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By H Esterhuizen, W Hartman

Rockfalls or significant deterioration of mine openings can have significant safety and financial impacts for mining operations. The failure of drives in underground mines sometimes highlight deficiencies in the mine risk management systems in detecting geotechnical hazards and to prevent events that can have significant impact. Consequences from these failures includes fatalities, injuries, loss of revenue, additional cost, and potentially a loss in Ore Reserves. Where the impacts are severe, it also affects families and communities linked to the operation. The assessment of underground excavations requires consideration of the full range and spectrum of geotechnical hazards, design aspects, ground support, layouts and sequences. Where the assessment of these are insufficient or incorrect, it can result in drive failures. Care must be taken that meeting production targets and personnel pressures do not result in a situation where production take preference over a proper risk-based assessment of the drives to be mined. The risk management approach is now widely accepted in the mining industry for the control and management of risks in underground mines. Codes of Practices (COP’s), Ground Control Management Plans (GCMP), Principal Hazard Management Plans (PHMP’s) and technical guidance documents has become the norm for describing the mines main hazards, risk levels and intimating controls for safe passage of vehicles and mine personnel. However, where there is a disconnect between these documents and what is actually being done at the mine site, the COP’s and/or Management Plans become ineffective (or vice versa). This disconnect may occur due to the actual content of these documents, a lack of resources, or a lack of understanding about the implementation. There is therefore a need for sites to have a documented and implemented risk-based approach for assessing underground mine development. This approach or system needs to identify all hazards and other factors affecting mine development stability early on in the design process, and outline the risk classification and controls required. This paper presents an amalgamation and modification of previous processes for a Geotechnical Risk Management System for Underground Mine Development. CITATION:Hartman, W and Esterhuizen, H, 2018. A geotechnical risk assessment tool for underground mine drives, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 235–253 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By E Jak, M Shevchenko, D Shishin

One of the key aspects to develop sustainable metallurgical production is to ensure that the predictive power of thermodynamic tools is brought up to a new level of accuracy and reliability. Exploring new polymetallic processes, integrating primary and recycled materials, means utilising the uncharted areas within the Cu-Pb-Zn-Fe-Ca-Al-Mg-Si-O (major) – Cr-Na (slagging) – As-Sn-Sb- Bi-Ag-Au-Ni-Co (minor) slag-solids-metal-matte-speiss-sulfate system. This requires extensive integrated experimental and thermodynamic modelling study, which is underway at PyroSearch at the University of Queensland (UQ).

Aug 21, 2024

This paper first describes the essentials of the slurry shield method and its achievements, then problems encountered during driving tunnels and their countermeasures, and finally shows problems to be solved in the future. The author works at Tekken Construction Co., Ltd. as a director. All the data cited are based on material gained from the slurry shield tunneling works undertaken by the said company. The mark, viz*, indicates that Tekken Construction Co., Ltd. has obtained or is applying for a patent in the U.S., Europe and Japan. 1. CONSTRUCTION RECORDS BY SLURRY SHIELD METHOD AND ITS PROBLEMS (1) Shield machines in the future should have the following characteristics; a. to be able to drive less cohesive soil b. to make no change to the ground water table level c. to make it possible to let people work in normal air pressure d. to cause less settlement at the surface To meet the above conditions various kinds of mechanical shields have been are tried, viz. limited air pressure type, rotary cutter with slit regulator, screw-discharge type, blind shield, etc. As far as the author knows, however, they are not 100% successful. Tunnels need their own accuracy in accordance to the usage. Both ease of driving

Jan 1, 1976

By Liu Z. C

Evans' theory for chisel shaped picks is well known in the field of rock cutting technology. It has been widely accepted as a good mathematical description of how coal and other rocks break under the action of a simple wedge or chisel. Subsequently, Evans proposed a corresponding theory for pointed shaped picks. Theory along with experimental evidence from the laboratory has consistently shown that chisel picks are more efficient than pointed picks. However despite such evidence, pointed picks continue to be the preferred shape in most practical cutting applications. Evans' theory for pointed picks was developed in an attempt to shed light on this apparent incongruity. The theory although predicting forces of the right order was found to be deficient in several respects. This paper examines Evans' theory for pointed picks and proposes changes to it, which brings the theory much more into line with measured data. The issue of the relative efficiencies of chisel and pointed shaped picks is also examined on a theoretical basis and the apparent incongruity is Resolved.

