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By M. Abdollahy

In this paper, the hydrophobicity of chalcopyrite particles produced with different laboratory mills has been studied; different grinding mechanism in themills made some changes in particles shape, Image Analysis (IA) method was used to determine the shape properties of chalcopyrite particles which are ground by a laboratory ball mill, rod mill and ceramic ball mill. The shape characters are stated in terms of shape factors such as circularity, convexity, roundness and regularity factor. Hallimond tube was used to float chalcopyrite particles followed by determination of critical surface tension of particles, this parameter used as a criterion to study the wetting behavior of chalcopyrite particles. The correlation between shape properties and critical surface tension of chalcopyrite particles showed that the hydrophobicity of chalcopyrite was affected by the shape. Investigations showed that the circular, round and more convex particles that produced with ceramic ball mill had lower hydrophobicity with higher critical surface tension (?c). The results also showed that the hydrophobicity of particles ground by ball and rod mills increased with the decrease of roundness, circularity, convexity and regularity factor of particles. Keywords: chalcopyrite, particle morphology, flotation, image analysis system, micro flotation method, hydrophobicity, shape properties

Sep 1, 2012

By Lilong Huang, Yuan Long, Li Shi, Guowang Zhang, Xiao Xiao

"Graphite is the key raw material of new carbon materials such as graphene and spherical graphite. The size and completeness of graphite flakes directly affect the performance of new carbonaceous materials.The research aims to increase the yield of large flake graphite by way of preventing the flake graphite from being damaged during the grinding process. A series of grinding and flotation studies on the flake graphite samples of Yichang in Hubei Province were carried out by vertical stirred mill . The damage coefficient L characterising the degree of graphite flake fractured and corresponding formula was proposed to determine the quality of the grinding and grinding of the flake graphite. The way the damage coefficient L of graphite flake would be affected if with different mill, different media material and size, stirrer speed were investigated. The test results show that vertical screw stirred mill helps the protection of large flake of graphite as well as the graphite liberation. When grinding to the same fineness, the damage coefficient L of graphite flake is 1.20 for vertical stirred mill, while the damage coefficient is 2.93 for ball mill. Minimum damage coefficient of graphite flake was obtained when using 6 mm polyurethane coated ball as grinding media, under the condition that rotation speed of the stirrer within the range of 100~130r/min. The grade of graphite in the concentrate floated from the ground product was 94.16%, the rate of recovery for graphite was 94.66%, and the content of +0.15mm was 54.83%.1 INTRODUCTION Flake graphite is a very important non-metallic mineral[1,2],and due to its special flake structure, the greater the scale and the higher the C grade, the value of its application is larger too. Therefore, in the grinding of graphite sorting process, We should minimize the destruction of graphite scales.. In this paper, graphite mine in Yichang, Hubei Province was used as the raw material for the study. Rough concentrate with C-grade of 36.49% was prepared by rough grinding and coarse separation. Then a series of grinding and flotation studies on the rough concentrate were carried out by vertical stirred mill , which aims to increase the yield of large flake graphite and to provide technical support for improving the beneficiation process of graphite ore."

Jan 1, 2018

By Y. H. Zhang

Mechanism of BK501 in desiliconization from bauxite was studied by use of flotation test, EDS, ?-potential, FTIR. Results of flotation show that almost all of diaspore can be depressed when BK501 is put into pulp ranging from pH 4~12, in the meanwhile kaolinite is slightly activated. In the light of surface analyses, it is concluded that the adsorption of reagent on the diaspore is dominant by chemical interaction. Moreover, kaolinite may float more by addition of BK501 because of flocculation.

