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By Javier Ramirez

"Recent R&D pilot plant testing was done to validate a full industrial scale system for recovering residual magnetite from the tails of an iron ore concentration plant. The recovery system is based on an autogenous heavy media separator treating a tailings slurry at 0.45% solids by weight. A 3,100 m3/h capacity concentrator was installed based on the testing findings. Excellent metallurgical results have been observed in two years of continuous operation. This experience is the basis for the proposal of a novel process consisting of the preconcentration of base metals ores; the idea being to obtain a heavy bulk concentrate of the polymetallic minerals and discarding in one step the light gangue mineral components. The bulk concentrate then proceeds to conventional froth flotation. The reduced volumetric flow of the bulk concentrate allows a reduction in the size of the subsequent flotation circuit. A prerequisite for the heavy media separation is a fine size grinding of the ore and a correspondingly high degree of liberation of the mineral species to be recovered. A process scheme is also presented in which the gravity concentrator works in conjunction with a companion tailings thickener for process water recovery. The underflow from this thickener, having paste consistency, can be sent to a tailings dam or mixed with Portland cement for mine backfill. The process water in the system is managed at an estimated recovery in excess of 98%. Additional R&D work using this novel approach is being considered by a large iron ore concentrator for removal of liberated silica from the final concentrate; and for upgrading 3.5 million tons of a marginal hematite reserve owned by the mining company.INTRODUCTIONGravity preconcentration (static and dynamic) of sulphides prior to froth flotation has been and is being practiced at various concentrator plants (Asarco´s Young Mill: heavy media cone; Mount Isa: DSM cyclone; Afton Mines: Denver jigs; Tsumeb Mine: Reichert cone) (Burt, 1984). The idea behind installing preconcentration equipment is to reduce the volume of feed processed on flotation, thus requiring smaller flotation plants although other advantages may be of importance, such as obtaining richer concentrates due to higher grade feed, better process water and energy management, and reduced flotation reagent consumption.The SedconTM solid/liquid separator is a versatile process unit patented in Mexico (MX/u/2007/000305). As a gravity device, it may be classified as an autogenous heavy media dynamic concentrator. Figure 1 depicts the Sedcon (Sedimentador de conos) separator. The four main components are as follows: the feedwell for efficient mixing of the pulp with dilution water and flocculant (and coagulant for water clarification); the inner cones (passive elements for solid/liquid separation); the discharge underflow cone; and the scraper mechanism. The standard discharge cone is a 60° inclined cone for general applications. For paste tailings thickening applications, a deep cone with a 69° inclined cone is used."

Jan 1, 2016

By Arnfinn F. Prugger, Fritz F. Prugger

"The Saskatchewan potash beds are overlain by a number of water-bearing formations. There are water zones in the footwall as well. These aquifers created difficulties during the construction of shafts to the potash beds at 1()(}() m depth, and they pose a continuous threat to the safe and efficient operation of potash mines in the province.The first shafts to be sunk in Saskatchewan encountered major problems during shaft sinking. Of the 17 potash shafts started in the province, five had major water inflows during shaft sinking or after production startup, and one was abandoned because of water problems. The biggest obstacle encountered during shaft sinking was a poorly consolidated sand-shale-clay-siltstone unit commonly called the Blairmore Formation, which occurs at a depth of about 500 m. The initial problems with shaft sinking were overcome in the 19605by using European methods of freezing and the installation of cast-iron tubbings or a double-steel lining through water bearing horizons.From the start of production in the early 19605, operators have been aware of the ever-present hazard of potential water inflows into mine openings from permeable units in both the hanging wall (carbonates of the Dawson Bay Formation which occur 15 m to 50 m above the mining level) and the footwall (carbonates of the Winnipegosis Formation which occur 50 m to 150m below). This awareness has been reflected in conservative over-all extraction rates and mining layouts specific to local conditions. In spite of this consciousness, a number of water problems have occurred in operating mines. These have resulted in everything from simple increases in expenditure to the shut-down of one mine in 1987.In this paper a history of water problems in the Saskatchewan potash industry is given, followed by a summary of measures that are now commonly used to avoid these problems. A description of each inflow event is given, and the attempt is made to analyze the causes of each occurrence. Based on what was learned f rom each event, suggestions are made to prevent future water inflows into potash mines."

