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By M. Fooladi Mahani, M. R. Izadpanah

The knowledge of the thermal shock resistance of refractory materials is of outmost importance due to their wide range of applications in various industries, namely; ceramics, oil refinery, thermal insulation, nuclear power, chemical and petrochemical industries. Thermal shock resistance is measured in terms of the number of cycles that a refractory material can withstand when subjected to sudden temperature changes. This property is measured experimentally by heating a sample of the material and cooling it in a known environment then the number of cycles it withstands this treatment without spalling is a measure of its thermal shock resistance. Although this method of experimentation has long been the practice, but it is both expensive and time consuming. Various studies have been carried out to predict this vital property, however, the rang of applications are limited. The present study employs a test rig by which temperature distributions in magnesite samples are accurately measured. This information plus other results obtained from relevant tests on related properties are used to develop a model which predicts the number of quench cycles withstand by different materials when subjected to sudden temperature changes. The comparison of the theoretical values using the solution of the presented model with experimental data for different materials having different thermal resistance shows a closed agreement.

Jan 1, 2004

By Par G. Jönsson, Joachim von Scheele, D. S. Sarma, Mukul Goyal

Dust from flue gas cleaning systems at iron and steel production is frequently considered as a waste problem, but it is actually a potential raw material source. By using a technology like the oxyfuel based OXYFINES technique, it can be melted into a suitable form. The product from this processing, however, needs to meet the requirements of a recyclable raw material, here particularly a top-charged blast furnace feed. The present work has been focused on characterization of the product produced from these dusts by OXYFINES technology. The investigation has been carried out on samples of processed dusts from a European integrated steel mill. It was done by means of chemical analysis, density measurement, light optical microscopy, X-ray diffraction, scanning electron microscopy combined with energy dispersive spectroscopy, and micro indention hardness measurement. Special attention was paid to the presence of zinc, an element that might be harmful while recycling the material (e.g., in a blast furnace). The results show that the product contains four different regions with different morphologies and properties in the material, which are discussed in detail. The overall conclusion is that by processing the dusts in this way, a raw material suitable for recycling in a blast furnace can be obtained.

Jan 1, 2004

By D. A. Livingstone

"INTRODUCTORY REMARKS BY PANEL CHAIRMAN - D. A. LIVINGSTONEThe mining industry has progressed significantly from the dusty mines and mills of decades past to the modern processing complexes of today, and improved technology has made great strides in eliminating debilitating lung discuss. More recently, the public's environmental awareness is also working to enforce more stringent regulations and controls in tl1e matter of dust in working places.There are numerous excellent texts and handbooks outlining the principles of collection of dust produced in the various unit operations entailed in the crushing, screening and the transport of ore. However, it is painfully obvious that dust emanating from belt return idlers and scrapers, take-up pulleys, skirting, larger and deeper chutes, clean-up operations, etc., which I choose to refer to as fugitive dust, presents some seemingly unmanageable difficulties, or at least difficulties inordinately costly to correct. Possibly static electricity is adding to the difficulties. In my view, these problems are magnified in many of our B. C. operations where ore from open pit mines in cold climates is frequently crushed in unheated buildings, thereby precluding the simple and obvious use of water sprays for dust suppression.It is hoped that the presentations and discussion which follow will emphasize some of these unusual problerr.s and suggest corrective measures, either tried or planned."