Jan 1, 1995

By M Zoorabadi, B Hebblewhite, S Saydam, W Timms

Based on the cubic law, the hydraulic aperture of rock discontinuities has the most significant effect on the hydraulic conductivity of jointed rocks. The hydraulic aperture of rock discontinuities is a stress-dependant parameter and reduces with increasing applied stress. Furthermore, the rock stress increases with increasing depth. Therefore, hydraulic aperture is a depth-dependant parameter. In this paper, new empirical equations are introduced to calculate the hydraulic aperture of rock discontinuities at different depths. These equations were developed on the basis of back analysis of compiled packer tests from different actual cases. They provide the capability to calculate range of variation and average hydraulic aperture when the orientation of discontinuity and field stress tensor are given. Furthermore, it is possible to calculate the hydraulic aperture of rock discontinuities when its value is given for another depth. A hydraulic aperture of 7.7?µm was calculated by this method, comparing well with a reported site value of 8.3?µm for rock discontinuities at the Stripa mine project at a depth of 385?m. These new equations can be used by analytical or numerical methods to estimate the hydraulic conductivity of jointed rocks.CITATION:Zoorabadi, M, Saydam, S, Timms, W and Hebblewhite, B, 2014. New empirical equations to estimate the hydraulic aperture of rock discontinuities at different depths, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 375–380 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By T J. Beardsmore, N Wyche, D Flint, T J. Griffin

Western Australia (WA) is currently the world’s largest iron ore producer, and mining of its huge reserves and resources of iron ore has become a critical part of the state’s economy and regional development. Iron ore exports from WA have reached 760 Mt/a, corresponding to shipping more than one Mt per turn-of-the-tide from the state’s ports. The iron ore sector dominates all commodities produced in WA, and in 2016 accounted for 77 per cent of the state’s royalty receipts, 56 per cent of mineral and petroleum exports (by value) and 50 per cent of mining industry employment. Expenditure on exploration for iron ore (including that for resource estimation and conversion to ore reserves) has declined markedly, from its record peak of $1100 M in 2012 to $280 M in 2016, placing it second after gold. Foreign investment has been a key element underpinning development of the iron ore industry from the 1960s until today, and will likely continue to be so into the future.CITATION:Flint, D, Wyche, N, Beardsmore, T J and Griffin, T J, 2017. The importance of iron ore to Western Australia’s economy, in Proceedings Iron Ore 2017, pp 7–12 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By P Holtham, R Dunne, D Stoll

Flash flotation is a process designed to remove coarse, liberated, fast floating minerals from hydrocyclone underflow. Irrespective of liberation, coarse particles would normally remain in a grinding circuit until they are reground fine enough to report to the hydrocyclone overflow. Additionally, minerals of high density also report to hydrocyclone underflow despite being fine in size and/or liberated because hydrocyclones separate on the characteristics of both particle size and density. Dense particles continually reporting to the hydrocyclone underflow can lead to over-grinding and the production of ultra fine particles. These particles exhibit slow flotation kinetics and thus are difficult to float in conventional flotation circuits. Therefore, removing coarse, liberated particles from the hydrocylcone underflow by flash flotation has the potential to improve recovery and can improve dewatering unit operations and reduce grinding costs.The impact on the overall performance of the flotation circuit by removing coarse, fast floating minerals prior to conventional flotation is not well understood. Ultimately, predicting the overall recovery improvement provides the justification for the installation of a flash flotation cell within the milling circuit. This paper will describe attempts to estimate flash flotation recovery improvements to the overall circuit using kinetic data from simplified batch cell flotation tests combined with limn-based modelling techniques.CITATION:Stoll, D, Dunne, R and Holtham, P, 2012. Modelling the impact of flash flotation from batch cell flotation tests using limn, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 179-184 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

