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By T. Estelle Gardner, A. R. Taylor

Heat capacity measurements were made on sodium bromide ( NaBr ) and sodium iodide ( NaI) in the temperature ranges of 7 ° to 300 ° K and 56 ° to 300 ° K using an adiabatic calorimeter . Smooth values of heat capacity, entropy , enthalpy function , and free- energy function were calculated from the heat capacity data at 10° K intervals and at 273.15° and 298.15° K. Entropy and free energy of formation values at 298.15° K also were calculated for the two compounds using entropy values determined in this study and other data reported in the literature . The entropy values calculated at 298.15 ° K were 20.75 ± 0.06 entropy units (eu ) for sodium bromide and 23.55 ± 0.07 eu for sodium iodide .

Jan 1, 1964

By F. S. Crawford

Companies which have been engaged in safety work for a number of years are becoming increasingly aware of the fact that it is not enough to supply guards for various pieces of machinery and equipment and to supply safety inspection to see that rules are being carried out. Studies of many safety organizations have demonstrated that the accidents which could have been prevented by proper guards constitute only a small percentage of the total acci- dents, and amount to perhaps not more than 15 per cent. Evidently, if success is to be attained in preventing all accidents which it is humanly possible to prevent, a company must have the cooperation of every employee. Mining particularly presents probably the greatest hazards of any industry. Prevention of accidents. is made increasingly difficult because men often work alone, although generally in pairs, and only in the concentrated systems of mining do they usually work in groups of more than three or four. Supervision is difficult, therefore, and much reliance must be placed upon the individual workmen. In mining, as perhaps in no other occupation, it is of the greatest importance that individual workmen should receive continuous safety education. Within the last few years safety education has come to the front as one of the most important of accident-prevention measures, although it is true that its importance has been repeatedly stressed by the United States Bureau of Mines and other national safety organizations since the inception of the safety movement many years ago. A review of the safety educational methods of some companies in the Lake Superior district should be of interest. Perhaps better methods are in use in other parts of the country, but the methods shown have been instrumental in many cases in reducing the number of accidents. In one mine in the district whose methods are described the frequency of accidents has been reduced to zero within the last two years. A number of other mines in the district have recently gone into the class having no lost-time accidents for considerable periods of time. One company in the Lake Superior region, operating over 30 mines, succeeded during one month of 1930 in operating every mine without having a single accident which caused lost time beyond the day of the injury. Records like these are increasing in number, and while it is believed that they are the combined result of different means of safety activity, it is undoubtedly true that many of these results were obtained through safety educational methods.

Sep 1, 1931

By C. E. Augustine, B. A. Landry, P. Nicholls

"Wien bituminous coal is burned in a hand-fired up-draft boiler used for heating purposes it has a decided tendency to produce smoke. A design of furnace and a method of firing and attendance that are satisfactory for fuels low in volatile matter, as anthracite or coke, are not necessarily Satisfactory for bituminous coals. It is therefore becoming common practice to use a special design of furnace for bituminous coals, in order to facilitate the combustion of the volatile matter and soot. This is done by (1) providing a larger combustion space to give more time for the combustion, (2) construction that will produce a better mixing of the gases and secondary air supplied over the fuel bed, or (3) keeping the gases at a higher temperature by preheating the secondary air, as may be done by surrounding them with refractory surfaces, or causing them to pass through a fuel bed of hot coke. A furnace may be built to use any or all of these methods of smoke prevention.In Bureau of Mines Technical Paper 303, Blizard5 and others give tests on a large heating boiler when burning coke, anthracite, and bituminous coal. Certair alternative furnace arrangements were used, but there was no material change in the furnace design for the various fuels. Since that time the manufacturer has made modifications in design to adapt it for use of bituminous coal, and additional tests have been made to determine how this change affected the production of smoke and the efficiency of the boiler."