Jan 1, 1991

By Peter S. Jack

"IntroductionTHE ORES treated at the concentrator of the Britannia Mining and Smelting Company, Limited, Britannia Beach, B.C., have always contained some lead, but it was not until 1950 that the combination of lead headings and lead price was such that recovery of this metal at Britannia became worthwhile. In that year, with the mining of a new orebody, the lead in the mill feed was raised from 0.07 per cent to 0.15 per cent. Chalcopyrite, sphalerite, and pyrite concentrates are produced by flotation at Britannia, •and 95 per cent of the lead in the mill feed reports with the chalcopyrite concentrate, so that the rise in lead headings was reflected almost wholly in the lead content of the copper concentrate. In 1950, investigation was started to determine if some of this lead could be recovered economically."

Jan 1, 1953

By D. Hamilton

The electrode of a PEM fuel cell consists of two distinct sections - the catalyst layer and the porous transport layer (PTL). There are several kinds of PTL material, although all use carbon fibres as the solid fraction. The fibres can be matted to form a paper, woven into a cloth, or chopped to form a felt. Despite the different morphologies of the media, they are all anisotropic in structure, that is the majority of continuous fibres lie perpendicular to the direction of bulk transport. Currently, no models account for anisotropy and all transport coefficients are calculated as volume weighted averages or from empirical correlations (not developed for fibrous porous media). The present work presents a new methodology for determining anisotropic transport coefficients in fibrous porous media. A numerical experimentation process is employed wherein random samples of the PTL are generated and used to solve a diffusion transport equation. Effective transport coefficients are determined by integration of flux across the domain boundaries once a steady state solution has been reached. Multiple random samples at each porosity are generated in order to predict statistical variance. The results are correlated for ease of implementation in full PEM models.

Jan 1, 2005

By H. Hejny

Given the current status of political discussion in Europe about raw materials issues, the sustainable development of the extractive industry and the reduction of its environmental and societal footprint are among the key topics in this discussion. In this context, the European Commission approved the EO-MINERS project (Earth Observation for Monitoring and Observing Environmental and Societal Impacts of Mineral Resources Exploration and Exploitation). The overall aim of EO-MINERS is to bring into play EO-based methods and tools to facilitate and improve interaction between the mineral extractive industry, authorities, and the society in view of its sustainable development while improving its societal acceptability. Developing generic, standardised and reliable EO-based products to monitor the environmental and societal footprint of mining projects is the way chosen by EO-MINERS to improve this interaction, along with the organisation of tripartite meetings gathering all relevant stakeholders. The project uses existing EO knowledge and carries out new developments on three demonstration sites (Sokolov lignite mining area, Czech Republic, Witbank coal field, South Africa, Makmal gold mine, Kyrgyzstan) to further evaluate and demonstrate the capabilities of integrated EObased methods and tools in monitoring the environmental and societal footprints of the extractive industry during all phases of a mining project, from the exploration to the exploitation and closure stages. It contributes providing reliable and objective information about affected ecosystems, populations and societies, to serve as a basis for a sound ?trialogue? between corporate stakeholders, governmental organisations and societal stakeholders. The project already developed a set of consolidated indicators based upon previous knowledge about mining-related issues along with interviews of national, regional, and local stakeholders. These indicators reflect known environmental and societal issues at mining sites as well as the interest of various relevant stakeholder groups. The process described in the EO-MINERS project ? policy assessment > indicator identification > choice of suitable EO tools able to serve monitoring task > monitoring by EO tools > making available objective information for fair dialogue among stakeholders ? is generally applicable to all stages of a mining project. The key to success will be the right choice of indicators addressing the problem and subsequently the right choice of suitable EO tools and finally the willingness of all stakeholders to find a common solution. To this end, the EO-MINERS project organises site-specific ?trialogue? workshops at each demonstrations site, which aim to provide relevant information in adequate quality to the stakeholders as common ground for discussions. Local stakeholders, including mining companies, regulatory bodies, and community representatives are invited to participate in these workshops where the relevance of the developed EO-based products to environmental and societal impact assessment will be discussed. The presentation will discuss results obtained during these trialogue workshops, as well as the success and difficulties and reluctances encountered. The project will further indicate ways and means how the EO products and other project results may be used for monitoring purposes in all phases of a mine.

