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By lves Matiolo, Jorge Rubio, Carlos Perez Guerrero, Denise G. Nunes, Fabiano Capponi

The problem (very old) of processing by flotation, the fine (“F”, 38-13 µm) and ultrafines (“UF”, < 13 µm) mineral particles continues to be a major technical challenge in the area of mineral processing. Many different processes have been proposed over the last three decades but, unfortunately, most of them have not found practical applications yet. This paper describes some advances in flotation research in fines (“F”, 38-13 µm) and ultrafines (“UF”, < 13 µm) mineral recovery by two different techniques. Extender flotation (EF) and flotation with bubbles with a wide size distribution-SB of copper sulphide ore fines (1 % Cu) were compared with a “standardised” (STD) mill laboratory procedure. Comparative evaluation was made through concentrate grade and recovery (size by size results included), “true” flotation recoveries and process kinetics. Copper porphyry samples, containing about 1/3 of the mass and about 37 % of the total copper content in the fines and ultrafines fractions were used. In the EF tests diesel-in-water emulsions were used as an extra reagent, added after the collector and frother addition. In SB tests, drawing air through an aspiration nozzle, directly in the pulp, generated bubbles sized about 50-200 µm. Both techniques yielded higher metallurgical efficiencies than the mill standard but better results were obtained with the extender flotation, with emulsified diesel oil (90 gt-1). Concentrate recoveries were of the order of 85-90 % (84 % in standard conditions), 14-17 % Cu grade (15 % Cu in the standard) and 3.5-4.5 min-1 for the Klimpel rate constant (3 min-1 in the standard). Size by size and true flotation results proved that metallurgical and kinetic gains, obtained with the two techniques, might be attributed to fines and ultrafines enhancement. Data obtained are discussed in terms of physical and physicochemical parameters related to aggregation and capture (of particles by bubbles) phenomena and the practical potential of these techniques are envisaged. The following figure shows size-by-size copper recoveries results, after classification of produced concentrates and tailings using micro-sieves. Results clearly show that flotation of the F and UF fractions is highly improved with injection of small bubbles (SB) and with the addition of an extender collector. It is believed that the techniques presented here will establish shortly a new basis for the flotation enhancement of the F and UF, aimed at solving a very old problem. This work is being continued, now at pilot plant scale, and results will be published en the near future.

Jan 1, 2003

By Seher Ata

This paper is concerned with the coalescence behaviour of two bubbles in dilute solutions of cetyltrimethylammonium bromide, methyl isobutyl carbonil and triton x-100. Two bubbles were produced at the tips of adjacent capillaries and the time elapsed between the first contact of the bubbles and film rupture was determined by means of a high speed camera. It was found that the amount of surfactant required to stabilise the bubbles increased in order of CTAB>TX-100>MIBC. The probability of coalescence decreased sharply with increasing surfactant concentration in CTAB and TX-100 solutions while with MIBC each bubble pairs resulted in coalescence, giving hundred per-cent coalescence probability.

Jan 1, 2014

Mineral flotation is effective over a relatively narrow particle size range of approximately 10 µm to 150 µm. If the upper particle size limit can be increased, however, a run-of-mine ore may be coarse ground, and only the middlings are ground further to achieve required grades. This will result in significant energy savings and increased throughput. In this communication, methods of increasing the upper particle size limit will be discussed on the basis of a flotation model that can predict flotation from both hydrodynamic and surface chemical parameters. An example of increasing flotation recovery by control of a chemistry parameter is given.

