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By C. Pawlik, R. T. Jones

Cobalt occurs together with copper in the southern African copper belt, and a large portion of this cobalt ends up in copper smelting slags, mostly dissolved in oxide form. It is possible to achieve high recoveries of cobalt by reductive smelting of the copper slags, using some form of carbon as a reducing agent in an electric furnace. For example, a 40 MW DC arc furnace was operated at Chambishi Metals in Zambia from 2001 to 2008, and demonstrated cobalt recoveries of around 80% from slag to an iron-rich alloy containing copper and cobalt. The alloy was atomized prior to leaching. With the recent increase in demand for cobalt (and the resulting high metal prices), there has been increasing interest in this process route. There is also an alternative hydrometallurgical process for recovering the valuable metals from the slag. The choice between these process options requires a trade-off between capital and operating cost and environmental acceptability. This paper examines the potential for cobalt recovery from slags, and outlines various process options. INTRODUCTION Cobalt has had a number of important uses in society since antiquity, and its principal use has changed dramatically over time. Since at least 2250 BC, cobalt-based pigments (cobalt blue) have been widely used to colour manufactured goods such as glass and pottery. Later, cobalt became known for its magnetic and wear-resistant properties and high-strength alloys, and most of the cobalt produced was consumed in the production of cobalt-based superalloys. The greatest recent growth in cobalt demand is due to it being essential to the rechargeable lithium-ion batteries used in consumer electronic devices and increasingly to drive electric vehicles. Cobalt is usually produced as a by-product of copper or nickel. The copper belt in the Democratic Republic of the Congo (DRC) and Zambia supplies most of the world's cobalt production. In 2018, the DRC was expected to produce 90 000 tons of the world total of 140 000 tons of cobalt (Shedd, 2019). This paper focuses on the southern African copper industry, and specifically the cobalt that is able to be produced as a co-product from this. A BRIEF HISTORY OF SOUTHERN AFRICAN COPPER SMELTING Copper deposits in South Africa have been documented since at least 1685, when the Cape governor, Simon van der Stel, ‘discovered’ the 'Copper Mountain' at Springbok. South Africa's first public commercial mining company (imaginatively called the 'South African Mining Company') was established in Cape Town in 1846, to exploit the rich copper resources that were believed to exist in Namaqualand.

Jan 1, 2019

By R. A. Nemchek

Over the years, concentrator plant design has evolved from a large number of small grinding mills to a small number of large mills. In many cases, all of the tonnage runs through a single mill (typically a large SAG mill), so that the plant’s performance hinges on the productivity of this one machine. Industry specifications attempt to address the critical nature of today’s grinding mills in a manner that is often overly complex, neglects economics, and is not clearly focused on the end user’s goals. This paper surveys current industry practices, and proposes an improved approach to standards writing recognizing that product design, procurement, manufacturing, and quality are all inter-related in contributing to a project’s success. The lessons learned here can be extended to specifications for all types of machinery.

Jan 1, 2012

By Patrick Laflamme, Jean-François Boulanger

Les minerais de cuivre sulfurés, qui représentent 80% de la production mondiale de cuivre, imposent une étape de concentration des minéraux, premièrement pour atteindre une teneur en cuivre minimale qui permette le traitement pyrométallurgique, mais aussi pour limiter la présence d’élément pénalisants (délétères). Cette introduction offre un survol des principes, limites et pistes d’améliorations touchant la concentration des minéraux de cuivre.

May 2, 2024

By D. S. Cronan, S. P. Varnavas

Abstract - Metalliferous precipitates from submarine hydrothermal discharges have been investigated at four inshore locations off Milos in the Hellenic Volcanic Arc. The fine fraction of the sediments shows considerable variability in the concentrations of elements frequently associated with hydrothermal activity. Manganese varies from 30 ppm to 2500 ppm, encompassing the entire range of values found off Santorini also in the Hellenic Arc. Iron occurs in lower concentrations than off Santorini and Yali, while other elements often associated with hydrothermal activity such as Pb, Zn, As, and Cu also show enrichments in sediments from the hydrothermal vent areas. Selective leaching studies have shown that most elements are variably distributed between the different phases of the sediments but with enriched Pb, Zn, and Mn mainly in easily soluble secondary phases. Hydrothermal inputs are strongest at Palaeochori Bay, less at Voudia Bay and lowest at the Airport Springs and Rivari. The weathering of sulfide and possibly other orebodies is also thought to contribute to some of the elements enriched, while background concentrations are largely supplied from detrital sources.