Aug 1, 2013

By Cheowchan Leelasukseree

Mae Moh mine, operated by Electricity Generation Authority of Thailand (EGAT), is the largest open pit mine in Southeast Asia. Its production is approximately 15 million lignite tons and 90 million m3 of waste, annually. The bottom of the final pit limit is designed to be approximately 500 m in depth. Presently, the pit depth is almost 250 m below original surface. The complexity of geological structures, such as faults, has caused a number of geotechnical difficulties. In a challenging lowwall area, called Area 4.1, an inclined weak bedding plane, G1, will be daylighted along the lowwall as following by mine plans. The dimensions of Area 4.1 are nearly 300 m wide and 90 m high. The friction and dip angles of the G1 interface are reportedly 12° and 15°, respectively. A three million m3 claystone block, resting above G1, would potentially slide down, and possibly cause a massive failure. EGAT engineers are acutely aware of the potential gigantic sliding failure and are modifying the mine plan in Area 4.1 to improve mine safety and minimize the displacement of the potential sliding block, reduce the possibility of failure and lower the additional mining cost as much as possible. The cut and fill mining technique was selected and studied to achieve those goals for mining in Area 4.1. With this mining technique, G1 will be partially daylighted. Therefore, an arch formation is induced with a sliding block above the mining area, which could perform as a temporary support undercutting a certain span. Initial studies of the behavior of the partially undercut slope are presented in this paper, along with a review of the similar failure history in Mae Moh mine and a 3-dimensional numerical model of the mine. The failure history review provides an estimation of undercut span without failure. The three-dimensional numerical model results, using 3DEC, gave an initial approximation of the displacement of the sliding block in Area 4.1. The next exciting study of the behavior of partially undercut slope is a trial undercut slope field experiment in Area 4.1. Currently, a trial undercut slope field experiment in Area 4.1 is under construction. In the field experiment, a number of monitoring programs will be installed in Area 4.1 to monitor and obtain information to allow a better understanding of the behavior.

Jun 1, 2012

By Brock Morrison, Bernt Ling

"The Kiruna Electric System is an all electric ramp haulage system developed for underground mining. This electric truck haulage system is currently operating on three continents. This paper will review the technology of the system, existing installations as well as the economical benefits to the mining industry. The system was designed and developed to extend and exploit the economical advantages of ramp haulage. Performance information is provided. IntroductionThe Kiruna Electric System has been the subject of a number of technical papers over the past sever al years. During that period, the content of the presentations has changed from concept and theory to prototype testing to description of installed and operating systems.The intent of this paper is threefold:1. to present a brief review of the technical features of the Kiruna Electric Systems;2. to review the existing installations with performance data; and3. to provide a description of on-going developments within the Kiruna Electric Program during 1991.The Kiruna Electric is a high capacity ramp haulage system for underground mining operations due to an All-Electric Drive System, including two heavy duty electric traction motors. The high capacity of the K1050E results from three factors:• payload - 50 tonne• speed - 18 km/hr to 20 km/hr up a IS0J0 ramp (total resistance)• availability - over 90010 during a 12-month period"

Jan 1, 1991

By Neil Westoll

Extensive Global Network ?Working together, AECOM provides clients with a unique blend of global reach, local knowledge, innovation and technical excellence. ?43,000+ team members worldwide ?450+ offices ?100+ countries ?6 continents The Changing Climate ?Climate change is ?official??IPCC 2007 ?Climate change will create instability, change and opportunities ?Companies that are resilient and adapt will survive and evolve ?CO2/GHG emissions will be curbed by legislation ?How will this affect the mining industry? ?How can the mining industry adapt to the new realities?

May 1, 2009

By C. O. Aksoy

Operating the underground marble quarries effectively, it is important to evaluate the deposit blocks economically which are affected by the suitability of the topography and configuration of bedding. The joint sets within the deposit and the spacing between these discontinuties are also of great importance. In this study, the marble deposits that could be geomechanically eligible for underground excavation have been selected throughout Turkey and these selected reserves have been classified accordingly by Q-Rating System. These classified marble deposits that forms groups of 1,2, and 3 (groups were determined by evaluating the O-rating, topography, quarry situation, cracks, joints etc.) are convenient for this type of production. Nevertheless, when the auxiliary factors (topography, location, production method etc.) regarding the deposit have also been investigated, the most convenient sub-group of deposits (Afyon Tiger Skin, Burdur Beige, Diyarbakir Pink and Mugla White) have emerged. The sizing of the pillars have been performed utilising Bieniawski?s stress profile. The LAMODEL software, developed by National Institute for Occupational Safety and Health (NIOSH), USA and run under the laminated displacement discontinuity method, has been used to size the pillars. This work brings in a novel opportunity to Turkey, in which no underground marble quarry has been attempted up-to-date similar to its several examples in Italy, USA, etc. This study serves as a reference for the marble operators and for the pioneering application of laminated displacement discontinuity method in hard rocks.