Jan 1, 2014

By Kang N. Zhong, Hui H. Luo, Yi H. Wei, Yu L. Wang

"More than 85% of phosphorous reserves in China occur as middle-low grade phosphate of sedimentary origin. The main gangues are dolomite, quartz, silicates, and clays. The characteristics of minerals are finely disseminated. Flotation results have shown that the floatability of apatite of this kind of ore is much worse than that of igneous and metasedimentary origin because of its high specific surface area. Although some effective depressants, such as naphthalene sulfonate and phenanthrene sulfonate, are used to decrease the MgO content in the P2O5 concentrate, its presence is still high (about 2%) in the Chinese concentrates. Meanwhile, the wastewater may cause some environmental problems. Batch flotation results and measurements of specific surface area and CO3 2- have revealed that there is a relationship between the floatability of apatite and the surface area.A two-stage flotation flowsheet, which includes a combination of direct and reverse flotation, was developed for beneficiating sedimentary phosphate ores. The direct flotation was conducted in an alkaline medium and most of the apatite and carbonate minerals floated leaving quartz and siliceous gangue in the sink. In the reverse flotation circuit, the floated product was further beneficiated in an acidic medium to eliminate the carbonate as a float product. Apart from the high quality of concentrate, the two-stage flotation also facilitated the treatment and the recycling of wastewater. A wastewater recycling procedure was developed and tested in a continuous flotation process. The key factor was the careful selection of effective and non-toxic reagents."

Jan 1, 2003

By V. A. Luganov

The processing of pyrite concentrates may be accomplished with a preliminary enrichment due to withdrawal of iron sulfides from initial concentrate. The withdrawal of iron sulfides is possible with the help of magnetic separation when the magnetic iron sulfides (pyrrhotites) separate from non-magnetic fraction?the sulfides of non-ferrous metals. The conversion of non-magnetic pyrite to magnetic pyrrhotites of adjusted structure occurs because of roasting with the withdrawal a part of sulfur. The resultant pyrrhotites are strong ferromagnetic with hexagonal structure. This paper contains results of studying magnetic properties of pyrrhotites, findings of the de-composition of initial pyrite with the consequence homogenizing of product and hardening of product of decomposition in liquid nitrogen. Define the type of pyrrhotites super lattice structure, was established that at increasing of sulfur contention the magnetic properties of pyrrhotites are change ? pyrrhotite begin evince the properties of antiferromagnetic material and magnetic susceptibility of material is interruptive changing from 0 to 1.7×10-3~1.9×10-3 SI units/g system. The paper contains results of technological researching of pyrrhotizing-magnetizing roasting of pyrite concentrates in different condition: in unoxidizing, with the decreasing contention of oxygen and in autogenous regime in air atmosphere. Established that the magnetic susceptibility of products depend of pyrite degree dissociation and achieve 2×10-3~3×10-3 SI units/g system at 40%~45% desulphurization. Defined the conditions of steady regime autogenous roasting, at resultant products possess coefficient of magnetization, and this can be used magnetic separation for separating ferromagnetic pyrrhotites from gangues and non-magnetic sulfides of non-ferrous metals. This technology of pyrrhotizing roasting is recommended for effecting in industrial condition. The initial materials and products of roasting subjected to chemical, thermogravimetric, Moss-bauer spectroscopy and X-ray analysis, defined the magnetic properties.

Jan 1, 2014

The effect of the acid anion on chalcopyrite (CuFeS2) leaching has been examined, under care-fully controlled conditions, in a range of acids in stirred reactors and columns at pH 1. Solution speciation calculations were performed to determine possible rate controlling species. The relative leach rates of Cu from chalcopyrite can be explained quantitatively entirely on the basis of solution speciation without the need to invoke any rational relating to surface structure/speciation. The rate of Cu release is first order with respect to Fe3+ activity. The stirred batch reactor experiments at fixed pH 1, Eh of 750 mV (SHE) and 75? showed that chalcopyrite leach rates were rapid in both HClO4 and H2SO4 with 100 % Cu recovery after 73h and 97 h respectively. However, the leach rate in H2SO4 was slower as compared to the HClO4 leach due to a slower increase in the activity of Fe3+ due to the formation of FeSO4-. The presence of Cl- in the leaches (HCl and H2SO4 with NaCl added) led to a low activity of Fe3+, due to the high activity of FeCl2+, resulting in very low leach rates. For the column leach experiments dissolution of Fe and Cu from the pH 1 HCl eluted chalcopy-rite column with quartz proceeded at several times the rate of any other column (chalcopyrite with and without quartz and/or pyrite leached with H2SO4, HClO4, HCl). Three observations indicate that galvanic interactions are not leach rate controlling role: a) The rate of leaching was not uniformly increased for the non-quartz containing columns where the two sulfide minerals, chalcopyrite and pyrite, are in physical contact as compared to the analogous quartz containing columns where they are not; b) there exists a reasonable correlation between the rate of Cu release and the effluent Fe3+ activity for all columns thus indicating that the leach rate is determined by solution speciation; and c) in all cases the proportion of Fe to Cu leached indicates preferential dissolution of Cu over Fe. However, the proportion of Fe to Cu is either the same or greater than expected on the basis of the single mineral columns. This indicates that chalcopyrite is not dissolving preferentially to pyrite.

