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By A. Anderko, R. D. Springer, R. D. Young

A thermodynamic model has been developed for calculating phase equilibria and other properties of multicomponent electrolyte systems. The model has been designed to reproduce the properties of both aqueous and mixed-solvent electrolyte systems ranging from infinite dilution to solid saturation or pure solute limit. The model incorporates formulations for the excess Gibbs energy and standard-state properties coupled with an algorithm for detailed speciation calculations. The excess Gibbs energy model consists of a long-range interaction contribution represented by the Pitzer-Debye-Hiickel expression, a second virial coefficient-type term for specific ionic interactions and a short-range interaction term expressed by the UNIQUAC equation. The accuracy of the model has been demonstrated for common acids and bases and for multicomponent systems containing aluminum species in various environments.

Jan 1, 2005

By D. R. Winchester

"I wish to thank you and your organizers for inviting me to address you at this point in time when we are all concerned for the future of the mineral industry in Canada.My topic ""Some Initiatives of Government Assistance to Industry Applicable to Mineral Processing"" is purposely limited in scope. To cover the entire range of initiatives in detail would take me all day, and at best, would be a mere recital of program titles, and a one sentence summary of the contents of the program. As you know, OREE or Regional Economic Expansion, is in the process of being amalgamated with elements of the Department of Industry, Trade and Commerce. We will become Regional Industrial Expansion or ORIE. If the name Canada Dry becomes popular, I don't think we will object as we hope to become a good mixer. The entire departmental thrust has been re-evaluated, and is in the process of being re-constituted to better serve the nation, and industry as a whole. Amalgamation of the industrial, trade promotion and marketing support skills of IT&C, with the regional development orientation and decentralization program delivery mechanisms of DREE, will, it is believed, provide better support to industry on a national and regional basis."

Jan 1, 1983

By M. Kunst

The creep behavior of three AJ62 alloys was investigated in a wide range of stresses and temperatures. Multi-level tensile creep tests revealed a distinct primary creep stage and a high stress exponent up to a value of 10. The threshold stress concept which is commonly used in combination with high stress exponents was utilized in the analysis of creep behaviour. This resulted in an effective stress exponent for the AJ alloys indi¬cating dislocation climb as the dominating creep mechanism. In addition, microstructural observations of the lamellar eutectic and of the a-Mg-matrix were carried out using opti¬cal microscopy, SEM and TEM. The creep properties of the alloys are discussed in the context of microstructural parameters such as phase volume-fraction, stability and solute supersaturation.