Jun 1, 1929

By Vernon C. Davis

"INTRODUCTION This report describes the work done and presents the data obtained from limited diamond drilling at the lead-zinc deposits cf the Belle Eldridge Gold Mines, Inc., in Lawrence County, S. Dak. during the summer and fall of 1943. The work was undertaken in an effort to increase reserves and step-up production of zinc and lead so vitally important to the war program.The geology, topography and existing mine workings were mapped and studied. Subsequently, six vertical core-drill holes were put down from surface sites.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our natural resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, Oliver C. Ralston, chief, analyzes samples and makes beneficiation tests, if such are necessary.Special acknowledgment is made to John Paul Gries, geologist, South Dakota School of Mines, for mapping and interpretation of geology and topography, logging of cores obtained, and his assistance in guiding the drilling."

Mar 1, 1948

The latest Active List of Permissible Explosives and Blasting Devices was published in July, 1929, as Bureau of Mines Report of Investigations 2947, 2 under the title or "Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1929.' Subsequent Reports of Investigations 2253, 2958, 2962, 2972, 2988, 2992 and 3000, were issued to record the official actions taken during July, August, September, October, 1929, and January, February, and March, 1930. No changes were made during November and December, 1929, and April, 1930. The following additional changes in the list recording the actions taken during May, 1930, are now authorized. [ ]

Jan 1, 1930

By X. Shi, N. S. Dala, V. Vallaythan

"Cellular damage induced by silica dust is known to be associated with increased fragility and destabilization or destruction of the cell membranes. The mechanism by which silica dust effects biological membranes is still unknown. Using the ESR spin-trap methodology, we find that hydroxyl radicals are generated in aqueous suspensions of freshly ground silica. The amount of the radicals generated depends on the extent of grinding and ""freshness"" of the dust. Using linoleic acid as a model lipid, we show that the silica dust causes lipid peroxidation via ·OH, 02-, or linoleic acid related radicals as intermediates. Catalase and superoxide dismutase inhibit the formation of these radicals. The results suggest that free radicals associated with freshly ground silica and the related lipid peroxidation of the memberanes may be the starting point of the silicotic processes.INTRODUCTIONDespite considerable-effort over the years, the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrosis are still not fully understood (1,2). It is generally thought, nevertheless, that the interaction of the quartz particles with the cell membranes is the starting point of the silicotic process (3). We felt that the mechanism of the membrane damage by quartz might involve oxygenated free radicals because (a) a suspension of quartz particles in contact with alveolar macrophages has been reported.(4,5) to initiate an enhancement of lipid peroxidation, defined broadly as the ;oxidative deterioration of polyunsaturated components of lipids, and (b) hydroxyl (·OH) radicals are known to be capable of peroxidation by abstracting hydrogen atoms from cell-membrane lipids (6) and initiating lipid peroxidation in lysosomal membranes (7). Moreover it is known that exposure of cell membranes, fatty acids and unsaturated food oils to ionizing radiation, which generates ·OH. radicals, causes rapid peroxidation (6). Earlier studies o~ the aqueous chemistry of quartz suspensions have reported detection of HzOz (8), implicating the formation of ·OH radicals as transient species, but, we are not aware of any report of the detection of ·OH radicals in quartz suspensions and this provided the motivation for the present undertaking. Since it is known that, because of their high reactivity (hence short life time) in aqueous media, the ·OH radicals cannot be detected via electron spin resonance (ESR) directly (9,10), we have used ESR combined with the spin-trap methodology (9) for studying the •OH formation."

Jan 1, 1988

By Peter L. Swanson

NIOSH has developed an automated PC-based seismic monitoring system for use in mine ground control studies. The distribution and coordination of data acquisition and processing functions across a local area network (LAN) is a central feature of the system. Design requirements include (1) the use of lowcost, off-the-shelf, data acquisition and computer hardware, (2) the capability of automatically merging waveform data sets from different types of monitoring systems, (3) delivery of raw and processed data underground and on the surface, as well as to remote sites, and (4) automated data collection and processing over long periods of time without the need for human intervention. Current mine-wide installations utilize multiple, autonomous seismic networks located both underground and on the surface and provide 20 to 40 stations within a radius of several kilometers. Event locations, magnitude estimates, and other processed data are distributed for display and analysis on network nodes both underground and in the offices of mine engineers and managers. This paper describes the system's hardware and software components, examples of installations in hard-rock and coal mines, and a few observations from western U.S. longwall coal mines.

