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By Jr. Flynn

This U.S. Bureau of Mines publication is a compilation of fundamental cyanide chemistry data obtained through review of the scientific literature. It includes information on thermodynamics and chemical equilibria, ultraviolet-visible and infrared spectra, and the chemistry and photochemistry of cyanide, chemical species derived from cyanide, and metal cyanide species. It also includes guidance on the use of the data for solving practical problems in precious metals applications. This publication is intended mainly for use as a reference by personnel in the precious metals industry and regulatory agencies, and other cyanide users, to provide comprehensive information on cyanide chemistry. The document should assist in the formulation of effective policies for cyanide control in the construction, operation, and closure phases of precious metals mining and metallurgical operations. In addition, the data in this publication will be useful in other contexts, such as dealing with industrial cyanide usage, cyanide-containing wastes and associated environmental problems.

Jan 1, 1995

By F. Keller, E. H. Dix, L. A. Willey

The consideration of alloying elements for aluminum has led to a series of investigations of the equilibrium relations between aluminum and those alloying elements. Therefore, the aluminum end of the aluminum-antimony diagram has been studied. The general form of the aluminum-antimony equilibrium diagram has been worked out by Campbell and Mathewsi and by Tammann.2 Canlpbell and mathews described principally the beginning of solidification. They found the curve of beginning of solidification rising gradually from the melting point of pure alunlinum to a maximum at about 67 per cent. aluminum. After a slight lowering of the curve at a little greater antimony concentration the curve again rises to a maximum at 18.4 per cent. aluminum, which corresponds to the compound AISb. The curve then drops to the melting point of pure antimony. Tamrriarln explained the maximum occurring at about 67 per cent. aluminum as the result of the slow formation of the single compound AISb. The space lattice of the compound AISb, according to Owen and Preaton,³ is face-centered cubic, the antimony atoms being intermeshed with an identical aluminum lattice. Very little, if any, work has been done on aluminum alloys containing small amounts of antimony. The Present Investigation It has been the purpose of this investigation to determine the solid solubility of antimony in aluminum and also to investigate the eutectic temperature and concentration. The experimental work has been carried out in a manner similar to that described in a previous paper4 from this laboratory.

Jan 1, 1931

Traditionally, capital costs of major resource development projects have been estimated as a single amount to which a percentage accuracy has been assigned based on the method of preparation of the estimate, that is, on the amount of information available to develop the estimate.However, there is a growing recognition of the importance of a probabilistic approach to capital cost estimates, and of a more rigorous calculation of estimate accuracies and of the presentation thereof. Accuracies can be expressed with more certainty as a percentage of the estimate amount where the percentage represents one standard distribution on the probability curve for the capital cost of that specific project. Thus confidence levels can be stated for various estimated amounts - for example, it can be stated that there is an 85% chance that a stated amount will not be exceeded, or a 90% certainty that a (higher) amount will not be exceeded. Moreover, the right skewness of the probability distribution curve for most projects can be readily recognised and reflected in the evaluations. This enables senior executives and board members to have a clearer understanding of investment uncertainties, and the possible magnitude of commitments.

