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By Jing Zhan, Tian-zu Yang, Wei-feng Li, Li-Hua Jiang, Shi-yan Xu, Jian-yang Huang, Chuan-fu Zhang, Yan-qing Fan

The amount and activity of coal, reduction temperature and other parameters of the process of bottom-blown reduction of liquid high lead slag were investigated in laboratory. Methods to strengthen the bottom-blown reduction process were studied by industrial production. The results were in the follows: the reduction temperature was 1150℃; reduction time was 1.5h; the reductant was anthracite; lead content in slag was controlled to 2%; the rate of coal was 7% and gasification loss of coal in high temperature was severe; liquid lead slag reduction rate was faster with coal; prolonging the reaction size had little effect on reducing lead in slag; the size of the reactor can be further reduced.

Jan 1, 2015

By Pengqi Zhang, Mingcheng Bing, Lixiong Shao, Shuxing Qiu, Qingyun Zhang, Shengfu Zhang

Coal desulfurization has been regarded as an effective pretreatment for clean fuel and less environmental pollution. The microwave irradiation was used to desulfurize the Nantong coal leached with H2O2 and NaOH. The results showed the desulfurization rate of the coal is very low by directly microwave irradiation, while the coal samples leached with H2O2 and NaOH by microwave irradiation could effectively improve the desulfurization rate. The optimum desulfurization conditions were obtained as 10-min irradiation time, 800 W irradiation power, particle size below 74 μm, 1:1 concentration ratio of H2O2:NaOH, in which the desulfurization rate reached 51.14% of the total sulfur content. Attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectra of coals structure before and after treatment have shown the bands in both coals changed slightly except the relative intensity of some absorption ones. It can be found that most of FeS2 and –S–S– functional groups transferred after treatment, while –SH and –S=O– had almost no changing by ATR-FTIR spectra analysis. The structures of coal matrix would not be broken by microwave irradiation in reasonable the reaction conditions.

Mar 1, 2017

By KNona Liddell

Many metal recovery processes Involve heterogeneous reactions In porous media accompanied by fluid flow and mass transfer. Modeling such systems Is difficult because of the number of rate processes Involved and is complicated even further by effects due to the structure of the porous medium. Data on even bulk properties of the medium are often severely limited or unavailable. For many such systems, a cell model may provide, an attractive alternative to models based on transport ,mechanisms in a differential volume. A cell model requires less input data and is computationally efficient. Identical residence time distributions can be obtained with models of both types, and both allow conversion and concentration profiles and histories to be calculated. The formulation and properties of cell models for metals recovery are described in detail.

Jan 1, 1996

By Wei Liu

A new process for extracting cadmium from the electric precipitated dust produced by ISP process was studied. A leaching rate of 89.1% of cadmium was attained by leaching the dust with NH3?H2O-(NH4)2SO4 system under the best leaching conditions: ratio of liquid to solid(l:s)=2.5, c(NH3):c(NH4+)=3:5, total concentration of ammonium and ammonia=8 mol?L-1, leaching time= 1.5h, temperature=35. The most troublesome impurity of lead could be deposited from the leached out solution automatically after put it static more than 15h when the total concentration of zinc and cadmium was up to 45gL-1 , and the final concentration of lead was 0.0047 gL-1, which meant 99% of it was removed. Metallic cadmium which contained cadmium more than 99% was prepared by electrowinning under the conditions: current density=750Am-2, total concentration of Cd2+ and Zn2+>25gL-1. The current efficiency was about 87% and the energy consumption for every ton of cadmium was about 548KWht-1. Main impurities of the metallic cadmium were copper and zinc and all of they could be got rid of in the following pyrometallurgical refining step.

Jan 1, 2006

By Binxu Zeng, Mark Jolly, Xiaojun Dai

"The traditional investment casting foundries use batch melting and chunky running systems to produce casting components. This method leaves the energy saving issue as subsidiary one. In our research project, one of the partners, the AEROMET international PLC provides the thin wall aluminium component ""filter housing"" for test. The AERO MET uses traditional casting route to produce the filter housing, which only gives 5% --10% yield. In this paper, numerical simulation method is used to analyse filling and solidification of the casting running system. The CRIMSON running system of the filter housing is designed by using casting simulation software, MAGMAS and Flow3D. By working with AEROMET, various configurations of the casting running systems were tested and analysed. Using them ultiple life cycle approach, the energy content of new process is compared with traditional one. It indicates that the CRIMSON process only uses 36% of energy consumed by the traditional route.IntroductionThe investrnent casting is a metal for ming process using expendable patterns, which is a standard casting technique and is widely used to produce quality parts. Its accuracy, versatility and integrity tie itself to important and precious engineering components in Aerospace industry. However, traditional investrnent casting process usually uses chunky runner system and gravity filling method. It not only reduces the casting yield of the product but also causes the pouring defect during the casting. As author's previous research showed that gravity filling method pouring basin and down sprue are two main resources of entraimnent defects generation. No matter how good the running system is, entraimnent defects such as double oxide films (DOF) and bubbles will I get into the casting to cause problem."