By Valois R. Shea-Albin

An accurate assessment of the vertical stress on a coal seam at depth is important for mine design. Vertical stress calculation techniques presently available either are not sufficiently accurate or cannot handle complex surface topography. Therefore, the U.S. Bureau of Mines developed a computerized method to calculate vertical stress exerted on surfaces at depth that includes the effect of topography. Two input data sets are required: a digital elevation model containing topographic elevations and a coal seam file defining coal seam elevations at depth. Boussinesq's equation then quantifies the vertical stress resulting from topography. The computerized method was tested on a coal seam overlain by a complex topography where a vertical stress map encompassing several square miles was produced. Results show that depth mitigates the affects of surface topography, while the coal seam topography has a direct effect on the vertical stress. In comparison to the computerized method, the direct stress method overestimates stress under hills and underestimates stress under valleys. The largest difference between the two methods occurs under the steepest topographic relief. A limitation of the computerized method is that stresses cannot be accurately determined near an outcrop.

Jan 1, 2010

By T. J. Ballard

The Ore Knob mine, in Ashe County, N.C., was one of the largest producers of copper in the eastern states during the 1870's. The ore occurs in a fissure vein, which strikes N. 64° E. and dips nearly vertical. The country rock is granite gneiss. Drilling indicated that the vein structure is approximately 200 feet wide and 1,500 feet long. The vein material shows evidence of replacement of the original gneiss by sulfides. Solution cavities in the vein were noted in some places. The ore minerals and pyrrhotite, chalcopyrite, pyrite, and minor quantities of sphalerite. The gangue contains biotite, magnetite, albite, calcite, and many silicate minerals.

Jan 1, 1948

By S. P. Kinney

During 1925, at Holt, Ala., the United States Bureau of Mines made a study of the composition of the gases at four elevations in the shaft of a furnace producing foundry iron. A report3 of the work was published in 1927. Some of the results of this investigation are shown in Figure 1. As indicated, the gas at the center of the shaft is low in CO2 content, while the gas in the vicinity of the wall is higher in CO2. The composition of the gases at the top and at the center of the stock column was not far different from the composition of the gas at the top of the bosh. The investigation indicated clearly that lean gas was channeling through the center of the column. More recently the study was enlarged in scope to include investigation of a furnace operating on Lake Superior ores in the Chicago district. A series of planes between the stock line and tuyères was surveyed. Means and apparatus were developed for obtaining, between the inwall and the center of the furnace, the gas composition, gas velocity, and temperature on each plane. A complete report4 of the investigation has recently been published.

Jan 1, 1929

By Jon C. Volkwein

The U.S. Bureau of Mines has developed a method to measure methane and other gases during the auger mining of coal. An intrinsically safe commercial gas detector with a built-in data logger was mounted in the center of the hollow conveying auger. A sampling head through the wall of the auger conducted a gas sample to the detector. Results showed that gas levels can be monitored on a continuous basis during the auger mining of coal and the data retrieved upon completion of the hole.

Jan 1, 1994

By R. D. Govier

The U.S. Bureau of Mines has developed a thin-film X-ray fluorescence technique to rapidly determine Cu, Ni, Co, Fe, and Cr in super alloy leach liquors. Total analysis time per sample was less than 15 min, as opposed to several hours for traditional wet chemical methods. Precision and accuracy were checked by replicate analyses of solutions similar in composition to leach liquors, whose analyte concentrations were well known. Coefficients of variation for all elements were found to be less than 2 pet. With the exception of the results for Fe, all relative errors of estimation were also found to be less than 2 pet. Bulk liquids are not introduced into the spectrometer; thus, the potential for damage to the instrument by leakage of corrosive liquids is eliminated.