Jan 1, 1990

By Dana C. Reinke, David K. I Ingram

Researchers at the National Institute for Occupational Safety and Health partnered with the water well industry to develop engi­neering control technologies and training products to address noise exposure at the job site. Noise­induced hearing loss continues to be a problem in the well drilling industry. Research con­ducted by NIOSH found that air rotary drill rigs produce sound levels more than 90 dB(A) over the course of an eight­hour workday. Sounds levels above 90 dB(A), identified during hammer drilling and the hammering of casing, exposes workers to levels that can damage hearing. A typical air rotary drill rig provides no barrier, for noise and dust pro­tection, between the drill’s control panel and the drill stem. The development of a partial cab is the clearest example of NIOSH’s research partnership with the water well industry. NIOSH researchers determined that an engineering noise control to protect the oper­ator at the rig’s control panel would be effective, based on typical work site conditions. Many surface rigs do not have full cabs as a result of the original equipment manufacturer design or the high cost of aftermarket products. Developed as a partial cab, the NIOSH engineer­ing noise control design addressed stakeholders’ needs associated with cost, transport, and worker usage (Figure 1). Field tests found the partial cab effective in reducing sound levels at the rig’s control panel, a typical location for a drill rig operator. Sound levels at the control panel were reduced from 104 to 96 dB(A) (Figure 2). Coupled with continued use of personal protective equipment, such as hear­ing protection devices, the partial cab can help to reduce noise exposure. NIOSH researchers created a CD with informa­tion about noise exposure and the partial cab. Most important to well drilling companies is information on how to construct and attach the partial cab to drill rigs. The CD can be viewed on a standard computer and includes a video of the partial cab in use on a work site. Computer­aided design drawings are included on the CD and provide detail of the cab design as well as information on construction mate­rials and design details. Additionally, the CD provides background infor­mation on noise­induced hearing loss and hearing protection devices to increase knowledge about this occupational health concern. This information can be viewed by all company employees to help promote the partial cab’s importance to workers using the cab. More information on the partial cab noise control technology can be downloaded from www.cdc.gov/ niosh/mining NIOSH researchers also examined the health and safety training needs of workers in the ground water industry. It was quickly realized that most workers learn health and safety on the job and do not attend any sort of formal training. In addition, there is not a lot of time for daily “tailgate talks” or “shop talks” on health and safety issues. As a small business industry, the owner is often operating a drill rig along with his other employees. In general, new employees learn the job in an apprentice style sys­tem. As a result, workers and owners have few opportunities to access uniform health and safety information based upon the job — an outdoor work environment with daily change in work sites. With this information, NIOSH researchers devel­oped two products that deliver health and safety information to fit into the daily work of well drillers. Both are information circulars and are available through download at www.cdc.gov/niosh/mining and the NGWA Web site at www.ngwa.org/publication/ publications.cfm. These circulars are: Water Well Safety Bits. This booklet provides information in a “quick bites” style. It is pre­sented in a magazine format and can be left on

By J. P. Van Cruyningen, M. J. Puro

"A 2400 acre extension to the existing Tailings Area is under development at Inco's Copper Cliff Milling operations.The new area is being developed in stages as production levels dictate thus minimizing immediate capital expenditures while permitting disposal operations to proceed as further site work progresses.The first stage of the new storage site will be fully operational by early 1987 and will include a 400 acre site specific to the storage of Pyrrhotite rejected from milling circuits. The Pyrrhotite site is located in the centre of the Tailings area and is designed for water cover throughout much of its projected life.The new development incorporates perimeter dams designed to operate with low phreatic levels for maximum structural stability. Acid seepage water is collected behind secondary impermeable dams for return to the Tailings Pond.Tailings are deposited by up-stream methods permitting segregation of coarse fractions for use in future lifts of the perimeter dams."

Jan 1, 1987

By Gabriel Esterhuizen

Underground stone mines in the United States make use of the room-and-pillar method of mining. A prerequisite for a safe working environment is that the pillars should adequately support the overburden and the pillar ribs and rooms should remain stable during mining. At present pillar dimensions are either based on experience at neighboring mines or on strength equations that were developed for metal or non-metal mines. This paper presents a pillar design methodology that was developed from a study of pillar performance in operating stone mines. Data were collected that describe the rock mass quality, pillar conditions, mining dimensions and intact rock strength. The results showed that current mining practices have resulted in generally stable pillar layouts with no recent cases of extensive pillar collapses. However, a small number of single failed or failing pillars were observed in otherwise stable layouts. Numerical analyses were used to supplement the observations and develop a pillar strength equation that describes the stable and small number of failed pillars observed. The developed strength equation can be used to design stable pillar layouts provided the factor of safety is greater than 1.8 and the width-to-height ratio of the pillars is greater than 0.8. The paper concludes with guidelines for applying the developed equation and selecting appropriate input parameters.

Jan 1, 2008

By Worthen Bradley

A BETTER understanding of what is happening in the domestic quicksilver industry, and what is likely to happen, can be had after reviewing some of the highlights of the past four years. Hitting the high spots in chronological order, they are: February 1939-Army and Navy Munitions Board starts investigation on civilian and war needs of certain "strategic materials," including quicksilver, with a view to recommending stock piles. Every known producer is canvassed by the end of the year.

Jan 1, 1942

By Brent Blanchard

Dallas/Fort Worth Airport recently took a major step in its fiveyear expansion project with the explosive demolition of the Hyatt Regency Hotel West. Built in 1965, the Hyatt Regency held the distinction of hosting five U.S. Presidents over the years and was reportedly one of the first hotels in the world to be built within an airport’s boundaries.

