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By B. M. O'Harra

Zinc smelting is frequently termed a ba.ckward art. The term is hardly true, for great progress has been made in recent years in the design and in the thermal efficiency of the retort furnace, in the quality of retorts, in the recovery of zinc, and in the ability to treat more impure and complex ores. The fact remains, however, that the peculiar physical and chemical properties of zinc have delayed such immense advances-large smelting units, high recovery, lowunit costs, and ability to treat low-grade ores-as have been made in the metallurgy of lead and copper. In current retort-smelting practice, the ores, if carbonates, are calcined to remove carbon dioxide; or, if sulphides, are roasted to remove sulphur. The sulphur must be eliminated as completely as possible, usually to less than 1 per cent. This means that the roast must be continued for a long time at a high temperature, with resulting high cost and small capacity per furnace. The roasted ore is mixed with about 50 per cent of its weight of reducer, which may be fine coke, anthracite, or nonbituminous coal. This mixture is charged into horizontal fire-clay retorts. The retorts used in this country are about 8 inches in internal diameter by 4 feet in length and hold 50 or 60 pou~ds of ore. The diameter of the retort is limited by the tirrie required for the heat to penetrate to the center of the charge; the length by the strength of the retort, which at the high temperature employed can not support the weight of the charge if the span is more than about 50 inches. The retorts are heated externally by coal, natural gas, qr ·producer gas to a temperature of 1,200° C. or more. The zinc oxide is reduced to zinc, which is volatile at this temperature, and passes into a conical fire-clay condenser. attached to one end of the retort, where it conde_nses to liquid zinc and is removed. Twenty-four hours are required for distillation, and because of the low heat conductivity of the retort walls 11.nd of the ore charge itself, the heat efficiency even of the most modern regenerative furnacei;; is only about 12 per cent. The retorts have a short life, 30 to 6Q days, at the high temperature required-; zinc losses are heavy, usually 10 per cent or more; and the proportion of impurities in the retort charge must be carefully controlled to prevent the rapid corrosion of retorts. For these reasons, much work has been done in an e:ff ort to, find cheaper and more efficient methods o.f recovering zinc from its ores. Various methods have been proposed for smelting in the blast furnace. Some of these contemplated the production of zinc vapor and its condensation to liquid; others attempted to produce liquid zinc directly by smelting under pressure. It is now realized that fundamental difficulties render these proposals impracticable. The electric furnace for smelting offers obvious advantages in the way of the efficient utilization of energy, large units, easy attainment of high temperatures, and the possibility of treating complex ores. E. H. and A. H. Cowles first suggested a design for an electric furnace for the reduction of zinc ores and patented their process in 1885. Their attention was soon directed to other uses for their furnace and nothing further of importance was done in the electric smelting of zinc until about 1900. Several investigators then started work upon various processes and had more or less success. The chief difficulty they encountered was the impossibility of obtaining more, than a small amount of the zinc as liquid metal because most of the zinc vapor condensed as blue powder. Interest in the electrothermic metallurgy of zinc increased, many patents on processes and furnace design were taken out, and the literature on the subject grew, until in 1914 and 1915 the problem seemed to be approaching solution. About this time the hydrometallurgy of zinc, the development of which had been lagging somewhat behind that of the electrothermic metallurgy, sprang into the limelight and a commercial process was soon perfected. This rapid development, perhaps aided by the war premium on the high-grade spelter produced by electrolytic deposition, distracted attention from electric smelting to some extent, though progress continued. With the perfection and standardization of the electrolytic process has come a better realization of its limitations, especially the necessity for large-scale operation ·and the difficulty of obtaining high extraction. Because of these limitations the electrothermic metallurgy of zinc still has a field of its own and in fac-t promises to become a strong competitor of both hydrometallurgy and retort smelting except under conditions highly favorable to the latter methods. Because of the imperfections of the retort and electrolytic processes and the promise that the electric furnace offers in overcoming these imperfections, the. United States Bureau of Mines, in cooperation with the Missouri School of Mines and Metallurgy, has undertaken a study of the electrothermic metallurgy of zinc.