Jan 1, 1999

By C. Allen, M. Gangal, J. Stachulak

"Most underground diesel equipment is equipped with diesel oxidization catalysts (DOCs) to reduce carbon monoxide and hydrocarbon emissions. DOCs do not alter nitrogen oxides concentrations but can promote the oxidization of nitric oxide (NO) to the more toxic nitrogen dioxide (NO2). Vale and CanmetMINING have been researching how to reduce worker exposure to diesel emissions by testing mining equipment DOCs. Results indicate a > 77% decrease in carbon monoxide concentration but a 46–315% increase in NO2 concentration for 8-mode test cycles. It is recommended that DOCs that increase NO2 emissions be evaluated regarding their continued use in underground operations.RÉSUMÉ La plupart des équipements miniers souterrains sont équipés de catalyseurs d’oxydation diesel (DOC) afin de réduire les émissions de monoxyde de carbone et d’hydrocarbures. Les DOC ne modifient pas les concentrations des oxydes d’azote mais ils peuvent faciliter l’oxydation du monoxide d’azote (NO) en dioxyde d’azote (NO2), plus toxique. Vale et CanmetMINING effectuent des recherches pour réduire l’exposition des travailleurs aux émissions de diesel en analysant les DOC des équipements miniers. Selon les résultats, une diminution > 77 % dans la concentration de monoxyde de carbone est atteinte mais elle est accompagnée d’une augmentation de 46 à 315 % de la concentration en NO2 pour des cycles d’essais à 8 modes. Il est recommandé d’évaluer les DOC qui augmentent les émissions de NO2 pour décider de la poursuite de leur utilisation dans les opérations souterraines."

Jan 1, 2016

By Jucheng Wang

Unplanned open stope dilution is a major cost factor for many mining operations, even though significant advances in empirical and analytical approaches for estimating stope dilution have been made. Many factors that influence hanging wall dilution are still either ignored or assessed in purely subjective terms. Undercutting the stope hanging wall on both the overcut and undercut development are well recognized factors which contribute to hanging wall instability and dilution. In many mines, undercutting the hanging wall breaks the integrity of the rock mass that may form along continuous foliation or bedding planes parallel to the stope hanging wall contact, reducing stability. This undercutting also increases the zone of destressed or relaxed rock that may potentially fall into the open stope as dilution. An approach is introduced for quantifying the effect of undercutting on potential stope dilution. An extensive database of stope case histories has been collected to look at dilution from Hudson Bay Mining and Smelting operations (HBMS) in Flin Flon.

May 1, 2002

By R. B. Taylor

"The Delnite mine is in the northwest part of Deloro township, Cochrane district. The property consists of 307 acres on the so-called 'South Break' in the Porcupine camp. The Company was formed in 1934 to take over the holdings of La Roche Mines, Limited. Gold has been produced continuously since June 1, 1937. The value of the gold recovered to date (December 31, 1946) has been $7,456,000, and the average grade of ore $6.81 a con.The ore at the Delnite occurs in relatively narrow, persistent, quartz-ankerite veins, which generally contain tourmaline and have a ladder-like structure. The gold occurs in the free state, and in association with pyrite and arsenopyrite, the two chief sulphides. The host rock is fine-grained, highly carbonatized andesite of Keewatin age."

Jan 1, 1954

By S. C. Bouffard

Barrick's Zaldivar operation in Chile produces copper by heap leaching, solvent extraction, and electrowinning. The heap consists of a dynamic pad, and its stacking and operating conditions have changed over its 11 years of operation. These changes have included pad re-mining midway through the cycle, tightening of the irrigation drip lines, an increase of the coarseness of the particles, and an increase of the heap height. This paper reviews the heap operating data to understand the effects of these changes on the kinetics and recovery of copper minerals. Field tests demonstrated that neither re-mining nor tightening the irrigation grid added value for both low and high grade oxide and sulfide ores. The P80 of the feed ore was increased by 0.8 mm, which did not reduce the copper recovery of oxide and sulfide ores. The increase of the heap height above 8 m lowered moderately the copper recovery from sulfide minerals, and very slightly the recovery from oxide minerals. Despite the lower recovery, the higher tonnage stacked in the taller heap increased the copper output. Optimizing the chemistry of the agglomeration and feed solution holds more promise for increasing the copper recovery than the above physical changes.