Apr 1, 2005

By Yanping Xiao, Ton van Sandwijk, Gus Van Weert, Larry McHugh, Thomas Zabev

"All attempts to remove significant amounts of arsenic from enargite via neutral or reductive pyro routes have required operating temperatures between 600 and 700 º C, too high to propose an equipment development program. Operating at reduced pressures, or using hydrogen or elemental sulphur as a sweeping gas did not help to lower these temperatures. Admixing iron powder gave excellent results, but still required 700 º C. By fortuity, in recent experiments to produce tennantite from an enargite mineral sample, it was observed that enargite was completely converted to bornite, chalcopyrite with minor residual tennantite within an hour at 400-450 ºC. This is believed to be due to the presence of pyrite in the mineral sample treated. All earlier decomposition work appears to have been done on predominantly enargite (i.e. low pyrite) samples, or at high operating temperatures, ignoring possible reactions at lower temperature. The decomposition of enargite into iron substituted tennantite plus some bornite under evolution of liquid elemental sulphur, followed by further decomposition of this tennantite into bornite and volatile arsenic sulphides, appears experimentally feasible at these low temperatures and mimics described ore genesis pathways at > 250 ºC in saline solutions. We suggest two pathways to describe the observed experimental results:20 Cu3AsS4 + 12 FeS2 ???5 Cu10Fe2As4S13 + 2 Cu5FeS4 + 31 S(l)31 S(l) ???31 S(g) (evaporation)5 Cu10Fe2As4S13 ???10 Cu5FeS4 + 10 AsS(g) + 5 As2S3(g)"

Jan 1, 2014

By E. Goodwin

"Maclaren Forest Products Inc.Lime is commonly used for the neutralization of acid, and the removal of heavy metals in mine waste waters. However, the precipitation of heavy metals as hydroxides must take place under conditions of controlled pH, to produce minimum concentrations of dissolved metals. An account is presented explaining the concepts applied to lime-treatment processes at Bell Mine during the period of a supernatant discharge to Babine Lake; October 18, 1982to January 25, 1983. IntroductionBell Mine of Maclaren Forest Products Inc., Babine Mining Division, an open-pit copper mine, is located on Newman Peninsula, Babine Lake approximately 65 kilometres northeast of the town of Smithers, British Columbia (Fig. 1).A depressed market for copper metal in 1982 forced a management decision to suspend operations at the mine for an indefinite period from October 3 I, 1982. For some time prior to the mine closing date, mine management was concerned about the increasing level of supernatant in the tailings pond , and its possible effects on the stability of the dam when cycloning of mill tailings ceased. Consideration of these potential hazards led to an application being filed with the Provincial Waste Management for a permit to discharge the excess water to Babine Lake. This large lake, an important link with several significant salmon spawning sites, is a major contributor to the British Columbia commercial fishing industry. Jurisdiction for the environmental affairs in the area is shared by the Department of Fisheries and Oceans, the Environmental Protection Service, and the Provincial Waste Management Branch. These agencies were directly concerned in the formulation of discharge permit following joint consultation, and exchange of information with the company on environmental concerns. An approval was finally granted to discharge approximately 1,000,000 cubic metres of supernatant from the tailings impoundment at Bell Mine into Hagan Arm, Babine Lake from October 18, 1982 with a daily discharge not to exceed 9000 cubic metres. Provisions were made that a particular discharge procedure be followed, and that the company would be responsible for setting up a sampling and monitoring program to safeguard the quality of the effluent."