Jan 1, 1923

By John D. Spencer

Projects aimed at achieving the least disturbance to the Nation's air, water, and land resources in the mining and utilization of coal continued to be a feature of the Bureau of Mines coal program. This reflects the current concern about damage inflicted on the environment by our growing and increasingly affluent society. Mine Health and Safety research, along with investigations related to all other aspects of coal extraction and use, also continued to be implemented and expanded.

Jan 1, 1970

By R. S. Dean

This is the fourth of a series; of annual report of the Metallurgical Division to be released in this form and cover the fiscal year July 1, 1937, to rune 30, 1938. This report is not merely a recitation or brief of the year's work; it contains technical information in usable form, although a some of this has appeared or will he issued in greater detail in separate reports. The table of contents that follows fists the principal investigations accomplished and those that are being continued. Other projects are being begun and contemplated for the next year.

Jan 1, 1938

By R. S. Dean

[Methods s of preparing the manganese metal that has been used in chemical and metallurgical investigations have passed through a cycle. Most of the investigations made before the turn of the century, used Moissen's pyrophoric manganese.3/ This material was made by electrolysis into a mercury cathode and distillation in vacuo. The material was essentially pure, and investigations in which it was employed (with proper precautions against oxidation) led to accurate results on tie intrinsic behavior of metallic manganese.]

Jan 1, 1941

By D. Harrington

A uniform hoisting-signal code for mines hoisting from more than one level, if adopted by all mining States, would be beneficial to employees and owners alike and should largely reduce the number of hoisting accidents. Misunderstood hoisting signals cause many shaft accidents involving injuries to men, damage to equipment, and loss of production from the resultant delay. Many of the metal-mining States have adopted codes for hoisting that are effective within the borders of that State but usually entirely different from the signal code, if any, in use in an adjoining State. For many years safety engineers have recognized this lack of uniformity as a distinct hazard, but a uniform code has never been adopted by the States or by the mining industry in those States that have not incorporated signal codes in their mining laws or mining regulations.

Jan 1, 1944

By William W. Adams

The quarrying and related industries of the United States made a large gain in employment (man-hours of work) in 1942 with a somewhat smaller number of men employed than in 1941. This was accomplished chiefly by increasing the number of workdays per man and also by increasing the length of the workday. In spite of the greater volume of work performed, the industry had a more favorable accident-frequency rate in 1942 than in the previous year. Accident and employment reports from operating companies showed that the industry employed 84,270 men for an average of 271 days per man in 1942, with a volume of work of almost 181 million man-hours. The average workshift comprised 7.93 hours, and the number of man-shifts worked totaled nearly 23 million. Injuries from accidents in and about the quarries and plants caused disability to 6,461 employees, 112 of whom died as a result of their injuries, including 28 employees whose lives were lost in a single disaster. The accident-frequency rate in the industry was 35.73 per million man-hours worked, comparing favorably with a rate of 40.11 for the previous year. However, the figure for 1942 included a death rate of 0.62 per million man-hours which, because of the disaster referred to, was considerably higher than the fatality rate of 0.44 for 1941. Had the disaster not occurred, the fatality rate for the industry for 1942 would have been 0.46. The major disaster in which 28 lives were lost occurred on March 26 at the Sandts Eddy quarry of the Lehigh Portland Cement Co. near Easton Pa.

Jan 1, 1944

By Paul W. Johnson

A computer program for calculating capital and operating costs from material and energy requirements and equipment costs for use in preparing cost estimates for metallurgical process evaluations has been written by the Bureau of Mines' College Park process evaluation group. The program permits rapid recalculation of processing costs when changes of data or equipment are desired, and produces tables of capital and operating costs suitable for publication. Equipment cost summary tables for each process section end supplemental information for input-data checking is included in the computer printout. The program is written in Fortran IV except for several subroutines which are written in machine assembly language for the IBM 7094.3 With a few modifications, the program can be used on other computers.