Jan 1, 2014

By Liu Chun-Bao Sun, Hong-Jun, Wei Zhang, Tao Xu

SABC circuits have gained widespread attention within China, and are being gradually applied to many mines. However, the domestic knowledge of comminution process is still relatively basic, and the design and production management of the application of SABC technology lack guidance of scientific theories. This research project focuses on the Phase I SABC milling circuits of Wu Shan Porphyry copper mine. Targeting the design and operation problems of existing process and circuit, and without increased investment and alterations in equipment, the new technologies will combine ordinary crushing and grinding theories as theoretical guidance, and borrow JK Simulation Software (JKSimMet) for analysis in order to optimize the comminution process, efficiently allocate production output and energy consumption, eventually resulting in increased production and energy efficiency. Using JKSimMet Simulation Software, and combining theoretical optimizing and practical production techniques, as well as the on-site situation, the eventual SABC comminution process and circuit optimization plan is: increasing the grinding Ball charge from 8% to 10% v/v in the SAG mill; Setting the Ball charge in the Ball mill to 27% v/v and the maximum operating power draw to 5 800kW; replacing the HP Series crusher with a TRIO TC84 crusher, which is without a power controller, and adding a pebble bin. The final optimization result is: Maximum system processing capacity increased between 20%-26.7%, specific energy consumption reduced by more 2.0 kWh/t, creating an economic benefit of over 300 million RMB, thus achieving the goal of increased production, reduced energy consumption, and improved profitability.

Jan 1, 2014

By L. A. Nemchinova, M. A. Arustamian

"For a long time tailings piles of mining and smelting complexes have met the eye being a prospecting feedstock source for many industries. Nowadays, 6.5 million tons of copper and cooper-zinc processing tailings are stockpiled in the Urals annually, as there is no technology of its processing to provide a full and complex metal extraction within mining and processing operations. In spite of large volumes of mining wastes, not more than 20% of annual overburden, approx. 10% of processing wastes, approx. 40% slags (1) are involved into processing.Based on today’s complex of economic, environmental and social challenges of ore processing, waste processing technology using existing capacities is a burning issue. Mining wastes characteristics (including fine dissemination, variability of physical and chemical properties of mineral surfaces under impact of oxidizing, leaching, etc.) predetermine challenges arising out of its involving into processing and justify high capital intensity of new construction or reconstruction projects followed by replacement of existing processing lines with new ones.In this paper, the authors propose flotation technology for mature tailings of copper, copper-zinc and polymetallic ore processing. The technology developed provides for upgrade of existing process flowsheet diagrams at minimum costs to produce additional saleable products including low-grade copper concentrate, saleable zinc concentrate and gold concentrate thus facilitates sustainable use of depleting minerals and operational efficiency due to cost-efficient processing of already mined materials, being in fact, final semi-products located near existing operations. This is particularly important for operations with standby capacities and not engaged workforce."

Jan 1, 2018

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001)."

Jan 1, 2018

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um

New modern water treatment technologies required for arsenic removal from waste waters contaminated extensively by various background sources from mining, industrial waste, agricultural waste, painting industry and natural geological bed rock system etc. Arsenic is a widely dispersed element in the earth's crust and exists at an average concentration of approximately 5 mg/kg. Arsenic (As) and heavy metals may be released from the mine wastes to the ground and surface water systems, as well as the geological environment due to their solubility and mobility. This research focuses on the effect of accelerated carbonation process for successful removal of heavy metal arsenic anions from artificial waste water and mining waste waters. This accelerated carbonation process is a simple and novel method with 85 ~ 88% removal efficiency. Carbonation has been studied as a process to further improve immobilization of solidified/stabilized waste and granular waste. After successful removal of arsenic anions from solid mining waste and its potential benefits for producing construction materials. Besides, the industrial and urban management systems are generating bulk solid mining wastes, and most often dumping them in open fields. To prevent the landfilling with mining waste, many efforts are being made for the recycling of different types of mining solid wastes with a view to utilizing them in the production of various construction materials.

