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By Thomas R. Yanske, Jonathan E. Carmack, Lyndon M. Clark

In order to maximize the extraction of high grade pillars at The Doe Run Company, artificial pillars are created using cemented rock fill (CRF). CRF pillars aid extraction of pillars in two ways. One is to offer back support for the immediate area where pillars are being extracted. The second is to increase the post failure residual strength of pillars surrounded by backfill. The CRF is produced using a combination of minus 1.0 m run of mine (ROM) rock and minus 5 cm crushed rock. Depending on the operation the CRF slurry is either produced in an underground or a surface batch plant. The slurry and rock are transported to the fill area by truck where they are mixed and placed in 1 m lifts. To reduce the amount of CRF needed, fill fences are constructed around the perimeter of the CRF pillar. Within these fences ROM CRF is placed in lifts until within 0.6 m of the back after which minus five centimeter CRF is slung tight to the back utilizing slinger trucks. In constructing these artificial pillars a number of set procedures have been established to ensure that the work is done both properly and safely.

Jan 1, 2001

By Henry S. Brown

At least two dozen massive sulfide deposits in the southern Appalachians have supported significant mining operations. Literally hundreds more deposits are known to exist, but are too small to be of commercial interest. Essentially all that are being, or have been, mined are those deposits that were exposed at the surface when first discovered. It is reasonable to assume that many more massive sulfide deposits, large and small, exist hidden not far beneath the surface. The ideas I am sharing with you here today are based both on my personal studies of some of the deposits and on descriptions of deposits in the literature. An attempt will be made to account for the genetic interpretation problems raised by many of these deposits posessing both "syngenetic" and "epigenetic" features. In addition, an examination will be made of the possible relationships between the massive and the not-so-massive sulfide deposits in this region. Hopefully, these observations added to those of others will eventually lead to the synthesis of a better model on which we can base exploration programs in the southern Appalachians.

Jan 1, 1976

By Kenneth A. Gutschick, Harry L. Francis

A large number of minerals and chemicals (Table 1), some mineral-derived, are used in the treatment of both potable water and domestic sewage waste water and solids (Anon., 1990). In water treatment there are ten principal process uses as shown in Table 2 (Anon., 1990), which also lists the major chemicals in each process. Since lime (calcium oxide, calcium hydroxide, and dolomitic lime) is the largest chemical (by tonnage) used in water treatment, this chapter will deal primarily with this product. Note that it is included in five of the process uses shown in Table 2, and that indirectly it is also used in at least one other category (taste and odor control, where lime is used with potassium permanganate to provide optimum pH condition). POTABLE WATER TREATMENT Water Softening The biggest use for lime in water treatment involves water softening, where it serves to reduce carbonate hardness caused by dissolved bicarbonate and carbonate compounds. Currently there are more than 1000 domestic water softening plants (Table 3) located in most sections of the country, but particularly in Ohio, other midwestern states, Florida, and Texas, where limestone bedrock abounds (Anon., 1990). Among the other uses for lime in water treatment are coagulation, disinfection, and removal of heavy metals due to high pH softening, removal of certain radioactive and organic compounds and fluorides, neutralization of acidic water, removal of silica, particularly with dolomitic lime, and removal of color. Most of the above advantages accompany water softening, although at some plants lime is used specifically for one purpose, such as silica removal with dolomitic lime, minimizing pipeline corrosion by addition of lime to correct an aggressive water, and others. Hardness in water comprises two types - carbonate hardness, caused by dissolved calcium and magnesium carbonates and bi- carbonates, and non-carbonate hardness caused by dissolved non- carbonate salts, particularly calcium sulfate, calcium chloride, magnesium sulfate, and magnesium chloride. Total hardness is the sum of the carbonate hardness and non-carbonate hardness. Waters are classified as soft (0 to 75 mg/L as CaCO,), moderate (75 to 150 mg/L), hard (150 to 300 mg/L), and very hard (above 300 mg/L). Most water plants strive to reduce total hardness to about 100 mg/L, although in recent years the tendency in some cities has been to allow a little higher value in order to reduce both chemical costs and the amount of water softening sludges produced. There are four basic types of softening plants: lime softening, primarily to reduce carbonate hardness; lime-soda softening, for reduction of both types of hardness (in some plants caustic soda is used in place of soda ash, but it is more costly); split lime-zeolite, where a base exchange mineral is employed in place of soda ash (this system also requires salt [sodium chloride] to regenerate the zeolite mineral); and finally zeolite softening, which is generally used in small systems for private houses and small municipalities. Principal disadvantages of the latter system are its relatively high cost and the salt requirement, which introduces considerable quantities of soluble salts into the waste water discharge system.

