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By Peter V. Avotins

During last year's AIME meeting in New Orleans, Deepak Malhotra and I were discussing some of the topics that would be presented in this Symposium. It seemed appropriate that along with papers on specific reagent and flocculant types, we should address research management aspects of new product development. This development is a long, arduous task that requires a significant technical and fiscal commitment by the chemical company and potential users. A flow chart depicting the research process is shown in Figure 1. The sequence of events are plotted on an undefined time line. Our experience has shown that it takes 3-5 years to complete a typical reagent development project. A new project starts with an idea of how to do something better. The ideas range from relatively simple product modifications to opportunities created by technological change. An example of this is the use of flocculants in tailings operations to close the water recycle loop. The change was brought about by the need to conserve water and comply with environmental statutes. The result was the development and wide-spread use of synthetic polymers to help in solid-liquid separation. More recently the ups and downs of oil prices have led to development of coal water slurries as an alternative to fuel oil. The slurries contain high levels of chemicals (up to 3%) to insure proper stability and burn characteristics. There are technical changes under way right now that may lead to ideas for other new products. One exciting source of new technology is the ability to manipulate genetic material of microbes to select for specific capabilities. This has evolved by leaps and bounds over the past 5 years. Biologically assisted leaching and removal of wastewater impurities are two possible end uses. I'm sure that there are many others. The ideas can originate anywhere and are often half-baked at first, but to lead to new products they must be refined to provide project definition and eventually a research plan. A chemical ,development project cannot be started without approval to commit the company's resources. The internal selling job is often very difficult. The company must see clear financial benefits in order to launch efforts that may not pay off for many years. It is critical to project the total market, profitability, eventual market share, and timing of introduction of the new product. There is much uncertainty in this and the research manager is often skating on thin ice to retain his credibility. Once we obtain support from upper management, the research team is assembled to start the project. The teams generally consist of organic chemists, research metallurgists, and technicians. They have access to analytical scientists and technicians for surface and analytical chemistry. The projects are often augmented by help from university staff and consultants. This is particularly true where there is a need to develop fundamental understanding of the technology in addition to synthesis of chemicals. The project now proceeds along two lines. First, there is an emphasis on understanding the prior art. Extensive literature and patent searches are undertaken to provide research leads and to keep from "reinventing the wheel" and infringing on someone else's patent. The scientists and technologists are qualified to conduct computer-assisted library searches. This process usually uncovers 80-90% of the relevant information. The remainder is very much harder to get and requires the help of professional library search staff with scientific backgrounds. Along with literature searching, the team begins synthesis of new compounds. These are screened by use of techniques such as microflotation or filtration in a Buchner funnel. The scientists are looking for the direction of response as they modify structural features . Inevitably, a large number of candidates reach the next stage, a laboratory bench test. At this point it is possible to set up a research plan and use project management techniques to monitor progress. The bench tests are conducted in larger equipment, usually requiring 100-1000 grams of test substrate. Typical laboratory flotation tests are run in Denver or Wemco cells.

Jan 1, 1986

By Karl Ingmarsson

Larger mines spend millions of dollars annually on rock drilling tools, but often purchase based on historic consumption. The results vary from excess inventory to acute tools shortages. These lead to emergency sourcing, sometimes mixing products that don’t perform optimally. Boart Longyear analyzed the usage pattern of 96 thousand drill bits at thirteen different underground mining contracts, showing very high variability. The monthly standard deviation on a product level was 42%, with the highest for development and low volume bits. A new rule of thumb is suggested to carry only one month of safety stock for high volume bits, but increase to three months for low volume bits. This balance will reduce the risk of outages with less inventory. The accuracy can be improved by considering the specific conditions at each mine and reclassifying individual bits for a different safety stock level. Root cause analysis and collaborative forecasting between mines and suppliers can lead to further optimization of availability and inventory levels.

Feb 1, 2024

By Thomas H. Dubaniewicz

(XP) enclosures to enclose electrical ignition sources to prevent propagation of an internal methane-air explosion to a surrounding explosive atmosphere. Researchers at the National Institute for Occupational Safety and Health (NIOSH) conducted a lithium-ion battery thermal runaway test within a modified MSHA-approved XP enclosure to assess thermal runaway containment. Thermal runaway produced jet flames emanating from the cover joint at several locations and distorted the cover joint and bottom plate of the enclosure beyond allowable limits. The test demonstrates that XP enclosures may not provide adequate explosion protection against lithium-ion battery thermal runaway. This paper suggests some approaches to mitigate the hazard.