Jan 1, 2013

By Leo Brewer, Kazuyoshi Shimakage, Mamoru Mitomo, Toshiyuki Nishimura, Yoichiro Uemura, Shinji Hirai

"In the synthesis process of ß -La2S3 via the sulfurization of La2O3 powder using CS2 gas, La2O2S was formed. This occurred at an initial stage of the reaction for sulfurization temperatures below 973K, and ß -La2S3 was also formed at a shorter period for higher sulfurization temperatures. It was found that the oxygen content in ß -La2S3 powders decreased gradually with an increase in sulfurization temperature. On the other hand, the carbon content in these powders increased gradually with an increase in the sulfurization temperature. Though it has been reported that ß -La2S3 was transformed to Y -La2S3 at 1723K± 50K, the sintered compact of double-phase Y -La2S3 and ß. -La2S3 was formed at a rather higher temperature of 1973K when the synthetic powder of ß -La2S3 containing a high amount of oxygen was used. However, phase transformation of -La2S3 to Y -La2S3 progressed preferentially with a decrease in the oxygen content of synthetic ß -La2S3 powder. The Seebeck coefficient of the sintered double-phase Y -La2S3 and -La2S3 was higher than that of the single-phase Y -La2S3, reported previously.Introduction La2S3 exists in three polymorphic forms that are similar to a series of Ce2S3, Pr2S3 and Nd2S3: a, ß , and Y'. The a -La2S3, which is stable at low temperature, is irreversibly transformed to ß -La2S3 of various compositions in the solid-solution range between La2S3 and La3S4, at 923 ± 50K. The -La2S3 may also be an oxysulfide of La10S14O2. Moreover, the ß .-La2S3 phase is transformed to Y -La2S3 ,which has a Th3P4 structure, at 1573 ± 100K. The melting point of Y -La2S3 is 2398 ± 30K where this temperature is similar to those of common refractory materials such as silica and alumina. Therefore, it can be predicted that y -La2S3 which has a high melting point and a thermodynamic stability due to the strong affinity of La for S, would have &high refractory character and chemical inertness in many molten metals. The y -La2S3, colored vivid faint yellow is stable up to 623K in air, where oxidation starts. y -La2S3 is frequently used as pigments for plastics and paints3. Furthermore, Y -La2S3 which is a semiconductor, is considered to be useful as a thermoelectric conversion materials, because it has a high Seebeck coefficient."

Jan 1, 2000

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from the University of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from the University of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

By Zhao wen Wang, Ramana G. Reddy, Min Li

"The electroreduction of Co(II) in l-butyl-3-methylimidazolium tetrafluoroborate (BMlMBF4) ionic liquid was investigated by cyclic volatrnmetry at 353 K. The results show that the reaction of Co(II) to Co is irreversible in one step with two electrons transferred. The diffusion coefficient of Co(II) was estimated to be 7.6 x 10-8 cm2 s·1 at 353 K. Then the electrodeposition of cobalt was studied at different cathodic potentials (-0.80 to -0.95 V) and different temperatures (333 to 363 K) in BMIMBF 4 containing 0.20 mol L-1 Co(BF4)z. The deposits were characterized using scanning electron microscope (SEM), energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD). SEM images show that a uniform, dense, and compact deposit was obtained at -0.80 V and 333 K. The deposits were identified as high-purity metallic Co for all experiments by EDS and XRD.IntroductionCobalt is known as a hard magnetic material and cobalt alloys have been shown to have excellent magnetic properties with adequate mechanical durability and corrosion resistance, which are needed for high performance magnetic recording applications [1-4]. The electrodeposition of Co alloy in the aqueous solution is generally difficult because of the narrow electrochemical potential window of water, which leads to the low current efficiency and worse quality of deposits due to the hydrogen embrittlement. Thus, aprotic ionic liquids (ILs) are expected to be the ideal alternative media for electrodeposition of cobalt or its alloy since ILs usually provide a wide working potential windows, negligible vapor pressure, and acceptable conductivity for electrolysis without the occurring of hydrogen evolution [5, 6]."