Jan 1, 1994

By R. Woods, O. A. Kiehn, C. A. Born, F. N. Bender

Development of the flotation reagent scheme at Climax Molybdenum Company's mine at Climax Colorado is reviewed. Features of the mineralogy, milling practice and background of reagent changes are outlined. Special attention is given to the hitherto unpublished details of the application of depressants for copper and lead impurities. The present rougher flotation reagent scheme utilizes a neutral hydrocarbon oil, low in unsaturates and wax, as collector with a sulfated coconut oil emulsifier and pine oil frother. Lime and sodium silicate are used as rougher conditioning and slime dispersant agents. Chalcopyrite and galena impurities are de- pressed in both rougher and cleaner plants by stage addition of Nokes reagent and sodium cyanide to yield a metallurgical grade molybdenite concentrate containing greater than 90% molybdenite and less than 0.5%, 0.1% and 0.05% iron, copper and lead impurities, respectively.

Jan 1, 1976

By A. Bruynesteyn

I would like to talk to you today about microbiological leaching or, the solubilization of metal values due to the action of Thiobacillus ferrooxidans. Bacterial attack of sulfide minerals has been going on for centuries but only recently was it discovered that the acid and iron often found in coal mine drainage is produced by bacterial action on the iron sulfides in the coals. Not until 1950 was it proven that bacteria were playing a role in the dump leaching of sulfide ores. B. C. Research became involved in microbiological leaching in 1955 while examining mine drainage from the copper-zinc mine at Britannia Beach, north of Vancouver. Since 1955, B.C. Research has maintained a continuous re¬search program on microbiological leaching which, due to its applied nature, was put under industrial sponsorship in 1962. Most of the information pro¬vided in my talk today has been gathered under this sponsored research program and I would like to express our appreciation to the many sponsors who have made our work possible.

Jan 1, 1970

By J de Cuyper, S. Ramachandran, L. A. Vazquez, N. L. Grauerholz, W. Freyberger

A novel process is described for the selective flotation of scheelite from low-grade (- 0.5% W03) tungsten ores having appreciable quantities of calcareous and siliceous gangue minerals. Specifically developed for the Tempiute, Nevada facility of Union Carbide, the process yields tungsten concentrates exceeding 15 percent W03 with at least 85 percent recovery. This condition was not achieved through conventional processes. This process consists of conditioning the ore pulp with judicious amounts of lime, followed by soda ash and sodium silicate as modifiers. The scheelite is then floated using a mixture of oleic and naphthenic acids as collector. Contrary to the common observation as to the deleterious effects of calcium in fatty acid flotation systems, lime addition is found to be beneficial in achieving satisfactory results. The process has also shown excellent results on a Brazilian scheelite ore.

Jan 1, 1976

By G. T. Adel

This paper presents the highlights of a general-purpose simulator for mineral processing plants that is being developed at the University of California, Berkeley. The state-of-the-art structured design methodogy based on a top-down design approach is being used to construct a modular and completely structured simulator such that it is independent of the unit operation models and routines. The simulator provides for two levels of operation allowing prebuilt or user-built simulation flowsheets depending upon the degree of computer knowledge expected of the user. The philosophy used in designing this simulator appears to be unique in the field of flowsheet simulation. The paper also includes a mini-example demonstrating the usage of the simulator.

Jan 1, 1982

By Stephen G. Whittaker, Rosalind A. Schoof, Martha J. Steele

In determining remedial action objectives for metals in soils, the U.S. Environmental Protection Agency typically assumes that the metal concentrations in house dust are the same as the metal concentrations in soil. Data now available from several studies that were conducted in mining communities suggest that for some metals, concentrations in house dust may be lower than those in soil. This paper reviews available data on the relative soil and indoor dust concentrations of arsenic and cadmium and examines how changing assumptions regarding indoor dust concentrations of arsenic affects risk assessments and determination of cleanup levels.

Jan 1, 1992

By M. Leduc, M. Backens, M. E. Smith

An emerging technology for sustainable development in mineral development, tailings co-disposal™ is a means to dispose of conventional mill tailings within the void space of a waste rock dump. This method, while not applicable to all tailings systems, can offer a significant reduction in short-term and long-term environmental liability, land disturbance, closure costs, and negative public image. The concept is to dispose of the tailings simultaneously with the waste rock or leach ore, controlling the ratio of tailings to coarse material such that the resulting dump is stable both physically and chemically. The resulting co-disposal dump can be as safe as a conventional waste dump. In the case of alkaline tailings in a potentially acidic waste dump, the acid production can be buffered or slowed.