The mining of Australia's rich and diverse mineral resources has been central to the development of the continent by "Europeans" over the past two hundred years. Mining has historically been encouraged (to varying degrees) by development-orientated state governments (the. managers of largely Crown-owned resources) and since Federation, by successive Com- monwealth governments (which have seen mineral development as a means of generating export revenue to fund predominantly social-welfare orien- tated budgets). This marriage of convenience between governments and the mining industry has to date served all parties well. However, Australia's entry to a new world economic environment at a time that community percep- tions are changing (owing to an education-inspired challenge to "old" values) is challenging the hitherto held assumption that mining develop- ment is always aligned with the well-being of the State and community. Issues such as the type and extent of State/Commonwealth government taxation, resource ownership and control, the environment, land use con- flict, the extent and desirability of secondary processing and infrastruc- ture funding are being debated in the public arena. Opponents of mining in the community are well-organised and are well funded, articulate and more importantly, they have effective communication channels with most governments, irrespective of political complexion. Apart from some television-orientated corporate image building and recent efforts by AMIC, the industry's response to this challenge has been unco-ordinated, poorly directed and arguably ineffective. Professionals working in the industry are concerned about the community's perception of themselves and their industry. Recognizing that the Australian democratic system ensures that, in the large, government at its various levels, is reflective of and responsive to the views and aspirations of people, the industry's response must be wide- ranging, equally articulate and couched in a form which is politically acceptable. New objectives in providing information to the public and its educators must be formulated. Moreover, professionals are looking for new directions from industry leaders. The Institute is well placed to facilitate this process.

Jan 1, 1988

By N Madani

Linear interpolation of geo-related variables is important to different aspects of mining engineering such as long and short-term mine planning. The ore deposit description attained from spatial modeling of blast hole datasets has been widely taken into account, particularly, for short-term mine design and grade control, so as to define the ultimate destination of a mined block. It is approved in practice that making the wrong decision leads to losing a huge amount of money for choosing the destination of a mined block. In the case of complex ore deposits, the issue of estimation of variables in the region is questionable and somehow tedious. Due to this fact, modeling those complications in the co-spatial behavior of the grades in multi-element deposits prompts one to employ enhanced geostatistical techniques. Traditional approaches of this purpose such as polygon, inverse distance weighted and even (co)-kriging approaches, are incapable of reproducing those complexities such as non-linearity, heteroscedasticity and geological constraint that frequently exist among the variables of interest in those deposits. Another difficulty in employing those linear interpolations in grade estimation is smoothing effect, in which the estimated grades are over and under estimated. CITATION: Madani, N, 2018. 3D estimation of variables with complexity in cross-correlation structures, in Proceedings Complex Orebodies Conference 2018, pp 49–52 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

The research, development and testing of a Blast Control Plug (U.S. Pat. #4,754,705) funded by the U.S. Department of Energy is described. The plug's function is to improve blasting efficiency through the enhancement of stemming effectiveness and thereby reduce drilling and blasting costs. The plug comprises a solid unit placed in the blast hole within the stemming column above the explosive. It is designed for use with back filled drill cuttings or any other suitable material The research and development program comprised the testing of the plug in small diameter holes in competent rock for both bench and crater blasting configurations and full scale field trials in multiple hole and row blasts using blast holes of from 76 to 387 mm in diameter. Test measurements included stemming displacement and velocity, face movement and extent, peak air over pressure and ground surface peak particle velocity. Data acquisition equipment included a Spin Physics SP2000 high speed video motion analysis system, and acoustic and seismic monitoring units. Substantial reductions in stemming ejection velocity or ejection elimination were achieved whilst reducing stemming length by up to 35% over conventional practice. Peak air blast pressures were also reduced by between 8 and 25 dB. A strong inverse relationship between rock face movement and stemming ejection velocity was found. The implications of the importance of stemming effectiveness in blasting and computer blast simulation is also addressed.