Jan 1, 2007

By J. Seidel

In 2009 Newmont Mining Corporation’s annual global spend on grinding media reached $94M USD, having doubled in the five years since 2004. The major contributing factor to the spend escalation during this period was unit consumable price, with total media consumption also rising as a function of annual ore tonnes milled. In an effort to better understand and manage the growth of this expenditure a significant supply chain management program was implemented. This was complemented by a series of technical initiatives focussed on grinding media specifications, quality management and the prediction of grinding media wear rate as a function of physical ore characteristics. This paper discusses the methodology and outcomes of these activities.

Jan 1, 2012

By Kevin Azocar, Jim Hazzard

"Slope stability analysis is performed most commonly using limit equilibrium calculations or numerical models assuming a two-dimensional slice through an infinitely long slope surface. In areas such as open pit mining, where most slope surfaces are not planar, the importance of curvature becomes important due to the economic gains associated with creating a steeper slope. With advances in computing capabilities within the last decade, three-dimensional slope analysis can be performed within reasonable time frames. Some work has been done on the potential importance of curvature on slope stability, mainly assuming homogenous materials with a circular shear-failure mechanism. However, many open pit mines are excavated in jointed rock mass where a completely different set of failure mechanisms can be seen. Depending on the geometry and radius of the pit, the curved geometry may influence the factor of safety and failure behaviour compared to a two-dimensional slice.A series of numerical analyses were performed to investigate the effect of curvature on jointed rock slope stability compared to an equivalent two-dimensional slope analysis. By using discrete element method models, the influence of joint planes and interaction between distinct blocks can be seen. With a three-dimensional model, the effect of curvature can be combined with multiple joint sets at any orientation, which cannot be seen in a single slice. Numerous three-dimensional models are created, along with an equivalent unit-thick slice. The effect of curvature on a variety of different types of failure mechanisms is observed, and graphical relationships are created to quantify the difference between the three-dimensional factor of safety and the two-dimensional factor of safety based on the degree of curvature."

Jan 1, 2015

By Denis Bois

La Bolivie est un pays en développement qui compte une tradition minière qui précède même l?établissement espagnol en Amérique. Pendant toutes ces années, l?exploitation minière s?est faite sans grands égards pour l?environnement. Au cours des dernières années cependant, le gouvernement bolivien a modifié ses lois afin de rendre nécessaire la prise en compte de l?environnement dans le processus d?exploitation d?une mine. Dans le cadre d?un projet MRN-ACDI1 visant à renforcer le secteur minier en Bolivie et ses retombées pour la population, l?URSTM2 a été mandaté pour développer et mettre en place un programme académique de gestion environnementale minière, basée sur l?expertise canadienne. Ce programme vise à renforcer les institutions académiques boliviennes responsables de la formation en environnement minier en Bolivie ainsi que les ministères et agences gouvernementales concernées.

May 1, 2001

By G. Tozsin

A six-stage sequential leaching procedure was used to assess the leachability of heavy metals from waste rock in Antamina Mine. Sequential extractions procedure is well established for fine and small (? 1g) samples. However procedures for coarse and large test samples are lacking. This study presents results of the sequential leaches tests conducted on relatively coarse and large representative samples in terms of the availability and mobility of metals. Selective chemical reagents were used to extract metals from six different fractions where metals released with each subsequent extraction are believed to be bound tighter than those released in prior steps and therefore less likely to be leached.

