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By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Clay, Gilmer, and Lewis Counties, W. Va. In 1966, almost 1.3 million tons of coal was mined in these counties, of which more than one-half was from the Pittsburgh coalbed. Washability analyses were made of 16 coalbed samples. Of these, only 11 samples could be upgraded to metallurgical quality. For steam or power generation five of the coals were of low sulfur content as received. The remaining samples were generally of medium sulfur content even after upgrading.

Jan 1, 1969

By BUREAU OF MINES

In 1948 the United States became a net importer of oil. Coupled with an unpre- cedented domestic production of 5,900,000 barrels daily, imports approximating 500,000 barrels made available a total supply of 6,400,000 barrels a day. Thus, by herculean effort, the oil industry was able to meet an extraordinary demand at home and, in addition, to ship abroad almost 400,00 barrels daily of petroleum and products. The country's oil position now differs greatly from that prevailing at the be- ginning of World War II. Then, actual oil production averaged about 4 million bar- rels a day, and productive capacity probably was greater than 5 million barrels a day. As the demand of the military and industrial machine grew with the rising tempo of the drive toward victory, the United States not only met its own needs but pro- duced about two-thirds of the total oil requirements of the Allied Nations, excluding Russia. As a people, we can be deeply grateful that the Nation's petroleum resources were adequate and sufficiently developed to support such a tremendous effort. Even in those critical hours when immediate needs were the paramount issues, a prudent Congress paused to contemplate the importance of an assured long-term supply of liquid fuels. From these deliberations came the Synthetic Liquid Fuels Act of 1944, which authorized research and development work on new sources of oil coal, oil shale, and agricultural and forestry products. ce World War II, a civilian demand for 6 million barrels of petroleum prod- ucts has become the order of the day every day. By drilling as many as 39,000 new wells a year, the production rate has been increased enough to meet domestic require- ments by a bare margin. Some imports were necessary, however, to fill both domestic and foreign demands, and these doubtless will increase. Is this policy of exploration within the United States and the development of oil in foreign countries adequate insurance for the fulfillment of our future national needs? This question has two aspects one purely civilian and economic in character and the other significant from the standpoint of our national defense. There are now approximately 4,000 producing oil fields in this country. At first thought, it would appear that production could decline in a considerable number of these fields without materially affecting the over-all daily output. However, 48 percent of the oil comes from only 111 major fields which contain 50 percent of the total proved domestic reserves. It is apparent, then, that the flow from large fields - having proved reserves of 100 million barrels or more each must be sustained if daily production is to be kept at the present levels. Essentially, this means that new major fields must be discovered about as rapidly or perhaps more rapidly than the older ones lose productive capacity. From 1940 through 1947, only eight major fields with estimated reserves of more than 100 million barrels each, were discovered and proved - an average of one such field a year. The total estimated reserve of these eight fields was less than 1 year's supply at the present rate of use. As drilling continues, some existing fields ultimately will prove reserves larger than those now known. Without a pronounced increase in the num- ber of major discoveries, however, the prospects for increasing our present productive level are not encouraging. Any gap that appears between domestic productive capacity and demand could be filled with supplies from proved oil resources abroad. Assuming cheap pipe-line and tanker transportation to the United States, freedom from exorbitant taxes and charges

Jan 1, 1949

By G. W. Birge, D. E. Wolfson, J. H. Lynch

This report presents all available 900 ° C BM- AGA carbonization and related data for coals from the principal beds of the southwest Virginia field in a form which permits ready comparison of product yields and properties of coals and cokes . Thirty- one channel samples from Buchanan , Dickenson , Russell , Tazewell , and Wise Counties were carbonized at 900 ° C in an 18 - inch - diameter retort . Blending properties of 10 of the coals were studied , and expansion of most of the coals and blends was measured in the Bureau of Mines sole - heated oven . Ash Most of the samples were chemically suitable for metallurgical use in coking blends , and their coking properties generally were satisfactory . content exceeded 10 percent in only three samples , and none of the coals contained more than 1.5 percent sulfur . Dry , mineral - matter - free fixed - carbon content of the coals ranged from 62.1 to 77.5 percent . Expansion behavior varied widely , ranging from 16.8 percent expansion to 27.6 percent contraction .

