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By Jarret Thomson

An understanding of groundwater flow is essential for many aspects of mining. This is especially true for the process of shaft sinking through the sandstones of the Manitou Falls Group in the Athabasca Basin of northern Saskatchewan. Experience has shown that the hydraulic conductivities of these sandstones can be relatively high, especially in zones containing natural fractures. To develop a better understanding of the inflow potential into a shaft, a laboratory testing program was undertaken to investigate the hydraulic conductivity of fracture core samples from the Manitou Falls Group. This program involved the measurement of hydraulic conductivities under steady-state flow conditions, while cycling the effective confining pressure across a span that is representative of in-situ conditions. The change in fracture aperture was simultaneously recorded at each confining stress level. It was found that existing relationships relating aperture and flow did not accurately capture the behavior of the samples tested. The effects of fracture staining and infilling were also investigated, and were found to have a notable impact on the hydraulic conductivity.

Jun 1, 2012

By G. S. Ospanova

The results of complex processing sulphide copper ore and advantages of recovery of copper by vat and heap leaching, sorption, cementation and electrolytic solutions processing and utilization of waste material after heap leaching of copper for production of building materials were investigated. The combined chemical solvents with the additives of oxidizing agents are developed at the KazNTU. The solvents are inorganic or organic chemical reagents, which form complexes of Cu, Au, Ag, Pt, Ni, Sr, Co etc. Recovery of non-ferrous metals from solutions and purification of industrial waste waters is carried out on the base of using new synthetic and natural sorbents (from local raw materials) which are able to bind ions in both cationic and anionic forms depending on type of ligands and external conditions. Optimum parameters of copper sorption were determined. The developed wasteless technologies of copper extraction from sulphide ores with usage of new non-toxic solvents and accessible sorbents with full recycling of water are tested in pilot scale heap leaching, and are recommended as the ecological, economical and practical alternative to traditional methods.

Jan 1, 2007

By Hrayr Agnerian

The fair market value of an exploration property is determined by its potential to host a mineral deposit. This potential is gauged by the results of previous exploration, exploration stage, meaningful past expenditures and remaining targets that are not yet tested. Values of exploration properties can be viewed as distinct points in a three-dimensional space defined by orthogonal axes, namely: Exploration Stage (x-axis); Cumulative Expenditures (y-axis); and Property Value (z-axis). In general, these values are estimated by applying activity factors on previous exploration expenditures, e.g. an activity factor of 100% for an active property with good potential and a factor of 50% for an active property but past expenditures have not upgraded the property. At certain periods, a market factor may also be applied to reflect the activity of mineral property acquisitions. For properties that do not exhibit any exploration potential, only nominal values are applied.

Jan 1, 1996

By P. Leo

The hot deformation behavior of a Mg-9A1-1Zn alloy produced by high pressure die casting has been investigated by means of compression tests in the temperature and strain rate ranges of 125-300°C and 10-5-10-1 s-1 and torsion tests over 150-450°C and 5, 0.5, 0.05 5-1 . The compression samples were deformed in the die-cast state or after homogenization at 415°C for 2 h to evaluate improvements. A premature fracture at 45° with respect to the compression axis was observed in samples strained at low temperatures and high strain rates. The torsion specimens were tested as received or after a predeformation-homogenization treatment. In addition to constitutive analyses suitable for modeling previously published, the results are fitted to a relationship between strain rate normalized by diffusion coefficient and flow stress normalized by modulus. The results fit well with a set of published creep experiments that were conducted in the range of 70-150°C.

Jan 1, 2006

By R. Fukuzawa

"The objective of this research is to evaluate the magnitude of carbon prices required to drive process development and innovation for the global nickel industry in a direction that tackles the multifaceted sustainability challenges that the industry faces, including air pollution reduction and greenhouse gas abatement. The results suggest that the currently considered carbon prices are not sufficient to drive innovations in processing methods or upstream pollution prevention. The co-benefits of climate change mitigation and pollution prevention cannot be readily realized under climate change policy alone. Increased coordination between climate change policy and performance-based environmental legislation is necessary. INTRODUCTIONNickel is an important metal in our modern society as it is used in stainless steel, alloys, electroplating and rechargeable batteries, all of which are integral to our economic growth and development (Eckelman, 2010).However, nickel production is energy intensive and therefore susceptible to emerging climate change policies, which may lead to production curtailment and/or increased unit costs of production unless changes in efficiency or energy sources are made (Mudd, 2010). The industry is faced with multi-faceted constraints: future technology must not only deal with metallurgical, financial and environmental constraints but also promote low energy and low carbon practices. This presents a challenge for this industry where technology innovation, development and commercialization are often lengthy, risky and costly processes (Imrie, 2006).Climate change is one of the many challenges faced by our society. Others include other pollution to air, water and land, resources shortage and economic development. From a policy perspective, it is important to balance multiple and often competing needs in an integrated manner. It would require some levels of trade-off in order to maximize the overall effectiveness but also to ensure that one policy does not undermine other policy objectives.The aims of this study are to evaluate how developments in climate change policy would affect the nickel industry in the context of existing environmental regulations and how the industry could respond under these constraints."

