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By Terence M. Gordon, Mati Raudsepp, Gregory M. Dipple

Four methods of measuring mineral abundance in a rock are examined for their potential in assaying for high-tech industrial minerals. One method uses X-ray powder-diffraction data and the other three rely on whole rock chemical data and information on mineral assemblages and mineral compositions. All four methods were employed to estimate wollastonite content in diamond drill core of skarn collected as part of an exploration program and are compared to visual estimates of wollastonite content from core logs. These techniques for assaying wollastonite span a considerable range ofaccuracy and expense, and combined, define a non-linear relationship between these variables. Accuracy increases rapidly relative lo expense up to total costs of about $50 per analysis. Assay methods in the $50-100 per analysis range have associated errors of 5-10% relative and probably suffice for most exploration programs. Improvements in accuracy above this level require a much larger investment. The most expensive assay technique (-$300 per analysis) yields the most accurate measurement of grade (relative error -1%). Its application may best be limited to periodic checks on other assay techniques and for fine-tuning ofmineral separation procedures.

Jan 1, 2001

By W. J. Adams

It is recognized that within life cycle assessment that the eco-toxicity potentials (TPs) derived for metals require additional research to improve their reliability. Current models used to develop TPs do not include important fate process for metals such as speciation and bioavailability. Toxicity potentials are standard values used in LCA to enable a comparison of potential toxic impacts between substances. Huijbrechts (2001) calculated toxicity potentials for 181 substances utilizing the USES model for six impact categories, i.e. freshwater aquatic ecotoxicity, marine aquatic ecotoxicity, freshwater sediment ecotoxicity, marine sediment ecotoxicity, terrestrial ecotoxicity and human toxicity (not considered here). Marine ecotox potential for metals is typically high using this approach, whereas most open ocean metal concentrations are very low. A sensitivity analysis of the USES-LCA model was undertaken using copper as an example. Results indicate: fate processes on the global scale are driving the marine water and sediment TPs for copper most; the second most important fate parameter is sedimentation from the water and burial in deep sediment layers; inclusion of speciation and bio-availability processes would be very beneficial; more accurate estimates of input parameters should be used, and the PNECwater and PNECsediment and all partition coefficients for metals should be updated in the model.

Jan 1, 2007

By J. E. Nesset, F. Rosenblum, J. A. Finch, R. Payant

ABSTRACT Under certain conditions of moisture and oxygen, sulphides can spontaneously self-heat. We tested a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by the rest potential difference between sulphides and particle size. A series of binary sulphide mixtures was tested. Individual sulphides and mixtures with low rest potential difference did not self-heat, but mixtures of high rest potential difference did. When testing pyrite-sphalerite mixtures, self-heating increased inversely with particle size, with the fineness of the pyrite governing self-heating, indicating the rate-limiting step is the reduction reaction. The results support the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on hydrogen sulphide as an intermediate product is proposed. The understanding gained will be of interest to those involved in storage, shipping, and disposal of sulphides.

Jan 1, 2012

By T. Hofbauer, M. J. Dry, G. B. Harris, C. W. White

"Urban Mining is a term that is increasingly being used, and represents an appreciable source of secondary materials for the metals extraction industry, a source that does not incur mining costs, but does, at present, incur considerable disposal costs. Electric Arc Furnace Dust (EAFD) is probably the most common of these materials, with an estimated global production of 8 million tonnes annually, of which 1 million tonnes is generated in North America. The contained annual metal value in EAFD at current prices is of the order of $6 billion, yet, apart from the zinc, virtually none of this is recovered.Despite many attempts over the years, with pyrometallurgical, hydrometallurgical or hybrid processes, currently the only commercially viable method of treating these materials is smelting in a Waelz Kiln (or a Rotary Hearth Furnace), which essentially recovers only the zinc, in an impure oxide form, and generates a secondary slag waste, which is still toxic and requires disposal. This paper describes the development of a chloride-based treatment process to recover all components of the EAFD in a marketable form, which centres around the novel hydrochloric acid recovery and recycle operation. Laboratory, miniplant and pilot plant data are presented, leading to the definition of a viable process flowsheet enabling the recovery of pure iron and zinc products (the principal components of EAFD), together with secondary products such as copper, silver, lead, cadmium, magnesium and manganese. A rigorous mass-energy balance is used to examine the preliminary economics involved."

