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By A. P. Gize, J. F. W. Bowles, D. J. Vaughan, S. J. Norris

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Geological evidence from tropical laterites indicates clearly that platinum group metals are taken into solution and precipitated to form grains larger than those in the source rocks. Platinum and palladium move differentially in the surface environment, with Pt partitioning into soils and eluvial or alluvial deposits while Pd remains more mobile in natural waters. Natural organic acids, particularly humic acid, can interact with platinum-group elements and concentrate them even in areas where their content in rocks is very low. Experimental work has confirmed that Pt and Pd can be taken into solution by humic acid at room temperature and in geologically short time-spans. Solubility and deposition may be controlled by physicochemical conditions, reaction kinetics or an adsorption effect, or there may be two competing reactions, solubilisation assisted by organic matter and a kinetically slower metal precipitation

Apr 1, 1994

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

By R. Poulin, C. F. Gleeson

The Birimian rocks of the region are gold-bearing and show many similarities to those of Burkina Faso. All three greenstone belts (Goroual, Tera and Sirba) host gold-bearing quartz veins. It appears that, contrary to previous misconceptions, lateritic terrain is not an unfavourable environment for exploration geochemistry. This is demonstrated by the results for the Koma Bangou area, where soil and termite-mound geochemistry have been successfully used in the search for gold. Soil provides an effective sampling medium where it is shallower than about 2 m; there is evidence that some soil anomalies are enhanced by the presence of secondary (botryoidal) gold. In areas of thicker, allochthonous soil cover, termite-mound sampling is more effective. At Koma Bangou an identified resource of some 11 100 000 tonnes with an average gold grade of 2.44 g/t has been reported. The gold mineralisation occurs in quartz veins and stockworks aand in the wallrocks of shear and fault zones that trend N, NW and NE. The host rocks are a granodiorite-syenite porphyry and intermediate metavolcanic rocks and tuffs

Apr 1, 1996

By R. Venugopal, T. C. Rao, N. Suresh

Experiments were carried out using the cyclone to treat coal in the size range -2.0+0 mm. The diameters of the cyclone outlets (vortex finder and spigot) were varied to study their effects on cyclone performance. The cyclone products were deslimed over a screen with an aperture of 0.075 mm. The performance of the separator was studied for washing coarse coal (-2.0+0.075 mm) and fines (-0.075 mm). Performance curves were plotted for the separation of -2.0+0.075 mm coal. The concept of a generalised distribution curve was adopted to predict cyclone performance. A mathematical representation was derived from the generalised distribution curve. The specific gravity of separation for individual size fractions showed a decreasing trend with decreasing particle size down to 0.85 mm, beyond which a reverse trend was noted. It was also found that the fine size fraction (-0.075 mm) does not separate on the basis of size or specific gravity but follows the water distribution

Apr 1, 1995

By J. H. Morris, G. M. Steed

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Oxygen isotope analysis indicates that quartz, carbonates and muscovite could all have formed in near-isotopic equilibrium with the mildly saline H2O-CO2 ore fluid at 330 degrees C. Calculated values for O, C and S in the ore fluids imply derivation from a deep, homogeneous source region and are consistent with formation either as a direct or an indirect result of igneous processes. Values for delta-O18 plot a little outside the accepted magmatic range, but have almost certainly been modified by exchange reactions with wall rocks. These reactions were also the most likely cause of deposition of the ore constituents. The chemical and isotopic character of the fluid was similar to that in many Archaean and later mesothermal auriferous vein systems, especially the Mother Lode region of California. If the Southern Uplands-Longford Down accretionary complex conceals an Ordovician arc, the tectonic setting was also broadly comparable

Jun 19, 1905

By R. A. Lord, H. M. Prichard

efficiency is discussed from both experimental and

Apr 1, 1994

By H. K. Taylor, B. Denby, L. D. Smith

Contributions by H.K. Taylor and G.A. Davis discuss the three papers published in Transactions IMM A, vols. 103 and 104, with responses by Smith and Dowd

Dec 1, 1995

By T. M. Williams, P. M. Green

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The sediment geochemistry of streams draining Southern Uplands and Lake District turbidites was compared with lithogeochemical data for the source greywackes, using stratigraphically defined catchments. Several systematic trends in element abundance variation between source and stream sediment can probably be applied more widely to interpretation of drainage geochemistry. Pb and Zr increase markedly from source rock to sediment, by adsorption on clay and zircon grain concentration. Variation of feldspar-related elements Rb, Sr, K and Ba appears to be controlled by source grain size and compositional maturity. Ni shows surprisingly little change and Fe and Co are only slightly raised. Cr is particularly useful, with variations superimposed in anomalously high regional levels. Abrupt changes in Cr distribution in stream sediment coincide with stratigraphical boundaries, allowing drainage data to be used as a surrogate for whole-rock values