Jan 1, 2004

By R. L. Jones, D. D. Runnels, D. P. Dupon, D. J. Cline

To establish meaningful remediation goals and monitoring programs in areas disturbed by mining and associated industries, it is desirable to determine the natural concentrations of metals that existed in these areas prior to being disturbed. In mineralized areas, multiple natural populations of metals and associated components may be present. This paper describes a method for characterizing the natural background chemistry by means of probability distribution dia¬grams. The method can be applied to water, soil and other natural materials. In a study of a complicated hydrogeologic system at the Kennecott Utah Copper North and South Operational Areas near Salt Lake City, UT, probability distribution diagrams were used to differentiate between natural background waters and waters impacted by human activities. The probability distribution diagrams allowed a component-by-¬component interpretation of the chemistry of ground¬water and surface water over a large geographic area. Natural chemical background populations and anthro¬pogenic effects were identified Although the method is illustrated for mining-related sites, the same approach can also be used for other natural and anthropogeni¬cally impacted sites.

Jan 1, 1999

By Steven W. Hunt, J. Patrick Powers, Roger C. Ilsley

Artificial groundwater recharge has been used successfully to mitigate water level drawdown in upper alluvial deposits during construction of the Milwaukee deep rock tunnels. Recharge wells in rock as well as soil were used. The effort reduced settlements from consolidation of compressible estuarine deposits, and has minimized damage to existing structures. The paper describes the geology that presented the consolidation problem, and the hydrogeologic conditions that caused the drawdowns. Also presented are the details of recharge well design, construction, operation and performance in an urban environment. The project design calls for grouting and lining of the tunnels to control groundwater in the long term.

Jan 1, 1991

By H. M. von Seebach, M. P. Trubeljal, L. G. Austin

Six US coals and a crystalline quartz were tested in an instrumented laboratory high-pressure grinding rolls machine equipped with 100-mm-diam. rolls. The machine was choke-fed to maximize the capacity. As expected, the specific capacity decreased with increased grinding pressure for each material tested. Among the six coals, there were significant differences in the critical angle of nip, the effective feed porosity and the variation of strain at the gap relative to the grinding pressure. Although a precise correlation was not obtained, the overall effect of these factors was that, at a given grinding pressure, the specific capacity increased as the Hardgrove grindability index of the coal increased. The relationship between the specific capacity and the grinding pressure for a given coal was independent of feed size down to 150 µm. However, smaller feed sizes produced anomalous results, and the flow within the feed hopper was restricted.

Jan 1, 1996

By G. E. Wasson

Coal in most refuse ponds including those owned by Consolidation Coal Company can be recovered by froth flotation techniques. Laboratory studies show that the flotation conditions required for coal recovery varied greatly from pond to pond. The variables found to be most important for high coal recovery and low product ash were: a) the amount and type of flotation reagents and b) the degree of conditioning before flotation. Coal recovery at a rate of 0.504 kg/s (2 tons/hr) was demonstrated at a pond site employing a mobile froth flotation unit.

Jan 1, 1988

By J. P. Allen, D. A. Rice, H. L. Abercrombie

Cobalt, nickel and manganese can be recovered quickly, cleanly and selectively from cobalt-rich manganese ocean crust by leaching in dilute acid solutions in the presence of hydrogen peroxide. Common selective precipitation methods can then be used to recover these metals from the leach liquor. The leaching reaction produces only oxygen as a byproduct, and the waste residue from leaching was tested and found to be nonhazardous under existing EPA specifications. The leaching process is effective in either fresh water or seawater. This research is a part of the Bureau of Mines program to identify the mineral resources of the Exclusive Economic Zone and devise methods, for recovering their valuable components.

