburst machine demonstrated reasonable instantaneous advance rates, however, there are still a number of future developments/design changes which need to be addressed prior to the PCF technology being trialed again in a production environment. This paper benchmarks conventional drill and blast at Leinster against the Sunburst Excavator machine performance within similar tunnel dimensions and rock conditions. In addition to productivity and cost information; environmental considerations, support and labour requirements are also discussed. Problems with the current machine design are highlighted and possible future design changes are suggested. The Sunburst machine could be a suitable technology for advancing development through weak to moderate rock conditions and may also reduce overall support costs. With the potential for automation and the ability to reduce rock damage into the development tunnel walls, it is proposed that the Sunburst machine warrants further consideration.

Jan 1, 1995

The purpose of this paper is to provide a ælook behindÆ the Coal Mine Health and Safety Act 2002. The more important policy considerations in the development of the Act are described along with a summary of the main provisions of the Act. The Act, together with supporting regulations and other instruments will formalise the use of risk management as a necessary discipline in the systematic management of occupational health and safety. It must be recognised that the purpose of this paper is not to provide a legal interpretation of the legislation nor is it to provide legal advice. Rather, the main purpose is to provide some indication of the underlying intent behind the Act.

Jan 1, 2003

By Albano C, Antila A, Flykt B

A method for relating operating variables and dewatering parameters of Thunes disc filters in the LKAB pelletizing plant at Malmberget in Sweden, via empirical mathematical models is described. Near orthogonal experimental design was used, where all independentvariables were allowed to span over their domain of variation and pseudo-randomly distributed among the experiments. The dewatering parameters are dependent on many variables and instead of using a traditional mechanistic model, an empirical model based on multivariate data analysis was chosen. The way of expressing the relation is by regression coefficients obtained from partial least square regression (PLS). Two empirical models were generated. The models were validated using an extra set of 56 experiments. The dewatering parameters were related to the design variables with few experiments, and user-friendly response surface methodology was used to determine the optimal conditions.

Jan 1, 1989

Proposals designed to use stockpiles and buffer stocks to achieve price stabilization and better resource use have a long history. They are super- ficially simple to understand. The benefits seem clear. And yet I am well aware that this is not a simple subject: the more one studies it, the more complex it becomes. Worldwide interest in re- source management, while receiving fresh impetus from the OPEC actions, also has a long and chequered history. Those venturing into such ter- ritories must be forewarned of the traps and pit- falls which abound. Interest in these schemes has waxed and waned over the years with the fluctuating fortunes of the producers or consumers. As I write this paper towards the end of 1977, I am acutely aware of the low ruling prices for zinc, copper, and nickel. These sacrifice prices remind me that it is difficult, for example, for a surveyor, to be calm and rational if he is up to his neck in a swamp full of crocodiles. He might be forgiven for forgetting that the aim was to drain the swamp! I am also aware that when swamps are drained, painful and dangerous stumps sometimes stick out. Hence, in looking at the subject of stockpiles and resource management we must not set our sights too high, perhaps not initially hope for perfec- tion, if we want to secure worthwhile changes. My approach is to acknowledge a bias for the market system. We have, however, had experience (remember the 1930s) of some weaknesses in the untrammelled operation of free markets. Thus our international economic relationships over the past 20 or 30 years have been based on a desire to retain as much as possible of a liberal world trading system backed by such organizations as the GATT, IMF, and the U.N. to ensure the necessary cooperation. Some nations have seen this system work only partially in their best in- terests. GATT, for example, has been reasonably effective in liberalizing trade in many manufac- tured goods but far less so in regard to agricultural or semi-processed goods.

Jan 1, 1978