Jan 1, 2006

By François Robert

"The Eastern Abitibi Sub province (Quebec segment), contains two main types of gold deposits: the common quartz-vein type and the rare pyritic type. Both occur in areas dominated by volcanic rocks and are spatially associated with major fault zones.Quartz-vein gold deposits consist of simple to complex networks of quartz-carbonate-pyrite veins in reverse shear zones and extensional fractures. They occur in areas dominated by mafic volcanic rocks and are commonly associated with small syn- to late-tectonic porphyritic felsic intrusions. Associated alteration, which postdates peak metamorphism, is dominated by carbonatization, sericitization and pyritization of the wallrocks. These deposits formed late in the geologicalevolution of the Abitibi.Pyritic gold deposits range from deformed massive sulphide lenses to zones of syntectonic pyrite-rich veinlets and associated pyrite disseminations. These deposits occur in environments dominated by felsic volcanic rocks that are typically converted to sericite schists near the deposits. The associated pre-metamorphic aluminous alteration is now characterized by metamorphic sericite, andalusite, kyanite and chloritoid, overprinted by a late retrogression of alumino- silicates. These deposits probably represent deformed volcanogenic massive sulphide deposits, but the timing of gold introduction in these is not fully understood.The differences in geological attributes reflect significant differences in the genesis these deposits: the pyritic deposits probably have a multistage genesis, including a pre-tectonic stage, in contrast to a single stage late-tectonic genesis for the quartz-vein deposits.RESUMELa partie Est de la Sous-Province de l’Abitibi( segment québécois) renferme deux types de gites d' or: ceux de type ""veine de quartz"" et ceux, plus rares, de type ""pyriteux"". Ces deux types se trouvent dans des secteurs particulièrement riches en roches volcaniques et mantrent une association spatiale avec des zones de failles majeures.Les gites de type ""veine de quartz"" correspondent à des réseaux de complexité variable de veines de quartz-carbonate-pyrite se développant dans des zones de cisaillement inverse et des fractures de tension. Ils se concentrent dans les régions dominées par des roches volcaniques mafiques et s’associent fréquemment à de petites intrusions porphyriques felsiques syn- a tardi-tectoniques. L’altération associée ace type de glte est postérieure à la phase majeure du métamorphisme et consiste en une carbonatisation, une sericitisation et une pyritisation des épontes. La mise en place de ces gites est tardive par rapport à l'évolution géologique de l'Abitibi.Les gites d' or de type pyriteux consistent en des lentilles de sulfures massifs déformes, des zones d' abondantes veinules pyrite uses syntectoniques, et des zones de pyrite disséminée. Ces gites se retrouvent dans des empilements contenant surtout des roches volcaniques felsiques qui sont transformées en schiste à séricine pres des gisements. L’altération a l’umineuse pre-metamorphique associée a ce type de glte a donné naissance, lors du metamorphisme regional, a la sericite, a 'andal ousite, a Ia lcyanite et au chloritoi""de; par la suite, les alumino-silicates ont été affectes par une alteration retrograde tardive. Ces gites representent probablement des depOts de sulfures massifs volcan gènes déformes, mais la chronologie de la mise en place de l'or dans ceux-ci est encore mal comprise.Les caractéristiques géologiques propres à chacun de ces types de gites reflètent des conditions de formation différentes: le type ""pyriteux"" montre une histoire génétique polyphasée, incluant une étape pre-tectonique alors que le type ""veine de quartz"" s’est développe au cours d’une seule phase tardi-tectonique."

Jan 1, 1990

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By R. J. McCarthy

In-pit Crushing and Conveying (IPCC) is increasingly being considered by mining companies as a means to reduce their dependence on trucks and thus, fuel, tires, labour, etc. There is potential for great savings in operating costs which ultimately can mean better economics for a mining project. Vale has considered the application of IPCC at its Moatize coal project in Mozambique. Up to three studies have been conducted with the latest, at a pre-feasibility level, showing some promise. This paper explores the mine planning and IPCC engineering elements required in an IPCC study, their application to the Moatize project, and the drivers which most impact the viability of IPCC at Moatize.

Aug 1, 2013

By Frédéric Flament

The aim of this paper is to present the development of a data validation software as component of a commercial mass balance package. Data reconciliation through mass balance is basically an optimization problem constrained by the law of mass conservation. As any optimization problem solved with a modern and robust software application, erroneous information or starting point will always lead to a solution, whether it is realistic or not. Moreover, good information wrongly weighted by an incorrect error model will lead to the same bad ending. In an industrial context where competition requires accurate information, data reconciliation without validation can be disastrous and calls for data validation before and after reconciliation. The challenge in automated data validation resides in the development of general theoretical solutions. Until now, none has been presented and only partial solutions are available. The development presented in this paper incorporates some of these partial solutions. The integration of human knowledge into the application paved the way to a more general solution. The combination ?theoretical validation ? human expertise? proved to be flexible and reliable enough to be integrated in a commercial data validation package. Numerous examples though industrial applications are presented. These applications demonstrate the validation of raw measurements, user support in the development of error models and validation of reconciled measurements.

May 1, 2001

Access to accurate real-time information is critical to maintaining efficiency and competitiveness in any modern minerals processing facility. At MMG LXML Sepon Copper Operation in Lao P.D.R., controlling the copper grade of the feed to the leaching circuit is paramount for maximising productivity and copper recovery. Since 2008, real-time analysis data has been available to process engineers from the Geoscan on-belt analyser installed on the Copper Mill feed conveyor. Access to accurate real-time results from the Geoscan has allowed the process engineers to strictly control blending based on copper grade to overcome variability in the plant feed, where conventional sampling and laboratory analysis is difficult, error prone and time consuming. In addition to enjoying these benefits since the Geoscan’s installation, in recent times the process engineers have expanded the use of the Geoscan by observing elemental results other than copper grade to control different aspects of the operation, focussing on the reduction of Gangue Acid Consumption. This paper discusses the process of expanding the Geoscan use at the operation, including an explanation of the calibration process. Additionally, a brief description of the Geoscan and its use at MMG LXML Sepon Copper Operation is provided, as well as a summary of recent calibration and analysis results. A discussion of future works concludes the paper.