Jan 1, 2014

By R. H. Schonewille

One of the many challenges in developing new metallurgical processes is choosing the best option for validating process design parameters and establishing the process operating window. Historically this has been achieved by constructing pilot or demonstration plants of considerable size and complexity, to enable integrated operation of all key process units for a significant duration. While this would appear to be the best option for minimizing technical risk, it is often impractical from a perspective of cost, schedule, resources or bulk sample acquisition. Such an undertaking can even provide a false sense of security, as the optics of running a complete scaled-down version of a commercial plant suggest a high level of process understanding, regardless of the challenges encountered during operation. Xstrata Nickel has undertaken numerous process development and improvement projects over the past 15 years to support green field project development and continuous improvement in existing operations. The approaches used have included; computer simulation, cold flow modeling, construction of pilot test units in third party facilities, commercial plant referencing and the more conventional construction of integrated test plants. Regardless of the strategy employed, the keys to success have included; managing stakeholder expectations, involving the commercial plant design engineers in the planning stage, anticipating subsequent data and sample requirements and most importantly, constructing and operating complex demonstration plants only as a last resort. This paper provides examples of various process development approaches used by Xstrata Nickel and discusses the rationale specific to each project.

Jan 1, 2011

By A. L. Valdivieso

"The correlation obtained by plotting pH of maximum adsorption of dextrin versus the isoelectric point of involved metal hydroxides can be used to predict the depressing effect of dextrin on flotation in ""pure"" sulfide mineral systems. Sulfides are strongly depressed by dextrin whenever their surfaces are coated by the corresponding metal hydroxide. The efficiency of dextrin as a depressant is affected by the adsorption of the sulfhydryl collector. Hydrolyzable cations modify this relationship in flotation of sulfide ores. This type of deviation of the real-life systems from the predictions based on the behavior of the pure systems shows the possible ways that could be followed to further improve the obtained correlations. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists ofCIM Sudbury, Ontario, Canada Edited by"

Jan 1, 2009

By Jae-Chun Lee, Rajiv Ranjan Srivastava, Min-seuk Kim, Byung-Su Kim

Recycling of spent hydrotreating catalysts (HTC) can potentially contribute towards the sustainable extraction of metal values. Treating such materials by hydrometallurgical methods to separate metals from the leach liquor of either acid/alkali media is a major step. In the present study, separation of molybdenum from HCl leach liquor of spent NiMo type HTC has been investigated by applying solvent extraction using Cyanex-923. For this, the chloride solution containing 973 mg/L Mo, 254 mg/L Ni and 1634 mg/L Al was taken as the aqueous feed. The parameters including contact time, concentration of the extractant, acid and chloride, and phase ratio were varied to investigate their effect on the extraction efficiency. The McCabe-Thiele plot suggests that > 99% Mo-loading using a 2-stage extraction process. From the molybdenum depleted solution, nickel was selectively extracted by Cyanex-301 leaving Al in the raffinate.

Jan 1, 2014

By Richard S. Allen

"The casual visitor is not apt to think of the Adirondacks as a one-time hive of mining and manufacturing activity. However, where there are mountains there are usually minerals and northern New York State is no exception.The Adirondacks are a rocky shield, a great stone cap pulled down over what is now northern New York. The bedrock consists of layered metamorphic rocks which were once sandstones or limestones on the bottom of a shallow sea that covered the region 1000 million years ago. The highlands are composed for the most part of the igneous rock anorthosite. Ancient earth upheavals at temperatures of at least 750°C mixed molten masses of anorthosite and the minerals it contained with the older metamorphic rock, resulting in deposits of iron-titanium oxide s, red garnet and other valuable minerals. Of these, the most readily recognizable was iron.The first hint of the existence of iron ore in the Adirondack Lake Champlain region of upper New York State seems to have come from a Swedish naturalist, Peter Kalm (1716-1769), who travelled through French Canada and visited the military outpost of Fort St. Frederic in 1749. In July of that year, Kalm wrote:""Among the kinds of sand which are found on the shores of Lake Champlain; one is black and the other garnet-colored... and they sparkle when the sun shines. All the grains of this sand without exception are attracted to the magnet, the uppermost or black sand being about a quarter inch deep...""Concerned primarily with the fur trade, the officers and men who occupied this remote bastion of La Belle France were apparently unaware of the industrial and commercial possibilities beneath their feet. No deposit of iron was then known to exist any closer than the Three River s area in Lower Canada."