Jan 1, 2014

By Chris Plackowski, Bruckard. Warren J., Anh V. Nguyen

"Enargite is a significant penalty mineral in the copper industry and its separation from many copper sulfides by flotation is difficult. The separation may be crudely achieved using selective oxidation techniques or through the use of pulp potential control. This paper summarizes our latest contributions to a better understanding of enargite surface electrochemistry and hydrophobicity. Oxidation, roughness, hydrophobicity and species formation on the surface of natural enargite were examined by a novel experimental approach that combines electrochemical techniques, atomic force microscopy, X-ray photoelectron spectroscopy and droplet evaporation tensiometry. It allows for synchronized electrochemical control and examination of the oxidative surface morphology, speciation and hydrophobicity of enargite at pH 4 and pH 10. At low pH, surface layer formations consisting of metal deficient sulfide and elemental sulfur were identified associated with a limited increase in roughness and heterogeneous distribution of surface species produced by initial rapid dissolution of Cu, followed by diffusion limited surface layer deposition. At high pH, a similar diffusive mechanism associated with oxidation products consisting of copper sulfate and hydroxide and a significant increase in surface roughness were established. Receding contact angle measurements showed no significant difference in the contact angle on a surface oxidized at pH 10 and the freshly polished surface. Contact angle increased from 46° on the polished surface to 59° after oxidation at pH 4. Competing effects of hydrophilic copper oxides and hydroxides, and hydrophobic species of elemental sulfur on the mineral surfaces under oxidizing conditions at pH 4, and the change in surface roughness at pH 10, contribute to the changes in enargite hydrophobicity under electrochemically-controlled oxidation conditions. Most likely, both surface species and surface roughness produced by oxidation are critical to the changes in the wettability of enargite and other sulfide minerals."

Jan 1, 2014

By E. V. Koporulina, E. L. Chanturiya, M. V. Ryazantseva, E. S. Zhuravleva

"The morphology of the surface of sphalerite, galena and chalcopyrite and the adsorption of butyl xanthate under conditions of preliminary treatment of minerals by the products of water electrolysis were studied using atomic force microscopy (AFM) and Diffuse Reflection Infrared Fourier Transform Infrared Spectroscopy (FTIR). It was determined that practically all types of treatment by electrochemically modified water (a product of non-diaphragmatic treatment, anolyte and catholyte) lead to an increase of surface roughness of the studied minerals due to formation of small rounded shape particles. In contrast to that, after treatment of chalcopyrite by anolyte, its surface becomes smoother. Various effects of treatment by the water electrolysis products on the adsorption of chemical and physical forms of butyl xanthate on the studied sulfides were established. As a result, the efficiency of the complex of AFM and FTIR methods, as one of the ex-situ approaches for monitoring the surface state of sulfide minerals and direct investigation of BKx adsorption products was demonstrated.INTRODUCTION In mineral processing, copper-zinc sulfide ores are one of the most complex products in view of their mineral composition, fine dissemination, complex inter-growth and the proximity of the technological characteristics of copper, zinc and iron sulfides. For the most complete disintegration, fine grinding of ores to a size of 0.074-0.044 mm is necessary. Consequently, the main method for processing of such ores is flotation, which bases on the difference in physical and chemical properties of the mineral surfaces, in particular, degree of wettability. The separation of copper and zinc minerals and their separation from ferrous and other sulfides, sulfosalts and rock mineral is a very difficult task (Chanturiya, 2000). For the successful separation of copper and zinc minerals in the appropriate selective concentrates, it is necessary to find conditions for the most complete liberation of ore and rock-forming minerals and for increase the contrast in physical and chemical properties of their surfaces. Despite significant progress in the processing of copper-zinc sulfide ores, the problem of the selectivity of the separation of the main ore minerals has not yet been fully solved and requires innovative approaches (Chanturiya, 2015). To date, various methods of preliminary energy processing of complex ores are used: magnetic pulse treatment, impact by high-voltage nanosecond pulses, electrochemical effects (including products of water electrolysis (Chanturiya et al., 2014; Bunin et al., 2015; Chanturiya et al., 2014a; Chanturiya et al., 2016), processing with flotation reagents, etc. Electrochemical treatment of water in various modes allows to obtain products of electrolysis with different oxidation-reduction properties: acid anolyte with a high oxidation potential and dissolved oxygen content, an alkaline catholyte with high reducing properties and a product of non-diaphragmatic treatment with enhanced reduction properties."