Jan 1, 2016

By Y. J. Yu, C. D. Zhang, Y. S. Zhao, W. G. Liang, Y. D. Geng, J. L. Bi

"In this study, the coefficient of thermal expansion (CTE) and thermal conductivity (TC) of shale in two perpendicular directions, vertical and parallel to the bedding of the rock, are firstly measured by experiment. The experimental results show that the CTE of the shale in the vertical direction is 1.69 times as much as that in the parallel direction, while the TC in the parallel direction is 1.83 times larger than that of the vertical direction. Based on the no initial strain assumptions, numerical simulations for the thermal cracking in shale are carried out with the obtained coefficients. Using finite element method and thermal-mechanical coupling theory, two fracture mechanical parameters, KI and J-integral of the shale are also analyzed for the shale thermal fracturing. The simulation results show that both KI and J-integral reach the maximum when the fracturing angle equals to 0° in the shale, namely parallel to the bedding direciton. It is also found that the two fracture parameters decrease with the fracturing angle increasing. Additionally, the thermal fracturing effect of the shale is evaluated under a given scenario. The study is significant for shale oil or gas recovery by in situ pyrolyzing method.INTRODUCTIONOil shale is regarded as a kind of unconventional resource that can contribute to production of shale oil and hydrocarbon gases (Rahm & Dianne, 2011). As is known that there is a large deposit of oil shale in China, and present technology for exploiting oil shale still concentrates on open-pit mining, obtaining shale oil by retorting shale on the ground (Li, Tang, Xue, Zheng, & Du, 2014; Qian, Yin, 2008). However, this technology has a bad effect on the environment and leads to severe resource waste for utilizing oil shale. Exploiting oil shale by in-situ method for ‘green mining’ is widely necessary in China (Kang, Wang, Cao, Liang, Chang, & Liu, 2013; Waters, Dean, Downie, Kerrihard, Austbo, & McPherson, 2009; Zoback, Kohli, Das, & McClure, 2012). One of effective method to exploit shale oil is heating oil shale in-situ underground. For instance, the in-situ conversion process (ICP technique) from Shell Company etc. used a direct heating method, and convectional heating oil shale underground by injecting superheated steam from Mining Technology Institute, Taiyuan University of Technology and constructing horizontal fracture in vertical wellbore from Chevron Company use indirect heating method (Chaudhary, Ehlig, & Wattenbarger, 2011; Hazra, Lee, Economides, & Moridis, 2013; Zhao et al., 2010). The convectional heating method contains complicated procedures with phase transition in double-media of fracture-matrix of oil shale subjected to multi-physical fields coupling including stress, fluid and temperature (Zhao et al., 2010). The characteristics of thermodynamics, solid mechanics and seepage of oil shale have been investigated separately (Hopkins, Rosen, & Hill,1998; Kang, Zhao, & Yang, 2008; Yang, Zhao, Kang, 2010; Zhao, Yang, Feng, Liang, & Kang, 2008; Zhao, Cao, Zhao, Lin, & Wang, 2008). However, it is quite difficult to solve constrained problem of each physical parameter in multi-physical fields coupling for oil shale pyrolysis."