Jun 19, 1905

By R. H. T. Garnett

N.B. This paper provoked much (positive!) discussion in later issues, with responses from the author (and thanks also for the many private contributions he had received) - see under Garnett R.H.T. Expanded version of a paper originally presented at the Alluvial mining conference, London, 11-13 November 1991 and published in Alluvial mining, Barking: Elsevier Applied Science for IMM, 1991, p.115-156. The usual measure of performance in gold and tin dredging is the R/E factor. It compares actual production or recovered grade for a given period with that estimated from the original sampling. The factor is a multiple of four component factors, each ideally approaching 1.00. The factors are concerned with estimation, selection, excavation and treatment. The estimation factor reflects the errors involved in determining the grade and depth of single drill-holes or pits. An optimum selection factor is achieved by a higher drilling density. The excavation factor is affected by failure of the dredge to excavate the total volume contained within its course. The required dredge throughput rate influences not only the success in digging recovery but also the treatment factor. No two alluvial deposits are the same, but, in general, the greatest divergence from 1.00 is invariably demonstrated by the estimation factor. A major divergence in one of the other factors may also be the cause of the R/E factor being significantly different from 1.00. The component factors are examined in detail and historical trends in R/E factors are discussed

Sep 1, 1991

By M. Feely, W. G. O'Keefe, C. O'Reilly, M. P. Holdstock

A petrographic and microthermometric study of fluid inclusions in the Kentstown Granite, crosscutting quartz (VI) and calcite+quartz (V 2) veins in the granite and calcite+quartz (V 2) veins in the overlying sediments was performed on samples taken from the borehole. Comparisons of the type 1, type 2 and type 3 fluid inclusion populations recorded in the present study with those from other Irish Caledonian granites strongly suggest a similar fluid evolutionary history. Furthermore, the low-temperature CaC12-rich brines (type 5) of this study, which must be syn- to post-Lower Carboniferous in age, have correlatives both in Irish Caledonian granites and in the Lower Carboniferous base-metal deposits of the Irish midlands

Jun 19, 1905

By R. Allington, G. Walton

The approach has been applied with success to the restoration of chalk workings in southern England, and research and trials relating to restoration blasting and the replication of limestone dale landforms have been undertaken. An essential prerequisite for application of the technique is rigorous geomorphological analysis of the locality to ensure that final quarry landforms are consistent with the local geomorphological and landscape setting. It is always important to ensure compatibility of the final landform with the intended after-use, and to achieve this it is also essential that such restoration schemes have a sound geotechnical basis. A disadvantage of the approach is that final slopes tend to be flatter, especially in weaker strata where natural slopes are not steep; the implications for reserves may be unacceptable, particularly in quarry extensions

Aug 1, 1994

By R Lastra, J. A. Finch

An artificial standard material has been developed and used to examine the robustness of some of the procedures for correcting stereological bias. Different mineral liberation distributions were constructed from the standard material. The particles were mounted, sectioned and the sectioning data measured with an electron microscope interfaced to an image analyser. Four correction procedures were used and the corrected and true liberation distributions compared. It was found that the large-sections correction provided a simple, uncorrupted correction. Hill's fast approximation performed well except in cases of narrow liberation distributions; the sectioning data appeared to support the assumption that the locked section and locked particle distributions are identical. Barbery's correction performed well in most cases, having difficulty only with the very irregular liberation distribution. The PARGEN correction was able to provide a good estimate of the true amount of free material, but had difficulty in predicting the locked particle distribution

Jun 21, 1905

By G. M. Steed, A. O. Oyinloye

The deposit lies in amphibolite-facies biotite granite-gneisses of Proterozoic age, 4 km east of a major crustal break known as the Ifewara-Zungeru fault. Gold mineralisation is contained in a zone of quartz-carbonate (mainly calcite) veins and hydrothermally altered gneisses with associated small-scale intrusions along a steeply dipping second-order fault zone that roughly parallels the main fault. Gold is present mainly at grain boundaries between quartz and carbonate as discrete particles up to 100 micrometres in size, in general association with sparse, scattered pyrite, pyrrhotite and some base metal sulphides. Adjacent to the gold-bearing zone the granite-gneisses have been hydrothermally altered with minor volume increase, most notable enrichment being in K2O, S, Pb and Cu (and Au). High concentrations of Th, Y, Ce and Zr in the granite-gneisses imply derivation from S-type granites. It is likely that their high heat production capacity maintained the high temperatures needed to transport gold in the hydrothermal systems. It is most probable that the mineralisation dates from the Pan-African orogeny (650-450 Ma)

Apr 1, 1996

By R. K. Dunham, D. J. Reddish, X. L. Yao

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 10pp., 10 refs. The integrated approach combines a powerful ground movement prediction program with a knowledge-based expert system. ESDAS (Expert Structural Damage Assessment System) was developed to evaluate mining subsidence damage in the form of risk and in terms of the three vital contributing components (mining factors, site factors and structural factors). Using a certainty factor risk assessment technique, the system can be used to predict the likely damage to a particular structure subjected to mining subsidence. A previously developed powerful ground movement prediction program, SWIFT (Subsidence With Influence Function Techniques), has been combined with the expert system to allow the mining factor to be more accurately determined in a broader range of mining layout. Since SWIFT can be calibrated to any particular coal field using local subsidence data, it is believed that the integrated system could be used in any coal field worldwide for the assessment and control of mining subsidence damage risks