Jan 1, 2003

By H. Hoberg, M. Langen, B. Hamacher

Since the term "abandoned hazardous sites" was first coined in the 1978 environmental report of the Council of Environmental Specialists, a number of different types of technology has been developed in the Federal Republic of Germany for the remediation of contaminated soils /l/. At former sites of the mining industry, such as metallurgical and coking plants whose soil has been contaminated by organic and inorganic pollutants over decades of industrial activity, there is an exceeding necessity for soil remediation. Also, many former locations of metal processing works, battery factories or scrap yards have been contaminated in particular by heavy metals. Wet mechanical soil decontamination has proven successful over the past 10-15 years in the purification of these soils The process goal is the enrichment of the pollutants in certain plant products and the separation of a pollutant concentrate from the decontaminated soil. Table 1 lists the steps of the highly advanced wet mechanical soil decontamination process to achieve this process goal. Table 1 lists both the name of each process step and its goal in terms of a direct separation of the pollutant or the preparation of the soil for subsequent separation steps. For the separation of heavy metals, density sorting and separation techniques utilising flotation were specifically used. The use of chemical auxiliaries such as acids and lye is limited to special cases because these in themselves produce additional environmental impact and the economical effficiency of these techniques compared to conventional methods is lowered by supplementary process steps for water purification. The subject of this presentation is to consider how soil decontamination processes can be effectively improved through a description of the material properties of soils contaminated by heavy metals, and through carrying out basic investigations about the adsorption of heavy metals. Soils of different origins, especially those from former mining and metallurgical sites, were used for the experiments.

Jan 1, 1995

By R. J. Baumgartner

Sustainability issues are from rising interest and importance for the mineral industry worldwide. In order to bring them into management processes and to improve decision processes, economic, ecological and social aspects of products, services or technologies have to be assessed. In this paper, the concept of integrated sustainability assessment is presented. Each aspect is assessed with quantitative or qualitative methods. The results of these ecological, social and economic sub-assessments are integrated by the means of Fuzzy Logic in order to regard preferences of decision maker and circumstances of decision situation. An example demonstrates the application of this new instrument.

Jan 1, 2005

By André Brasil

Dado que las represas de relaves construidas por el método de aguas arriba presentan deficiencias relacionadas con los aspectos constructivos y de seguridad, es difícil evaluar la variabilidad real del depósito basándose apenas en los procesos de campo. En ese sentido, el presente texto desarrolla un modelo para describir y simular el mecanismo de formación de las represas de relaves considerando las variables externas (concentración y caudal de descarga) e internas, así como muestra soluciones analíticas y numéricas comparados a nivel laboratorio.

Sep 9, 2007

By Kristen R. Bingham

"Today, more than ever, drilling and blasting contractors are challenged to manage the ever-changing risks associated with blasting operations. New neighborhoods are encroaching upon mine sites and blasting projects are confronted with increasing scrutiny by permit issuing authorities and nearby residents disgruntled by new construction. The act of transporting explosives material to and from thejobsite is far from easy and trouble-free. At the same time, the pressure to stay in compliance with the growing number of government regulations continues to mount. While new tools and technology are appearing in the workplace to address some of these challenges, losses still occur. Can the datagenerated by this technology help drilling and blasting contractors make better decisions? While basic risk management principles are still applicable, do new tools and technology assist in the effort to prevent losses? What are the downsides? In this age of new technology, is face-to-face interaction still necessary? While technology is certainly a useful component in the drilling and blasting world, can it be helpful in defending claims?"

Jan 1, 2017

By Hasan Ozturk

Laboratory testing examined the effect of a variety of intrinsic rock properties and environment conditions that influence the adhesive bond between rock and thin spray-on liners. The liner materials used for these tests were Tekflex, provided by Fosroc, Castonite, provided by Rohms and Haas Co., Rockweb provided by Spray-on Plastics, and CS 1251 2K, provided by Master Builders. Some of the variables examined include: rock strength (tensile/compressive strength) rock mineralogy, rock surface roughness (grain size, fracture/joint roughness), and surface contamination (oil, water or dust). Under optimal conditions, adhesive strengths reaching at least 3 MPa can be achieved. Where the rock surface is contaminated with dust or the rock is weak in tension, it may be difficult to reach adhesion strengths of 1 to 1.5 MPa.