Jan 1, 2014

By Shengli Wu, Jiacong Zhang, Mingyin Kou, Bingjie Wen, Heng Zhou

The COREX process, which is considered to be able to replace the blast furnace, still has some gaps to reach the designed productivity. The metallization degree is regarded as one of the limitations of the COREX process. In the present work, several parameters affecting the metallization degree of direct reduced iron (DRI) are analysed by SPSS software (Statistical Product and Service Solution). Melting rate, oxidation degree of reducing gas, oxidation degree of top gas, top gas consumption per ton of burden, temperature of reducing gas, and burden distribution index are con firmed as the main factors affecting metallization degree. Based on this, a linear equation has been developed for predicting metallization degree. Additionally, improving the melter gasi fier vault temperature appropriately, increasing the proportion of high volatile matter coal, and optimizing the type and particle size of iron ore and the pattern of burden distribution have been shown to improve the metallization degree.

Mar 1, 2018

By Itavahn Alves da Silva, Jose Dimas de Arruda, Amanda Aparecida Fátima Arruda, da Silva de Souza, Carlos Antonio da Silva, Varadarajan Seshadri, Samuel

The knowledge of the flow field inside a continuous casting mold is essential to improve operational efficiency of the process and also to achieve better inclusion control. Physical modeling, PIV technique and CFD have been employed to assess the velocity distribution in the metal- slag interface region in a slab mold. The analysis of results shows how higher casting velocity and lower immersion depth of submerged nozzle can lead to higher turbulence in the slag-metal interface. The effects of density difference between slag and metal and interfacial tension between the phases have been highlighted.

Jan 1, 2016

By Kazutaka Kunii

It is invariably certain that after punching for IC Leadframes, scrap metal were generated. These seraps were re-dissolved and in order to use as raw material for leadframes, it is necessary to remove the Ni plating. In this study a simple method was developed for the removal of Ni plating by surface oxidation of Ni plating. For this purpose a fundamental study was carried out on the oxidation behavior of Ni plating. Results showed that by controlling the oxidation condition, a considerably high rate of Ni could be removed.

Jan 1, 1996

By Jianhua Xin, Min Chen, Lei Xu, Haohua Deng, Nan Wang

A mathematical model of converter slagging and steelmaking process by replacing part of lime with limestone is established. The rate equations of oxidation reactions and lime dissolution in converter under the limestone substitution proportion increasing from 25 to 50% can be obtained and the effects of limestone substitution proportion on the variations of the composition of hot metal, slag and converter gas during the steelmaking process are investigated. In the process of converter slagging and steelmaking by replacing part of lime with limestone, increasing the hot metal temperature and the lance height could be favor to increase the content of FeO in the slag and accelerate the limestone decomposition and dissolution. With the limestone substitution proportion increasing from 25 to 50%, the maximum of oxygen supply ratio increases from 10.7 to 19.7% and the temperature drop of converter bath is 8–60 °C.

Mar 1, 2018

By Hongli Wen, Guangkun Shen, Qiong Deng, Shoujian Huang, Min Gan, Xiaohui Fan

"Due to the low iron grade and high sulfur content, pyrite cinder is difficult to be directly used for iron-making. In this paper, technology of magnetic roasting -grinding and magnetic separation -acid leaching was put forward for reclamation of pyrite cinder. For pyrite cinder of TFe53.51%, S2.20 %, studies showed that good magnetic effect can be achieved at roasting temperature 650~7000, reducing atmosphere CO/(CO + C02) 10~20% and roasting time 10~30 minutes. In separation conditions of grinding size -0.045mm accounting for 96.09% and magnetic field intensity of 1240 GS, iron concentrate of TFe64.81 %, S0.18% and iron recovery rate 91.44% was achieved. Acid leaching was studied to strengthen desulfurization. Results showed that high-quality iron ore concentrate of TFe66.3 l %, S0.10% was obtained under the conditions of hydrochloric acid mass fraction of 5%, pulp density of30%, leaching temperature of70? and leaching time of2 hours.IntroductionPyrite cinder is produced as a by-product of sulfuric acid industry [1] Domestic production is more than 12 million tons every year and occupied area is over 10 million square meters [2,3]. The pyrite cinder outdoor not only pollutes air but also damages surrounding surface [4] It after treatment used for iron-making is an ideal reclamation approach for its rich iron which is commonly 40-60% [5]. But pyrite cinder gets low utilization for its low iron grade and high sulfur content in China [6]. Therefore, comprehensive utilization of pyrite cinder has profound significance to environmental protection and the development of domestic iron and steel industry."