Jan 1, 2012

By Emmanuel Henry

Hanging wall deformation monitoring at the Kiruna Mine is a major concern for Luossavaara- Kiirunavaara AB (LKAB) since underground production is deepening towards the Kiruna Town. In the quest for more effective monitoring techniques, LKAB decided to evaluate satellite-borne Synthetic Aperture Radar (SAR) interferometry?s ability to monitor ground subsidence by generating continuous deformation maps from satellite radar images. While adopted by other geoscience-related industries, SAR interferometry is still relatively untested in the Mining industry. This paper describes how subsidence is actually monitored on the Kiruna Mine?s hanging wall and gives an insight on SAR interferometry?s principle. The encouraging results are discussed as well as the technique?s benefits (continuous deformation mapping, low cost, fast, etc) and limitations (sensitivity to snow and vegetation cover).

May 1, 2003

By J. J. Ferreira, M. L. Thurston, I. L. Chinn, D. M. Rose

"Concerns about using microdiamonds for resource estimation have been raised by workers because multiple diamond populations exist in many parts of the mantle source region, small diamonds in kimberlite could be exposed to proportionately greater levels of resorption and modification, and euhedral microdiamonds could crystallize immediately prior to kimberlite eruption. This paper addresses these concerns; discusses the geology of the mantle, the principal diamond host rocks, and the impact of mantle processes; compares micro- and macrodiamond properties and features; and outlines steps to identify and mitigate the risk of diamond resorption and its impact on the diamond grade-size relationship.RÉSUMÉ Des travailleurs se sont interrogés sur l’utilisation de microdiamants pour estimer la ressource; en effet, de multiples populations de diamants existent dans plusieurs secteurs de la région source dans le manteau. Des petits diamants dans la kimberlite pourraient être exposés à des niveaux proportionnellement supérieurs de résorption et de modification; de plus, des diamants idiomorphes pourraient cristalliser immédiatement avant l’éruption de la kimberlite. Le présent article traite de ces questions, discute de la géologie du manteau, des principales roches-mères des diamants et de l’impact des processus dans le manteau, compare les propriétés et les caractéristiques des micro- et des macrodiamants et définit les étapes pour identifier et mitiger le risque de résorption des diamants et son impact sur la relation entre la taille et la qualité des diamants."

Jan 1, 2016

"An unparalleled growth in the Canadian coal industry in 1970 coincided with increasing awareness by Canadians of their environment and their geography with its accompanying transportation factors. R and D on coal moved with greater emphasis toward solving problems in these areas as well as continuing with strong interest in coal preparation, carbonization, combustion, ""weathering'', spontaneous ignition, storage, exploration and geology. Long-range ""basic"" research was not forgotten in that work continued on coal-based carbons, coal chemistry and agrobiological uses for coal. This paper reviews the status of these many areas of coal research at the beginning of the seventies and takes note of some of the more significant legislation and projects brought to the author's attention. No attempt is made to itemize or to describe in detail all the worthwhile projects, many of which are reported elsewhere."

Jan 1, 1971

By X. Wu

Tunnel Boring Machines (TBMs) are widely used for tunneling in urban areas because of their high advance rate, precise as-built profile and minimal impact to buildings and traffic on the ground. For a tunnel built by a TBM, there are strict requirements on alignment control and safety. To meet these requirements, it is important to monitor the position of the TBM. In the current practice, the TBM position data, including advance distance and line and level deviations, are reported manually to the managers on a daily basis. To interpret and analyze the position data, the managers also need to refer to various construction drawings. This practice is untimely, inefficient, and error prone for decision making. To improve the current practice, an automatic approach for real-time as-built tunnel product modeling and visualization is proposed, based on TBM position and orientation data autonomously sourced from the Virtual Laser Target Board (VLTB) TBM Guidance System developed at University of Alberta. Related information of the tunnel project, such as the as-designed alignment, soil layers, the ground, existing utility lines, is also visualized together with the model of the as-built tunnel. The modeling algorithm is presented step by step. Its application in a real-life drainage tunnel project is discussed and limitations are also identified.