May 1, 2004

By Koch D. F A

An electrochemical study of the dissolution of gold in aerated cyanide solution shows that the dissolution rate is determined by the nature of the surface. A passive film (probably a basic cyanide) formed at -0·6 V vs a saturated calomel electrode inhibits both the anodic dissolution of gold and the cathodic reduction of oxygen. Thallium has an "activating" effect on these reaction mechanisms.INTRODUCTIONIn general the dissolution rate of a solid in a liquid is studied by weight loss measurements or analysis of the solution at known time intervals. However, if the solid is a metallic conductor, on which a redox reaction can occur at the metal-solution interface, it can be studied by electrochemical techniques. Electrochemical measurements have the advantage that the overall reaction can be separated into its components, in some cases by electrical measurements alone, and in others by a combination of these with analytical determinations.The overall equation for the dissolution of gold in aerated cyanide solution may be written4Au + 02+ 8CN- + 2H20 = 4Au (CN)2- + 40H- ..... (1)which can be separated into the two electrochemical componentsrepresenting the oxidation of gold and the reductionof ogygen respectively.4Au + 8CN-,= 4Au(CN)2- + 4eand O2+ 2H20 + 4e = 40H- These two reactions occur at the gold-electrolyte interface and it is the purpose of this paper to discuss the mechanism...

Jan 1, 1964

By Rolland L. Blake

The Bureau of Mines is concerned with extracting minerals from residual geothermal brines after their heat content and some demineralized water have been recovered. This literature study is based on a survey of the literature and discussions with individuals knowledgeable on various aspects of the subject. This report examines the potential of the domestic geothermal mineral resources, considers the technical problems involved, and outlines possible effects on the environment from reservoir fluid withdrawal and reinjection. Geothermal resources in the Western United States were extensively explored during the 1960's. Limited development operations included exploratory drilling and operating wells producing hot brine, separating steam for experimental electric power generation, and recovering minerals in solar evaporation ponds or in extraction plants. Interest in the recovery of minerals and salts from geothermal fluids waned because of corrosion and scaling problems and low or no market value of the mineral products. Most of these problems can be controlled with existing technology and careful planning of processes and equipment. Extracting geothermal minerals is technically feasible, but the problems of low or no market value for major mineral products, and insufficient amounts of more valuably major products, make mineral recovery uneconomical at present.

Jan 1, 1974

By P. Botane, A. Cailleau

"Compagnie Miniere Esperance operates a gold primary ore body. The ore is processed through crushing, grinding and gravity concentration generating tailings with remaining fine gold. Analyses of the tailings proved a residual gold grade sufficient for a chemical treatment.As lab tests proved the technical feasibility of a pre-concentration using flotation, an on-site pilot operation has been carried out to assess the continuous circuit performances, define the best configuration and obtain enough data for the industrial circuit sizing.Data collected during the pilot campaign have been used for calibrating a process simulator built with the USIM™ PAC software. The simulator validated the feasibility of upgrading the existing plant, including the reprocessing of tailings to obtain a good fine gold recovery in a small amount of concentrate. A preliminary capital cost has been achieved to assess the flotation workshop profitability.INTRODUCTIONCompagnie Miniere Esperance (CME), a mining company based in French Guyana, operates a gold primary ore body in open pit. The ore is processed through crushing, grinding and gravity separation in two stages: a top plant and a bottom plant. A “coarse” pond contains tailings of the top plant; this product feeds the bottom plant. Tailings of the bottom plant are stored in the “fine” pond.Analyses of the fine ponds proved a residual gold grade sufficient for a chemical treatment. However, direct cyanidation would require a too large installation, regarding the local conditions (accessibility, supplying and meteorological conditions).It has been then decided to test the feasibility of a pre-concentration using flotation. Lab tests have been carried out by SGS Lakefield (Canada) in March 2007, which proves the technical feasibility."