Feb 1, 2024

By A. Peppas

Perlite is a naturally occurring siliceous rock, which can be expanded from four to twenty times its original volume when heated at a temperature close to its softening point. The expanded perlite is characterized by increased sound and thermal insulating properties. However, the conventionally expanded perlite products have high porosity and low mechanical properties that limit the range of their applications in the construction and chemical industry. The present work aims at the development of new closed porous microcellular material from perlite with enhanced mechanical and physical properties to be applied in new applications, like joint compounds, functional fillers for special paint types, special blasters and mortars, artificial marble. For the production of these new materials a vertical electrically heated furnace with six different heating zones and controlled gradient temperature profile was used. The effect of major process parameters, like temperature and air flow, on the quality of the produced materials was studied using Greek perlite from Milos Island. The quality of the new products was evaluated in terms of their bulk density, compression strength, water and oil absorption, surface area and pore volume. The experimental results show that the produced materials are characterised by improved mechanical and physical properties compared to the conventionally expanded perlite products.

Jan 1, 2006

By R. R. Klimpel

The use of froth flotation as a means of separating and upgrading sulfide mineral concentrates is standard industrial practice throughout the world. It is ap-parent from observing the industrial practice of sulfide mineral flotation over the last decade that progress is being made in optimizing the operating aspects of flotation. Examples of this are the availability of improved instrumentation and related computer control devices, the modification of mechanical flotation cell designs, the introduction of column cells, better reagent dosage control, blending of feed ores, increasing attention to coarse and fine particle separations, the successful introduction of new frother chemistries, etc.

Jan 1, 1989

By R. L. Grayson, N. P. Reddy, D. A. Kinzler, S. Yuan, W. R. Myers, R. A. Wells

An examination was conducted on the impact of roof conditions and the mining cycle in determining a representative respirable mass concentration at the mid-shearer location on a longwall panel. Multiple personal gravimetric dust samplers, operated at a flow rate of 2.0 lpm, were used at different locations along the face to isolate the concentrations and variances associated with good and bad roof conditions under both the cutting and cleaning mode of operation. The number of samples needed to estimate the population variance at a given confidence level was analyzed. In addition, the statistical analysis showed that the coefficient of variation of dust concentrations at different locations and under different conditions ranged from 0.185 to 0.475, with an average value of 0.283. The estimates of the average dust concentration for a shift and the variance of the dust concentrations were calculated. A total of 48 data points were available for an [a x b] factorial ANOVA (analysis of variance). The estimates of the variance components were determined. The results from F-tests indicated that both the roof conditions and mining operations had a significant effect on the respirable dust concentration. There was no significant interaction effect between mining operations and roof conditions. In conclusion, this study shows that not only should sampling and analytical errors be considered in determining the required number of samples for a good estimate of the long-range exposures of miners, but also fluctuations of concentrations due to mining operations and geological conditions should be taken into account.

Jan 1, 1991

By L. V. Wade

The use of longwall/shortwall mining systems is under increasing scrutiny by the U. S, coal industry as a means to reverse the decline in productivity. The success of these mining systems depends to a great extent upon designing the system hardware to best suit local conditions. Of particular importance in this regard is designing the various elements of the total ground support system, including face, face end, and gate road supports, to accommodate local geologic conditions. This presentation centers on the problem of selecting the face support system. The existing geologic situation can influence the selection of the face support hardware in a variety' of ways. In general terms, these influences can be grouped into the following four areas: 1. The capacities required of the support unit; 2. The roof, coverage supplied by the support units; 3. The flexibility required of the support unit to meet changing geologic conditions; and 4. The required stiffness characteristics of the individual support units both vertically and horizontally. The following will center on the first area, i.e., the required d capacities of the support unit, in particular, the maximum required load density for a particular geologic situation.