Jan 1, 2015

By J. R. Andrews, R. P. Young, J. M. Reyes-Montes

"Microseismic monitoring provides insight into the location and extent of rock-mass fracturing induced by cave mining, enabling interpretation of the cave profile and validation of predictive numerical models. Source location uncertainties can lead to misinterpretation of the inferred characteristics of the fracture network. One principal source of uncertainty is the velocity model used to invert the location algorithm. Large-scale 3D numerical models of modulus changes across a caved mass can represent such complexities in the location algorithms, allowing more accurate interpretation of the microseismic activity. A Northparkes mine case study applies this advanced approach to microseismic data interpretation.RÉSUMÉ Le suivi microsismique fournit des renseignements sur la localisation et l’étendue des fractures de la masse rocheuse induites par l’exploitation par blocs foudroyés; cela permet d’interpréter le profil de la chambre foudroyée et de valider les modèles prédictifs numériques. Les incertitudes quant à la localisation de la source peuvent conduire à des mésinterprétations des caractéristiques inférés du réseau de fractures. Une des principales sources d’incertitudes est le modèle de vitesse utilisé pour inverser l’algorithme de localisation. Des modèles numériques tridimensionnels à grande échelle des changements du module d’élasticité à travers une masse foudroyée peuvent représenter de telles complexités dans les algorithmes de localisation, permettant ainsi une interprétation plus juste de l’activité microsismique. Une étude de cas à la mine Northparkes applique cette approche avancée à l’interprétation des données de microsismicité."

Jan 1, 2016

By J. A. Brothers, M. R. Foran

"AbstractThis paper reviews the progress made in the manufacture of hydraulic cement from iron blast-furnace slag by simply grinding the granulated material with other constituents. The influence of the chemical and mineralogical composition of the slag, the conditions of granulation, the manner of drying, and the fineness of grinding, on the hydraulic properties of the cement, is discussed. The effect of additions of lime, portland cement, and anhydrite, alone and in combination, on the physical and cementing qualities of the mortar and concrete made from Sydney blast furnace slag, is shown in tables of data and is reviewed in some de- tail. The work at the Nova Scotia Technical College has shown that a cement equivalent in every respect to portland cement can be made from basic blast furnace slag- by the us2 of certain quantities of portland cement as an activator.IntroductionBlast furnace slag is a potentially valuable material for the manufacture of hydraulic cement. It is a by-product of the manufacture of iron in the blast furnace, and is formed by the combination of the silica and alumina .of the iron ore with the limestone flux. The metallurgist terms a slag .acid or •basic according as the percentage of lime is less or greater than the percentage of silica plus alumina. The basic slags have the •more pronounced hydraulic properties."

Jan 1, 1950

By S. J. Cook

Copper, a world commodity, and the first metal used by man, played a great part in the beginnings of modern civilization, which rests so dependently on the utilization of metals. Then, long after the close of the so-called 'bronze age,' when iron and steel had attained great prominence as the world's most important metals, the practical application of electricity to industry and commerce, for the improvement of every phase of man's multitudinous activities, gave a new impetus to the production of copper. Improved metallurgical practice made it possible to work low-grade properties at a profit. Research disclosed many new uses for copper. The metal, now produced from the mines of the world in the proportion of about one pound to every 50 tons of pig iron, has attained an importance which rivals that of iron and steel in the commerce and daily life of every nation. New fields of copper-bearing ore have been discovered in Canada in recent years. Established mines in the United States and Chile are producing on a great scale. Africa looms up as one of the great question marks in the future of copper. Whereas, a few years ago, the end of the world?s resources was predicted as being in sight, the evidence now available seems to show that the copper production of the world is likely not only to continue, but to increase for a long time yet to come. Canada's future in copper is a great subject; in the present paper only a few of the most outstanding factors affecting Canada's destiny in this large field may be noted, but if consideration of the points raised herein serves to focus attention on the magnificent possibilities of Canada as a producer of copper, the preparation of the paper will be more than justified.

Jan 1, 1928

By John C. Wilmot, Robert E. Brewer, Royce J. Smith

In March 2003, Phelps Dodge started up an innovative pressure leach facility for processing copper concentrates at the Bagdad mine in Arizona. This paper describes the development of the concentrate leaching plant at Bagdad and the operational results from start up to present. Optimization efforts and an approach to mineralogical modeling of the concentrate to calculate oxygen utilization are also presented.

