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By W. E. Wallace, S. -G. Xing, M. J. Keane, J. C. Harrison

"SummaryDiesel-exhaust particles from two sources were dispersed in aqueous mixtures of dipalmitoyl phosphatidyl choline, a major component of pulmonary surfactant, and were tested for genotoxicity. Diesel samples from the same sources were extracted with dichloromethane and transferred into dimethyl sulfoxide and subjected to the same assays. Both types of extractions yielded similar results in both the Salmonella mutagenicity assay and the sister-chromatid exchange assay using V79 cells. After separation of the samples into supernatant and sediment fractions, the activity of both diesel samples was shown to reside exclusively in the supernatant fraction for the solvent-extracted samples, and exclusively in the sedimented fraction for surfactant dispersed samples. These findings indicate that genotoxic activity associated with diesel particles inhaled into the lung may be made bioavailable by virtue of the solubilization / dispersion properties of pulmonary surfactant components.While diesel engine emissions are associated primarily with transportation, they are also very common in the workplace. Estimates for the U.S. are that as many as 1.35 million workers in as many as 80 000 workplaces are exposed to the combustion products of diesel engines (NIOSH, 1988). These occupations include, but are not limited to mining, agriculture, motor vehicle maintenance, fork lift truck driving, truck driving, and tunnel and bridge operation."

Mar 1, 1992

By E. C. Lane

This report presents the results of the Bureau of Mines' twenty-first semiannual survey of motor gasoline marketed in the United States. The 12 cities in which samples were collected have teen chosen as representative of the more important marketing territories, as it is obviously impractical to obtain a sample of every gasoline sold in the entire country. The survey reveals that the motor gasoline which is being marketed in the United States this winter is decidedly more volatile than that sold a year ago. Samples from all cities show a decided improvement in volatility except those from Laramie, Wyo., which show a small decrease in volatility.

Jan 1, 1930

By B. J. Moore

This publication contains routine analyses and related source data for 419 natural gas samples from 22 States collected during calendar year 1964 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the Bureau of Mines since 1917. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863/ and 576.4/ Six previous publications have been made to present the results of 6,293 gas analyses made by the Bureau of Mines, Helium Activity, prior to 1964. The first three, Bulletins 486,5/ 576,6/ and 617,7/ contain analyses and related source data on 5,214 gas samples collected from

Jan 1, 1966

By B. J. Moore

This publication contains routine analyses and related source data for 278 natural gas samples from 14 States. All of the samples were collected during calendar year 1973 as part of a continuous survey of the free world for occurrences of helium in natural gas. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576.3 Fifteen previous publications have presented the results of 10,201 gas analyses prior to 1973. The first three, Bulletins 486,4 576,6 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960. The other 12 publications,7 which were issued as information circulars, supplement the three bulletins and contain 4,983 analyses of samples collected since 1960. This publication is the 13th publication supplementing the three bulletins.

Jan 1, 1974

By L. G. Trudell, J. W. Smith, K. E. Stanfield

Representation of actual oil yields from sections of the Green River formation oil shales by two types of drill - cutting samples was evaluated . Average oil yields of single sets of mud cuttings from hydraulic rotary drilling in Colorado and gas cuttings from pneumatic rotary drilling in Utah were compared statistically with yields of core samples taken from adjacent holes . Oil yields from gas cuttings were identical to oil yields of core samples . Mud cuttings appeared to represent a section of the formation conservatively , the deficiencies increasing with increasing richness of sample . Because a large amount of the oil - yield data currently available for the Green River formation is based on mud- cutting samples , development of a valid correction method by additional testing is needed .