Jan 1, 1983

By Maxim Martel, Karolan Tremblay

Westwood Mine has experienced several episodes of increased seismic activity. While current geotechnical characterizations such as RMR, GSI, and Q' index can identify the general rock quality and zones at risk of convergence, they fail in identifying zones at risk of seismic activity. Previous research at Westwood Mine has shown a correlation between seismicity and areas with strong rheology contrasts. To characterize this contrast, 300 UCS tests were analyzed with their associated geochemical data, and statistical analysis and regression were performed using IOGAS software to establish a relationship between resistance and geochemistry. UCS-generated data with XRF results were transferred to Leapfrog Geo to create a block model of intact rock strength. This block model dataset was used to perform a competency contrast block model, and back-analysis of specific seismic sectors at Westwood Mine were conducted to validate the model. The purpose is to develop an established geomechanical tool capable in identifying areas with greater seismic risk associated to a change in the rock strength characteristics. By identifying those areas, mitigation measures can be implemented to minimize impact of seismicity on the operation.

Jan 1, 2023

By G. Deschênes

Located in North West Tanzania, Buzwagi is an underground narrow-vein gold mine owned by Barrick Gold. The plant was commissioned in 2000. The reserves are estimated to be more than 25 years. The ore, containing gold, silver and copper mineralization in sulphides, is processed at 3,300 tpd. This paper presents the results of an investigation to determine the performance of an ammonia-cyanide leaching approach to recover gold from two samples. Coarse gold was recovered by gravity prior to leaching. The gravity tailings had the following composition; 1.97 g/t Au and 0.31% copper for the medium cyanide soluble copper (MCSC) sample and 2.80 g/t Au and 0.53% Cu for the high cyanide soluble copper (HCSC) sample. Experiments were conducted for 72 hours in stirred tank reactors with monitoring and control of parameters. The straight cyanidation produced gold extractions of 76.1% for the MCSC sample and 84.6% for the HCSC sample. Associated cyanide additions were 6.1 kg/t and 11.5 kg/t respectively. The gold extraction of the MCSC sample was improved to 88.8% using 350 ppm NaCN and 700 ppm ammonia. The associated cyanide and ammonia additions were 2.5 kg/t and 1.7 kg/t respectively. For the HCSC sample, 82.5% gold extraction was obtained using 500 ppm NaCN and 600 ppm ammonia. The cyanide addition and ammonia additions were reduced to 3.8 kg/t and 1.0 kg/t respectively. No significant decrease in gold extraction was noticed when the cyanide and ammonia were reduced to 150 ppm and 500 ppm respectively. In the presence of ammonia, a significant amount of cyanide was oxidized to cyanate by the cupric ion. In the absence of ammonia, the formation of copper cyanide was the predominant reaction responsible for consumption of cyanide.

Jan 1, 2012

By L. L. Sirois

Because segments of the Canadian mineral-based economy are dependent totally or in part on foreign sources of certain minerals, their well-being may well be affected by inability to obtain these minerals. Where such dependency exists, it is therefore important that contingency plans be available to counteract possible price increases or lack of supplies by means of technology, developed well in advance of any pending crisis . Canada is vulnerable to possible future real or artificial shortages of certain foreign-produced mineral commodities, and science and technology can provide information for the development of policies for counteracting efforts by foreign exporters to control prices or limit supplies.

Jan 1, 1977

By John E. Udd

In early 2000, CANMET-MMSL was engaged by the Ontario Ministry of Labour (OMOL) to conduct an international study of the practices, in several key mining jurisdictions, of determining the criteria that are used to decide when the wire ropes used in mine hoisting are to be retired from service. Subsequently, the writer visited key officials and institutions in Canada, the USA, the Republic of South Africa, the United Kingdom, Germany and Poland. Material from the Australian province of New South Wales and Hungary was also included. The report that resulted included, among other sections; (1) the history of wire rope and trends in manufacturing technology; (2) a review of mine hoisting practices; (3) the requirements as regards safety factors; (4) a review of the players and the inspection practices; (5) the criteria for rope replacement; (6) a look into the future to outline the developments that could take place in both hoisting and rope inspection practices in Canada; (7) recommendations. Subsequently, the report was issued as a book by OMOL, and as a CD-ROM by the Mining and Mineral Sciences Laboratories, Natural Resources Canada. In this paper the author presents the key findings and the recommendations made in the study.

May 1, 2003

By A. Rao, J. A. Davidson, B. L. Jones, K. W. Bowes, D. Craib

Supported by ANSTO, Groundwater Science and Inception Consulting Engineers, Boss has embarked on a series of technical projects aimed at reinforcing the Project’s capability to meet its export permit production capability. This paper will focus on three aspects of this technical program: Reducing the cost of resource expansion through smart use of low cost, surface target generation techniques; Improving the rate of uranium leaching and solution stability (gypsum, jarosite) through lixiviant chemistry modifications; and Development of an ion exchange (IX) process to increase production capacity, and integration of IX and the current solvent extraction circuit with the existing uranium precipitation and product preparation circuits.