Jan 1, 1969

By G. W. Jones

"INTRODUCTION As part of its work in promoting safety, the Bureau of Mines is investigating various means of eliminating or mitigating the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explosibility of many complex gaseous mixtures may be calculated in a rather simple manner without the necessity of performing laborious laboratory experiments. An earlier publication 3/ described the method of determining by calculation the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen. The information published in the above report permitted calculation of the limits of inflamnability of such gases as are liberated by mine fires, gases from explosives, automobile exhaust gases, gases present after mine explosions, blast-furnace gas, and other gases of similar type.Gases liberated in certain potash mines in the western part of the United States sometimes contain ethane, in addition to the gases named. An investigation was made to obtain data from which the limits of inflammability of such gaseous mixtures could be determined by calculation. 4/Similar data have been Published covering all types of natural gases containing wide ranges of concentration of nitrogen and carbon dioxide.5/"

Dec 1, 1944

By Paul G. Marinos, Vassilis Marinos, Evert Hoek

The Geological Strength Index (GSI) is a system of rock mass characterization that has been developed in engineering rock mechanics to meet the need for reliable input data related to rock mass properties required as input for numerical analysis or closed-form solutions for designing tunnels, slopes, or foundations in rocks. The geological character of the rock material, together with the visual assessment of the mass it forms, is used as a direct input for the selection of parameters for predicting rock mass strength and deformability. This approach enables a rock mass to be considered as a mechanical continuum without losing the influence that geology has on its mechanical properties. It also provides a field method for characterizing difficult-to-describe rock masses. Recommendations on the use of GSI are given and, in addition, cases where the GSI is not applicable are discussed.

Jan 5, 2007

By William Seymour, L. D. Schmidt

A preliminary survey of coke and steel plants conducted by the Bureau of Mines in cooperation with the Office of the Solid Fuels Administrator for War and with the advice of the Coke Production Committee indicated that production of pig iron could be increased. appreciably if present blast furnaces were supplied with a more uniform coke.4/ Nonvarying percentages of ash , sulfur , and fixed carbon in the coke , together with uniform physical characteristics , such as size , strength , and porosity , would aid the blast -furnace operator greatly in his trial - and - error methods of obtaining maximum production . With nonuniform raw materials he must employ certain factors of safety in operation , such as an excess of coke , an excess of limestone , and operation of the furnace below the maximum rate . Even so , he often has trouble from iron not being up to specifications , hot tops , high blowing pressures , furnace hanging up , etc. The more uniform his raw materials (of which coke is probably the most important) , the nearer to ideally can he run his furnace and thereby save raw material and increase production . One cause of nonuniformity of the coke produced by ordinary American plant practice is the prevailing lack of precise control of the bulk density ' of the coal charge in the byproduct oven . This report summarizes the available information on the subject of bulk density of crushed coal and its control . It includes brief reviews of some of the literature , some results obtained at plants visited by the authors , and results of a few preliminary tests made at the Pittsburgh Station of the Bureau of Mines .

Dec 1, 1943

By John Paul Gries

This Bureau of Mines report reviews the mineral industry of the Black Hills area, including Butte, Custer, Fall River, Lawrence, Meade, and Penning- ton Counties, S. Dak.; and Crook, Niobrara, and Weston Counties, Wyo. It includes discussion of geological occurrence, processing, and potential of 27 commodities that have been produced from the nine-county area. The value of mineral production exceeds $70 million annually. Gold and petroleum account for two-thirds of the total, followed by clays, cement, sand and gravel, and rock. The combined mineral industries annually consume 268 million kilowatts of electrical energy, 933 million Mcf of gas, and 2 million barrels of fuel oil. Water consumption is about 10,000 gallons per minute. About 2,700 persons are employed on a year-round or significant part-time basis.

Jan 1, 1974

By D. J. Parker

On Thursday, March 18, 1937, the country was shocked by news of a terrific explosion at the New London, Tex., school, which caused the death of 280 pupils rind 14 teachers. The explosion occurred at about 3:05 p.m. in the largest of the 11 school buildings on the campus. Figure 1 shows this building, market; "Main high school building?, with respect to other buildings, pipe lines, oil wells, and gas lines on the property.