Jan 1, 2004

By Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"In natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the content of MoO3 varies from 2% to 10%. As a result, the flotability of seyrigite (scheelite with molybdenum) turns to be weaker. One seyrigite mine, which has been built for 3 years,still could not produce qualified seyrigite concentrate due to the weak flotability of seyrigite (Mo-bearing scheelite) in raw ore. In our experimental research, through adopting new seyrigite collector TA-3 and advanced mineral processing technology, the seyrigite concentrate with a grade of 65.62% WO3 at a recovery of 87.47% was obtained for the raw ore containing 0.19% WO3 and 0.074% Mo. By applying the new technical achievement, for the raw ore containing 0.272% WO3, the seyrigite concentrate assaying 68.03% WO3 with a recovery of 77.56% was obtained in industrial production.INTRODUCTIONIn natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the scheelite is changed to be seyrigite (Ca[(W,Mo)O4]) (Ma, Bian, & Wang, 2013). The content of MoO3 in seyrigite varies from 2% to 10% usually, the content of MoO3 in some of the seyrigite even reaches 34%. The flotability of seyrigite is weak (Zhang, 2007), and the seyrigite is difficult to be recovered by flotation with common collectors and regulators. One scheelite mine in Anhui China, which is a skarn type seyrigite mine, has not produced qualified concentrate yet since 3 years it has been built due to the limit of beneficiation technology. Therefore, it is necessary to conduct research on the collectors with high efficiency and developing advanced processing flow for this kind of ore."

Jan 1, 2016

By N Robb

This paper gives an account of the laboratory testing, plant testing and final inclusion of the two-stage sulphuric acid leaching process in the Milliken mill. Operational results for September, 1962, are presented, showing a uranium extraction of 95.5 per cent, with a saving of some 16 lbs. of 100 per cent H~S04 and some 9 lbs. of lime per ton milled. Methods for effecting further improvements in the process are indicated. HISTORY P RIOR to the incorporation of two-stage leaching, the process for the treatment of uranium ores at Milliken consisted of a single-stage sulphuric acid leach, followed by a solution recovery step involving washing in thickeners and two-stage filtration. The thickener overflow solution was subsequently concentrated and purified by ion exchange, and the uranium was recovered, by two-stage precipitation, as ammonium diuranate. Figure I illustrates this flowsheet. For satisfactory extraction of uranium from the. Milliken ore, a high residual acidity, of the order of 40 grams per litre of free acid in the discharge solution, must be

Jan 1, 1963

By J. B. McKay

It is the purpose of this paper to present an initial report on the construction and operation of the Fluo-Solid roaster at the property of Campbell Red Lake Mines, Ltd., Balmertown, Ontario. The roaster prepares for subsequent cyanidation the bulk flotation concentrate obtained from four hundred tons per day of gold ore. The mill flow-sheet 'includes jigging and amalgamation; flotation; cyanidation of flotation tailing; and roasting followed by cyanidaition of flotation concentrate plus amalgamation tailing. Overall mill recovery for the year 1950 was 90.2 per cent. Recovery possible by straight cyanidation of this ore would not exceed 80 per cent. The ore contains considerable arsenopyrite and pyrrhotite as well as pyrite, with lesser quantities of nickel, zinc, and copper minerals. The mineralization is for the most part extremely fine. The roaster first went into operation on August 7th, 1949, and at the end of 1950 it had roasted 10,916 tons of concentrate. The average recovery of gold from calcine during that period was 94.86 per cent in the primary stage of calcine cyanidation. The average assay of calcine residue from primary cyanidation for the entire period was 0.37 oz. per ton. Both laboratory tests and plant metallurgical balance calculations indicate a further recovery of approximately 10 per cent of this 0.37 oz. when the calcine residue is again cyanided, in the flotation tailing cyanidation circuit.

Jan 1, 1951

By G. E. Willey

F OR many years, only one grade of structural steel has been used in volume in Canada. Its characteristics have not been altered appreciably and its long use speaks well for its performance. This standard grade of structural steel may be bought and specified as C.S.A. G40.4 steel or the American equivalent, A.S.T.M. A7. The principal limitations and requirements of this specification are shown in Table I. Within the last five years there has been a growing awareness among the steel producers and steel fabricators that economic forces are at work which make desirable the availability of new and better grades of structural steel. Competition from other materials has increased. The use of concrete bridges and pre-stressed concrete beams is a prime example. New sources of steel from outside the country have become a threat to the Canadian industry and its high cost-price structure. The need for improved properties in the steel, to make possible technologic

Jan 1, 1962

By K. Winterton, Carruthers. J.