Aug 1, 2013

By R. P. Viljoen, A. L. Sokolov

"The distribution of mineralized provinces is analyzed on the basis of their genetic link with specific blocks of the earth's crust including ancient platforms, mobile belts and zones of tectonicmagmatic activation. Mobile and fold belts surround the Siberian platform in Russia and the Kaapvaal craton in South Africa, with decreasing age zoning away from ancient platform margins. The main differences in the geological development of the two cratonic areas are: (1) the long period before the final stabilization of the Siberian platform (3600 Ma to 1600 Ma) and the comparatively short period of time for the stabilization of the Kaapvaal craton (3600 Ma to 3050 Ma) and (2) the intensive multiple activation of the marginal zones of the Siberian platform and the tectonicallycontrolled, magmatic sedimentary, intracratonic activity, typical of the Kaapvaal craton. Mineralization of the Siberian platform is largely characterized by marginal reactivation zones of differing ages although mineralized intracratonic Cu-bearing basins of Proterozoic age are also known. Mineralization of the Kaapvaal craton is mainly related to the formation of the intracratonic basins i.e., Witwatersrand (Au, U) and Transvaal (Au). The latter is characterized by multi-age volcanic-intrusive activity including the emplacement of Bushveld Complex (Cu, Ni, Pt, Cr, Au, V). The Siberian platform is characterized by the prolonged development of inherited mineralization from Archean until the late Mesozoic. The main period of mineralization in the Kaapvaal craton is restricted to the middle Proterozoic.The Baykal-Patomskaya and Namaqua-Natal mobile zones occupy similar positions adjacent to the Siberian and Kaapvaal cratons, respectively, and demonstrate similar modes of metallogenic development: i.e., the early formation of exhalative Pb-Zn-Cu deposits during the early stage and magmatic Cu deposits during the late stage. The more remote mobile belt near the Siberian platform, the Trans-Baykal, is characterized by intensive multi-age mineralization (Wo, Mo, Sn, fluorite), related to a period of tectonic-magmatic activation. The Saldania Belt occupies a similar position near the Kaapvaal craton but is known for its poor Au, and Cu mineralization. It does, however, have some similarities with Trans-Baykal Belt in regard to Mo-W bearing granitoids.The phenomenon of interference of geosynclinal, orogenic, platform, and tectono-magmatic activation regimes is known for the Russian section of the Pacific Ocean Volcanic Belt."

Jan 1, 1994

By Simon C. Dominy, Alwyn E. Annels, Mark A. Noppé

Abstract - Mineral Resources and their subsequent conversion to Ore Reserves are of key importance to mining companies. Their reliable estimation is critical to both the confidence in a feasibility study, and also to the day-to-day operation of a mine. Together with sampling, assaying, geological and other errors introduced during interpretation and estimation, additional errors are likely to be introduced during the application of technical and economic parameters used for conversion of resources to reserves. There is thus a requirement for high-quality interpretation and estimation to be supported by high-quality data. Any company expecting to make sound investment or operational decisions must base this on both relevant and reliable information. An Ore Reserve statement generally contains a single set of grade and tonnage figures without a discussion of the potential inherent errors in these estimates. Some sensitivity studies may be run, but confidence limits are rarely quoted and, if they are, often do not take into account many of the factors that cause uncertainty in the grade and tonnage estimates. Mineral Resource and Ore Reserve estimates thus carry certain errors leading to uncertainty and risk; some of these are unquantifiable for various reasons, for which the operator should be aware. This paper presents a review of the potential sources of error that might occur during a resource estimation program, which are carried through into the reserve estimate. A number of methods are discussed that allow the estimator to be more transparent about the inherent risks in his/her estimate. Emphasis is placed on data quality, and the requirement for strong quality management to be linked to continuous improvement.

Jan 1, 2002

By C. Paulo, W. N. Wheeler, M. Kalin, M. P. Sudbury

Many researchers have tested the addition of various phosphatic materials, including Natural Phosphate Rock (NPR), to mining wastes. It was assumed that iron in the waste would form FePO4 precipitates, restricting oxygen access to pyrite surfaces and reducing oxidation. Phosphate additions were based on stoichiometry (phosphate mass to sulphide content of waste). Although some interesting, positive results were obtained with low dosages, these were considered accidental, not having followed the expected stoichiometry. In 1991, we began experimenting on tailings and waste rock with NPR, postulating that if chemo-lithotrophic microbes on the mineral surface accelerate oxidation, then heterotrophic (oxygen-consuming) microbes would reduce oxidation. All wastes with NPR produced effluents with elevated pH and low metal acidity. Later, microscopic investigations of the rocks found an organic layer on the mineral surface, which was confirmed by independent research organizations repeating experiments with very low NPR mass additions to sulphidic wastes. In 2013, heterotrophs were identified and quantified as they grew on German lignite with NPR. These data conclusively showed that the development of heterotrophic biofilms is a consequence of adding waste NPR leading to a reduction of sulphide oxidation and improved effluent from sulphidic mining wastes. We document our gradual understanding of the effects of NPR on the reduction of sulphide oxidation, covering 23 years of research.