Jan 1, 2009

By V. O. Tenorio, J. Puell

"Dump design is critical to effective mine planning in large scale open pit mines. Capital and haulage costs are considerable from early stages and through the life-of-mine as these dumps gradually become immense structures. Delivered mining rates, as well as certain spatial and physical constraints, provide a set of parameters of mathematical and economic relationship that creates opportunities for modeling and thus facilitates the measuring and optimization of ultimate dump design by using programming and empirical techniques while achieving economic objectives. This paper presents a methodology to optimize the ultimate dump design by minimizing its total dumping costs. The methodology consists of the formulation of a generalized model based on the relationship of the main dump parameters, followed by the use of linear programming to find the solution that minimizes the haulage total cost, and finally through a series of iterations, modifies the preliminary solution by projecting it to the topography and creating the ultimate dump design. A case study applied to a waste dump exemplifies this methodology. INTRODUCTION Open pit mine operations move large amounts of material on a daily basis from the shovel faces to the appropriate destination points. Hustrulid et al. identified three major destination places where the material receives downstream treatment after its delivery: mill processing, leaching dumps, and waste rock dumps [1]. The corresponding destination is given by a cut-off grade criteria, ore type, and the possibility of obtaining the maximum metal recovery. Dump leaching technologies have developed substantially since 1975 [2], and have enabled mining facilities to beneficiate low grade sulfide and oxide ores. As a consequence, the number of active dumps have increased since then and the entire mine configuration, which is limited in itself, has changed. The proper location, design, and construction of a mine dump must serve the safety, environmental and economic goals of the long-range mine plans. Therefore, an optimized use of the available surface area in the mine is highly desired."

Jan 1, 2018

By W. Zheng

Pipelines can develop stress corrosion cracks in either intergranular or transgranular form. Since the mid-1980s, numerous colonies of transgranular cracks have been found across Canada and many other countries in the world. While the intergranular form of cracking has been well studied in the past 40 years, the mechanisms governing SCC in near-neutral pH environment, i.e., the transgranular form of the cracking, are yet to be understood in greater depth. Over the past ten years or so, a large number of research publications have been available on this subject and this paper summarize our latest progress in understanding the mechanistic aspect of the problem. Better understanding of the role of mill scale surface and the steel metallurgy in crack initiation has been indicated in the recent literature. However, the initiation of SCC in the lab research still relies on loading conditions that are far more aggressive than those encountered in the field. Most crack growth studies in the past are also performed under very aggressive mechanical conditions, which could have prevented the observation of environment effects. However, more recent research at lower K or Delta K ranges seems to suggest a strong role of the environment. Naturally, modeling of growth should reflect the effect of the environment, steel metallurgy, and the changing mechanical properties of the pipe steel with time. For a specific steel in a given environment, the crack growth rates tended to increase with the strain rate, indicated either by the nominal applied loading frequency or by the calculated crack tip opening rate. Future research needs to address the issue of concurrent growth of multiple interacting cracks. More attention should also be given to concurrent initiation of multiple cracks in a colony, as failure is usually caused by a coalesced crack not by an individual crack. The effect of soil environment should not be limited to the chemistry of soil solution; other factors such as cathodic processes, the variation of environment with time and physical conditions of coatings should also be considered as part of the study.

Jan 1, 2005

By Roberto Balarini Junior

Tribological behavior of Si3N4 balls sliding against Al2O3 discs in water was investigated by studying the influence of parameters such as initial surface roughness and circular axial run-out of the discs. The objective was to relate these parameters with the occurrence of the phenomenon known as ultra-low friction coefficient (ULFC), which is characterized by µ < 0.01, including the correlation with running-in duration. As a general trend, greater initial surface roughness and circular axial run-out resulted in greater running-in duration. In addition, it was verified that a mixed lubrication regime (hydrodynamic and boundary) is required to guarantee the occurrence of ULFC by comparing the calculated minimum film thickness with the composite roughness of the worn surfaces. Also, ICQ-OES analysis of the water after the tests indicated that a silicon concentration greater than 1.3 mg/l should be fundamental for the occurrence of µ < 0.01.

Jul 31, 2018

By L. D. Patts, J. D. Noll, S. E. Mischler, G. H. Schnakenberg

In this study, we evaluated the ambient diesel particulate matter (DPM) concentrations (at the intakes and exhausts of the mine) as the entire vehicle fleet of a stone mine switched from using 35% biodiesel to using a water emulsified fuel (PuriNOx). Elemental carbon (EC) was reduced by 45% when a PuriNOx blend containing 10% water replaced 35% biodiesel and by 57% when a PuriNOx blend containing 20% water was used. Other factors such as engine duty cycle and production changes could potentially cause some day-to-day EC fluctuations, and no direct comparison to commonly used dieselfuels (No. 1 or No. 2) was achieved. Therefore, a second study was performed in a controlled “isolatedzone” environment to fametal mine, comparing PuriNOxto No.1 diesel fuel in a load haul dump vehicle. The EC fraction of the DPM was reduced by about 71% when the PuriNOx blend containing 10% water was used and by about 85% when the PuriNOx blend containing 20% water was employed. This study did not determine how the water emulsified fuel would affect the engine or power.