Jan 1, 2018

By Cuim R., M. L. Li

Fankou Lead-Zinc Mine produced pyrite concentrate (P.C.) from the zinc tailings by rougher and scavenger flotation before 2010, with the averaged S grade of 40.54% at recovery of 79.34% ( to the feed of S circuit). On the one hand, the economic value of P.C. increases with its purity, on the other hand, when the S grade of P.C. feed to sulfuric acid manufacturer is over 47%, the pyrite cinder can reach a high Fe grade of 62% which can be directly sold as iron concentrate. On this background, engineers in Fankou Mine set the P.C. with S grade of 47% as target. The direct way to reach that goal was to clean the rougher P.C.. Lots of cleaning flotation tests were conducted and the compromised strategy was to produce two ranks P.C. with the S grade of 47% and 38% at the recovery of 44.20% and 36.17%, respectively. The dual-product flowsheet was successfully industrialized in 2010. In order to further improve the quality of P.C., gravity separation was introduced into the flowsheet. The numerical simulation and separation tests were performed to evaluate the beneficiation and classification performance of hydrocyclone as it treated the rougher P.C.. It was shown that the underflow of hydrocyclone could addressed the S grade of 47%, and the finer size overflow could also be enriched to P.C. with S grade of 47% by flotation, due to the contained pyrite with well liberation. That is to say, with the ingenious addition of hydrocyclone to treat the rough P.C., single P.C. with S grade of 47% could be achieved. The new flotation-gravity separation flowsheet was commissioned to produce the high quality P.C. at the end of 2013. The averaged S grade is 47.20% at recovery of 82.26% in 2014. The two steps flowsheet improvement maximizes the enterprise benefits and leads to simple utilization of Fe in pyrite in downstream industry.

Jan 1, 2018

By B. Y. Tuo

This article presents results of studies performed to determine the feasibility of using low-grade limonite ores from Yunnan deposit. Laboratory tests and commercial trials have shown that the magnetic separation can be performed with a high high-grade concentrates. The quality of the preparation concentration meets the requirements for blast-furnace smelting. The results as a whole demonstrate the feasibility of utilizing bank limonite ore. Yunnan limonite?s magnetic separation, roasting magnetic separation and flotation experimental study shows that grade of the ore grade can been from 32.91% heighten to 58.64%, a recovery of iron is 90.87%, productive rate is 51% through orthogonal test optimization; roasting magnetic separation can obtain that the grade of iron preparation concentrate is 61.16%, recovery is 67.39%, productive rate is 36%. As far as economy and enviormental protection is concerned, strong mag-netic suggested a more appropriate process. Keywords: Limonite; Roast; Magnetic separation

Jan 1, 2014

By W. Pawlos

"The paper will present the methods of visual observation and recording of movement paths of coal grains of different physical properties in the paramagnetic liquid. The paths were recorded with a video camera in the working chamber by means of a specially constructed device, acting as a periscope, which were then transformed into digital images.Experimental movement paths were confronted to the paths obtained in a theoretical way by means of solving differential equations of movement. The outlet level of a grain of the same physical properties from the separator is a random variable with normal distribution which modal value is equal to the outlet level of a spherical grain, calculated from the solution of grain movement equations. At these assumptions it is possible to calculate the height of the passage from the separator working chamber to separate a given product with a given separation accuracy, measured by a probable error and to determine separation conditions."