Jan 1, 2014

"In today’s world of complex projects, where engineering and execution are supported by a high level of project management and systems, how critical is the human factor in design engineering. Based on his involvement on a variety of projects, Tony Lipiec will relate his experiences as the impact of 4 factors: the ‘team’ involved in the design and execution of the project; the project and information systems supporting the project; the impact of scope, time, and budget; and finally the selection of the proper success criteria to judge the project and the people who have enacted the project.The discussion of the team will relate to the quality of people and the impact of their knowledge, attitude and experience. It will also look at the relationships and interests of the various stakeholders. Decision making and taking responsibility will be discussed.Supporting the team are the management, document and information systems. The value that these systems bring to the project as a whole will be examined. How project size impacts the applicability of the systems will be discussed.Scope, time and budget are recognized as critical. Reference will be made to the interplay between these components which are vital to project success. The issue of iterative design and whether it is necessary will be considered together with the development of supporting technical information.Finally the selection of the proper success criteria and the awards provided to the team can have a big impact on the final, production success of the project. The author will discuss his views on the impacts of these on EPCM projects."

Jan 1, 2016

By K. Bunney, R. Pleysier

The deportment of a suite of elements through representative gold ore processing unit operations in cyanidation has been investigated. Chromium and lead are not soluble in alkaline cyanide solutions. Arsenic, antimony, cobalt, molybdenum, selenium, tellurium and vanadium are soluble, but typically do not adsorb onto activated carbon to any appreciable extent. Silver, copper, cadmium, mercury, nickel and zinc to varying extents report along with the gold to the carbon eluate. Cadmium, mercury and zinc can report to the carbon regeneration kiln off-gases. Strontium is soluble and adsorbs on carbon where it remgins.

Jan 1, 2011

By Chin J. Chang

Powder metallurgy (P/M) technique is known for its capability of producing near-net-shape parts. Its specific characteristics have resulted in low cost and eliminated of many secondary machining. However, more and more P/M parts do require additional operations to fulfil their complex geometric features and surface roughness. Many of the machining factors that influence the machinability of cast and wrought steel parts, such as cutting speed, feedrate, coolant, tool geometry and shape, are also considered in the machining of P/M components. The special feature in P/M structure is the porosity that can decrease the machinability and shorten the tool life. Different variables have been considered in the machinability of P/M materials. Densities and the free machining additive manganese sulphide (MnS), are the two main factors of material composition, which dominate the P/M machining performance. Machining process is the main method that generates the desired working surface of machining components. This paper will discuss the metallurgical structure of the powder metallurgy components, their physical properties and possible issues when encountering machining operation. Turning operation has been tested in this investigation to show the relationship between the cutting speed, federate, cutting forces and chip formation. This investigation also discusses how the free machining additive, manganese sulphide, affects the P/M structure and machinability in order to understand how the metallurgical structure can affect the machining operation and, how to obtain the optimised surface results.

May 1, 2001

IBI Alliances ? Government ? People ? Academic ? Associations ? Media ? Customers ? Agencies ? Shareholders ? Industry consultants ? Investment Authority ? Geological Survey ? Department of Mines ? People ? Local Residents ? Mineworkers ? Academic ? University of Guelph ? Uganda Vermiculite Institute ? Associations ? TVA ? Organic Certification ? Media ? Canada ? International ? Customers ? Advocacy role ? Agencies ? Regional International

May 1, 2006

By G. Simard, D. Boudeville, A. Leclerc, A. Boivin

"The objective of this work is to study the various parameters that affect the overflow clarity of gravity settlers used in the precipitation circuit of alumina hydrate from the Bayer process. A mathematical model incorporating the size distribution of the feed suspension (Multi Size Group model), its diphasic nature (Schiller Naumann model) and the presence of turbulence (Shear Stress Transport model) has been solved numerically using ANSYS-CFX software. Preliminary results indicate that the overflow clarity is mainly controlled by lateral diffusion of fine particles (~20µm) from the exit of the feed well and by their upward transport from the sediment bed interface. Also the turbulence pattern in the settling zone seems to play a significant role in this vertical transportation. The validity of the model has been verified by comparing the measured solid concentrations from a pilot classifier with the calculated ones. This model could provide mineral processing plant operators and designers with a tool to optimize the configuration of classifiers with respect to the overflow clarity.INTRODUCTIONProblemIn the Bayer process, alumina hydrate precipitation from the saturated liquor is initiated in settler by adding crystallization seeds. Most of the precipitated alumina settles to the bottom of the tank while the liquor and the remaining alumina rise to the top, where they are removed at the overflow. Ideally the overflow clarity, which depends on the operational mode of the classifier, should be controlled within targeted limits."

Jan 1, 2016