Jan 1, 1964

By Laird Crocker

This report describes a study of beryllium recovery from sulfate leach liquor by di-2-ethylhexyl phosphate (EHPA) solvent extraction in conjunction with caustic stripping. The work was one phase of Bureau of Mines research on process development for Spor Mountain, Utah, ores. Solution for the solvent extraction studies was prepared by sulfuric acid leaching of ore containing 0.6 pet BeO, Before solvent extraction of beryllium, the leach liquor was treated to prevent coextraetion of iron by either (1) removal of ferric iron by amine solvent extraction or (2) reduction of ferric iron to nonextractable ferrous iron by treatment with sulfur dioxide. Beryllim was extracted from the aqueous leach liquor by countercurrent multistage contacting with a kerosine solution of EHPA. The loaded organic solution was stripped with sodim hydroxide solution. Subsequently, beryllium hydroxide was precipitated by boiling the sodium beryllate strip solution and converted to beryllium oxide of 98 pct BeO-grade by calcining. Material of this grade can be directly processed into beryllium-copper alloy or be used as starting material for further refining to produce high-purity, nuclear-grade beryllium. Over 90 pct of the beryllium contained in the leach liquor was recovered as beryllia.

Jan 1, 1963

By Robert W. Freedman

The Bureau of Mines investigated methods of analysis of free silica in respirable dust, including both work done at the Bureau of Mines and work done elsewhere. The review covers both coal dust and noncoal dust, taking into account both existing and proposed chemical and spectroscopic procedures.

Jan 1, 1971

By D. Harrington

Approximately 6,000 coal mines are operated in the United States. All of them have in some degree the elements that are likely to contribute to an explosion, hence it is surprising that explosion disasters are not more frequent and that many mines have been operated for years and finally worked out and abandoned without experiencing an explosion. The absence of coal-mine explosions does not always indicate that effective efforts have been made to prevent them but rather that the nine has been fortunate in that the combination of circumstances necessary to cause an explosion has not existed. In view of present knowledge of the methods of preventing explosions, disasters are inexcusable and discredit the mining industry. The methods of preventing mine explosions are known to experienced, well-informed persons engaged in coal mining, yet despite this knowledge far to many coal-mine operators continue to use practices and methods that they should know have resulted in numerous explosions. Moreover, many mine workers persist in following past procedure irrespective of consequences and in breaking safety rules or indulging in practices almost certain eventually to result in disaster. Continued failure to apply known common-sense methods of accident and explosion prevention unquestionably will cell for ultimate enforcement of law.

Jan 1, 1940

By Marcia L. Harris

The National Institute for Occupational Safety and Health (NIOSH), as part of its continuing research program for evaluating coal dust explosion hazards, has investigated several areas in which current practices may need to be updated in order to adequately protect mines against coal dust propagated explosions. In the United States, current rock dusting requirements remained largely unchanged since 1969. US Title 30 Code of Federal Regulations Section 75.403 is based on a coal dust particle size survey performed in the 1920s and later was supplemented by full-scale testing of the rock dust ability to inert a coal dust explosion. NIOSH recently conducted a comprehensive survey of US underground coal mines to determine the range of coal particle sizes found in dust samples collected from the mine entries. Due to advancements in technology and modern coal mining techniques, the current coal dust particles in intake airways are significantly finer than those found in the mines in the 1920s. According to past full-scale dust explosion test results, the current rock dusting practices used in today?s mines to inert a coal dust explosion may not be adequate. Other closely related issues such as rock dust testing methods and sampling procedures are discussed.

Jan 1, 2009

By Robert E. Meredith, Thomas T. Campbell

An investigation was undertaken to examine the feasibility of employing low- temperature nonaqueous baths for electrodepositing some of the refractory metals of the ferroalloy group . To date , such metals as tungsten , molybdenum , and vanadium have been produced only by high - temperature processes that are technically difficult and sometimes cumbersome in operation . Deposition studies were performed in a wide variety of organic solvents , including amides , ammonia derivatives , ketones , polyhydroxy alcohols , and ethers . Compounds prepared and used as solutes included the chloride and bromide salts of vanadium , tungsten , and molybdenum . Studies were conducted over a temperature range of 20 ° to 200 ° C under inert atmosphere . Conductivity and current potential data were obtained for all baths that contained reasonable solute concentrations . Qualitative solubility data were obtained for compounds of ferroalloy metals in a variety of solvents . In general , all solutes showed low solubility in ethers and ketones but reasonable solubility ( in excess of 20 grams per liter ) in alcohols , amides , and ammonia derivatives . No successful metallic deposits that would encourage further study were obtained with any of the systems that were examined .