Jan 1, 1990

By A Karrech, C Schrank, O Gaede, I Canbulat

Strain-based failure criteria have several advantages over stress-based failure criteria: they can account for elastic and inelastic strains; they utilise direct, observable effects instead of inferred effects (strain gauges versus stress estimates) and they model complete stress-strain curves, including prepeak, non-linear elasticity and post-peak strain weakening. In this study, a strain-based failure criterion derived from thermodynamic first principles utilising the concepts of continuum damage mechanics is presented. Furthermore, implementation of this failure criterion into a finite element simulation is demonstrated and applied to the stability of underground mining coal pillars.In numerical studies, pillar strength is usually expressed in terms of critical stresses or stress-based failure criteria where scaling with pillar width and height is common. Previous publications have employed the finite element method for pillar stability analysis using stress-based failure criterion, such as Mohr-Coulomb and Hoek-Brown, or stress-based scalar damage models.A novel constitutive material model, which takes into consideration anisotropy as well as elastic strain and damage as state variables, has been developed and is presented in this paper. The damage threshold and its evolution are strain-controlled, and coupling of the state variables is achieved through the damage-induced degradation of the elasticity tensor. This material model is implemented into the finite element software Abaqus and can be applied to 3D problems.Initial results show that this new material model is capable of describing the non-linear behaviour of geomaterials commonly observed before peak strength is reached as well as post-peak strain softening. Furthermore, it is demonstrated that the model can account for directional dependency of failure behaviour (ie anisotropy) and has the potential to be expanded to environmental controls such as temperature or moisture.CITATION:Gaede, O, Schrank, C, Canbulat, I and Karrech, A, 2014. A strain-based failure criterion for pillar stability analysis, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 393–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

The Australian Constitution specifies certain powers of the Commonwealth Government to be used in its capacity as the national government. Certain of these broad powers result in the Com- monwealth having a facility to play an important part in the development of the mining industry. The State Governments, however, by virtue of their wide powers to regulate matters within the boundaries of a particular State, are more directly involved in the day to day administration and standards of activities of mining operations. In this respect the Common- wealth has something of a dual role because of its "State-like" responsibilities for the mainland Terri- tories. The components of the role that the Common- wealth Government discharges in relation to the mining industry are qualified to varying extents at particular times by the political persuasion of the Government. In absolute terms the components are as follows. 1. Economic management. The Commonwealth's fiscal and monetary policies have an important effect on industry as well as on State finances. In particular, the taxation regime employed by the Commonwealth Government is of direct importance to economic decision-makers in the mining industry. 2. International matters. International trade and commodity matters are, more and more, becoming an everyday part of the conduct of a nation's foreign affairs. 3. Exports. The Commonwealth Government, via the constitutional powers over overseas trade, have exercised varying degrees of control over mineral exports to achieve particular objectives. 4. Foreign capital and investment. Australia in general, and the mining industry in particular, is and will continue to be a net importer of capital. There appears to be bipartisan political agreement in Australia that foreign investment policy must be enunciated to ensure that investors. are in no doubt that Australia welcomes beneficial investment and technology from overseas. 5. Environment and Aborigines. Governments, both Commonwealth and State, have in recent years become more involved in these areas in response to their interpretations of community aspirations. 6. Energy. Access to assured supplies of energy is now viewed, by Governments worldwide, as a desirable asset to ensure the well-being of a nation's people and industries.