Aug 1, 2013

When underground extractions occur beneath or in close proximity to valleys and other forms of irregular surface topographic features, the observed vertical subsidence at the base of the valley is less than that would be expected in flat terrain, while the valley sides are observed to move inwards towards the centre of the valley. The reduction in subsidence at the bottom of the valley is referred to as upsidence and the convergence of two sides of the valley is termed valley closure. Research coupled with mining experience over the past few decades in Australia has identified valley closure subsidence as being very real and quite significant part of non-conventional subsidence effects, which always have adverse effects on natural features, with risks to water flow and aquatic ecosystems. In this paper, we describe a threedimensional numerical modelling approach to investigate the geomechanical mechanisms which cause the valley closure subsidence behaviour, using distinct element computer package 3DEC. The calibrated models can accurately predict subsidence and horizontal displacements, and they are subsequently extended to specifically study the effect of a series of mining geological and topographical factors on valley closure subsidence phenomenon, by developing a range of hypothetical scenarios. Previous analyses carried out using a two-dimensional numerical modelling technique have identified the potential parameters that affect the valley closure subsidence, which mainly include longwall position, horizontal stresses, valley sloping angle, and valley shape. Further three-dimensional analyses regarding the relationships between the major factors and valley closure subsidence are discussed in this paper. The results have significant implications with regard to both the underlying mechanisms that lead to this nonconventional subsidence behaviour, and how these should be incorporated in future valley closure subsidence prediction and mitigation of its impacts on natural features.

Jan 1, 2015

By R. M. Oliver

THE Falconbridge property is almost completely covered with over-burden to a depth varying from 60 to over 200 feet. This overburden consists of grave], sand, and boulder, with bands of very fine silt, and there is usually a layer of water-bearing quicksand adjoining the r:ock surface. In previous shafts sunk at Falconbridge, this water-bearing quicksand had given considerable trouble, and further difficulties were expected in sinking No. 5 shaft, due to its greater size. The method described in this paper is the one adopted in sinking this shaft, after the matter had been carefully considered. No. 5 shaft is located 2,400 feet east of the old main No. l shaft, and is sunk in norite in the hanging-wall of the ore-body, which is, however, ? practically vertical to the deepest known intersection. The greatest depths of overburden prevail on the south side, or footwall, of the ore-body, and this, together.. with the fact that the footwall is wet and more badly fractured, swayed the final decision to sink in the hanging-wall. After the shaft site had been chosen and cleared, a diamond drill was set up a few feet away and a hole bored to a depth of 405 feet to test the over-burden and character of the norite bedrock. The depth of overbudren indicated by the hole was Ill feet, with the last 10 feet water-bearing. The norite was rusted and broken up for only a few feet below bedrock. A steel sinking shield (Figure l) was assembled at the shaft location, and consisted of 5/8-inch plate, 5 feet deep, built around a frame of 6 inch by 6 inch angle-iron, and braced at the corners with the same material. Twelve-inch I-beams held the shield as rigid as possible. In order to reduce binding against pebbles to a minimum, the shield was constructed with a 1-inch batter on all sides.

Jan 1, 1938

By M. G. Stamatakis, C. Zagouroglou, C. Helvaci, J. Kanaris

"Abstract -Borate minerals, such as colemanite, ulexite and borax, have been reported in Tertiary continental basins of West Anatolia, Turkey, and Samos Island, Greece.Tuffaceous rocks interbedded with the borates are rich in authigenic silicate minerals such as zeolites, potassium feldspar and opal-CT, all of which have a genetic association with the borates. Chemical analyses of the tuffaceous rocks show variation in major elements due to the varying percentage of carbonaceous, detrital, and volcanic derived material.The volcanic activity in the vicinity of each particular lacustrine basin created ion-rich fluids from which a series of borates were precipitated under arid climate. Additionally, the saline-alkaline character of these fluids was responsible for the diagenesis of the silicic glass of the tuffaceous rocks, altering them to silicates and silica polymorphs."