Jan 1, 1937

By W. W. Adams, T. D. Lawrence

"The National Safety Competition conducted by the Bureau of Mines, United States Department of the Interior for the promotion of safety in mines and quarries, has just been closed for seventeenth consecutive year. Enrollment covered more plants than in any previous contest. Moreover, a larger volume of employment was represented than in the contests of previous years, and several new plants were enrolled for the first time. Six safety trophies are awarded annually in these competitions one to the leading plant in each of six groups. An anthracite, mine in Pennsylvania, a bituminous-coal mine in West Virginia, a metal mine in Tennessee, a nonmetal mine in Virginia an open-cut mine in Minnesota, and a quarry in Alabama won the 1941 trophies.To be eligible to win a trophy, a mine or quarry must have had at least least 25 men working under ground or in the pit for not loss than 100 days. The number of man-hours worked must total 30,000 or more. Mines or quarries having no accidents during the year are rated according to the number of man-hours worked. If there are no plants with accident-free records, the mines and quarries in each of the six groups are rated according to their accident-severity rates; the plant having, the lowest rate is declared the winner.The Sentinls of safety trophies presented to the winning mines and quarries in the six groups were donated by the Explosives Engineer magazine to promote safety in the mineral industry. They are held by the winning companies for 1 year or until won by other mines and quarries."

Jul 1, 1942

By Leslie D. Marrus

This project and final report represent an effort to collect, analyze, and verify reliability and performance data on currently available medium -to-high seam models of continuous miners being used in underground coal mining. The analysis determined availability, mean time and tons between failures, amounts of down time associated with various failures, labor and part costs required to correct failures, and various indices of maintainability. Machine performance and reliability are discussed relative to cumulative tons (machine age) produced and production rates (machine loading). It was determined that performance can be significantly improved given preventive maintenance programs that will increase machine availability.

Jan 1, 1976

By Arno C. Fieldner, Howard I. Smith, J. W. Paul, SAMUEL SANFORD.

Many mine samples of coal are analyzed each year in the laboratories of the Bureau of Mines. The analyses are made in connection with investigations relating to fuels belonging to or for the use of the United States Government, the causes of accidents in coal mines, the geologic relations of coal beds, and the character and the value of the coal and lignite in the public lands. The systematic collection and analysis of such samples in connection with fuel investigations was begun in 1904 at the Government fuel-testing plant at the Louisiana Purchase Exposition, and was under the direction of the United States Geological Survey for six years. Descriptions of the coal samples collected between the beginning of this work, July 1,1904, and the transfer of the fuel-testing and mine-accident investigations to the Bureau of Mines, July 1, 1910, were compiled and published in Bureau of Mines Bulletin 22.a Descriptions and analyses of samples collected during the fiscal years 1911 to 1913 were published in Bureau of Mines Bulletin 85.b The present bulletin presents analyses and descriptions of samples collected during the fiscal years 1913 to 1916. In order that the material in this bulletin may be used to supplement that presented in Bulletins 22 and 85, the same plan of geographical classification has been followed, the analyses and descriptions of the samples being grouped in alphabetical order according to the State, county, and town near which the mines or prospects sampled are situated.

Jan 1, 1918

By K. L. Paciorek

The aim of this program was to develop a reliable and meaning-ful basis for assessing certain safety aspects, namely fire and, in particular, toxicity hazards of articles employed in underground coal mining operations. The present investigation was concentrated on the thermal oxidative degradation of representative hydraulic fluids. To achieve this goal all products formed on thermal oxidative degradation of the fluids studied were analyzed, identified I and the amount of each individual species present was determined quantitatively on a weight of product per weight of material basis. The weight/weight data thus obtained can then be factorized to reflect the relative toxicity of each individual species present, using for example the Threshold Limit Values adopted by the American Conference of Governmental and Industrial Hygienists, whereby an overall "toxicity index" can be arrived at which makes it possible to compare the different fluids and/or classes of fluids in a quantitative manner insofar as their toxicity is concerned.