Jan 1, 2020

By M. Mirnezami, J. A. Finch, S. Uddin

A fast, reliable and practical way of measuring zeta potential using sedimentation potential method is proposed. A cell was designed along with the instrument control software to determine the required variables simultaneously i.e. sedimentation potential, specific conductivity, volume fraction of solid as well as pH. High purity alumina and silica powders were used as test samples. Measured zeta potential using the proposed technique was comparable with the results by electrophoresis.

Jan 1, 2009

By M. Goto, F. Kubota

"In this study, we show the successful separation of rare earth metals, which are indispensable elements for the high-tech industry, from a solution containing a metal mixture by using a liquid-liquid extraction and liquid membrane based on ionic liquids. We employed newly synthesized N, Ndioctyldiglycol amic acid (DODGAA) as an extractant for rare earth metals. The DODGAA exhibited a high affinity for rare earth metals such as Y, Nd, Eu and Dy and the extraction efficiency was greatly enhanced in ionic liquids (ILs). Furthermore, stripping of the metals was readily achieved by using an acid solution. INTRODUCTIONRare-earth metals have important applications in cutting-edge technologies employed in the electronics, information technology, and automobile industries. As Japan does not have many natural metal resources, maintaining a steady supply of imported rare-earth metals is important. The total amount of rareearth metals imported into Japan was 19,000 tons/year in 1996, and this amount increased to 40,000 tons/year over the following decade (Kramer 2010). Japan is now one of the world’s major importers of rare-earth metals (Kramer 2010). However, more than 90% of the rare-earth metals imported into Japan come from China, the world’s leading supplier of rare-earth metal resources, due to their low costs. This situation made us realize the importance of a second resource of rare-earth metals: “urban mines” or discarded electronic waste. Rare-earth metals are generally separated from their natural ores by solvent extraction. However, since urban mines have different metals and the concentrations of rare-earth metals are usually low, highly efficient separation and recovery methods are required for rare-earth metals.Recently, ionic liquids (ILs), which are molten salts at room temperature, have attracted considerable attention since they are novel, environmentally friendly solvents (Kubota & Goto, 2006; Han & Armstrong, 2007). The use of ILs in liquid-liquid extraction of rare-earth metals has been reported (Kubota et al., 2012). In some cases, the IL-based systems showed better extraction ability and selectivity than those showed by the conventional organic solvent extraction systems(Nakashima et al., 2003, 2005; Hirayama et al., 2008; Fang et al., 2012). Therefore, more efficient solvent extraction processes by using ILs can be developed. In this study, we investigated solvent extraction processes in which ILs are employed and discuss the possibility of using ILs in the separation and recovery of rare-earth metals from electronic waste."

Jan 1, 2012

By Angus D. Campbell

Introduction Gowganda forms part of the general Cobalt area. Its rocks and ores are very similar to those of the other parts of the area. While its total production of silver is only 4 per cent of that of the famous Cobalt silver camp, its 1928 shipments contained 42 1/2 per cent as much silver as those of Cobalt for that year. During twenty years of production, 15,000,000 ounces of silver have been shipped from Gowganda. Of this, over 8,000,000 ounces have been shipped in the past five years. The area has thus made for several years a substantial contribution to the wealth of Ontario. Its future depends to a great extent on the priee of silver, which is now, unfortunately, at a record low price. This paper is a discussion of how the Gowganda ore-shoots occur, together with some notes on the milling of the ores at the Castle-Trethewey Mines. The first part is written in the hope of stimulating further study of the silver occurrences, which may lead to further discoveries. The second part, besides being a matter of record, may be of some use to operators of small mills. The drawings in the several Figures illustrating the text are by W. D. Stroud, mine superintendent of the Castle-Trethewey Mines, the benefit of whose opinions I have had in compiling these notes.