Jan 1, 1976

By N. Maleki

In recent years, research and development of magnesium alloys have been greatly promoted by the lightweight requirements in critical industries. The use of these alloys, however, has been restricted by their limited mechanical properties especially at high temperatures. The disadvantages can be overcome by producing Mg matrix composites. The Mg?Si alloys containing in situ Mg2Si particles have found a great potential as structural materials. Unfortunately, Mg2Si compounds are prone to form undesirable coarse Chinese script morphologies, which would deteriorate the properties of the materials. Refinement of microstructure is performed for improvement of wear and corrosion resistance. This paper investigates the microstructure and corrosion behavior of pure magnesium, unmodified and modified magnesium matrix composites reinforced with Mg2Si particles. The Mg2Si/Mg composite was prepared via a normal cast route, and then various amount of zinc was added to melt in order to modify the Mg2Si reinforcement particle morphologies. The microstrucrures were characterized by optical and scanning electron microscopy followed by EDX analysis. The corrosion behavior of Mg/Mg2Si composite was investigated by using potentiodynamic polarization measurements. The results showed that by addition of zinc, the average size of the primary Mg2Si became significantly decreased from about 100µm to about 20µm, as well as its morphology changed from dendritic to a polyhedral shape. However, by adding extra amount of zinc many primary Mg2Si particles become coarse again. It was also found proper amount Zn addition increased the corrosion resistance of Mg/Mg2Si composite.

Oct 1, 2011

By R. Pelletier, Herny. E., C. Allaire

Corrosion of refractory linings by molten metals is controlled by interactions between penetration and chemical reaction. Corrosion of aluminosilicates by molten aluminium is no exception. The early stage of corrosion can be described as a particular case of reactive wetting over a porous medium. Although the reactivity between aluminium and silica is great, which should improve wetting and penetration, the presence of air and the formation of a protective oxide layer disfavours initial penetration. This paper presents the results of an exploratory study on the effect of some parameters on the initial stage of aluminium penetration. Penetration kinetics and metal intrusion tests have been performed on alumina and silica powders with pure aluminium and Al¬5%Mg. Capillary models are used as tools of interpretation. Penetration kinetics tests had a poor reproducibility and the kinetics itself can not be explained very well by the capillary-tube-bundle model. On the other hand, a capillary model initially developed for ice intrusion into freezing soils produced predictions in reasonably good agreement with intrusion pressure measurements. The effect of particle size and alloy composition can be predicted using this model. However, the effects of temperature and powder chemistry need additional interpretations to be rationalised. An unusual resistance to penetration of silica powder by molten aluminium have been observed in a series of experiments. This led the authors to the strange conclusion that oxygen should be seen as an excellent non-wetting agent and that there might be ways to use it in industrial applications.

Jan 1, 2004

By Pieter van Nierop

Outline ? What is gasification? ? Gasification Technologies ? Gasification ?The early years ? Gasification ? The last decade ? The Alberta Situation ? The Importance of Gasification in Alberta ? Polygeneration ? Development ? Conclusion

May 1, 2004

By Heinrich Möller

The electro-oxidation of 0.1 M ethylene glycol at gold, platinum and gold-platinum alloy electrodes in different heat treatment conditions has been studied in 0.5 M NaOH, at room temperature. Poisoning of all the electrodes occurs. However, the alloy electrodes poison at a faster rate than the pure gold and platinum electrodes. This indicates that the initially higher activity of these electrodes cannot be the result of decreased poisoning through a "third-body" effect.

Oct 1, 2003

By V. I. Birss

Planar solid oxide fuel cells (SOFCs) offer great promise as stationary power generation devices, primarily due to their flexibility in terms of fuels, high energy conversion efficiency (when both electricity and heat are captured), and their relatively low fabrication costs. However, the anode performance can be compromised by such factors as exposure to certain sulfur-containing fuels and the deposition of coke when using hydrocarbon fuels. In terms of the cathode, its performance is limited primarily by the slow kinetics of the oxygen reduction reaction, while its lifetime can be negatively affected by factors related to the corrosion of currently used stainless steel interconnect materials. This talk will present an overview of these challenges and some possible solutions to these problems. The presentation will also focus on how electrochemical methods can be used to evaluate and improve the performance of SOFC anodes, cathodes, and interconnect materials. In addition, recent promising research efforts directed towards performance enhancement of SOFCs through the use of nanoscale electrocatalysts will be discussed.