Jan 1, 1963

By J. H. Tylczak

The Bureau of Mines studied the effect of alloy additions on abrasive wear of low-alloy steels. A dry-sand, rubber-wheel abrasion test appa-ratus using ASTM G65-Sl procedure B was used for the abrasive wear tests. Eighty-six material heat-treatment combinations were abrasion tested. Results of these tests were analyzed statistically using regression analysis to see if additions of Cr, Mn, Mo, Ni, Si, AI, Cu, and S were significant in affecting the abrasive wear rate of low-alloy steels. Regression analysis was also used to confirm hardness and C affect on the abrasive wear rate of these steels. It was found that for all the steels taken as a group, increased amounts of Mn significantly reduced the wear rate, while increased amounts of Mo and S1 increased the wear rate. Analysis also confirmed previous research done by others, that increasing hardness and amounts of C reduced the wear rate. For the hardened steels taken as a class, only increasing amounts of C and Mn reduced the wear rate, while increases in Si increased the wear rate. In the class of unhardened steels, increases in C, Mn, and S re-duced the wear rate, whereas increases in Mo increased the wear rate. The steels with the best resistance to wear were two hardened experimen-tal steels similar to AISI 1055 and AISI 107S.

Jan 1, 1986

By R. L. Brown

This report is the 18th in a series summarizing Bureau of Mines research and technologic work on coal and related investigations. The previous 17 reports have covered fiscal years, but this report covers not only the fiscal year from July 1, 1952, to June 30, 1953, but also July through December 1953, to bring the report to a calendar-year basis. Most of the material in this report relates to publications issued during the reporting period, Some work is mentioned briefly on which publications have not yet been issued or on which data are riot expected to be published, for security or other reasons, and in a few instances publications issues before the reporting period but not included in the previous report are mentioned.3/ Further details on the published work described herein may be found by referring to the publications cited in the footnotes. During the reporting period, the Bureau directed its research and technologic work on coal toward developing end encouraging increased conservation and more efficient use of our mineral fuel resources through more efficient and safer mining methods and improved methods of preparing and utilizing these fuels. Some significant advances, particularly in coal-mine safety, mining methods, and development and utilization of low-rank coma have been made.

Jan 1, 1954

By Jr. Hazen

Relationships that may exist between assays and sample interval lengths when using unequal sample intervals in mine sampling have been investigated as part of the larger research problem of adapting statistical methods to the analysis of weighted average grades. The theoretical relationship between the amount of difference in the weighted and unweighted average grade of ore and the size of the correlation coefficient between assay value and sample interval length was found to be linear. Numerous examples of actual field sample and assay data, which have been obtained by using unequal sample intervals, are documented, and the differences between weighted and unweighted average grades of ore and the correlation coefficients between assays and sample interval lengths have been computed and plotted on graphs. Differences between these actual field data and the expected theoretical linear relationship are examined. It is hypothesized that the use of unequal sample intervals in mine sampling is, in fact, stratified sampling in a statistical context. The sampler establishes stratification by selecting unequal sample intervals on the basis of differences in lithology, changes in rock type, characteristics of mineralization, or differences in metal content. Statistically} methods currently used in mine sampling, involving unequal sample intervals, fail to consider differences in the inherent variances in grade of ore within the various strata established by using unequal sample intervals. Consequently the strata are sampled with different precision. This difference in precision of sampling between strata may account for much of the deviation between the plotted points representing actual field sampling data and the theoretical linear relationship between the amount of the difference between weighted and unweighted average grade of ore and the size of correlation coefficient between assays and sample interval lengths.

Jan 1, 1966

The principal activities of the Bureau of Mines Explosives Research Center (now Safety Research Center) during fiscal year 1968 (July 1, 1967, to June 30, 1968) are reviewed in part 1. Part 2 presents short abstracts of the publications issued during this period in the Bureau series and in other media. Part 3 describes a short study on the thermal decomposition of RDX and HMX not destined for publication elsewhere. ACKNOWLEDGMENTS The Bureau gratefully acknowledges the support received through cooperative agreement in fiscal year 1968 from The Manufacturing Chemists Association.