Jan 1, 2014

By Y. H. Zhang

Mechanism of BK501 in desiliconization from bauxite was studied by use of flotation test, EDS, ?-potential, FTIR. Results of flotation show that almost all of diaspore can be depressed when BK501 is put into pulp ranging from pH 4~12, in the meanwhile kaolinite is slightly activated. In the light of surface analyses, it is concluded that the adsorption of reagent on the diaspore is dominant by chemical interaction. Moreover, kaolinite may float more by addition of BK501 because of flocculation.

Jan 1, 2014

By P. Fawell, C. Castillo, C. Ihle

"The need to reduce fresh water consumption has pushed many Chilean mining companies to utilize seawater obtained from distant locations. At the same time, increasing amounts of fine particles in copper tailings raise new operational challenges, in particular, the thickening and transport of tailings featuring significant fine fractions, which are predominantly clays. In the present paper, we study the role of salinity – using seawater and NaCl – on the flocculation efficiency of copper sulphide tailings to which kaolinite was added. To mimic the water recovery stage in thickeners, flocculation has been induced in jar tests and the corresponding aggregate size distribution has been estimated from chord length distribution data obtained using a focused beam reflectance measurement (FBRM) probe, at various mean turbulence intensities. Results show that for constant flocculant dosing, a measurable influence of the salt on the resulting aggregation exists. For each case, resulting optimal turbulence levels are also reported, a particularly interesting feature when comparing flocculation efficiency of the coarse and fine fraction. INTRODUCTION The concentration of copper minerals through comminution and flotation is intensive in the use of fresh water. The need to reduce the consumption of fresh water and the environmental standards associated with increasingly demanding mining operations have driven improvements in the techniques of recovering water from tailings. The challenges are even greater when required to treat minerals with high clay contents. In Chile, kaolinite is one of the most important clays to consider due to its abundance in the tailings from many operations. The most common and highest throughput unit operation in the mining industry for the recovery of water from tailings is gravity thickening, with sedimentation of fine particles assisted by flocculation. Flocculation is the process of forming aggregates by contacting the suspended particles with a flocculant. The flocculant is typically a water-soluble synthetic long-chain polymer, where copolymers of acrylamide and sodium acrylate are the most common types used in the Chilean mining industry. The aggregation mechanism includes the following key steps: (1) flocculant distribution through the suspended particles, (2) flocculant adsorption onto particle surfaces, and (3) collisions between particles leading to polymer bridging to form aggregates, but concurrently (4) breakage of aggregates becomes a factor under prolonged shear (Gregory, 1988)."

Jan 1, 2018

By P. Coghill, P. Revell

"Geo-sensing is the ability to routinely measure or infer rock properties at a range of scales using non-destructive scanning devices. These devices can provide information and data flows to support integrated decision making across the minerals value chain. Geo-sensing has been used for many years in minerals exploration using technologies such as satellite imaging and airborne geophysics but to date the use of sensing technologies in between the mine and mill has been very limited. The aim of this research is to develop new mineral sensing technologies that can enable grade engineered ore streams through the rejection of low value gangue or deleterious elements either in the pit or during transfer to the mill. This paper focusses on the research and development being carried out by the Cooperative Research Centre for Optimising Resource Extraction (CRC ORE) and its associated members on new sensing technologies. At the start of their development these technologies were classified on the Technology Readiness Level scale at 3 (TRL3), equivalent to a proof of concept. Laboratory testing and design is aimed at progressing these sensing technologies to TRL5 which is ready for testing at an end users site. New data obtained during the laboratory testing and design phases are presented in the paper demonstrating performance specifications such as detection limits and measurement speed which can be used to infer the pod size of gangue that can be rejected at scale. Grade Engineering® and coarse gangue rejection are considered as key drivers for the mining industry to address the higher mining, processing and environmental costs associated with ore bodies with declining grades. This is an industry wide problem and the development of mineral sensors is seen as key enabling technologies for Grade Engineering® and coarse gangue rejection. The technologies presented in this paper enhance value through early decision making of ore quality and improve the overall resource value case through improved grade and throughput engineering."