Jan 1, 2003

By A. Gül

This investigation was carried out with low grade Murgul-Cakmakkaya copper ore once used to be dumped away as waste material. Sulphide minerals in the ore sample observed are chalcopyrite, pyrite, sphalerite and to some extent molibdenite; quartz, calcite and dolomite are the gangue minerals. The ore sample assays 0.28% Cu, 2.94% Fe and 3.36% S. Mineralogical study of the ore sample showed that adequate liberation of chalcopyrite for flota-tion was achieved below 100 µm. In flotation tests Aerophine 3418-A was the collector employed, NaOH or Ca(OH)2were the pH modifiers. Deactivators used were sodium meta bi-sulphide, starch, dextrin and lime. MIBC was the frother used throughout the tests. Test results showed that starch alone was the most suitable depressant to give the optimum metal content and recovery val-ues. Activated charcoal was used to adsorb excess collector species in the flotation pulp during cleaning stages After two stages cleaning of the rougher concentrate using starch as the depressant a copper concentrate assaying 21.2% Cu was obtained with 79.5% recovery while the tailings contained 0.01% Cu and metal losses were about 3%

Jan 1, 2014

By C. L. Tang

Parts of the wastewater are reused directly and the rest moderately purified and reused, so the utilization rate of wastewater of the whole processing plant reaches 100 percent. At the same time, beneficiation indicators have been improved stably, and great economic and social benefits have been achieved.

Jan 1, 2014

By M. A. Naimanbayev, Zh. A. Baltabekova, N. G. Lokhova

"Integrated utilization of natural resources using energy-saving and waste-free technologies is relevant around the world. This applies to such type of raw material as titanium-magnetite ore. Shortage of ilmenite raw materials in the Republic of Kazakhstan for titanium slag melting challenges the search of alternative titanium-containing raw materials, titanomagnetites in particular. At the same time there are deposits of indigenous titanomagnetite ores of huge reserves, which can become the complex raw material for production of iron, titanium and vanadium. Tymlay field in the South-Eastern part of Chu-Ili watershed is of particular interest, within the Karasay ore unit with iron content of 30,4 and titanium dioxide - 10%, and after beneficiation titano-magnetite concentrate contains Fe-52,4; TiO2-of 16,06%. Technology of titanium-magnetite concentrate ore-thermal melting was developed at Tymlay deposit producing hot metal and low titanium slag that can become the raw material for titanium production using chloride method. Slag produced in course of titanomagnetite ore-smelting consists mainly of alumosilicates and sodium silico titanates, magnesium and calcium titanates, titanium dioxide and lower titanium oxides. Following operations were carried out to improve titanium slag quality: slag sintering with sodium hydroxide; cake leaching with water to remove water-soluble impurities; to reduce the number of operations impurities leaching with hydrochloric acid was combined with pyrohydrolysis of titanic acid; rutile concentrate production (85% TiO2, 7,66% SiO2), silica removal by means of sodium hydroxide solution treatment, finally sellable rutile concentrate was produced with titanium dioxide 91-92% and silica 1,7 to 2,0% content. Based on research results technological scheme of titano-magnetite concentrate processing at Tymlay deposit was proposed producing hot metal and certified rutile concentrate, suitable for chlorination."

Jan 1, 2018

By Katarina Theander, Robert J. Pugh

The generation of froth with a critical degree of stability and height is an important aspect of the froth flotation. In this paper we have studied the synergism and anti-synergism in frothing behaviour in a mixed flotation collector/frother mixture (a model fatty acid; sodium oleate and a model frother; nonionic (polyethyleneoxide alkyl C14E6). Values of the collector / frother molecular interaction parameters (the ß-parameters) were determined from the surface tension data using regular solution theory. The frothing characteristics of the system were evaluated using a glass column equipped with a series of conductivity electrodes, which enabled the water content of the froth to be determined. From these measurements, the dynamic frothability and static froth stability were determined. It was concluded that the synergism/anti-synergism in frothability was depended on the molecular composition of the surfactant system, the diffusion of monomer to the thin film interface and on the breakdown of the mixed nonionic/anionic micelles.