Jan 1, 1978

By I Govender, T L. Moodley

Tumbling mills are grossly inefficient, using only 5 per cent of the total energy supplied for actual breakage. A significant proportion of this inefficiency is unavoidable owing to geometric limitations; rotating drum systems are prone to exhibiting certain regions (energy barriers) that resist particle entry thereby restricting the transfer of energy. Though such systems are inherently inefficient, improved modelling schemes may lead to slightly enhanced efficiency through better microscale predictions of key breakage drivers (stress, force). Central to achieving such incremental advances is the development of a universally accepted rheology for dense granular flows. Armed with a better understanding of these macro-scale ingredients, classical process modelling offers an efficient, spreadsheet friendly framework for recovering the spatial distributions of the comminution drivers. At this real-time level of process control, it should be possible to tune comminution operations towards more energy efficient configurations – the ultimate goal of this research. The present work employs validated DEM data to recover the full continuum field which will ultimately serve as a basis for calibrating process model outputs based on different rheological hypotheses. Such a continuumbased approach captures tensor properties like the shear stress and strain rate – both of which are necessary to developing a dense granular rheology. Moreover, DEM captures this data at the momentum transfer timescale of 10-6 s – no other measurement technique is capable of this level of spatial and temporal resolution. Importantly, the confidence in this DEM data is strengthened because it has been validated at the continuum scale using Positron Emission Particle Tracking (PEPT) kinematic measurements. Validated DEM data is derived from batch experiments conducted within a 300 mm ID laboratory drum using three and five millimetre glass beads at 60 and 75 percent critical speed; such mill speeds are typically encountered in the tumbling mill industry. Dimensional analysis is conducted using critical rheological parameters (shear rate, shear stress, granular temperature etc), which are key to not only developing a granular rheology but ultimately will be used to tune our mechanistic models.

Aug 24, 2022

Modelling of Synergistic Effect of Cyanex 302 and D2EHPA in Zinc Solvent Extraction A comprehensive model is presented to predict the synergistic effect of D2EHPA and Cyanex 302 on co-extraction of zinc and manganese. The experimental results indicated that pH, temperature and the extractants ratio have strong effects on the extraction process. Correlations were proposed to predict the distribution coefficient of zinc and manganese between two phases at different conditions by multiple linear regression. The correlations were simplified by eliminating less important terms by analysis of variance. Optimum conditions (ie pH, temperature, extractants ratio and aqueous to oil phase volumetric ratio) for obtaining maximum separation of zinc from manganese at different zinc concentrations and number of extraction stages were determined. For finding the optimum condition genetic algorithm was used. Comparison the model estimations and the experimental data show that the presented model has good ability to predict the behaviours of zinc extraction system over Cyanex 302 and D2EHPA.

Sep 13, 2010

By P Mugebe, M Yahyaei, M S. Kizil, R Low

This paper seeks to establish an empirical relationship between the impact of mining technological innovation implementation and a company’s market value. The company’s market value is represented by its stock price. In a bid to ascertain the relationship, a stock price prediction model is sought to be established using the firm-specific factors impacted by the implementation of innovative technology. This work is performed under the watch of the prevailing macroeconomic factors. The background anchors in the understanding that the difference between the economic status of a mineral deposit and its uneconomic status lies in the level of mining technological innovation most prevalent at a given time (Hartwick, Olewiler and Preuss, 1986; Wellmer and Scholz, 2017; Wright and Czelusta, 2003). This is derived from productivity improvement, resulting in sustainable profitability due to technological innovation. Unfortunately, there is not an adequately established relationship that links this technological innovation impact to the share price performance of the mineral commodity company.