Jan 1, 1993

By Robert Maquil, Gilles Didier, Walter Steiner

"The 1580 m long dual-tube motorway tunnel Markusberg near Schengen, Luxembourg experiences strong swelling phenomena in each tube related to a 35 m wide diagonally crossing rock layer, some150 to 200m from the east portals. Overburden over the roadway is 26 to 30 meters. Tunnel construction started in 1998 and the tunnel was opened in 2003. The tunnel was driven downgrade from the West, the heave phenomenon started to occur as the tunnel approached completion. No indications of the presence of anhydrite and dissolved sulphates were known prior to tunnelling. Water samples had been taken from the beginning of construction and the concentration of anions and cat ions determined. Sulfate content was substantial, in one well it reached 22 mg/l, this high concentration requires the presence of other ions, in particular sodium and chlorine. Based on the knowledge at the time of construction heaving ground was removed from the tunnel invert and a free space was left below the roadway that is covered by a transversely spanned slab. In addition a series of posttensioned tiebacks were installed below the sidewalls. The void left in 2003 was 1.7m high and closed to less than 0.5 meters in 2007 then it became necessary to widen the free space. A central trench was dug with a height of about 2.5 meters and the benches were lowered.Level surveying had been carried out since 2002. In 2006 two extensometers were installed, one in the zone of strongest heave, the second at the edge of the swelling zone. The extensometer in the center of the swelling zone indicated heave with an essential constant rate with seasonal variations, the heave is concentrated in layer from 2 to 5 meters that heaved by nearly 300 millimeters within 5 years or 60 mm/year, which equals to approx. 1% extension per year. At the abutments heave rates of 20 mm/year where the support resistance is higher were observed. With data from other case histories a relation of heave rate with support resistance was established. Based on the numerous field observations hypotheses for the complex in-situ swelling processes, involving rock mechanics, mineralogical, soil mechanics and hydrogeological aspects were developed"

Jan 1, 2015

By Seshadri Seetharaman, Nurni N. Viswanathan, Haijuan Wang

The present work aims at some process modifications in specified metallurgical processes, wherein CO2 can be used successfully as an oxidant for decarburization in steelmaking and applied in some non-ferrous metals production processes. During the decarburization of Cr-containing high alloyed steels, the present researchers investigated the possible use of CO2 instead of Ar-O2 mixture and could successfully decarburize the steel melt without significant loss of alloyed Cr to the slag phase. A mathematical model was developed based on the bubble formation accompanying the chemical reaction: C(molten steel)+ CO2(gas)= 2 CO(gas). The model predictions were tested by laboratory scale (1 kg) experiments carried out in an induction furnace and very good agreement between the model predictions and experimental results were observed. A national project has been sanctioned in China for the implementation of CO2 in decarburization of ferroalloys as well enable the addition of pig iron in the electric arc furnace process when the scrap supply is limited. New processes have been developed for the utilization of CO2 in the case of non-ferrous processes. A novel method of treatment of Al dross by leaching with water and capturing the evolved NH3(formed by the hydrolysis of AlN) has shown very promising results.