Jan 1, 2003

By Lang Shiping

The criteria for designing a crushing chamber are presented and a program for designing the shape of the chamber is proposed. During the chamber shape design, major design parameters are analyzed first, optimized parameters are determined next and the basic shape of chamber is figured out finally. In the basic chamber design program, the influence of abrasion of basic chamber shape and material characteristic are not accounted for usually. Here, based on the minimum abrasion of chamber shape and uniform particle size theory, the equation for chamber surface curve and the transcending function were formulated and a low-abrasion chamber was designed. Since the chamber shape designed based on experience and experiments is not necessarily the best, optimal design of the crushing chamber shape was carried out. Cubic spline function was used to represent the chamber shape curve and a mathematical model was formulated. The optimal shape solution was obtained using a complex method. Finally, the optimal chamber shape was determined by matching the moving cone stroke S, moving cone speed N and the moving cone bottom angle Thus, superior technical performance of the cone chamber was achieved.

Sep 1, 2012

By M. I. Panayotova

Some of effluents released by copper smelting plants are highly acidic (pH = 0~1) and contain arsenic and copper in relatively high concentrations (10~20 g/L). Usually arsenic is removed by precipitation with different reagents, such as lime, iron salts, calcium salts, aluminium salts, etc. Precipitates (often voluminous) that require further handling are formed and copper and other valuable components are lost. A method is presented for copper and arsenic extraction from acidic effluents. Effluents are treated in specially designed closed electrochemical cell without chemicals? addition. Gases formed are collected and treated for decomposing the eventual traces of As-bearing compounds and ensuring the environment protection. Initially copper of grade of 85 % is electro-won. Further about half of the initially available arsenic is separated as low-soluble, low volume mixture of intermetallic compounds, oxides and some elemental arsenic. At the next stage the main part of the left arsenic is immobilized as low soluble stable compound. Arsenic content in the treated acid is in the range 0.20~0.25 g/L. Acidity of treated effluent after first two stages remains practically unchanged and the solution can be re-used. Physicochemical and electrochemical processes, governing copper and arsenic removal, are discussed.

Jan 1, 2014

By R. K. Logric

Bor flotation tailings are very interesting from two reasons: first, is having due value presently, and second represent serious pollutant into this region of Balkan. This paper is only one small part of investigation about processing of valuable minerals from tailings, and desulphurization of this biggest pollutant in the same time, by refloating. The main objective of this work is to pay attention on this problem for resolve greatest environ-mental problem of Serbia and Balkan in the nearly future. Bor is potential regional risk spot, since that failure of its tailings dams would release high amounts of toxic materials that would reach the Danube River. The basic goal of this experimental investigation was finding some possibility for flotation tailings treatment by classical froth flotation. In order was obtained material effect through copper recovery, and environmental protection by moving the rest of reprocessing into the safe place. The work present obtained results of laboratory tests in two laboratories: laboratory of mineral and recycling technology at the faculty in Bor, and laboratory of department of mineral processing of ITNMS in Belgrade.

Jan 1, 2014

By S. Titkov

At present, Russia is engaged in processing, 3new plants of hard-to-process potash ores with increased content (up to 10 - 12%) of insoluble impurities (insoluble residue ? I.R.). This required additional research to improve the process of potash ores flotation. Based on the study of the effect of dispersive properties of frother and its flow rate on the efficiency of aliphatic amines with different length of the hydrocarbon radical (as sylvite collector) there was showed the possibility to apply high molecular amine with length of hydrocarbon radical C20 ? C26 by normal temperature of circulated plant salt solution (saturated solution KCl ? NaCl ? H2O). There was designed and tested in plant conditions the modified amine collector with the length of the hydrocarbon radical C16 - C26, improving flotation of Sylvite under normal temperature of circulating salt solutions at potash flotation plants. There was made the study of the influence of the hydrocarbon radical length of alkylmorpholine on the Halite flotation from intermediate products of sylvite recleaner flotation with different content of I.R. (silicate-carbonate slimes), at normal and elevated temperature of salt solution. On the basis of the application of modified alkylmorpholine for Halite flotation, there was developed the process of further beneficiation for the intermediate products of sylvite recleaner flotation from potash ores with increased content of insoluble impurities, which can eliminate the circulation of the intermediate products in the process flow sheet of sylvinite ore processing and increase the KCl recovery into the finished product. Keywords: flotation, potash, halite, alkylamine, alkylmorpholine

Sep 1, 2012