Jan 1, 1970

By Árpád B. Palotás, Adel F. Sarofim, John B. Vander Sande, Lenore Rainey Christian, J. Feldermann

"Interest in the fine structure of soots and carbon blacks is motivated by a variety of possible applications. The structure provides information on the origins of the particles and on their adsorptive and reactive properties. This paper describes a method for quantification of the structure of soots and carbon blacks based on direct electron microscopic observation followed by image analysis of these materials. High-resolution transmission electron microscopy (HRTEM) provides a very detailed observation of particle structure. The differences in soot structure, because of its complexity, may not be easily quantifiable with the human eye; therefore, high-level computer software has been used to manipulate HRTEM images. This technique involves the application of fast Fourier transforms (FFT) to single particles and the measurement of characteristic parameters such as interplanar spacings and crystallite sizes from these particles. The methodology and application of this characterization technique are presented here. Results are shown for dif¬ferent samples obtained from soot and carbon black particles selected to illustrate the capabilities of the methodology. Quantitative information can be obtained on structural characteristics, e.g., interplanar spacing, circularity, orientation, elongation, and length distribution of lattice fringes, as well as on the fractional coverage of the extracted pattern. c 1996 Wiley-Liss, Inc.This paper presents a combination of techniques for recognizing and classifying different carbonaceous materials, using their structural morphology. A new method to assess and quantify the parameters which define such structures is proposed and discussed. The technique is based on the use of HRTEM (high-resolution transmission electron microscopy) and computational image analysis.It is well-known that carbonaceous materials like graphite, soots, coals, cokes, chars, etc. possess characteristic structural appearances which can vary from mostly random or amorphous to a perfectly ordered graphitic crystalline structure (Buseck and Bo-Jun, 1985; Buseck et al., 1987). The carbon structure has been variously described as turbostratic (Oberlin, 1989) or as crumpled sheets (Rouzaud et al., 1991) to indicate that parallel layering, reminiscent of graphite, is observed over dimensions of nanometers, but that these planes or crystallites show disorder over larger scales. The degree of order of such structures is strongly dependent on the thermal treatment of the material as well as on the composition of the source of the carbonaceous material. The value of the electron microscope in studying the morphology of such materials has been well-established, and abundant information is available (Ishiguro et al., 1991; Lahaye and Prado, 1978; Buseck, 1992).The use of HRTEM has brought further insight into this matter. Qualitative assessment of the structural order of such materials has been attempted over a long period of time in order to differentiate between various sources or treatments. There is, to date, no successful method available for quantifying the structural characteristics of various carbonaceous materials. This paper presents a technique which is able to recognize dif-ferent materials and to quantify the structural parameters of those materials using HRTEM and computational image analysis, including pattern recognition techniques.In the case of perfectly ordered graphitic crystals, electron diffraction is widely used for obtaining details on structure. Analysis of diffraction patterns can reveal parameters such as interplanar spacing, d002, crystallite size along the c-axis, Lc, crystal size in the plane of the layers, L., mean number of crystallites, Nc, etc.Complicated electron microscopy methods such as defocusing, tilted illumination, axial illumination, etc., often have to be used in order to characterize complex materials such as randomly oriented crystals in soots and carbons. Obtaining the right fo"

Jan 1, 1998

A symposium on the health hazards of respirable dust in the mining and milling of talc was held on May 8, 1973, in Washington, D.C. The results of medical effects on both human and animal subjects were presented. Methods for identification and classification of talc minerals were also presented. Analytical techniques discussed included X-ray diffraction, scanning electron microscope observation, electron probe, and optical microscopy.