Jan 1, 2018

By Evvie Chockalingam

Acid mine drainage (AMD) is a perennial problem particularly in abandoned mines, occurring due to the oxidation of sulphidic mine wastes. AMD is usually characterized by high concentration of dissolved metal ions, sulphate and low pH. The efficacies of substrates such as rice husk and the bark of Eucalyptus tereticornis (Sm.) are assessed for the removal of metal ions such as iron, zinc and copper from acid mine water obtained from an abandoned copper mine. Over 99 % of Fe, 98 % of Zn and 95 % of Cu removal could be achieved from acid mine water, with a concomitant increase in the pH value by three units using rice husk as an adsorbent. With respect to tree bark as an adsor-bent, about 96 % of Fe, 75 % of Zn and 92 % of Cu could be removed from the acid mine water with an attendant increase in the pH value by two units. The free energy of adsorption of the metal ions onto rice husk and tree bark is found to be negative in both the cases, while the adsorption process is endothermic in the case of rice husk and exothermic for tree bark. The adsorption process is found to adhere to the Lagergren pseudo-first order rate equation. The reduction of sulphate con-centration in the acid mine water is achieved using a typical sulphate reducing bacteria namely De-sulfotomaculum nigrificans. Desorption experiments indicate that about 88 % of Zn, 87% of Cu and over 77 % of Fe could be recovered from rice husk and over 70 % of Fe, 82 % of Zn and 77 % of Cu could be desorbed from the metal loaded tree bark using 5 M HCl. The possible mechanisms of metal ion and sulphate removal from acid mine water using rice husk and tree bark are discussed.

Jan 1, 2014

By N. A. Dementyeva

To improve gold recovery from preg-robbing carbonaceous ores a technology including gravity, flotation, recleaning of the flotation concentrate, intensive cyanidation of the gravity concentrate and carbon-in-leach (CIL) process for intensive cyanidation tailings and the recleaned concentrate was developed. The final flotation tailings are shipped to tailings disposal. Total gold recovery by the proposed technology from the ore with the head grade of 0.8 g/t was 83.9%. The gold loading onto the activated carbon from CIL process was 6.5 g/kg.

Jan 1, 2014

By Teemu Väyrynen, Matti Vilkko, Antti Jaatinen, Pekka Itävuo

"This paper shows that smooth and accurate feed-hopper level control is essential for consistent cone crusher operation. The objective of the paper is to define the best practices for tight control of cone crusher feed-hopper level. The paper discusses the challenges involved in a delay-dominant level control problem (specifically, dead-time-induced performance and stability issues, mass flow disturbances, process and actuator non-linearity) and proposes five corresponding control structures. The performance of the proposed control structure candidates is evaluated in a simulation study and, finally, a full-scale experiment is conducted for the best-performing candidate. The results of this study emphasize the importance of control structure selection. While the most obvious control structures failed to deliver the desired performance, the best result was achieved by using control structures that eliminate the conveyor transport delay (dead-time) from the control loop. In practice, the control loop dead-time can be eliminated by either using an actuator (variable-speed feed conveyor) that is connected directly to the feed-hopper, or by redefining the process boundaries closer to the used actuator (regulate the circuit mass balance instead of feed-hopper level). The presented control structures provide means to achieve a consistent cone crusher performance and size reduction. This facilitates efforts to improve the plant’s performance and increases the plant’s overall stability."