Jan 1, 2005

By Jennifer Young

Presentation Outline ? Introduction ? Aboriginal Inclusiveness ? Common interpretations, practices ? Aboriginal Community Expectations ? Lessons Learned ? Native Code of Conduct Introduction Jennifer Young ? Nestu'et (Mi'kmaq) means: becoming wiser, becoming more knowledgeable Aboriginal Inclusiveness ? Internal hiring strategies (affirmative action) ? Incorporating cultural awareness programs ? Approaches in governmental/organizational policy development Practices in negotiating economic development and fiscal sharing strategies

May 1, 2010

By Bruno Bussière

Acid Mine Drainage (AMD) from mine wastes is one of the most environmental challenge currently facing the mining industry. AMD is the result of the natural oxidation of sulphides exposed to air and water. When mining wastes have the potential to produce AMD, these reactive wastes have to be managed to meet existing environmental regulations. The LTA site (property of Barrick Gold Corp.) contains sulphide tailings that have the potential to generate AMD. The closure option Barrick selected was to construct a multilayered cover with capillary barrier effects (CCBE). The main objective of this CCBE is to prevent the production of Acid Mine Drainage (AMD) from the tailings stack covering an area of approximately 60 ha. Since its construction in 1996, the cover has been monitored to evaluate its performance. Two of the measured parameters are volumetric water content and matrix suction. This paper presents some of the main results from the monitoring program that started seven years ago. The results show that the cover is largely able to maintain a high degree of saturation (greater than 85%) in the moisture-retaining layer. The actual performance of the CCBE on the flat surface of the 60 ha site is even better than expected at the design stage. The area that requires more specific attention with the LTA cover is the influence of slopes that can reduce the performance of the CCBE during dry periods. However, these effects seems to be local and do not significantly affect the overall performance of the CCBE to mitigate the production of AMD at the LTA site.

May 1, 2003

By Réal Marcotte

L'industrie minière représente un apport économique important pour le Québec ; cette production est très diversifiée et répartie dans plusieurs régions. Hormis les forges du St- Maurice au XVIIe siècle, l'industrie minière québécoise commence en 1862 dans la Beauce avec l'exploitation de placers aurifères dans les affluents de la rivière Chaudière; à la même époque, on met en production les mines de cuivre Eustis, Albert et Capelton, près de Sherbrooke1; à partir de 1881, les mines d'amiante et de chromite au voisinage d'Asbestos et de Thetford commencent à voir le jour. Dans les années ?20, l'extraction de métaux précieux et usuels débute en Abitibi- Témiscamingue; durant les années '50, le fer et l'ilménite de la Côte Nord, ainsi que le cuivre de Murdochville et Chibougamau, commencèrent à être mis en valeur. Plus récemment, soit durant les années '80, le sel des Iles-de-la-Madeleine et le graphite des Hautes Laurentides s'ajoutèrent aux produits que nous commercialisons. Finalement, soit en 1998, le Québec devenait un important producteur de nickel avec le démarrage de la mine Raglan, au Nunavik. L'exploitation d'une mine peut nécessiter l'extraction de grandes quantités de roches stériles, particulièrement lorsque la production se fait à partir d'une fosse à ciel ouvert. De plus, étant donné que les minéraux et les métaux mis en marché ne constituent qu'une fraction du minerai extrait, il faut le concentrer : on se retrouve alors avec des proportions plus ou moins importantes de résidus finement broyés. Ces deux types de rejets totalisent bon an mal an environ 100 millions de tonnes. Lorsque cela est possible, ceux-ci sont, soit valorisés comme matériaux de construction ou retournés dans leur lieu d'origine afin de soutenir les murs des excavations. Toutefois, une bonne partie est accumulée en surface dans des aires aménagées spécifiquement à cette fin ; comme le montre la figure 1, la superficie utilisée à cette fin a progressé parallèlement aux booms miniers que nous venons de mentionner pour atteindre actuellement environ 15,600 hectares, dont environ la moitié sont situés sur des aires encore en activité.