Jan 1, 1974

By J. W. Watkins

This report describes in detail methods of making corrosion tests and chemical analyses that have been used extensively and satisfactorily in a study of plants in which various surface, waters and brines are conditioned and used for water flooding, brine disposal, and reservoir-pressure maintenance in Kansas, Oklahoma, and North Texas. The tests and analyses described were designed and adapted for use in the field in determining the relative corrosive and plugging tendencies of waters from various sources conditioned by different methods. Although the described methods were developed and used in testing oil-field waters in the Midcontinent oil-producing area of the United States, these same methods should be equally applicable to testing oil-field or highly mineralized waters throughout the world. Many of the methods used have been discussed by the writer (1)2/ previously, and some of them have been used for similar work in other laboratories. Early in the development of the practice of the subsurface injection of brines for disposal and increasing the recovery of oil, it became evident that different methods of chemical treatment and conditioning equipment would have to be devised to sustain desired injection rates into water-input wells. These changes became necessary because the highly mineralized waters produced with petroleum from deep formations became chemically unstable when pumped to the surface, owing to loss of dissolved gases as pressure and temperature dropped to atmospheric and to the contact with atmospheric oxygen at the surface.

Jan 1, 1954

By C. W. Van Noy

The procedure suggested in this report is intended for the use of engineers, esters, accountants, etc., in estimating the cost of chemical-type operations. It is intended to over operating costs, not investment costs, as the latter have been covered numerous other publications. However, as capital investment costs are reflected to a high degree in operating costs, it is important to point out that accuracy of investment costs is highly essential. Therefore, all factors that might be included under plant -capital costs should be considered, such as requirements of shops, employees' housing, etc. The procedure is designed primarily for use in types of chemical oper¬ations, such as the production of synthetic liquid fuels, anhydrous ammonia, and others of like or similar nature. Yet, no attempt has been made to cover the entire chemical industry.

Jan 1, 1949

By D. Harrington

The Bureau of Mines was created in 1910 largely to determine methods of preventing coal-mine explosions; the Bureau's studies have proved that coal dust, except possibly that of some grates of anthracite, can initiate an explosion in the absence of gas and that its ability to extend or propagate an explosion of either gas or dust has been responsible for nearly all of the widespread explosions that have taken place in bituminous and other nonanthracite mines in the United States in the present century. It is believed by many persons that all atmospheric dusts may be harmful if breathed in large enough quantities for long enough time; bituminous coal dust is generally considered to be essentially harmless physiologically, yet there is abundant evidence of definite damage from inhalation of bituminous dust mixed or unmixed with the dust of other materials. Attention un¬questionably should be given to allaying dust in bituminous mines, especially at principal dust-producing sources. This publication enumerates some of the sources of dust and describes practical methods of employing water as one of the most effective of the known methods to allay dust in bituminous mines.

Jan 1, 1938

By S. H. Lorain

"INTRODUCTION The veins of the Clark Fork district have been mined on a small scale since 1913. In May 1943, the district was examined by an engineer 3/ of the Bureau of Mines with a view to possible exploration for larger ore deposits that might be of value to the war effort. The area adjacent to the Hope, Whitedelf, and Lawrence mines was re-examined 4/ December 27, 1943. As a result, the Bureau of Mines started exploratory operations in the district during the summer of 1944 which was continued until the late spring of 1946. This report presents the data obtained from the investigation.ACKNOWLEDGEMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project' as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts the preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests."

Aug 1, 1946

By A. Wahab Khair

"This paper presents an analysis of fracture mechanisms in coal subjected to bi-axial state of stresses, indentation of laterally confined coal specimen. Coal specimens were loaded to failure by the straight wedge indenters at various lateral confinement pressures. Strain distribution and acoustic emission characteristics of coal specimens under stress were recorded. The influence lines of vertical forces acting on the horizontal straight boundary of the coal specimen for each type of wedge indenter have been established using holographic interferometry technique. The effects of wedge indenter angle, confinement pressure, and coal anisotropy on fracture types, failure modes, and post-failure conditions were studied. The results indicated that combined application of holographic interferometry and acoustic emission monitoring techniques is not only suitable ·for studying deformability of heterogeneous and microscopically discontinuous material under stress but it also enhances the mode of fracture during the post failure stage. INTRODUCTIONOne of the relevant processes in the coal cutting technology is the application of indentation theories. Since most cutting tools in the coal industry are wedge shaped most of the indentation research is found for a wedge shaped tool.A wide range of behavior is found in different rocks subjected to the wedge penetration. A rock which is elastic brittle at standard pressure might become elastic plastic at high confining pressure (Gnirk and Cheatham, 1963). It was also observed that some rocks will merely be crushed and indented by a wedge whereas others will crack and form chips, furthermore the existence or non-existence of chips depends mostly on the geometry of the indenter, type of rock and the depth of penetration (Evans and Murrel, 1958). However, coal cutting technology is mostly explained by models which use rigid wedge to penetrate into a brittle material in which both crushing and chipping will occur (Evans and Murrel, 1958, 1962)."