Jan 1, 1986

By F. P. Yungwirth

"IntroductionTrout Lake Mine is located about 5 km north of the Hudson Bay Mining and Smelting Co., Limited complex at Flin Flon, Manitoba. The mine was brought into production in 1982at the onset of a severe recession in the base metal market. The mine is operated as a joint venture with HBM&S, MMR and SMS.During the first several months of operation it became evident that there were opportunities to reduce costs at the mine significantly, and a productivity improvement subcommittee was formed to make recommendations. The first committee met in January, 1983 and consisted of the mine manager from Hudson Bay Mining, a geological expert and a maintenance expert from Outokumpu Oy, Finland, and a mine manager from Granges, Sweden.Recommendations from this committee were implemented during 1983 and a new subcommittee was constituted in 1984 to continue the work begun the previous year. The committee remains as constituted in 1984 and meets quarterly.The committee consists of M.A . Kirby , manager - Flin Flon Mines, HBM&S; Gustav Hoberstorfer of Mindelco , a Swedish mining consultant retained by Granges; Eero Laatio, mine superintendent of Keretti Mine at Outokumpu Oy in Finland; and Bob Bray, a mining consultant retained by Manitoba Mineral Resources.Many productivity improvements made in the operation are attributed to the work of this committee and other experts retained at various times throughout the mine life."

Jan 1, 1988

By Simon P. Fricker

Gold drugs have been used for the treatment of rheumatoid arthritis since the mid 20th century as disease-modifying antirheumatic drugs (DMARD) class. Methotrexate is often the preferred DMARD, and with the advent of new therapies gold drugs are now used infrequently. Since the introduction of auranofin in 1985 there has been no new clinically approved gold drug. In spite of this apparent lack of progress there has been a great deal of interest in the use of gold compounds for cancer therapy and early promising indications were achieved with a gold phosphine complex [Au(dppe)2]Cl. This compound was not entered for clinical trials, however, due to problems with cardiotoxicity highlighted during pre-clinical toxicology studies. Gold(III) is isoelectronic (d8) with platinum(II) and likewise forms square planar complexes. It is therefore tempting to speculate that such complexes would have similar antitumor activity to cisplatin. In order to stabilise the gold(III) oxidation cycloaurated complexes were synthesised with a single mononegative bidentate ligand, damp, (2-[(dimethylamino)methyl]phenyl), and two monodentate anionic ligands e.g. Cl or acetate. The damp ligand forms part of a five-membered chelate ring. The monodentate ligands are readily hydrolysed and are available for substitution. These compounds had limited anti-tumor activity in in vivo against human tumor xenografts. Mechanistic studies indicated that these compounds had a different mechanism of action to cisplatin. An alternative molecular target for these compounds is biologically important thiol-containing molecules such as the cysteine protease cathepsin B. Modifications were made to the Au(III) damp structure to give compounds with a six-membered chelate ring. These compounds were shown to be inhibitors of cathepsin B. Compounds were also tested for cytotoxicity against a panel of human tumor cell lines. Three compounds were selected for further evaluation against a human colon tumor xenograft. The compounds showed modest anti-tumor activity but with no marked improvement over the parent Au(III)damp complexes. Initial indications are that Au(III) compounds targeted against disease-specific thiol-containing biological molecules have potential as drugs, particularly for cancer. However, further work is required to produce a target-specific drug with a suitable pharmacological activity and toxicity profile.

Oct 1, 2003

By N. H. Grace

"IntroductionA STRIKING FEATURE of the past twenty years has been the application of organized scientific and industrial research to problems of national defence and security and to the development of our natural resources. It has been shown that effective research improves public health, increases the productivity of land, makes mineral wealth available, and increases the efficiency and productive capacity of industry. Alberta is a region bounteously provided with a variety of natural resources, and the Province has entered into a period of unprecedented industrial development. There is, surely, a great opportunity to bring scientific research to bear •on problems associated with the development of these natural resources.I propose to spend a little time discussing the term 'research', indicating something of the various types of research and those fields which appear to •be the particular responsibility of government bodies. It seems logical, also, to outline the course of development .of industrial and scientific research in the English-speaking world during the past twenty-odd years.Research is investigation, examination, or enquiry, and involves the application of human thought, and actions, to the unfolding of new knowledge. That knowledge may assume a variety of forms. Fundamental knowledge may be new facts related to some form of matter, to motion, space, thought, and so on. Those engaged in applying the natural sciences have no monopoly on research as this term is equally valid for those engaged in obtaining, sorting, relating, and interpreting the facts of history, literature."