Jan 1, 1976

By Grażyna Dzik, Adam Mirek, Krzysztof Król

The Upper Silesian Coal Basin is located in the area of the Upper Silesian Syncline and belongs to one of the most complex tectonic units in Europe. It occupies 5,650 km2. In 2020, there were 20 hard coal mines operating in the area. Seismological research in this area consists of observation of precursors/symptoms of shock generation and understanding of their effects. Studies (Teisseyre R. 1972, Mutke G. & Stec K. 1997, Stec K. 2007, Dubiński J. & other 2010, Idziak A. 2010) of complex impacts of rock mass provided a background for determining the conditions for the formation of exploitation and regional seismic shocks. Issues related to tectonic and exploitation stresses, successive extraction of coal seams at higher depths, operation in the vicinity of fault zones, often complex geological and organic conditions result in the activation of a discontinuity surface due to stress caused by deformation of rock layers, which, as a result, causes the emergence of strong shocks above 107 J. The article was based on analyses of extraction value, high-energy shocks, both of mining and tectonic-mining (so-called regional shocks) origin, against the background of changing operating conditions, which, as a result, creates an image of periodically changing seismic activity and location of strong shocks. Observation results show that, with an increase in exploitation depth and declining extraction, the number of strong shocks caused by tectonic stress (107 - 109 J) and exploitation stress (≥105 J) has been steadily increasing over the last 25 years.

Apr 26, 2022

By Robert Kimutis, Heather Dougherty, Eric Watkins

Gas wells have often intersected mining resources, but unconventional shale well drilling has more recently challenged mines to balance the risk of interaction due to higher pressures and larger quantities of gas. Full extraction mining, such as the longwall method, induces ground movement that may influence the casings if wells are drilled within the mining area. The possibility of a casing shear would lead to the risk of unplanned gas migration into the mine. This has the potential to quickly overcome the ventilation system and reach the explosive range which, if ignited, can have catastrophic consequences on the health and safety of underground workers. The utilization of network software to model mine ventilation is a common practice in the mining industry as a predictive tool for planning and monitoring and can assist with a well breach scenario over a large mining area. This work focuses on a well breach in between two longwall panels after second panel mining with gas entering primarily through the gobs of the adjacent longwall panels. Applying the network software Ventsim, a gob zone and ventilation network were created to better understand the distribution of gas within the mine and the limitations and effectiveness of a ventilation system. The model shows both a transient flow simulation and steady state concentrations throughout the mine ventilation system. Using a standard Pittsburgh coal seam longwall ventilation scheme, we find that the system can dilute a significant inflow of up to 700 cfm of methane.

Oct 12, 2023

By Clifford J. Lewis

The role of calcareous minerals in that area of the environmental improvement program involving the control or elimination of sulfur oxide emissions is discussed, and a new concept in gas scrubbing, rendering possible the use of calcareous rocks more extensively for this purpose, is presented. Calcareous rocks are defined as the more common limestones, consisting essentially of calcium carbonate and magnesium carbonate. The effect of magnesium carbonate on the reaction rate of limestones and lime toward sulfur oxides in aqueous scrubbing systems is pointed out. The relative economics of lime- stone versus lime as aqueous scrubbing reagents for sulfur dioxide are indicated.

Jan 1, 1974

By J. D. Miller

The processing of residues derived from various operations in the mining and metallurgical industry for by-product recovery is becoming more prevalent. A principal target for by-product recovery is flue dust produced by conventional smelting operations. Flue dust from zinc smelters has been processed for many years for the recovery of cadmium (1,2). The cadmium recovery technique which consists of a selective sulfation roast, followed by a water leach and zinc dust cementation, produces a lead cake residue (see chemical analysis in Table I), which consists primarily of lead sulfate.

Jan 1, 1975

By Steven F. Hoerger

Newmont Gold Company is the largest producer of gold in North America. Accurate resource estimates are critical to planning the mining in a year of over 90,000,000 t (100,000,000 tons) of mill, leach and waste grade material, from which over 47 t (1,500,000 oz) of gold are recovered. Resource estimates are updated frequently to take advantage of new drilling, improved geologic understanding and additional production reconciliations. At Newmont Gold, indicator kriging is the primary method being used to create resource estimates. Indicator kriging (IK) is a well accepted method of resource estimation; however, many details of the IK process which are critical to producing a useful resource estimate have not been well documented. An IK model must have several characteristics in order to be a useful resource estimate: the model must take into account geologic features of the mineralization; model creation cannot require too .much time; the model must accurately reflect the effects of selective mining; the model must be stored in an easily accessible format; and the model must be useable with a variety of cutoff grades. This paper will show how Newmont Gold implements the IK process in order to achieve these goals.