Nov 1, 2002

By Z. D. Hora

Of four main gypsum areas in the province, commercial production has only come from Falkland and the Kootenay and Columbia River valleys of southeast British Columbia. The Windermere deposit in southeast B.C. has been the major producer since /948. Gypsum and anhydrite from the Falkland deposit is used principally in cement-making at Kam/oops. GYPSUM deposits in British Columbia are known from four different areas: the southeast part of the province in the proximity of the Kootenay and Columbia River valleys; Forgetmenot Creek astride the British Columbia - Alberta boundary near Intersection Mountain; Falkland; and O'Connor River north of Haines . To date, commercial production has only come from Falkland and the southeast part of the province. Gypsum deposits of southeast British Columbia occur in the Burnais Formation of Devonian age. Outcrops of gypsum and numerous sinkholes indicating its presence are scattered over large areas of the Stanford Range. Several properties have been examined by industry in both the recent and more distant past. Significant production is reported from only two deposits. The Mayook deposit, active from 1926 to 1929 and from 1947 to 1954, produced approximately 95,000 tonnes of gypsum. The Windermere deposit, which has been active since 1948, is operated by Westrock Industries and has produced more than 6.8 million tonnes of gypsum. The Burnais Formation is composed principally of well bedded, finely 'laminated gypsum but also contains thin lenses of black fetid limestone and dolomite. Part of the Formation consists of breccia with angular carbonate clasts in massive, coarse grained gypsum. In several exposures, the Formation appears 10 be from 200 10 400 m thick, of which more than 75 Industrial Minerals in Canada per cent is gypsum . In the Stanford Range reserves mineable by quarry methods are estimated to be approximately 450 million tonnes.

Jan 1, 1984

By N. Maleki

Magnesium matrix composites are widely used in automotive and aerospace industries for achieving higher performance due to their light weight. The Mg2Si intermetallics compound in Mg/Mg2Si composite exhibits many excellent properties such as high melting temperature, high hardness, and low thermal expansion coefficient. However, under normal cast conditions, the primary Mg2Si phase exhibits coarse Chinese script or dendritic morphologies and the eutectic structures is very brittle resulting in the low ductility and strength of the alloys. Modification treatment is a very effective method to obtain fine microstructure and improve the mechanical properties of the alloys due to low production cost. In this investigation various amount of bismuth addition have been carried out on Mg?5wt %Si alloy to refine and modify the morphology of coarse Mg2Si in order to improve the corrosion resistance of the composite product. The effect of Bi content on microstructure of Mg2Si/Mg composite was investigated by optical and scanning electron microscopy followed by EDX analysis and X-Ray diffraction. In order to compare corrosion resistance of unmodified and modified specimens, Immersion test and potentiodynamic polarization (PD) were used. The results showed that by Bi addition, the size of primary phase Mg2Si was considerably reduced and the morphology was modified from a coarse dendritic shape to a polyhedral shape. The results also indicated that the corrosion resistance of Mg?Si alloys was improved by the addition of 1%wt of Bi due to the reduction, refinement and evenly distribution of Mg2Si phase. Indeed, both the morphology and distribution of Mg2Si intermetallic had a great influence on the corrosion behavior of Mg/Mg2Si composite.