Jan 1, 2013

By Moto Goto

Onahama Smelter of Onahama Smelting & Refining Co., Ltd. has two green- charge reverberatory furnaces; the old furnace was constructed in 1965 and the new one in 1973. This paper discusses the use of oxygen-oil burners in a green-charge reverberatory furnace and also compares the copper loss in slag between the two furnaces at Onahama Smelter. During the past ten years of operation, no shutdowns of the old furnace were necessary and the smelting capacity was increased by 25% by the use of two oxygen-oil burners. These burners are suitable for a green-charge reverberatory furnace to in- crease the smelting capacity without causing an increase of the exhaust gas volume and refractory erosion. After two years of operation of the old furnace, a bottom build-up in the charging zone of approximately 50 centimeters was experienced, and this build-up has stayed at this level since then. In 1973, a new additional reverberatory furnace was put into operation. Copper content in slag of the new furnace was lower by approximately 0.15% than that of the old one during the first several months after the start-up. Investigations were then made on the effect of the bottom conditions in the charging zone on the copper content in slag.

Jan 1, 1976

By Nagahiro Saito, Takashi Nishimura, Takamichi Ichikawa, Akio Fuwa

"Yttria-stabilized zircohia (YSZ) has high potential to be used as solid-oxide fuel cell (SOFC) electrolyte. However, the high efficiency of SOFC has not been yet achieved due to the high internal resistance of bulk electrolyte. The resistance becomes lower with the decrease in the electrolyte thickness. Thus, the decrease in electrolyte thickness leads to lower internal resistance. . The aim of this study is as follows: (a) to prepare the thin films of YSZ by inductively-coupled RF plasma-enhanced metal organic chemical vapor deposition (PEMOCVD) process using Zr(t-OC4H9)4,Y(DPMh and oxygeil, and (b) to reveal the relationship between the structural characterizations and the process parameters.1. IntroductionYttia-stabilized zirconia (YSZ) has, been widely used as not only heat-resistant materials but also the components in automotive oxygen sensors, electrolytes of solid-oxide fuel cell (SOFC)(1)(2) and the buffer layers for the high-temperature superconductor because of its low thermal conductivity, good mechanical properties and high ionic conductivity. However, it is said that the internal resistance of the bulk electrolyte is too high to be appropriate as a solid electrolyte for high-efficient SOFC. The authors believe that the thin YSZ electrolyte can give a high performance to characteristics SOFC, since the internal resistance becomes lower with the decrease of electrolyte thickness. Thus the process technology to prepare YSZ thin films is desirable and must be established.In recent years, the YSZ thin films have been reported by chemical vapor deposition (CVD), thermal CVD using metal chlorides (MC) of ZrCl4 and YC(3)(4), thermal CVD using metal organic compounds (MO)(5)(10) Zr(t-OC4H9)4 and Y(C11H19O2)(11) and plasma-enhanced (PE) CVD using MO. Here, these methods are called MCCVD, MOCVD and PEMOCVD. MCCVD has two disadvantages; a large quantity of chlorinated impurities in deposited films and high processing temperature (> 1273K). This high processing temperature leads to damage of substrates in particular, so the application of this technology is limited. On the other hands, the processing temperature by MOCVD becomes and is lower. Unfortunately, the accurate vapor pressures of these metal organic compounds have not been, known so: that it is difficult to control the composition and the film thickness by MOCVD method well. Moreover, the large amount of carbonic compounds in the films prepared by MOCVD method is produced. However, plasma-effect has been reported to decrease large amount of the carbonic impurities by PEMOCVD. However, PEMOCVD has many reaction parameters in plasma processing; the geometry of experimental apparatus, radio frequency, electronic power input and so on. Thus, the general understanding about the relationship among reaction parameters, the composition and crystal structure of thin deposit film by this method has not yet been established."

Jan 1, 2000

By M. T. Ernett

Significant amounts of arsenic are often present in effluents arising from the mining of sulfide ores for the extraction of metals such as copper, gold, lead and zinc. The arsenic is usually removed from the process effluent by co-precipitation with iron because of its common occurence in the mined ore bodies and the excellent adsorptive property of the precipitated hydrous ferric oxide compound. There has been controversy, however, over the long-term stability of the arsenic-bearing ferrihydrite which is produced. This paper presents the results of laboratory studies which indicate that the cations of calcium, magnesium, zinc, cadmium and lead, increase the pH range of effective arsenic adsorption in the Fe-As precipitate from 4-7 to 4-9. The increase in the pH range is similar for all of the added cations investigated. Sulphate ions are shown to have a minimal effect on the residual dissolved arsenate concentration. Silicate ions reduce the adsorptive capacity of ferrihydrite if they are present before the arsenic is adsorbed.

Jan 1, 1994