Jan 1, 1992

By John Marshall

Silverton was the queen city of the western mining towns in the early 1900s. Located high in the San Juan Mountains, the town constantly grew and changed. Yet, it was subject to the vagaries and whims of economics, politics and disasters, natural or otherwise. Breweries, smelters and sawmills serviced Silverton's swelling mining population, which reached several thousand at its peak. Two trains a day ran from Durango to Silverton, in addition to trains running from Silverton over the top of Red Mountain on to Ironton. They ran up Cement Creek to the little town of Gladstone and up the Animas River Valley to Howardsville, Eureka and Animas Forks. During these prosperous times, construction flourished. There were plenty of wooden structures, and many of these stand today. The first brick buildings were built by bricklayer Patrick Stanley in 1877. It took quite a while for the first car to arrive. Almost 28 years passed from the coming of the first train to the arrival of the first car. It was brought over 3,840-m (12,600-ft) Stony Pass from Creede, CO, in an incredible journey retold years later by Louis Wyman. "Dad's daydreams were not the idle musings or the fantasies of a mystic," Wyman said. "They had a way of erupting into reality. He advocated and built good roads," he said. "During the summer of 1910, he was up to his sweatband in a project that took in half the state of Colorado. He envisioned an automobile highway, unheard of at that time, running southwest from Denver through the scenic grandeur of the high Colorado Rockies. The road would traverse a thousand miles or more of the state's finest recreational land finally circling back to Denver. Years later, when all of the county roads had been connected, it became known as 'Colorado's Thousand-Mile Circle Route.' Of course, Silverton and the San Juans were bright stars along the way."

Jan 1, 1997

By W. R. Dearman, N. Turk

A seismic fissuration index (K) is defined as the ratio of the difference in the P and S wave velocities obtained when a dry rock specimen is tested both under a load equal to half the uniaxial compressive strength of the rock (Vo) and without an applied load (Vd) to the velocity obtained without an applied load (Vd), as K = (Vo - Vd)/Vd. A similar seismic fissuration index is also proposed for classifying the dry rock mass in terms of field seismic velocities. The field equation is extended by including the intact rock seismic velocities. K is found to be related to the porosity of rocks. The proposed equation can equally be used for characterizing saturated rocks, using S-wave velocities. However, the time average equation should be used for characterizing saturated rocks, using P-wave velocities, even though this equation gives upperbound estimates of the rock material and fracture porosities.

Jan 1, 1986

By Jan Visman, James W. Parkinson

GENERAL INTRODUCTION Sample collection, preparation and analysis are all steps in a single process designed to provide information about a much larger amount of material than the sample itself. For example, information about the ash content of a unit train load of coal may be derived from a single, relatively small sample of perhaps a few hundred pounds (liters) extracted from the entire shipment. These three steps can be thought of as links in a chain, allowing the simple analogy that the strength of the chain, or, in other words, the value of the information is only as strong as the weakest link. Sample collection, discussed in Part 1 of this chapter, is critical because analytical procedures can do no more than reveal the characteristics of the sample presented to the laboratory. If that sample does not properly represent the population to be characterized, neither will the analysis of that sample. Sample preparation is also a critical part of the chain. Any change in the nature of a sample between the time it is collected and the time it is analyzed will appear to reflect the nature of the population. For example, sample preparation procedures that allow air to partially dry the coal sample before reaching the laboratory will cause the sample analysis to indicate a lower moisture content than the sample originally had. Other changes can be more subtle. Second only to moisture loss, oxidation reactions generally cause the greatest problems. Oxidation of a coal sample can alter surface properties, changing flotation response. In extreme cases, combustion parameters, such as caking or agglomerating properties or mineral composition, such as pyrite content, can change. Water samples can also be altered by oxidation. For example, ferrous iron can oxidize to ferric iron, possibly changing water quality parameters such as pH. Sample analysis, the subject of Part 2 of this chapter, is the final link in the chain. Obviously, no laboratory procedure can correct for problems created by improper sample collection and preparation. At the same time, poor analytical techniques will create incorrect information about the total amount of coal from which the sample was extracted (the population) in the same manner as improper sample collection and preparation. The key to gaining correct information about the population is to view these three steps as parts of a single process. Following proper techniques through only one or two steps of the process will not produce accurate information.

Jan 1, 1991

By Biao Qiu

Longwall and/or room-and-pillar mining operations in multiple coal seams could not only induce subsurface and surface subsidence but also cause interactions between these mined coal seams. The interaction might destabilize mine structures and subsequently induce additional strata movements. Mechanical models to utilize the predicted subsurface deformations to assess the interactions and the consequences have been developed. The models are incorporated into a computer program, CISPM-MS, for predicting the final surface movements and deformations as well as the mining interactions associated with multi-seam coal mining operations. It predicts final surface movements and deformations caused by the individual mining operations and by the interactive effects. The program can also be used to assess mine structural stability in multi-seam mining operations. The paper presents the developed interaction models and their application in surface subsidence prediction caused by multi-seam mining operations. A case study involving mining in two coal seams, using longwall and room-and-pillar mining methods, respectively, will be used to validate the program.