Jan 1, 2015

By P. Tukkaraja, K. Katzenstein

"Block caving is one of the most economical and efficient underground mining methods and has gained popularity around the world especially for extracting low grade and massive ore bodies. However, during the extraction of ore from the draw bells, gases trapped inside the cave could emit into the working areas; hence, ventilation plays a key role in operating block cave mines successfully where gas emission is a concern. To design an effective ventilation system for a block caving mine, given the dynamic nature of the caving process, it is necessary to develop airflow characteristic curves (P-Q) for a given cave. This study uses a 1:100 scale physical model with an exhaust fan system, and a Computational Fluid Dynamics model of a block cave to investigate the airflow behavior through the cave filled with broken rock material. From this study, it was observed that the cave airflow resistance increases with the decrease in cave porosity and the particle size.INTRODUCTIONThe block cave mining method is gaining popularity owing to its low cost and high productivity. This study considered a case where this bulk mining method is used for the extraction of an orebody that contains uranium mineralization. During the extraction of broken ore from the draw bells, radioactive gases trapped in the cave zone could be released into the production drifts and could create unsafe working conditions in the mine. Mine ventilation systems play an important role in regulating the migration of radon in working areas. One of the strategies to control radon migration in a block cave mine is to exert negative pressure on the cave zone by using an exhaust fan above the cave zone. In order to select an appropriate exhaust fan system, it is necessary to study the airflow resistance of the cave zone (Loring & Nelson, 2006).Extraction of broken ore via drawpoints creates a void volume inside the cave called the air gap. Air gaps with larger heights can lead to air blasts in a block cave mine should the cave collapse. Besides that, the air gap can also lead to decrease in ventilation system efficiency due to recirculation of air flow and associated shock losses. Air gap height can also have a profound effect on the variation of cave airflow resistance (Erogul et al., 2015, 2017). The knowledge of cave airflow resistance is also important for predicting the intensity of an air blast. Cave airflow resistance is a function of cave properties such as broken rock size, air gap, and porosity inside the cave zone (Baysal et al., 2017). Initially, a scaled experimental model with a forcing system was developed to investigate the airflow behavior through the cave, however, this model couldn’t provide an observable change in the airflow resistance when the cave properties were changed (cave porosity, and airgap) This was attributed to the difficulties associated with forcing system in terms of achieving lower porosity values with the available material (lightweight shipping boxes) for simulating broken rock inside the cave zones, and controlling air leakage from the model (Ajitha et al., 2018)."

Jan 1, 2019

By M. Bryson, A. E. Brady, W. Dawes, G. Beer, N. Sehlotho

Mkango Resources Limited is developing the Songwe Hill Rare Earth Element Project in southeast Malawi. Since being awarded the exclusive exploration licence for the project in January 2010, Mkango has completed an extensive work programme including detailed mineralogical studies, geological mapping, geochemical sampling and trenching, environmental and social studies, two phases of diamond drilling, and extensive metallurgical test work. In October 2012, the company announced a NI 43-101 compliant mineral resource estimate comprising an Indicated resource of 13.2 million tonnes grading 1.62% total rare earth oxides (TREO) and an Inferred resource of 18.6 million tonnes grading 1.38% TREO. The Indicated mineral resource estimate formed the basis for commencement of the Preliminary Feasibility Study (PFS). The mineralogical program identified the fluorocarbonate mineral, synchysite, and the phosphate mineral, apatite, as the primary rare earth element (REE) bearing minerals. Extensive flotation testwork conducted at Mintek in South Africa has resulted in an effective regime to increase the REO grade 2.6 times. Initial leaching testwork by Mintek identified that a selective hydrochloric acid (HCl) leach can target the gangue minerals with minimal REE dissolution. Recent testwork undertaken at Nagrom in Western Australia has expanded on this work to develop a two stage HCl leach process incorporating HCl recycling. A downstream processing route of purification and cerium rejection to produce a cerium depleted high grade REE concentrate suitable as feed to a separation facility is proposed.

Jan 1, 2014

By M. Al Mukhtar, D. Hoxha, X. Brunetaud, D. P. Do, C. Auvray, L. Michel

"Mechanical behavior of rock joints is often the key factor governing the response of complex structures constructed in fractured rock masses such as underground openings or of objects assembling various stones blocks such as historical building walls or damaged marble statues. This paper aims at developing a theoretical model to describe the behavior of fresh joints based on the description of their morphology. The main idea of the model is to establish a link between the effective contact surface of joints and the frictional coefficient. Beginning from a chosen level of joint surface description where a joint is considered as “smooth”, the model describes the added friction with respect to the increase of the contact surface of the joints and the distribution of stress in these contacts. The model developed initially for asperities with regular geometry is firstly compared with existing models and then applied on fresh artificial joints. For that, healthy artificial joints have been characterised using in one hand classical CNL shearing tests and in another hand the morphology of joints. The joints surfaces are digitized before testing using a high resolution laser scanner (Konica Minelota Vivid 910) allowing to obtain a precision up to 10µm. From these scanned surfaces the morphology of joints is characterised on the profiles running in the direction of shearing and a mean value of friction is calculated using the developed model. This calculated value is then compared with that obtained from CNL shearing test and a good approximation is notedINTRODUCTIONThe role of the mechanical behavior of rock joints on the overall response of fractured rock masses is well established in many fields of engineering activity going from the stability of underground constructions (Souley M, Hoxha D, Homand F 1999), rock slope stability (Einstein H.H. Veneziano D., Baecher GB., O’Reilly K.J, 1983, Jaeger 1971), various rehabilitation of masonry construction, damaged stone artworks restoration (Michel L., Do D.P, Coignard B, Hoxha, 2014) and so on. In the same time the characterisation of the behavior of joints and their modeling is nowadays a dynamic field of research or/and investigations and many alternative approaches have been proposed (Barton, N.R. and Choubey, V. 1977, Tatone, S.A. Bryan, Grasselli Giovanni 2010, William C E. 2007). While empirical relations of shear strength with various parameters of the joint morphology are the most used in practice because of their simplicity (Barton. and Choubey, 1977, Barton 1973, Bandis S., Lumsden A. C. and Barton N. R. 1983) many other models of joint strength are developed based on mechanistic considerations (Haberfield CM, Johnston IW. 1994), multiscale approaches (Yang Z.Y., Di C.C., Yen K.C. 2001, Fardin N., O. Stephansson, Lanru Jing 2001) or micromechanical ones (A. Serrano, C. Olalla, R.A. Galindo 2014) to mention just a few of research trends on rock joints modeling."