Jan 1, 1963

By D. E. Wolfson

This report describes the carbonizing properties of the principal coal beds of Allegheny County, Pa., which rank low in the high-volatile A bituminous classification. Seven coal samples from 3 coal beds were selected for study, as follows: 2 each from the Redstone and Pittsburgh beds and 3 from the Upper Freeport bed. Selection was based on estimated reserves. The samples of Upper Freeport and Pittsburgh coals were satisfactory chemically for producing metallurgical coke. The ash contents of the samples of Redstone coal were moderately high. One of the samples of Redstone coal was high in sulfur content, and it would be difficult to upgrade to meet present metallurgical standards.

Jan 1, 1959

By W. M. Dressel

The objective of the research reported in this publication of the Federal Bureau of Mines was to devise a mineral dressing procedure that would concentrate zinc silicate minerals from certain deposits in southwestern Missouri. The best flotation results were obtained by batch laboratory flotation using sulfidizing agents and ethoxylated cocoamine. The flotation concentrate contained 70 percent of the zinc at a grade of 47.8 percent. Gravity concentration tests showed that 55 percent of the zinc could be recovered at a grade of 48.3 percent.

Jan 1, 1961

By McHenry Mosier

This paper is one of a series recently undertaken by the Mining Branch of the Bureau of Mines to describe current practice in diamond drilling for production at various mines throughout the United States and to discuss the relative merits of this method compared with drilling by percussion rock drills . The Bureau of Mines and the mining companies that are cooperating with it in this ' investigation have the objective of developing information on diamond -drilling blast holes for the benefit of all who are interested in the possible improvement of mining operations .

May 1, 1947

By G. W. Reimers

Exothermic oxidation reactions of sulfide minerals can produce self-heating situations in underground mines. If the self-heating is unchecked and the resulting heat is not sufficiently dissipated, the result can be spontaneous combustion fires. This U.S. Bureau of Mines report describes laboratory tests conducted to measure the reactivity of pyrite following treatment with additives to counter its self-heating tendencies. Thermal gravimetric analysis (TGA) and isothermal oxidation procedures were used to obtain information on pyrite ignition and the behavior of pyrite during low-temperature oxidation to ferrous sulfate. The determination of treatment effectiveness was evaluated by adding 5 wt pct of the compound to the pyrite before milling. The resulting samples were then heated in moistened air and after 24 h, the amount of pyrite oxidation determined. Results of these tests indicated that several phosphate compounds reduced the oxidation of pyrite to sulfate to about 50 pct or less compared with the oxidation of untreated sample at 200° C. Cupric sulfate reduced oxidation to about 20 pet untreated sample at 200° C. Sodium, calcium, and potassium chloride reduced pyrite oxidation to levels of approximately 15 pct or less of the untreated sample. Using only 1 pct of sodium or calcium chloride was effective in slowing pyrite oxidation to less than 20 pct of the untreated sample.

Jan 1, 2010

By A. W. Deurbrouck

The Bureau of Mines analyzed 13 samples collected from three Randolph County coalbeds. The Peerless and Sewell bed samples were generally of metallurgical quality as received from the mines or could be easily upgraded. How-ever, the Lower Kittanning coa1bed samples proved to be quite inimical to upgrading to metallurgical quality.

Jan 1, 1966

By F. S. Crawford

Interesting data on electric blasting and sinking of the Montreal No. 5 shaft of the Montreal Mining Co., Montreal, Wis., were obtained during the sinking of the last 877 feet of this shaft. Several unusual features and safety practices are also to be found in the Montreal mine. The Montreal shaft was sunk 2,156 feet from August 16, 1921, to May 1, 1924, and 877 feet from October, 1927, to June, 1928. The first section of the shaft was supported with steel sets spaced 5 feet on centers; and instead of lagging the walls were covered with three-eighths of an inch of gunite where Greenstone was encountered, and where quartz-slate was found (from the surface to the 12th level) the walls were lagged with tamarack lath treated with carbolineum, a preservative.