Jan 1, 2014

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001)."

Jan 1, 2018

By R. D. van der Weijden, W. F. C. van Wageningen

"Copper(II) can be recovered or removed from acidic copper sulfate solutions as cuprite or metallic copper powder by reduction with carbohydrates (van der Weijden et al., 2001, 2002). In order to make this process suitable for a commercial scale pipe reactor, process conditions and reactor configuration need to guarantee proper throughput of the dilute suspension. This is where crystal engineering also comes into view. Copper powder characteristics, such as size and shape of particles, influence the tendency to adhere to reactor walls and to agglomerate, which in turn influence the throughput. Furthermore, separation, drying, packaging and product quality, are dependent on the powder characteristics.In this paper the effect of both chemical and physical parameters on the shape and size of particles were systematically studied in a number of autoclave experiments. These parameters include mixing, Cu(II) concentration, pH, temperature, seeding, use of additives and reactor materials. Additionally, Monte Carlo simulations of copper growth inside a Kenics static mixer were made. Results show that the use of additives, and the use of static mixers influence particle characteristics the most."

Jan 1, 2003

By Pan, Jian, Siwei Li, Deqing Zhu

"It is great significance to realize the efficiently and comprehensively utilization of iron, manganese and aluminum from refractory high-aluminum and high-manganese iron ores. Aimed at the two types of low grade refractory iron ores, mineralogical characteristics were studied. The direct reduction behaviors and evolution of mineral compositions of single iron ores and their blended ones were analyzed, and the corresponding reduction mechanisms were demonstrated. The results showed that only a part of iron oxides in high-aluminum ore are transformed to metallic iron after reduction, while the other react with aluminum and silica to form fayalite and hercynite which are difficult to be reduced. For the high manganese iron ore, most iron oxides can be reduced to metallic iron and manganese oxides can combined with aluminum-silica minerals to form galaxite and tephroite, promoting the reduction of iron oxides. Co-reduction results demonstrate that reduction of high- aluminum ore can be promoted by adding with high-manganese ore. Metallization and metallic iron grains increase dramatically by elevate high-manganese blending ratio. At the ratio of 60% high- manganese iron ore in the pellet feed, iron-slag separate well with a slag assaying 28.51%~36.35% Al2O3 and the recovery of iron and manganese can be reached 93%, respectively. The high-aluminum rich manganese residue was recycled with H2SO4. INTRODUCTION The growth of the Chinese iron and steel industry has been pushed forward by its rapid economic development in recent years, and 1126 million tons of iron ore have been consumed in 2014, where 933 million tons were imported according to the data from World Steel Association [1]. However, iron resources are limited, and especially the reserves of high-grade iron ores are declining, so it is of significant importance to optimize the mining rate of iron resources [2] and to utilize low- grade refractory iron resources, such as high-aluminum iron ore."

Jan 1, 2018

By H. J. Schulze

From a colloidal science point of view (Schulze 1984, Nguyen & Schulze, 2004) five micro-processes are responsible for successful particle-bubble formation: the approaching of the particle to the liquid-air interface, the thinning and rupture of the intervening liquid film, the expansion of the three phase contact perimeter, the generation of sufficient large capillary force to stabilise the aggregates and the transport process of particles into and within the froth layer. Flotation reagents influence mainly the thinning and rupture of the intervening liquid film between particles and air bubbles, the expansion of the three phase contact after the rupture of the liquid film and the stability of the aggregates against external destruction forces in the flow field. But it exist also a non-negligible influence on the approaching of particles to the bubble surface during the encounter process and on their passing over into the froth layer and the froth stability.