Oct 1, 2011

By T. T. Chen, J. E. Dutrizac, G. Poirier

In the Waelz kiln process, EAF dust is converted to an Fe-rich slag, a (Zn, Fe)-rich dust that is recycled to the kiln and the Zn-rich Waelz oxide which is subsequently up-graded for the recovery of zinc. To clarify the reactions occurring, the Waelz kiln products from a European Waelz plant were characterized mineralogically to determine the mineral species present, their micro-textures and the metal carriers. The EAF dust contains 27 % Zn, and consists mainly of ZnFe2O4 and ZnO, together with minor to trace amounts of NaCl, PbCl2, KCl, CaO, Ca2Fe2O5, Fe203, FRO, Pb oxide and various Ca-Fe-Al-Mn silicates. The KCI and NaCI sometimes agglomerate the other particles. The slag consists of nodules which often exhibit colloform structures. The slag contains of variable amounts of Fe, FeO(OH), FeO, gypsum, Ca(OH)2, Ca2SiO4 and various Ca-Fe¬Al-Mg-Mn silicates as well as minor to trace amounts of ZnFe2O4, Cr-Fe oxide, Mn-Fe oxide and other species. The Waelz oxide contains 57-61 % Zn, and consists predominantly of ZnO, with minor to trace amounts of KCI NaCl, Pb(OH)Cl, Pb20(SO4), Pb chloride, ZnSO4, ZnFe2O4, Ca2SiO4, Ca2Fe2O5, Ca-Fe silicate and NaZn4(SO4)(OH)6Cl.6H2O. The KCI agglomerates the other particles in the Waelz oxide. The recycled dust appears to be a mixture of EAF dust and Waelz oxide, but it contains relatively more coarser-grained metallic Pb and Pb oxide particles.

Jan 1, 2004

Grinding with an electrochemically inert grinding media (i.e. high chrome white iron, or Magotteaux’s Duromax® alloys) shifts the pulp potentials to more oxidising conditions, increases the dissolved oxygen content and reduces the EDTA extractable iron concentration when compared with milling with electrochemically active grinding media (forged steel). These changes in pulp chemistry produce cleaner particle surfaces, reduce reagent consumption and increase concentrate grades and recoveries. This paper presents a robust laboratory test program that is able to not only demonstrates these effects but also provide an indication of the magnitude of the improvements that are possible. While laboratory studies are interesting, the proof is in the pudding! So, the paper provides an overview of plant trials conducted at a number of operations around the world, including: Newcrest’s Cadia Operation, Oz Minerals’ Prominent Hill Mine and Glencore’s Ernest Henry Mine. These successful plant trials clearly demonstrate that selection of the right grinding media alloy will yield savings in grinding media consumption and reagent consumption as well as increases in revenue through improved copper, gold and molybdenum recoveries. INTRODUCTION The key to a successful separation in mineral processing is the preparation of particles with adequate liberation under the correct pulp chemical conditions. While the importance of liberation on flotation separations is generally understood and well documented in the literature (Johnson, 1987; Jackson, Sutherland, Gottlieb & Quittner, 1989; Young, Pease, Johnson, & Munro, 1997; Greet and Freeman, 2000), the importance of pulp chemistry is more nebulous, particularly with regard to the impact of grinding media. Extensive work examining the electrochemical interactions between grinding media and sulphide minerals has been completed (for example, Iwasaki, Reid, Lex & Smith, 1983; Natarajan and Iwasaki, 1984; Yelloji Rao and Natarajan, 1989(a); Yelloji Rao and Natarajan, 1989(b)). Broadly, these studies indicate that most sulphide minerals are more noble than the grinding media used during comminution, therefore a galvanic couple between the media and the sulphide mineral(s) exists, which increases the corrosion rate of the grinding media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulphide minerals thereby affecting their floatability (Johnson, 2002).

Jan 1, 2019

By Linruo Zhao, Qi Yang, Akihiro Sato

TiN coating has a wide range of tribological applications from wear reduction of cutting tools to erosion protection of gas turbine engine compressor components. The performance of TiN coating depends on its microstructure, mechanical properties and adhesion strength which are influenced by the coating deposition process. In this study the effects of cathodic arc deposition conditions on the microstructure, hardness, adhesion and erosion resistance of TiN coating were investigated experimentally. It was found that varying deposition temperature, substrate bias and N2 pressure could derive a processing window in which TiN coating with superior erosion performance can be fabricated.