Jan 1, 1929

By V. A. Marple, K. L. Rubow, Y. Tao

"A personal diesel exhaust aerosol sampler has been designed and evaluated in both laboratory and field settings. The sampler uses size selective sampling for the determination of the respirable mass concentrations of mineral dust and diesel exhaust particulate matter found in underground coal mines. This design is based on the premise that diesel exhaust particulate matter is predominantly less than 0.8 um while mineral dust is greater than 0.8 gm. Operating at a flow rate of 2 L/min, the sampler consists of a 10 mm Dorr-Oliver respirable dust cyclone followed by an 0.8 gm cutpoint impactor and an afterfilter. Field evaluations consisted of sampling at 6 different locations in these underground coal mines. Measured aerosol concentration less than and greater than 0.8 um have been compared with a well characterized cascade impactor.Techniques must be developed for measuring the mass concentration of diesel exhaust particulate matter found in underground coal mines due to the health concerns associated with worker exposure to diesel exhaust particulate matter. Diesel exhaust particles are in the respirable size range and have been regarded as a potential occupational carcinogen by NIOSH (1988). Furthermore, a 1988 MSHA advisory committee directed MSHA to develop a sampling protocol for assessing worker exposure to diesel exhaust particles.The University of Minnesota and the Bureau of Mines, over the past 4 years have measured the size distribution of diesel exhaust particles and mineral dust, both in the laboratory and underground mines (Cantrell, 1987; Cantrell et al., 1987; Cantrell and Rubow. 1988; Marple et al, 1986; Rubow et al., 1988: and Watts et al., 1989). To date, measurements have been made in nine coal mines. Seven mines utilized diesel-powered equipment at the mine face while two used electric-powered equipment. The results of these field tests indicate that mineral dust and diesel exhaust particles can be differentiated on the basis of particle size. The measured particle size distributions have been found to be bimodal with a saddle point at 0.8 um. This has led to the hypothesis that one method for measuring worker exposure to diesel exhaust particles would be to collect size fractionated particle samples separated at 0.8 um with the diesel particles being less than 0.8 um and the mineral dust particles greater than 0.8 um.Aerosol size distribution measurements, using a micro-orifice uniform deposit impactor (MOUDI), have been conducted in the mine intake air portal, intake entry to the working section, haulageway, and section return entry. The MOUDI is a ten stage cascade impactor with particle cutpoints ranging from 0.1 to 15 um aerodynamic diameter (Marple and Rubow. 1984b; Marple et al., 1989). The sampling flow rate is 30 L/min."

Mar 1, 1992

By J. M. Stuve

Standard heats of formation (AH°p) of YbCl3 (c) and TmCl3 (c) were measured by solution calorimetry. Heat of solution data are given for ytterbium and thulium metals and corresponding anhydrous trichlorides in 4.360 molal hydrochloric acid. The derived standard heats of formation of YbCl3 (c) and TmCl3 (c) were -229,370 ±720 and -235,820 ±400 cal/mole, respectively, at 298.15° K. The resulting heats of formation for YbC13 and TmCl3 are about 1 kcal and 6.3 kcal more negative than previously published values.

Jan 1, 1967

By Donald W. Scott

Chemical thermodynamic properties for the ideal gas state from 0 to 1500 K are tabulated for all of the alkane hydrocarbons through C10. These properties are based on correlations of the extant data for the entropy, vapor heat capacity, and enthalpy of formation of individual alkanes and the equilibrium constants of alkane isomerization reactions.

Jan 1, 1974

By G. H. Cobb, J. L. Johnson, H. H. Heady

An infrared absorbance technique is described for analyzing anodic gases produced during the electrowinning of uranium , thorium , and rare - earth metals in molten fluorides . Typical components determined qualitatively in a gas sample are CO , CO₂ , CF4 , C₂ Fe , C3F8 , COS , CS₂ , and SiF4 . About 20 minutes are required to record and interpret the spectrogram , and report quantitative results for CO, CO₂ , CF4 , and SiF . The procedure is used for control during electrolysis .

Jan 1, 1964

By W. P. Yant

A previous report of the Bureau of Mines dealt with the toxicity of dichlorodifluoromethane, a new refrigerant that has a remarkably low toxicity. Continued research by the Frigidaire Corporation and toxicological experiments performed in the Laboratory of Applied Physiology of the University of Cincinnati revealed another organic fluoride, dichlorotetrafluoroethane, whose toxicity also appeared to be of a very low order and whose physical and chemical properties make it suitable for refrigeration purposes. In addition to low toxicity, safety in its use is further enhanced by its physical properties, which permit the design of equipment that operates at comparatively low pressures and hence mitigates the dangers and problems of leakage. The investigation described in this report was performed by the Bureau of Mines at the request and with the cooperation of the Frigidaire Corporation.

Jan 1, 1932

By M. M. Tilman

A series of alloys was laboratory prepared by adding up to 4 weight-percent cobalt to the basic composition of type AM 350 (AISI 633) stainless steel. Aging curves were established for each alloy at 750° F, 850° F, and 950° F for lengths of time up to 100 hours. A series of annealed steels containing as much as 1 weight-percent cobalt was cold-rolled 50 percent and aged for 3 hours at 850° F. No improvement in hardness due to cobalt was observed in the steels transformed by heat treatment. Slight improvements in hardness were observed in the steels transformed by cold working.

Jan 1, 1968