Sep 1, 2024

By A R. Gerson

Pyrite, chalcopyrite and mixed sulfide samples, with and without quartz (5 wt per cent S), were subjected to column leaching to mimic natural weathering (cyclic wetting and drying). The pH and SO4 2- concentration of the column effluent was measured over a period of 78 weeks. The pH of the pyrite-only containing column rapidly decreased and remained under pH 4 after 12 weeks of leaching. The pH calculated assuming a 2:1 ratio of H + generation and SO4 2- release was slightly lower than that measured. However, a reduced H + to SO4 2- ratio of 1:1 is predicted if the release of aqueous Fe 2+ is assumed rather than the formation of Fe(OH)3. The pH of all columns containing only chalcopyrite or a 1:1 mole ratio of chalcopyrite and pyrite remained at or above pH 5 for the duration of the leach even though significant SO4 2- was released. One column containing the same initial surface area of pyrite and chalcopyrite but only approximately 0.10 the mole fraction of S as chalcopyrite maintained a pH of greater than five for the first 56 weeks of leaching and showed sporadic acid production thereafter. It is well established that oxidation of chalcopyrite results in a surface layer of polysulfide material. It is the formation of polysulfide that neutralises the acid produced on S oxidation through to SO4 2-. Hence where polysulfide formation occurs extensively on chalcopyrite the resulting solution pH decrease will be less than that based on SO4 2- production. The oxidation rate of sulfide minerals increases with decreasing pH and hence acid formation via sulfide oxidation to SO4 2- causes the subsequent oxidation rate to increase. The addition of calcite (CaCO3)to a pyrite column not only neutralises the acid formed but also decreases the rate of release of sulfate to solution by a factor of approximately 30. This is also the case where chalcopyrite is present mixed with pyrite. The rate of release of sulfate from the mixed sulfide mineral columns (after the initial release of the sulfate already present) was between one-fifth and one-tenth that in the absence of chalcopyrite.

Jan 1, 2003

By N Davies, M J. Coward, P L. Hissey

Mount Isa Mines has four mining operations in Mt Isa with the X41 and Enterprise Mines producing copper and the Lead Mine and George Fisher producing lead zinc and silver. Each stream contributes ore to their respective concentrator at a feed rate and therefore metal ratio set out by the monthly schedule. Mine Planning and scheduling lead to a sales and operating plan (S&OP) and revenue projections which ultimately derives actual revenue /tonne and therefore cost/tonne. At Mount Isa, both the copper and lead/zinc streams produce ore from relatively new operations to be blended with material from more mature operations. It is critical to accurately predict the metal contribution from each operation in order to gauge the relative performance of each mine. Development mining ore contributions are estimated and reconciled, as are stope and bench sources. Performance is continually measured and assessed during extraction and grade adjustments are made to account for underbreak, overbreak and design modifications. It is critical to not understate or overstate the contribution from one operation relative to the other as this can produce a false picture of operational performance. Identifying process improvements are key to improving the business overall. Ore from the lead stream passes 17 measurement stations and two midstream reconciliation points before delivery to the heavy media plant (HMP), where the metallurgical circuit begins. From this point two concentrates are produced. A zinc concentrate for treatment off site and a lead concentrate for further on site processing. The lead smelter takes 100 per cent of Isa concentrates as well as a contribution from BHP-BillitonÆs Cannington Mine.

Jan 1, 2002

By R Crookes

Mine to mill optimisation is not a recently developed concept. It is one which is finally gaining greater acceptance in the Australian mining industry, possibly as a consequence of the downturn in markets and certainly made possible by the development of tools and techniques to measure and predict performance of mining equipment and milling plants. Fragment size after blasting has a major bearing on the performance of all aspects of mining and a major influence on the economics of the mine and mill. The process to optimise fragmentation consists of identifying the key factors, measuring their sensitivity through a modelling and trialing program and conducting economic evaluations on the changes on both the mine and mill. Management of the Ernest Henry copper-gold mine in Northern Queensland, Australia, has espoused the mine-to-mill concept and is actively pursuing excellence in blasting to drive down the total cost of mining. Ernest Henry has extremely hard, wet and heavily jointed geological conditions, and had high powder factors and a large percentage of oversize material reporting to the crusher or ROM stockpile. A blasting improvement program was undertaken between Ernest Henry Mining, Thiess Contractors and Orica Explosives to optimise the ore size distribution, particularly the oversize component, as a step to reducing production costs. Measures of success included bringing the rock breaker back from double shifts to part-time operation and increasing direct dumping into the crusher from 70 per cent to 92 per cent. Tools and technologies to predict and measure the performance of individual blasts are needed before it is possible to optimise fragmentation or the downstream processes. These include such specialised Orica Explosives tools as SABREX, POWERSIEVE, and POWERLINE and commercially available drill monitors. As important are the more common still and video camera, borehole loggers, measuring tapes, surveying equipment such as face profilers, and a high speed camera if possible. There are many tools which can be applied however it is rarely necessary or possible to use all of them due to time constraints and a point of diminishing returns. The critical point is knowing what the true parameters of the blast were compared to design -only then can the predictive tools be effectively utilised. Stage one of the program has seen gradual improvement as the understanding grew and practices have been implemented resulting in reduced bridging in the crusher, geological mapping with respective blast designs and the oversize component under control. This paper is about a process approach which links tools and technology to understand the fragmentation drivers and then to optimising the size distribution. The continuous improvement program continues . . .