Jan 1, 2003

By T. Fujita

The incinerated bottom ash includes titanium oxides and a small amount of chromium oxides. Initially, 89 % of chromium was removed from ash at magnetic flux density at several stages of wet magnetic separation from 0.05 T to 6 T. The bottom ash from an industrial waste incineration process includes about 10 % of TiO2. The minerals that contain titanium are rutile and perovskite. These minerals are paramagnetic and show low magnetic susceptibility, therefore, the high magnetic field strength, created by a superconducting magnet, is necessary to capture these minerals. At the first stage of separation, a magnetic field strength of 6T was applied in order to attract the particles that contain iron oxides to the higher magnetic field region. At the second stage of separation, the magnetic capture rate of weekly magnetic particles decreased with increasing the magnetic susceptibility of the aqueous solution (i.e. the medium for dispersing the particles) in order to separate the highly magnetic materials. The para-magnetic salt such as ferric chloride was dissolved in the water to increase the magnetic susceptibility of the medium. After a two-step wet HGMS with superconducting magnet, the grade of TiO2was increased from 10 % to 28 % with a recovery of 64 %.

Jan 1, 2014

By D. Whittles, S. Kingman, S. Bradshaw, N. Miles

The influence of microwave energy at high electric field strength on ore strength has been investigated. Two ores of varying mineralogy were treated in both multimode and single mode microwave cavities. After treatment, any change in strength relative to untreated ore was established. It was shown that in the multimode cavity reduction in strength was related to the applied power level. Results of tests carried out in the single mode cavities showed that, for both ores, reductions in ore strength > 50% could be achieved in very short periods (<1 second). Thermal stress analysis showed that the mechanism of microwave induced failure was the development of tangential stresses at the grain boundaries. It was concluded that operation at 915 MHz with high power and short residence times gives feasible scale-up possibilities.

Jan 1, 2003

By Wei Zhang, Jinhong Zhang

"In froth flotation, the adsorption of collector on mineral surface is critical for a successful flotation process. In present work, an atomic force microscopy (AFM) has been applied to study the adsorption of potassium amyl xanthate (PAX) on copper sulfides, i.e., chalcopyrite, chalcocite and bornite. The in-situ collected AFM images show that PAX adsorbs on chalcopyrite mainly in the form of oily dixanthogen; while it strongly adsorbs on chalcocite and bornite in the form of insoluble metal xanthate, which binds strongly with the mineral surface. The information obtained from the AFM study shed lights on the collectivity and therefore the selection of specific collector for different copper sulfide minerals in industrial practice.INTRODUCTIONFroth flotation, which treats the highest throughput in mining industry and produces the maximum economic outcome of any surface chemistry process, has been widely applied for the concentration of copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineral-bubble attachment and thus a high flotation recovery. Therefore, the adsorption of collector on mineral surface is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2018

By H. C. E. Regidor, M. G. Mena, H. D. Mendoza

Cyanidation leaching has always been the most widely used method of extraction of gold in the world. Its low cost and high selectivity has made it the prevalent choice for mining companies, and even for the small scale miners. The use of cyanidation in small scale mining has been an issue for the longest time, mainly due to the operation’s lack of safety measures, health care or environmental protection regulations. In pursuit of more environmentally friendly methods of extraction of gold, several alternative extraction processes have been explored, one of which is chlorination. The chlorination process is advantageous when recovering refractory gold locked in sulfides, as it simultaneously oxidizes the surrounding sulfides as well as dissolve any gold exposed to the lixiviant. This research was conducted to study and develop a safer alternative way of extraction of gold from small scale mining operations, without compromising the recovery of gold. In this study, a variation of the chlorination process has been employed for a refractory flotation concentrate wherein the majority of the gold is locked in sulfides. Hypochlorite-bearing reagents were used as the leaching reagents, and the method developed was a 2-stage leaching process in differing pH conditions. The solution pH and Eh was monitored all throughout the runs, and aliquot samples were taken at time intervals for analysis. SEM-EDS imaging was used to determine the mode of oxidation of the chlorination process, and the image obtained showed that the oxidized layer followed the shape of the particle, suggesting a diffusion controlled process. XRD analysis of the sample before and halfway through leaching further confirmed the oxidation of the sulfides. The amount of gold dissolved in the aqueous solution and in the solid residue were used as the basis for the determination of the recovery of gold. An average gold recovery of up to 84.38% was obtained using the developed method in just 7 hours of leaching. This method was then employed for a pilot-plant scale test and a gold recovery of 79.2% was obtained.

Jan 1, 2018