Jan 1, 2013

By H. Polat, Q. Hu, M. Polat, S. Chander

The electrostatic charge on spray droplets of ionic surfactant solutions and coal particles was measured and the results were correlated with the dust collection efficiency. When various surfactant were added, the magnitude of the droplet charge increased significantly and it was observed to be a function of surfactant type and concentration. The concentration of maximum droplet charge coincided with surfactant concentration where maximum collection efficiency was observed for these surfactants. Particles of coal also carried substantial amount of charge magnitude of which seemed to be a function of coal rank. Based on the results presented in this paper, it was concluded that ionic surfactant primarily act as a strong electrostatic charge inducer for droplets. Due to interactions between these highly charged droplets and naturally charged particles, the efficiency of droplet-particle collisions play a primary role when compared to the wetting and engulfment phenomenon which could only follow a successful collision. INTRODUCTION Water spray are widely used to suppress airborne dust in mine atmospheres (Walton and Woolcock, 1960; Kobrick, 1970; Hamilton, 1974; Jayaraman et al., 1986). Several investigators have considered the use of surfactants to enhance the effectiveness of water sprays especially for difficult to wet particles such as those of coal (Glanville and Wightman, 1979). The capture of dust particles by water droplets involves droplet-particle collisions, adhesion of particles to droplets, and engulfment of particles into droplets. Surfactants affect these sub processes through their influence on droplet charge, surface tension, and wetting. The last two mechanism have been thoroughly studied in recent years (Walker et al., 1952; Cohen and Rosen, 1981; Glenville and Haley, 1982; Chander et al., 1988; 1991). However, little attention has been paid to the role of electrical charge on particles and droplets on the collision and adhesion of spray droplets and dust particles. Airborne particles of dust have long been known to carry a significant amount of electrostatic charge (Hopper and Laby, 1941; Kunkel, 1948; Kunkel, 1950; Dodd, 1952; Liu et al., 1987; Kutsuwada and Nakamura, 1989). It is reasonable to assume that presence of charge on particles will effect their agglomeration and particle-droplet interactions. Polat et al., (1991) showed that virtually all freshly generated dust particles were agglomerated in air. They suggested that electrostatic charge and humidity were important factors responsible for agglomeration. Previous theoretical studies on the interactions between charged particles and collectors by Nielsen and Hill (1976) show that, the collision efficiency is a strong function of the particle charge. In addition to charge on particles, spray droplets might also carry substantial amount of charge (Chapman, 1937;1938; Blanchard, 1958; Iribarne and Mason, 1967; Jonas and Mason, 1968; Byrne, 1977; Bailey, 1988). In theoretical studies of interactions between a spherical collector and airborne particle, it was found that the collision efficiency was significantly altered depending on whether the collector and the particles were charged. If neither the collector nor the particles carried a charge, the collision occurred by inertial and gravitational forces. The collisions took place on the front part of the collector (the front capture). If either of the collector or the particles were charged, the collision was enhanced due to the induced image forces. If both the collector and the particles were charged, the collision efficiency was significantly affected by the sign of the charge as well as its magnitude. For oppositely charged collector-particle pairs a collision could take place on the rear of the collector even if the particle flied past the collector upon approach (the rear capture) (Nielsen and Hill, 1976; Wang et al., 1986; Chang et al., 1987). On the other hand, the columbic force became negligible as the particle size increased and the inertial force became dominant. The electrostatic attraction was predominant for particles of less than about 2.5 µm in diameter. For particles larger than about 8 µm the inertia of particles was sufficient to overcome the columbic force and inertial impaction became the dominant collision mechanism (Grover and Beard, 1975; Chang, 1987). Previous studies of dust suppression using charged spray droplets generated by applying high voltage to the spray nozzle showed significant improvements in collection efficiencies (USBM open file report, 1983; McCoy et al., 1985). However, it was considered that highly charged spray droplets obtained by direct charging might have

Jan 1, 1993

By Martin L. Smith, John M. Kemeny

In blasting, an optimal muckpile size distribution can be found in terms of mining and milling productivity and cost. Fragmentation control requires a means of modeling and evaluating blast results. A principle problem in the practical application of empirical blast fragmentation modeling is the evaluation of the muckpile's size distribution. Image analysis of video and photographic records of production size blasts at Cyprus's Miami and Thompson Creek mines is being used to provide data for estimating parameters relating fragmentation to blast design, energy factor and rock quality. The application of image analysis to the estimation of particle size distribution is reviewed with regards to the problem of fragmentation modeling.

Jan 1, 1993