Jan 1, 1976

By C. H. Riggs

"INTRODUCTION The injection of gas into the McClosky limestone in the adjoining, Griffin and New Harmony field in Indiana and Illinois and resulting increases in oil and gas production from this zone ore described in this report.Since 1911, the use of compressed air or as to increase oil production by supplementing natural reservoir energy has been widely adopted, and has resulted in the recovery of much additional oil, which otherwise would have been left underground. In many of the newer oil fields, including Griffin and New Harmony, a part of the compressed residue gas from natural gasoline plants is returned to the reservoir as a secondary method to increase oil and gasoline production. Part of the injected gas is stored underground for future use.By presenting data on many secondary recovery operations in a series of reports 5-9/ the Bureau of Mines has sought to stimulate interest in secondary recovery as a means of increasing oil recovery and current oil production for wartime needs. Most of the elder fields in the United States produce oil from sandstone reservoirs, and probably more than 90 percent of secondary recovery operations have been developed in oil bearing sandstones. During recent years, the volume of oil obtained by primary methods from limestone reservoirs has increased steadily, but as yet little has been done to recover, by secondary means,,the large volumes of oil left in limestone reservoirs when primary methods production are no longer profitable. Because of inherent differences in the origin and nature of the pore spaces between sandstones and limestones and because of differences in permeability and fluid content, secondary recovery methods, which are successful in sandstone-reservoirs, are not always applicable to limestones. Not much he been written concerning secondary recovery operations in limestone reservoirs, and few data are available to assist operators in developing such secondary recovery projects."

Jul 1, 1945

By William H. Lesser

Never before have mine managers in the anthracite region of Pennsylvania been so seriously concerned about the rising cost of pumping mine water. Many of them know that future pumping charges may affect their operating profits adversely to an extent that will make it necessary to abandon some mines. Increased pumping charges in the anthracite industry are currently comparable in importance with higher mining costs; in fact, profitable operation of some mines depends not only upon the cost of mining coal but also upon whether they can be kept free from water at reasonable cost. Pumping charges are relatively low during the early development of a mine, but they increase rapidly as development progresses. Numerous crop falls, strippings, and. abandoned adjacent properties contribute unfavorably to the volume of water produced during mining. The foregoing conditions and the existence of large underground pools below existing mining levels present water problems of such magnitude and cost that some mine owners cannot continue to operate profitably.

Jan 1, 1950

By Charles Will Wright

This paper will be of interest to those who are actually developing a mineral prospect or planning to do so, as well as to investors who are considering the problem of financing the development of the prospect, so that they may know what the risks are and what capital expenditures are necessary before a prospect may become a mine. The term "prospect" used broadly, as it is in this paper, is defined as any property that has a mineral showing of sufficient interest to warrant development, irrespective of prior work, Such previous exploration, however, may be extensive and consist of several tunnels or adits connected by raises, or of shafts with several levels. There may also be a small mining and milling plant on the prospect which, because of the lack of capital for development or the lack of markets for the products, is now idle. Such prospects may warrant further capital investment for development work or for a mine plant to raise to the stage of profitable production.

Jan 1, 1935

By W. I. Nissen

As part of its program to provide technology for reducing undesirable environmental impacts of mineral processing operations, the Bureau of Mines developed the citrate process for desulfurizing industrial stack gases that contain from 0.1 to 2 vol pet S02. In this regenerable flue gas desulfurization (FGD) process, S02 is absorbed from cleaned and cooled industrial flue gas with a citric acid-sodium citrate solution. The absorbed S02 is subsequently reacted with H2S to precipitate marketable elemental sulfur and regenerate the solution for recycle. Laboratory investigations of process parameters provided information for designing larger scale continuous operations. Information gathered from operation of two pilot plants, one at a copper smelter and one at a lead smelter, confirmed the laboratory results. Data were obtained for design and construction of a commercial-sized demonstration plant at the George F. Weaton Power Station, Monaca, PA. A preliminary operation of the plant was demonstrated, under a cost-sharing Bureau-industry contract. This bulletin describes the citrate process and gives results of the laboratory, pilot plant, and demonstration plant studies, as well as corrosion investigations.

Jan 1, 1985