Jan 1, 1930

By Matej Petružálek, Tomáš Svitek, Tomáš Lokajícek

"Migmatite from the Skalka region (Czech Republic) was chosen as the experimental rock material. It has macroscopically visible plane parallel structure (foliation). The foliation was caused mainly by biotite grains arrangement. The cylindrical samples of migmatite with subhorizontal, subvertical and oblique foliation were uniaxially loaded up to the failure. Network of 8 broad band sensors was employed for acoustic emission monitoring and ultrasonic sounding. A grid search method with anisotropic velocity model was used for AE hypocenters localization. The source types of successfully localized events were determined from the average first arrival amplitude. Structural anisotropy of tested rock material caused the anisotropy of its mechanical properties (peak strength, Young’s modulus) as well as a different way of fracturing process in dependence on the angle between axial stress and foliation plane. The combination of splitting, shearing and sliding was found to control the fracturing of sample with subhorizontal foliation. The shearing and sliding was dominant in fracturing of samples with oblique foliation. With greater dip of foliation, the role of sliding increased at the expense of shearing. Due to the favorably oriented system of microcracks already present, the shearing and splitting was at the same level during fracturing of the sample with subvertical foliation before nucleation began.INTRODUCTIONThe process of failure of low porosity rocks depends on their mechanical properties and actual stress and temperature condition. At the low pressure and low temperature, the most common way is brittle failure, which is a progressive process requiring the initiation, growth and coalescence of cracks (Lockner, 1993). Stress strain behavior of low porosity crystalline rocks, during the laboratory compression experiments, is divided into four characteristic stages: crack closure, elastic region, stable crack growth and unstable crack growth which leads to the brittle failure, Brace et al. (1966) , Bieniawski (1967), Lajtai (1974), Cai et al. (2004), Nicksiar and Martin, 2012 and 2013.The fracturing process of stressed rock begins with the crack initiation (sci), which for low porosity rocks occurs approximately at 40-50% of peak strength (sp) (Cai et al., 2004; Nicksiar and Martin, 2013). After the sci, the dilatancy begins and stable crack growth follows up to the crack damage threshold (scd), which is approximately at 80% of sp (Cai et al., 2004). After crossing the crack damage level, there is an unstable crack growth accompanied with nucleation of fault plane (sn) at 97-100% of sp. (Rao et al., 2011). The stress drop accompanied with formation of macro scale shear failure plane follows after peak stress is crossed."

Jan 1, 2015

By P. Clinton Milne

Uranium mines in Washington State include the producing Midnite and Sherwood mines and several mined-out deposits, the most productive of which was the Daybreak mine. The Midnite mine is generally classified as a hydrothermal deposit consisting of tabular orebodies in Precambrian pelitic and calcareous metasedimentary host rocks. The host rocks occur as roof pendants in a Cretaceous porphyritic quartz monzonite intrusive; the quartz monzonite averages 12 ppm U308 The uranium deposit appears to have undergone a complex genesis, involving a series of depositional and enrichment stages. The Sherwood uranium deposit, approximately 4 miles south of the Midnite mine, occurs near the bottom of a basal Late Cretaceous to Paleocene arkosic conglomerate. The conglomerate lies nonconformably on the porphyritic quartz monzonite that is associated with the Midnite deposit. The Sherwood and Midnite uranium deposits may have had a similar genetic history linked by a common uraniferous pluton source, ground-water action, and/or leaching of uranium-rich ash flows from now-eroded, overlying, Eocene volcanics. The Daybreak deposit, in northeastern Spokane County, consists entirely of secondary uranium mineralization (metaautunite) in a quartz monzonite pluton. Mineralization is confined to a low-angle fault zone and is most highly concentrated at the intersection of primary and secondary shears. Both hydrothermal and ground-water origins are feasible. Besides the Midnite-Sherwood area, 14 other areas in the western Okanogan Highlands physiographic province and Cascades region have favourable characteristics for uranium potential. Criteria include the existence of uranium occurrences, Tertiary basin sediments with intercalated volcanic and volcaniclastic rocks, favourable geochemical data, alkaline plutons associated with uranium occurrences or borders of Tertiary basins, and structural controls.

Jan 1, 1979

By M. Yavuz

As a branch of Operations Research, decision making is a widely used application in both science and social sciences. There are many different methods developed to solve decision making problems in the literature. In this study, Fuzzy Analytic Hierarchy Process (AHP) method is performed for the selection of reclamation project selection in an open pit mine and the optimal solution of the problem is investigated. Different reclamation project alternatives are prepared for an open pit mine, which continues to its production activities in magnesite sector in Turkey. The data obtained from Magnesite Cooperation is used in the application of the method. A decision-making process is prepared as considering the project alternatives for the purpose of selecting the most suitable reclamation project. The entire criteria that affect the decision-making process are identified and transformed into a hierarchical structure. The problem is solved by using Fuzzy AHP method developed according to this structure. It is found that Fuzzy AHP is a method that may help decision-makers in solving different decision-making problems in mining.

Aug 1, 2013

By M. Sengupta, A. A. de Gast

"With rapid deterioration in the urban environment caused by air pollution, the possibility of chemical reaction between dimension stone and the industrial waste gases present in the ambient atmosphere remains. The chemical reaction can cause expensive damage to building stone; it is essential that a stone evaluation for use in construction should assess the possibility of this type of decay. This paper endeavours to develop testing procedures for evaluating stone decay in polluted environments. Such tests can accompany other standard tests used in dimension- stone evaluation."

Jan 1, 1972