"Attempts have been made to produce hardened structures of a pseudomorphic type in various carbon and alloy steels. In order to obtain martensite with a fine distribution of cementite, an initial structure of fine lamellar or nodular pearlite is required; this may be obtained by conventional means. This is followed by partial austenitization and quenching.Two methods have been tried to induce partial austenitization:(a) A resistance (direct current) heating method involving rapid entry into the austenite field.(b) A new method, described as the ""threshold"" technique, involving homogenization of temperature just below A 1, followed by entry into the austenite field; two furnaces are required.The resulting structures have been examined for microstructures, hardness, tensile, and impact values. The tensile properties are comparable with those obtainable by conventional treatment methods. Impact values are disappointing, but this is explainable from the nature of the manifold changes occurring."

Jan 1, 1960

By J. -P. Lempainen, K. Haavanlammi, K. Valkama

The Outotec nickel matte chloride leaching process is especially suitable for small capacity standalone nickel refineries. The matte is leached with hydrochloric acid and oxygen in multiple steps in atmospheric OKTOP® reactors. Oxygen feed prevents reductive conditions and hydrogen formation in the leaching process. A sufficiently high acid concentration keeps the iron dissolved in the solution. The iron is removed after leaching by precipitation and the pregnant leach solution continues to metals recovery. The metals recovery from the chloride solution is done by solvent extractions, where ammonia is used for pH control. Copper and nickel are stripped from the organic phases into sulphate solutions. Metals can be recovered from the purified solution by conventional electrowinning. Other alternatives are precipitation or hydrogen reduction processes. The ammonium chloride in the solvent extraction raffinate is regenerated into ammonia. The calcium chloride solution from ammonia regeneration is routed to acid regeneration where sulphuric acid is added and ultra-pure gypsum is precipitated. The hydrochloric acid solution from this step is recycled back to leaching. The process yields good overall metal recoveries and expensive

Jan 1, 2014

By Jerry C. Tien, Yingjiazi Cao

"Coal spontaneous combustion (SponCom) is a natural phenomenon in underground operations, which can either happen naturally or be triggered by human activities. For underground operations, espe-cially in coal, SponCom can happen frequently as a result of air leakage, although its incubation period may vary depends on types of coal and surrounding environment, resulting in uncertainty in control. In China, most of the underground coal operations now use longwall mining method because of its superior safety, high productivity and efficiency. With an increased popularity, there is also an increasing necessity to study spontaneous combustion, its occurrence and management. There have been many theoretical analysis and experimental studies over the past half century hoping to understand the occurrence of coal combustion and its control measures to better understand the occurrence and to design controlling measures to limit the dam-age it causes. In this paper, research on coal spontaneous combustion fundamentals from these three aspects will be reviewed, gaps highlighted and possible directions for future studies. INTRODUCTION The history of anthropic development is the history of human's energy utilization progress. From the first usage of fire, people have been continuingly seeking energy resources on earth. Coal, as an abundant, economic and convenient source of fuel quickly became indispensable and made significant contribution to economic growth worldwide. With technology and societal development, people are becoming more and more coal-dependent, but at the same time, problems of fossil fuel combustion came into sight. In global coal mining industry, spontaneous combustion has now presented one of the most challenging safety issues, it is also believed that it has contributed significantly toward the climate change. It is essential that more effort be invested to examine the cause of SponCom and its control measures. Coal SponCom is a complex process, with both physical and chemical inter-actions among various interrelated factors such as local airflow distribution, ventilation pressure, methane emissions (if any), and physical surroundings underground. With the advent of powerful computers, simulation techniques and af-fordable modelling packages in recent years, significant advances have been made in understanding sponta-neous combustion. But because of the complex nature of combustion and varying underground conditions, there are still areas that need further examining. This paper will focus on illustrating the current research of coal spontaneous combustion and addressing research gaps and future study areas."

Jan 1, 2019