Dec 1, 1995

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By J. A. Finch, Zhenghe Xu

The competitive adsorption of xanthates on sulphide minerals in a binary mineral system (pentlandite and pyrrhotite) was studied using the pseudo-in-situ technique of attenuated total-reflectance FTIR spectroscopy. The minerals were placed in the same collector solutions, either separated by a glass wall or in direct contact with each other before magnetic separation and separate analysis. The effect of mineral interaction on xanthate adsorption was clearly demonstrated spectroscopically for the first time. At low concentrations of xanthate, its adsorption on pentlandite was activated by physical contact with pyrrhotite; the effect may be attributed to the enhancement of electron transfer through electrical contact between the two minerals. The results emphasise the need for caution in extrapolating results obtained from single-mineral studies to flotation practice

Jun 18, 1905

By A. M. Tunstall, N. Djordjevic, H. A. Villalobos

The damage zone behind a typical smooth-wall blast in the open pit was assessed by visually examining diamond drill core to identify blast-induced cracking, mapping core rock quality designations to identify changes in fracture frequency and conducting uphole seismic testing to determine changes in rock mass characteristics. The results from the three techniques show reasonable correlation. They suggest that major damage, in the form of fracturing of intact rock, occurs at least 7 m behind the smooth-wall blast and significant damage, in the form of opening and extension of calcite-filled fractures, at least 12 m from the blast. At greater distances the dominant damage mechanism is the loosening of existent joints within the rock mass. In the trachytes at El Soldado these damage mechanisms correspond to peak particle velocities of 2 000, 900 and 500 mm/s respectively

Jun 19, 1905

By K. Nielsen, J. Kristiansen

A series of laboratory blasting and grinding tests on three types of hard and competent rock (coarse-grained monzonite, fine-grained granite and very fine-grained gabbro) showed that a higher level of applied explosive energy enhanced grindability and produced a larger amount of fine (-0.106 mm) material. This confirmed reported industrial experience and the results of previous investigations. However, the results did not provide any information on the quantitative relationship between the energy applied in primary blasting and that required in subsequent comminution. Only about 1% of energy consumed in conventional grinding is used to create new surfaces, while power efficencies in cone crushers have been estimated at 70-80%. In blasting, up to 20% of explosive energy may be transmitted to the surrounding rock as elastic strain energy, leading to both primary rock breakage and the generation of microcracks

Dec 1, 1995

By Boorder De, B. S. Panov, A. B. Westerhof, V. A. Korcemagin

Paper presented at the conference on Economic geology in Europe and beyond II, models for <mineral deposits> in sedimentary <basins>, held in Keyworth, UK, 13-14 April 1994. The Hg and Sb deposits of the Mediterranean and Circum-Pacific Belts are often found at elevated structural levels, suggesting that their preferential occurrence in young orogenic belts is not a fundamental metallogenic feature but merely reflects their chances of surviving post-orogenic peneplanation. In western Europe their emplacement appears often to be related to late orogenic extensional events accompanied by a notable increase in heat flow. Although Nikitovka and Almaden have quite different settings, both appear to be related to deep-reaching shears. Together with brittle fault zones at higher levels, these provided pathways for fluid phases that originated at least partially within the mantle. The Nikitovka deposits are located in the Donets segment of the 2 000 km Pripyat-Dniepr-Donets palaeorift in the East European Platform. Initiated in the mid-Devonian with a possible Precambrian precursor, its listric boundary faults displace the Moho from a depth of about 50 km north and south of the rift to 35 km along the axes of the Pripyat and Dniepr segments. The steep central anticline of the Donets segment, within which the main Hg-Sb district is located, is interpreted to be associated with a reactivated fault reaching into the upper mantle. The Almaden syncline, formed during the Variscan Orogeny, may be an older pull-apart basin or half-graben associated with the collapse of the Cadomian Orogenic Belt. It is situated on a major ENE-WSW-striking shear zone which may represent a Late Cadomian transfer zone reaching into the mantle

Apr 1, 1995

By A. J. Davidson

A Cu-conducting solid electrolyte was used to develop the sensor. Instead of measuring the potential across the electrolyte from the reference material to the Cu-containing phase, a potential was applied and the stable current measured. This gave reasonable readings for copper-tin alloys, which agreed with the theoretical calculations, but was less satisfactory in the case of mattes because the surface area of electrolyte presented to the matte phase varied from sensor to sensor. To overcome this problem the potential was applied, the current was measured and then reversed and remeasured and the ratio of the currents was calculated. The current ratio is shown to be independent of the resistance of the electrolyte and the surface area of the electrolyte offered to the melt, but strongly dependent on the activity of the copper

Jun 21, 1905