Jan 1, 1988

By Roy A. White

The development of a fire and rot-resistant coating treatment for mine timbers, along with the associated processing technology, is described. Included are a literature search, laboratory studies of polyimide-fungicide coatings, and leaching and fungus growth studies on coated wood blocks. Finally, an economic analysis is performed tor various levels of production.

Jan 1, 1977

By R. C. Buehl

A pyrometallurgical process for recovering manganese from open-hearth furnace slags or low-grade manganiferous iron ores is described. The slag or ore is smelted in a blast furnace to produce spiegeleisen; the speigeleisen is then blown with air in a basic converter to give an oxide slag. This slag product contains 60 to 75 percent manganous oxide and may be considered a synthetic manganese ore. In the smelting operations coke rates for five test periods ranged from 3,255 to 4,130 lb per ton of spiegeleisen. The recovery of manganese in the spiegeleisen varied from 60 to 76 percent. Recovery increased to 83 percent when the open-hearth slag feed to the blast furnace was diluted with a high-? grade iron ore sinter to facilitate smelting. In blowing the spiegeleisen a cyclic procedure was developed that gave nearly 90 percent recovery of manganese in the slag product (synthetic ore) yet prevented excessive contamination of the slag by phosphorus and iron. The overall recovery of manganese was about 75 percent when iron ore sinter was used with the open-hearth slag in the smelting step. The metal remaining after oxidizing the manganese from the spiegeleisen contained approximately 3.5 percent phosphorus. It was refined in a basic converter by blowing with air in the presence of lime" A high--grade iron and a basic phosphate slag were produced.

Jan 1, 1965

By G. S. Scott

The Bureau of Mines is engaged in research to assess the hazards associated with the handling, storage, and use of combustible gases, vapors, and. liquids encountered in mines and in industry. As a part of this general pro-gram, numerous limits of flammability and ignition temperatures are being investigated for a wide variety of combustible materials, and methods are being developed to minimize the explosion hazards of these combustibles. The Bureau receives numerous requests for information on the explosion hazards of specified combustible mixtures under various conditions of use. This information circular has been prepared to assist those who may have similar requests. Destined primarily for the layman with a limited technical knowledge of the subject, it considers rather briefly the numerous factors that enter into the general problem of gaseous explosions and their prevention.

Jan 1, 1951

By Bernard M. Larsen, Clyde F. Williams, Edward P. Barrett

"Introduction.The Bureau of Mines at its Northwest Experiment station has been studying the production of sponge iron for the past four years, and during 1923 progress advanced to the point industrial applications can be safely considered. A furnace was operated commercially at silver City, Utah, producing about three tons of sponge iron daily.The Bureau was led to undertake this work by the interest in the use of sponge iron for copper precipitation and for conversion to iron and steel in the electric furnace.If a piece of iron oxide is completely reduced at such a low temperature (850 to 900° C) that no sintering or fusion takes place, then the piece of metallic iron formed has the same size and shape as the original piece of oxide on account of the removal of oxygen, the structure is finely porous, exposing a large surface of iron, and the apparent density is less than that of the original piece of iron oxide. This material is called ""sponge iron"". Chemically, it is a very reactive material."

Nov 1, 1924