Jan 1, 1952

By Charlie Graham

Our Approach ? Industry Trends ? New Forces at Work in Mining ? Deep Mining ? Energy projects ? Air power ? Hydraulics ? Electric alternatives ? Drilling ? Productivity ? Conclusions ? Transportation ? References

Oct 1, 2010

By Brooke Clements

The Buffalo Head Hills region is located approximately 350 kilometres northwest of the city of Edmonton in northcentral Alberta (Figure 1). The Alberta diamond joint venture consisting of Ashton Mining of Canada Inc., Alberta Energy Company Ltd and Pure Gold Minerals Inc. began exploring for kimberlites in the Buffalo Head Hills region in late 1996. At the time, the Mountain Lake diatreme, located 200 kilometres to the southwest, was the only reported kimberlitic rock in Alberta (Leckie et al., 1997, Figure 1). Exploration efforts since 1996 have successfully identified a new diamondiferous kimberlite province in Canada.

May 1, 2001

By D. G. Macintyre

Thick westward prograding clastic wedges were deposited along the margin of ancestral North America from Mid-Proterozoic to Mid-Paleozoic time. Periodic rifting and tectonic subsidence resulted in the formation of starved sub-basins along this otherwise passive continental margin. These sub-basins host important sedimentary exhalative barite-zinc-lead-silver deposits. In northeastern British Columbia, a thick succession of Paleozoic basinal facies clastic rocks is preserved within the northwest-trending Kechika Trough. Within the trough, sedimentary exhalative barite and barite-sulfide deposits occur in starved basin sediments of Middle Ordovician, Early Silurian, and Late Devonian age. The last are the most economically sigrrificant and are hosted by carbonaceous cherty argillites and siliceous shales of the Middle to Late Devonian Gunsteel Formation of the Lower Earn Group. The largest deposit, Cirque, has reserves in excess of 35 million tonnes averaging 100J0 (Pb +Zn) and 47 g/t Ag. Other potentially significant deposits include Driftpile Creek, Bear, Mt. Alcock, Fluke, Pie and Elf. Stratiform barite deposits are also common, particularly near the basin-to-shelf transition zone. The Late Devonian barite-sulfide deposits typically are zoned: interlarninated barite-sphalerite-galena-pyrite occurring near suspected vent areas grades outward into bedded barite. Laminated beds of pyrite typically occur in hangingwall siliceous shales, particularly above the inferred vent zone. The apparent absence of epigenetic stringer sulfide zones and footwall alteration implies that the deposits were formed from ponded brines at relatively low temperature. Away from the main deposits, the favourable stratigraphic interval is marked by the presence of thin beds of nodular and laminated barite and thin laminae of pyrite. Thin tuff beds also occur locally in this stratigraphic interval and are evidence for a Late Devonian volcanic event. A paleogeographic reconstruction of the Kechika Trough in Late Devonian to Mississippian time suggests that the barite-sulfide deposits formed in third-order starved basins between uplifted, northwest-trending horst blocks that were capped by shallow-water carbonate banks. The presence of intraformational breccias suggests that fault movement accompanied barite-sulfide precipitation. This tectonic activity may have allowed the escape of heated, overpressured metalliferous brines from permeable reservoirs within the sedimentary pile. Sedimentary exhalative deposits formed where these brines were exhaled as buoyant plumes onto the seafloor, cooled, and ponded in anoxic seafloor depressions.

Jan 1, 1992

By Robert B. Parsons

"The Canadian Exploration Incentive Program (CEIP), which was announced by the federal government on May 3, 1988, promises to maintain the viability of flow-through shares as a financing mechanism which has proven to be so crucial to the health of the junior exploration sector. This month, Tax Notes examines, the main features of CEIP, which will come into play on January J, 1989. IntroductionOn May 3,1988, the Honourable Marcel Masse, Minister of Energy Mines & Resources, and the Honourable Gerald Merrithew, Minister of State (Forestry and Mines) announced the Canadian Exploration Incentive Program (CEIP). Under CEIP, the federal government will make cash payments to eligible applicants equal to 30% of eligible exploration expenses. CEIP payments will be available with respect to both mineral, and oil and gas, exploration. In essence, the program will replace the ""mining exploration depletion allowance"" (MEDA) presently applicable to mineral exploration, and the Canadian Exploration and Development Incentive Program (CEDIP) which is presently available to the oil and gas exploration sector.This paper discusses briefly the main features of CEIP insofar as the program will affect mineral exploration. The comments herein are based on the Canadian Exploration Incentive Program Act which received Royal Assent on July 21, 1988, and on a discussion paper which was released by EM&R in May 1988. The bulk of the rules relating to the program will be in the form of regulations which have yet to be finalized. It is understood that EM&R would like to have the regulations in force by October I, 1988, when the oil and gas portion of CEIP becomes effective. (The rules relating to mineral exploration will become effective January I, 1989)."