Jan 1, 1992

By Hans G. Machel

In low-temperature diagenetic environments (0 c T c 60 - 80°C), elemental sulfur forms by six common processes: via (1) inorganic oxidation of H2S by molecular oxygen, (2) inorganic oxidation of H2S by ferric iron compounds, (3) polysulfide disproportion- ation; and via the microbial metabolic actions of (4) colorless sulfur bacteria, (5) colored sulfur bacteria, and (6) some types of thiobacilli. Economically viable deposits of native sulfur usually are formed by only one process: inorganic oxidation of H2S by molecular oxygen. The amount of elemental sulfur is also limited by three common processes that destroy it in low- temperature diagenetic environments: bacterial reduction, bacterial oxidation, and inorganic oxidation. In high-temperature diagenetic environments (80 - 10o°C c T c 150 - 200°C), particularly in sour gas reservoirs, there are seven common processes forming elemental sulfur: (1) SOdH2S reaction, (2) H2S- hydrocarbon reaction, (3) polysulfide disproportionation, (4) catalytic H2S decomposition, (5) C02-H2S reaction, (6) chlorinification, and (7) exsolution of physically dissolved elemental sulfur. Natural processes that destroy or remove elemental sulfur in such settings are hydrocarbon sulfurization, polysulfide formation, and advection. In most sour gas reservoirs, relatively small quantities of elemental sulfur occur as a free phase (solid or liquid). However, elemental sulfur often precipitates in copious amounts from the reservoir fluids via exsolution and polysulfide disproportionation during production of sour gas reservoirs. By extension, elemental sulfur may precipitate from reservoir fluids in relatively large quantities upon uplift and erosion of deep sour gas reservoirs, or from advection of sulfurous fluids into shallower settings via faults or other high-permeability pathways.

Jan 1, 1992

By Ulrich Maidl, Marc Comulada, Janosch Stascheit

"INTRODUCTION Cohesive soils are notorious for causing clogging of the cutter head and the excavation chamber of tunnel boring machines (TBMs). While clogging leads to a drastic reduction in excavation performance, it further induces higher wear of tools and other parts of the cutter head and may even prevent a controlled support of the tunnel face and, thus, lead to face collapse and excess settlements or sinkholes. Employing well-balanced soil conditioning techniques, the clogging tendency can be significantly reduced. The monitoring and control of soil conditioning as well as the timely detection of potential clogging tendencies require a close monitoring of all relevant machine parameters and measurements. To this end, a reliable and powerful Process Controlling software that gathers all machine and process-related information is a prerequisite for successful mitigation of clogging-induced problems. The remainder of this contribution is organized as follows: First, a brief introduction to the Process Controlling system PROCON is given. Afterwards, the mechanisms and mitigation techniques of clogging are discussed. Finally, an example is given how Process Controlling has been employed to soil conditioning in a tunneling project with highly clogging soils.PROCESS CONTROLLING Being both the active part and a huge measuring device, the shield machine represents the core component in mechanized tunneling. This machine comprises a manifold of complex components and devices that require constant supervision and control and, thus, is equipped with a manifold of different sensors that provide a continuous monitoring of the state and condition of the machine (Maidl & Stascheit, 2014). If these data are put into the whole context of the tunneling process, they can provide insight to the assessment and optimization of the performance and to the prediction of potential risks and hazards such as, for example, the tendency of clogging of the cutter head."

Jan 1, 2016

By F. Cappel

Except in a few special cases, it is necessary for solid fuel direct reduction in rotary kilns that iron-bearing materials be charged with a minimum grainsize of approx. 5 mm. For fines not usable in such form, the combination of sintering - as agglomeration step - and direct reduction were investigated. During reduction of sinter in rotary kilns prevail dependencies on sinter quality and varying reaction parameters, owing to the use of different coals, which led to a definite statement as to what quality sinter must have and which coals can be used.