Jan 1, 1989

By Arnold F. Stalder

The measurement of various gas concentrations in the atmosphere at a particular location has become a problem of considerable importance. Levels that need to be monitored vary from the range of percent for constituents such as oxygen to parts per million levels for gases like nitrogen dioxide. In particular, mine air can become contaminated with noxious or toxic gases from several sources: fires within the mine, diesel-powered equipment, and explosive sources. The contaminants that result are carbon monoxide (CO), carbon dioxide (CO2), and oxides of nitrogen (NO and NO2). Additionally, oxygen (O2) may be depleted. Thus, the workman can be exposed to potentially toxic or asphyxiating atmospheres. A device was needed that will continuously monitor the mine air in working areas and provide warning of hazardous atmospheres. The Mine Air Monitor was conceived as being a portable, rugged instrument capable of measuring the concentration of the various atmospheric constituents in the mine environment. The unit was to provide both warning signals and quantitative measurements when hazardous contaminants existed at too high a level, or when the oxygen was being depleted. The initial concept involved optical sensors for all of the contaminating gases to be measured, namely CO, CO2, CH4, and NO2, and an electrochemical cell to monitor O2. When the explosion proof requirements of Schedule 2-G made the concept appear to be unfeasible from the standpoint of weight and portability, the program was redirected and a three channel monitor employing electrochemical sensors was adopted. In this case the gases to be monitored were O2, CO and NO2. The remainder of the program was oriented towards obtaining good, commercially available lectrochemical sensors for the above gases, testing them, reducing deficiencies noted during these tests, and making the necessary modifications to integrate the three sensors into a Mine Air Monitor suitable for the mine environment.

Jan 1, 1974

The Bureau of Mines, in an effort to improve resource conservation, mine planning and development, is currently investigating the loading behavior of pillars in multiple-seam developments. The simultaneous mining of two or more coalbeds may cause instability between room-and-pillar operations resulting in an interaction known as pillar load transfer. Although pillars may be adequately designed for single-seam mining, the development of a second seam may complicate loading conditions in both operations. If pillars are not adequately designed to contend with this load transfer, failure of the mine structure may result. To improve multiple-seam development and pillar design, the Bureau studied the loading characteristics of pillars in three separate multiple-seam operations. In all three cases, instrumented pillars recorded increasing pressure after development of the second seam. Increases in the average pillar pressure ranged from 7 to 110 pct over predicted overburden loads. An analysis of pillar loading before and after second-seam mining indicates that the ratio of overburden to innerburden thickness is a critical factor influencing load transfer. Based on this relationship, safety factors for case study pillars are calculated and alternative design considerations are discussed.

Jan 1, 1988

By Jacob Schoder

This is one of a series of papers published by the Bureau of Mines on mining and milling methods and costs. The Tennessee-Schuylkill Corporation, Chloride, Ariz., mines and mills a lead-zinc ore containing gold, silver, and a small amount of copper. The mill products are lead and zinc concentrates that are shipped to smelters. The company was the second largest producer of lead and zinc in Arizona in 1937 and was seventh in gold production. Operations discussed are those being conducted at the mine in October 1938 and are representative of the complete operating period from 1936 to date.