Jan 1, 2010

By Amin Jafari

Macrosegregation has always been an important issue with the solidification processes, particularly in Direct-Chill Casting of Aluminum alloys, where uneven properties, surface and bulk defects and limitations in productivity can be arisen due to macrosegregation in the cast product. Following the global attempts to practically predict the macrosegregation, in the present work, a numerical model was developed based on an industrial scale DC casting process to simulate the solidification and macrosegregation in an Al-4.5%Cu billet. Interesting aspects of this investigation are concerned with an efficient numerical scheme to keep simplicity, consistency and desired physical resolution of the solidification phenomena together. In the mathematical model, coupled conservation equations of mass, momentum, energy and species were solved numerically using finite volume method. A different numerical scheme, called SIMTLE, was introduced to link the energy and species equations with the phase diagram of the alloy. Calculations were performed on an industrial case and obtained results were compared to available experimental data to assure the performance of the model. Different macrosegregation features were predicted and discussed on the solidifying Al-alloy billet.

Oct 1, 2011

By Geoff Goodyear

UHNL Corporate Profile ? Providing Helicopter Services since 1963 ? A Newfoundland Company head-quartered in Goose Bay, Labrador ? Operations, while primarily Atlantic Canadian, extend across Canada, the Arctic, Greenland ? 16 aircraft, all single engine / VFR Typical Industry Mission Profiles & Work Environments ? Types of missions include: ? Air Taxi & Executive Transport ? Mineral Exploration ? Forest Fire Suppression ? Medivac ? Wildlife Management & Research ? High Angle Rescue and Ice Blasting ? External Load & Long Line ? Mountainous Terrain Operations ? Aerial Application ? Power line Patrols & Construction The Helicopter ? Essentially the same aerodynamic principals as fixed wing but with some mechanical variations on the theme

May 1, 2001

By Z. D. Hora

has been no commercial production of either perlite or pumice in British Columbia. Several promising occurrences are known to exist but their development has been delayed due to difficult access and / or remote locations. The Empire Valley perlite deposit is located 120 km east of Clinton. The deposit appears to be a flat-lying volcanic flow 50 to 70 m thick that is part of an Eocene rhyolite and dacite volcanic assemblage. The Francois Lake perlite deposit occurs on the north shore of Francois Lake where perlite is part of a rhyolitic volcanic sequence. The exposure of perlite is about 13 m thick and is considered to be Eocene or Oligocene in age. The Uncha Lake perlite deposit is located about 5 km south Industrial Minerals in Canada of Uncha Lake. Perlite appears to be intercalated with porphyritic rhyolite flows that are comparable to those at Francois Lake. Showings are widespread but poorly exposed and thicknesses are unknown. The Mount Meager pumice deposit is located in the Lillooet River valley at the base of Plinth Mountain. Coarse pumice agglomerate forms a large talus slope that is undercut by the river. Unsorted, angular fragments up to 50 cm in diameter are intermixed with up to 30 per cent of sand and silt-sized particles. The exposed zone is about 200 m long and 50 m high; it is being considered as a source of lightweight aggregate.

Jan 1, 1984

By Isabelle Demers, Audrey Jalce

L’industrie minière génère chaque année une quantité considérable de rejets miniers, principalement sous forme de stériles ou de résidus de l’usine de traitement. Les stériles sont des roches sans valeur économique, excavées pour atteindre la roche minéralisée. Ils sont usuellement empilés en surface formant des haldes à stériles. Les résidus miniers sont des roches finement broyées, mélangées avec de l’eau, résultant du traitement du minerai. Ils sont généralement pompés et entreposés en surface dans des parcs à résidus. Cependant, leur stockage peut être sujet à des instabilités géotechniques, mais également géochimiques, pouvant entrainer des problèmes environnementaux majeurs, tels que le drainage minier acide (DMA). Le DMA se produit lorsque des minéraux sulfureux, contenus dans ces deux types de rejets, s’oxydent au contact de l’eau et de l’oxygène [1]. Le DMA se caractérise par une solution acide (pH inférieur à 6) riche en métaux, contaminant les eaux souterraines et de surface et représentant alors un danger pour la faune, la flore et la santé humaine [2]. La remise en état et la fermeture des sites miniers doivent donc être pensées dès la phase d’étude du projet d’exploitation, afin de proposer une méthode de gestion des rejets qui permettra de limiter les impacts environnementaux pendant et après l'exploitation.

May 2, 2024