Jan 1, 1983

By Steven J. Schafrik, Michael Karmis, Zacharias Agioutantis

3-D or pseudo 3-D visualization of orebodies and mining related processes such as loading and tramming, are now commonly used by the mining industry. An approach is presented that can aid the engineer in creating the visualizations necessary for accurate presentations for use in public relations, safety training, production projections, reclamation plans, etc. It is shown that the creation of such digital representations of mining environments are independent of the mining package used to create the original mine design. Once a proper model has been created, any view of the areas is possible. These views can be taken from any number of stationary points or entered into an animation showing the progress of a mining construction. The paper focuses on the presentation of the steps used to accomplish the visualization and an example is for a quarry fill placement project.

Jan 1, 2002

By M. Cimini

The main objective of this paper is to propose a new sustainability parameter, called Visibility Indicator (VI), to describe the influence of mining operations on the visibility of the open works in the site from the surrounding land. A further goal is to point out a procedure for Visual Impact Analysis and Assessment (VIAA) of mining and quarrying operations in the phases of elaborating and evaluating of the project and depleting the resources. The Visibility Indicator has been computed taking into consideration the evolution of the area involved in the exploitation activity.

Jan 1, 2003

By A. I. Kogut

Impurity minerals in fluorspar ores and concentrates from a deposit in Southern Africa have been studied by reflected light, transmitted light, and cathodoluminescence microscopy. The principal impurities are quartz, calcite, aegirine, apatite, ankerite, magnetite, goethite, and synchysite [Ca(La,Ce,Nd)(CO3)2F]. Cathodoluminescence microscopy was found to be very useful in studying the character of the fluorite and especially for recognizing the presence of apatite and calcite impurities. Fluorite exhibits blue, calcite shows yellow, and apatite has white, light purple, and pink cathodoluminescence. The cathodoluminescent character of apatite varies with its geological environment and position in the orebody. The results of this microscopic study show that phosphorus present in fluorite concentrates occurs principally in binary locked apatite-fluorite particles. Successive fluorite cleaner concentrates contain progressively smaller amounts of locked apatite-fluorite particles. Free apatite has been effectively partitioned to the final tailings.

Jan 1, 1995

By Rui Xiang Yang, Cong Li, Jia Zeng, Rong Liang Zhang, Wei Zhang, Chao Fan Tang

This research took the roasted products obtained by leaching copper (Cu) refining slag using waste acids and roasting leaching residues with calcium oxide (CaO) as raw materials and used oxidative leaching to extract Cu from roasted products using waste acids. Influences of the leaching temperature, liquid–solid ratio, and sulfuric acid ( H2SO4) concentration in waste acids on the leaching rate of Cu in the oxidative leaching process of roasted products using waste acids were investigated. The unreacted-core shrinking model of heterogeneous reactions was adopted to reveal the leaching kinetics of Cu in the oxidative leaching process of roasted products using waste acids. Results show that the leaching rate of Cu reaches 91.68% when the leaching temperature, liquid–solid ratio, H2SO4 concentration in waste acids, and injected airflow are 80 ℃, 8:1, 1.5 mol/L, and 200 mL/min, respectively. If the leaching temperature is below 80 ℃, the leaching process of Cu is controlled by the solid-film diffusion, and the apparent activation energy Ea is 11.0835 kJ/mol; at a leaching temperature above 80 ℃, the leaching process of Cu is governed by the interfacial chemical reaction, with an apparent activation energy Ea of 42.3183 kJ/mol. The liquid–solid ratio can positively influence the reaction rate constant. The apparent order of the leaching reaction of Cu is 0.632.

Jan 11, 2023

By Wendell R. Peters

Shallow underground voids resulting from early coal mining and other resource recovery activities over the past several decades are now being recognized as a significant cause of ground subsidence problems. Uncertain knowledge of abandoned coal mines also imposes potential hazards in current mining operations since water inundation or the release of methane gas is a serious hazard when mine excavation operations break into an abandoned mine. Requirements for detecting and mapping subversive man-made tunnels in previous work has led to the development of a surface- operated automatic earth resistivity survey system and associated computer data processing system for military applications. Field demonstration tests of this system have resulted in successful detection of tunnels at depth-to- diameter ratios greater than ten to one. Under the sponsorship of the Bureau of Mines, a similar high-resolution earth resistivity system was designed and constructed for use as a potential means of detecting coal mine workings. The hardware and software aspects of the new system are described together with applications of the method to the survey and mapping of abandoned coal mine workings. Field tests are presented showing the detection of both air-filled and water-filled mine workings.

Jan 1, 1981