Jan 1, 1939

By D. W. Bridges, R. O. Dannenberg, Laird Crocker

Preliminary solvent extraction studies , reported by the Bureau of Mines (5) , have been continued and expanded to improve on the previous estimate of process requirements . The solvent extraction portion of the process was examined at a scale large enough to enable meaningful extrapolation of the results to geometrically similar equipment of plant size . About 82 pct of the beryllium was recovered from approximately 0.5 pct beryllium oxide (Be0) Spor Mountain , Utah , ore by a process involving ( 1 ) sulfuric acid leaching , ( 2 ) counter current decantation (CCD ) washing , (3 ) iron ( III) reduction by sodium hydrosulfide ( NaHS ) , ( 4 ) beryllium solvent extraction by di - 2- ethylhexyl phosphoric acid ( EHPA) , ( 5 ) caustic stripping of beryllium- bearing EHPA, (6 ) hydrolysis of sodium beryllate - caustic strip liquor , and (7 ) calcination of beryllium hydroxide (Be ( OH ) 2 ) formed in step (6 ) . The resulting beryllia assayed 98 to 99 pct Be0 and was suitable for most nonnuclear uses . Best overall results were obtained by using pH 2 , 1.6 grams of BeO per liter of leach liquor as feed and 0.25 N EHPA in kerosine containing 2 wt vol pct (grams per 100 ml of solution ) isodecanol ( IDA ) as solvent . Analysis of the data indicated that a commercial plant would achieve 95- pct overall extraction operating at 45 ° C with 20 hp per 1,000 gal of dispersion in each of seven mixer- settlers , having 290 gal per ton of ore hourly mixer capacity and 90 gal per ton of ore hourly settler capacity . At least 79 lb H2SO4 , 13 lb sodium hydroxide (NaOH ) , 3 lb NaHS , 0.25 lb kerosine , 0.07 lb polyacrylic flocculant , 0.03 lb EHPA , and 0.007 lb IDA would be required in H2SO4 leaching and subsequent processing to recover 1 lb BeO .

Jan 1, 1964

By Richard L. Rains

The Bureau of Mines conducted a mineral investigation of the 29,000-acre Dixie Summit area near Elk City, Idaho, during the summer of 1989. At the Petsite mine a marginally economic, identified resource of 4.9 million tons with an average grade of 0.023 ounces gold per ton was delineated. Possible resources of gold, along with silver, copper, lead, and zinc, occur in at least eight other lode deposits. Placer gold may be recoverable by recreational-sized suction dredges in some stream drainages, Five lode mines in the study area have produced over 5,516 ounces of gold (placer gold production was not recorded), 4,757 troy ounces of sliver, 36,746 pounds of lead, and 3,800 pounds of copper. Current mining claims in or adjacent to the study area total 460 lode and 70 placer claims. There are two patented lode claims within the Dixie Summit study area.

Jan 1, 1991

By J. E. Pahlman

The Bureau of Mines performed research on a fluid-bed magnetic roasting process for nonmagnetic taconites that utilizes low-rank coals and lignites as reductants and fuels. Roasting tests on a Michigan nonmagnetic taconite were conducted at 600° to 725° C with lignite or subbituminous coal as reductants. Partial combustion of the reductant reduced the amount of heat externally applied to the reactor to maintain the desired reactor temperature. Cleaned, dried reactor top gases were recycled to recover a portion of the reducing potential in these gases without adversely affecting concentrate grade and iron recovery. Highest iron recoveries for magnetic concentrates were obtained at a roast temperature of 650° C with lignite and at a roast temperature of 725° C with subbituminous coal. Magnetic concentrates were obtained that were comparable with commercial concentrates.

Jan 1, 1976

By W. E. Robinson

A laboratory study wan made to determine whether drying and preheating Colorado oil shale with waste retort gases has any appreciable effect on its oil yield. Samples of crushed oil shale were heated at subretorting temperatures in a specially constructed electric furnace by gases similar in composition to waste gases from oil-shale retorts. The results of this study showed that preheating oil shale with nitrogen or a reducing mixture had no effect upon the oil or water yield. However, oxygen in the preheating gas caused a decrease of oil and an increase of water. In general, the oil yield decreased with (1) increase in oxygen content of the heating gases, (2) increase in temperature of the heating gas, (3) increase in heating time, and (4) decrease in the particle size of tho shale. The decrease in oil and the increase in water resulting from preheating were due to oxidation of the benzene-insoluble organic material (kerogen) rather than to oxidation of the benzene-soluble organic material (natural bitumen) in the shale, A small amount of oil was volatilized during preheating, which would constitute an additional loss if prober precautions were not taken to recover it. The results obtained in this laboratory study indicate that oil shale can be preheated without appreciable decrease in oil yield by proper selection of preheating conditions.

Jan 1, 1951

By Lee M. Manna

This report summarizes the program to design, fabricate, install and preliminary test a pneumatic braking system for 10-ton mine haulage cars. Major arrangement drawings are reproduced, pneumatic schematics, parts list and actual developed costs. Recommendations as to system improvements are made.

Jan 1, 1977