Jan 1, 1999

By X Ma

Kaolinite is of very fine particle size in nature and thus its dispersion plays a key role in the successful removal of kaolinite in iron ore flotation and selective flocculation processes. As the most widely used dispersant in the world, sodium silicate has been used as a standard dispersant for kaolinite in the iron ore industry. However, the actual effect of sodium silicate on the colloid stability of kaolinite particles and its dispersion mechanism remain unknown in the literature. In this work, the dispersion effect and dispersion mechanisms of some common inorganic and organic dispersants, including sodium silicate, polyphosphate and a low molecular weight polyacrylic acid, on kaolinite particles were systematically investigated through electrophoretic mobility and colloidal stability studies over a wide pH range. It was found that sodium silicate-kaolinite interactions only take place in the neutral and acidic pH range, while polyacrylic acid and polyphosphate interact with kaolinite from pH 3 to 10.5. Consequently, sodium silicate only disperses kaolinite at neutral and acidic pH. In contrast, polyacrylic acid and polyphosphate disperse kaolinite from pH 3 to 10.5, with strong dispersion effect observed at neutral and acidic pH. In the iron ore industry, selective fl occulation and reverse cationic fl otation, the most widely used flotation route, are both conducted at pH 10 to 10.5. The results of the present study show that, at such high pH, polyacrylic acid and polyphosphate are more effective dispersants of kaolinite, in comparison with sodium silicate.

Jul 11, 2011

By D R. L Vedoy, L Botha, S P. Gumfekar, J B. P Soares

Most of the known in-place reserves of oil sands are found in Canada. These oil sands ores are mined using various processes to extract bitumen. The by-product slurry resulting from the extraction process, known as tailings, is discharged into tailings ponds. Fine kaolin clays are an important ingredient of the tailings because they remain suspended in water for many years. Current polymeric flocculation/dewatering technologies use acrylamide-based polymers such as polyacrylamide (PAM), but sediments produced using PAM-based flocculants hold considerable amounts of water due to the formation of loosely-packed flocs. Anionic polymers are better flocculants due to bridging and the charge-neutralisation mechanism. In this paper, we will compare the synthesis of two flocculants: thermosensitive, anionic flocculants and thermosensitive, hydrophobically modified anionic flocculants. The first flocculant is a copolymer of acrylic acid (AA) and N-isopropyl acrylamide (NIPAM), in which AA is the anionic monomer. The second flocculant is a copolymer of NIPAM, AA and the hydrophobic monomer N-tert-butyl acrylamide. We evaluated the dewatering efficiency of 2 wt per cent kaolin using both flocculants by comparing settling rates at different flocculant dosages, charge neutralisation ability and supernatant clarity. To better understand floc formation, we measured the floc size formed by both flocculants at different flocculant dosages. We propose that the hydrophobic monomer in the terpolymer flocculant helps expel water out of flocs, ultimately decreasing the water content in the sediments.CITATION:Gumfekar, S P, Vedoy, D R L, Botha, L and Soares, J B P, 2015. Thermosensitive, hydrophobically modified anionic flocculants for dewatering kaolin clays, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 45–50 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015