Jan 1, 1988

By Friedrich Benthaus

"The natural and man-made realities on either side of the Atlantic are different. Therefore, a large part of the other side' s knowledge and experience cannot be transferred easily. In the following, the author will attempt to describe some of those developments in the German hard coal industry which may be of particular interest to readers on this side of the Atlantic.The area of the Federal Republic is quite small, especially if compared with a country as large as Canada. On a territory the size of the maritime provinces of New Brunswick and Nova Scotia, Germany holds coal reserves roughly corresponding to the total Canadian reserves. More than 20 billion tons of hard coal down to a depth of 1500 m, and more than 30 billion ton s of brown coal of lignite are technically and economically extractable acording to current technology.However, not only are Germany's coal resources more concentrated; the country is also densely populated, and there are dense networks of railroads and highways All components of the so-called infra-structure are available everywhere, be it electricity, any machinery or personnel. Public opinion is likely in favour of an increased utilization of coal.The coal industry is well developed through a long evolution covering centuries. As a consequence, there is an effective and intensive cooperation of numerous bodies and institutions concerned with coal mining, from government agencies including the inspectorate to suppliers, trade union s, producing companies, to jointly operated management and research organizations. In the Federal Republic, hard coal is mined in deep mines only, and lignite in general, only from open-cast pits. There is a complete organizational and geographic separation of hard and brown coal in Germany. Because the Federal Republic holds only insignificant mineral oil and very little natural gas deposits, coal is essentially the only and consequently the most valuable source of energy."

Jan 1, 1984

By Ana Adé

The use of gold compounds in homogeneous catalysed organic reactions has been undervalued for many years due to the preconceived opinion that gold is an expensive and extremely chemically inert metal. However, recent reports have changed this assessment and gold salts in small amounts are known to display high catalytic activity.[1] Thus, it has been reported recently that anhydrous AuCl3 catalyses the formation of C-C and C-O bonds (usually mediated by hydrochloric and other protonic and Lewis acids).[2] Some examples include Michael type additions, selective cross cycloisomerisation/dimerisation of propargyl or allenyl ketones, benzannulation between o-alkynylbenzaldehides and alkynes or cyclisation of alkenyl furans. It is noteworthy that some of these reactions[2a] can be also catalysed by silver salts but with much lower yields. The 1,3-dipolar cycloaddition of nitrones to alkenes is a powerful synthetic method that has found numerous applications in the synthesis of a variety of carbon frameworks.[3] Several laboratories have focused on the development of Lewis acidic reagents to modulate the selectivity of the reaction.[4] Despite the extensive study performed, there are not many examples in which a metallic complex catalyses the dipolar cycloaddition. Most of these reactions require the presence of a metallic complex and nitrone in a 1:1 molar ratio. Recently, we have carried out stoichiometric reactions of the N-benzil-C(2-pyridil)nitrone, 1, with different dipolarophiles in the presence of zinc and silver compounds.[5] Apart from an increase of the reaction rate and the selective formation of one of the possible isomers, we have shown the formation of zinc and silver-nitrone complexes during the reaction, which behave as the intermediates in the cycloaddition process. As suggested by the results obtained with silver complexes, we decided to test gold derivatives (in the oxidation states of I and III). Interestingly, we have found that they can be used not only as stoichiometric reagents but they can also mediate these cycloadditions in catalytic amounts (5 to 10 mol % respect to the nitrone). Here we present the results on the 1,3-dipolar cycloaddition reaction of the N-benzil-C(2-pyridil)nitrone (2-PyBN), 1, and methylacrilate, 2, (Eq. 1) catalysed by gold(III) derivatives.

Oct 1, 2003