Jan 1, 2015

By P. E. Cavanagh

THIS REPORT is not intended to be a ?comprehensive survey of the steel industry in Europe. For the past ten years the Ontario Research Foundation has been interested in several developments in the steel industry in Europe which it was felt would be of particular interest in Canada and might possibly find application in this country. This is an account of the present status of some of these developments. The economies of steel making in Canada are somewhat different than in the United States because of the nature of the market and the relative costs and availability of such raw materials as metallurgical coke and electric power. There are cases in Europe where a great deal of effort and money has been spent in trying to make steel profitably by methods which take advantage of locally available and cheap raw materials by modifying standard practices. ln cases wl1ere the investigations have been successful and the data are available to allow translation of the results into Canadian conditions, it is felt that such information may be of great benefit in the future in Canada and at !east should be known to all those in the steel industry in this country. The field to be covered in this report only comprises the steps from concentration and treatment of iron ores to production of iron and is only concerned with those commercially operating processes well known to us and judged to be of present interest in Canada.

Jan 1, 1957

By Garston H. Blackwell

For ageing open pit mining operations where the economic viability of another pushback is questionable, mine life can be extended by increasing the wall slope. If the steepening is started where ore intersects the pit wall, the capital outlay for waste stripping is minimal. Such a venture must be conducted safely, and a basic requirement would include loading equipment capable of working remotely. In the application described, alternatives in the choice of loader included equipment available on site, or the purchase and assembly of used equipment. Only electric cable shovels were in use at the operation, and it was thought that these would be more capable of digging high muck piles at the productivity demanded by an increasingly efficient mill, and in a challenging environment less suited to a rubber tired loader or hydraulic front shovel. A decision was made to convert an older electric cable shovel to remote controlled operation and to include the application of semi-robotic control. The conversion was completed successfully and is described, along with methods developed for remote operation of a shovel, and the application of various sensors for semi-robotic operation. A plan of operations to mine out several completed double benches and make two quadruple benches with wide catchment berms is depicted. On completion of this task, the working benches developed would be wide enough to operate at near full production. Prior to moving the remote controlled shovel back into the pit, a large wall instability became active, eventually closing the operation. The instability could have been safely mined using the remote controlled shovel.

Aug 1, 2013

By Edouard Asselin, Tasawar Javed

This study was conducted as a part of ongoing work to characterize sulphide concentrate leach residues generated under CESL (Cominco Engineering Services Limited) and Vale pilot and demonstration plant medium temperature (150 °C) process conditions. Three different samples were analyzed. Derivative samples were prepared by extracting gypsum, sulphur and amorphous/poorly crystalline iron oxyhydroxide phases from the leach residues. Thermal behavior of the samples was studied by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) in the temperature range 25 to 800 °C in both air and nitrogen atmospheres, with XRD analyses both before and after heating. Thermal transformation temperatures for different iron oxides/oxyhydroxides present in hydrometallurgical leach residues vary over a wide range which suggests the variable crystallinity of the phases. Raman spectroscopic analysis was carried out to help identify the type of iron phases in the residues. Furthermore, hydroxylamine hydrochloride (HaHC) and oxalate extractions were used to compare the fractionation of the amorphous/poorly crystalline iron phases in the residues. Given the compositions of the residues, any thermal events in the temperature range of 200 °C to 480 °C were attributed to amorphous/poorly crystalline iron phases.

Jan 1, 2014