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By R. L. Hopkins

Fifteen alkyl cycloalkyl sulfides and three dicycloalkyl sulfides were synthesized to provide reference compounds in the search for these classes of sulfur compounds in crude oils. In synthesizing sulfides by alkaline alkylation the order in which the reactants were added was shown to determine the yield and purity of the product.

Jan 1, 1966

By Torben Ulisses da Silva Carvalho

A lixiviação é um processo hidrometalúrgico que consiste na separação entre o metal e a ganga através da dissolução em meio aquoso do mineral contendo os metais de interesse. O presente trabalho utilizou o minério de cobre oxidado da Mina do Sossego, sendo lixiviado em escala laboratorial com diferentes períodos de tempo, utilizando o ácido sulfúrico como agente lixiviante. A partir desses ensaios foram construídas curvas contendo os teores do minério de interesse contidos no licor e no rejeito, além do cálculo da recuperação metalúrgica. Os resultados foram encontrados utilizando a técnica de titulometria. Houve notada variação dos teores encontrados, os quais aumentavam proporcionalmente com os períodos de lixiviação. Esse comportamento mostra a necessidade de um maior número de etapas nos determinados períodos de tempo para uma recuperação metalúrgica adequada.

Aug 16, 2017

By O. I. Ostrovski, D. K. Belashchenko

The aim of this paper is the construction of models of systems with ionic and ionic-covalent bonds (molten salts) using experimental diffraction data and the calculation of their structure and thermodynamic and transport properties. Modelling was performed using algorithm BELION, in which the non-coulomb part of interaction potential between ions in the model was determined by the method of iterative simulation which targeted agreement between calculated and experimental partial pair correlation functions (PPCFs). The ionic charges in salts, which can be fractional, were determined by minimization of internal energy. In this paper, the algorithm BELION is applied for chlorides of alkaline-earth metals. Pair potentials, PPCFs, atomization energies, self-diffusion coefficients and electric conductivity are calculated. The charge of alkaline-earth metals was in the range of 2.0-2.1, slightly increasing from Mg to Ba. Partial pair correlation functions and atomization energies of models agree well with experimental data for MgCl2, SrCl2and BaCl2. Keywords: molten salt, molecular dynamics, partial pair correlation function, ionic charge, atomization energy, diffusion.

Jan 1, 2004

By Sergio Neves Monteiro

In the present work, a ceramic foam elaborated with illitic clays was characterized. Properties related to density and compression strength were determined in samples fired at 1300oC, a temperature that permits the clay structure to generate and retain gases that will produce the foamy structure. The microstructure of the ceramic foam was studied by X-ray diffraction, scanning electron microscopy and mercury porosimetry. The results showed that the ceramic foam presents a bulk density of 0.38 g/cm3. The microstructure is formed by large open pores, quartz particles and vitreous phase.

Jan 1, 2006

By G. W. Leney

Introduction and Historical Background The office and mining operations of Pacific Asbestos Corporation are located near Copperopolis, California in the foothills of the Sierras about fifty miles east of Stockton. This is historic country in the heart of the old Mother Lode gold district. Mark Twain's famous story of the jumping frog, written here, is still commemorated in an annual contest in Calaveras County,' and the camp at Poker Flats, described by Bret Harte, was only a few miles from the present mine.2 Joaquin Murrieta, the famous Mexican bandit started his three year reign of terror in this vicinity,3 and Black Bart, the P08 laureate of the stagecoach robbers, held up his first stage at Funk Hill, just three miles north of the mine. His last robbery was at almost the place, on the top of the hill overlooking the Stanislaus River ferry crossing. Although this was his favorite country, and he traveled extensively through it, he was not a credit to his acclaimed profession of Mining Engineer because there is no evidence that he ever recognized the asbestos, and he was finally caught as a consequence of the robbery at the ferry.4 One of the old stagecoach roads crossed the Stanislaus River at the mine site, and the ferry landing may still be seen from the main haul road into the pit. The road itself is partly buried under the rock dumps. In spite of its location and apparently prominent exposure, the first work on the asbestos deposit was not recorded until 1904.5 Development of the present operations was started in 1959 by Jefferson Lake Asbestos Corporation, a subsidiary of Jefferson Lake Sulphur Company. Management control of the company changed hands several times and it was later reorganized under the name of Pacific Asbestos Corporation. In December, 1968, a controlling interest was acquired by H. K. Porter Company, Inc. Figure (1) shows the mill and office buildings as seen from a site near the entry road. The offices are at the left with the mill warehouse in the foreground. The conveyor at left center carrys mine concentrates up the hill from the crusher. In the background are the dry rock storage building and mill tailings piles. Since the beginning of mining operations in 1962, seven and three-quarter million tons of ore and fifteen million tons of waste have been removed from the open pit which now measures about 1400 x 1800 feet at its widest points. The lowest operating level is at an elevation of 726 feet about 325 feet below the original surface. Figure (2) shows the open pit looking toward the west end. The main haul road can be seen along the side of the pit. A shovel is operating at the bottom of the pit while a front end loader on the level above provides ore for blending. In the background are rock dumps for waste stripping. The company markets an annual production of 30-35,000 tons of chrysotile fibre in groups 4 through 7, under the Mother Lode Brand

Jan 1, 1972

By David G. Winter

The first test pile for the carrier pier and south wharf at NAVSTA Puget Sound was driven on December 27, 1989, and the final pile was tested on February 26, 1990. Implementation and modification of the test pile program were done by the owners (WESTDIV and ROICC-Everett), the engineers (ABAM and Hart Crowser), and the contractor and his subcontractor (General Manson Joint Venture and GRL). The site is located as shown on Figure 1. SUMMARY OF THE SOIL CONDITIONS A soil profile along the pier is shown as Figure 2. The soil units can be generalized as follows: ? Upper Silts - Fill, sandy silt, and clayey silt extending from the mudline to an elevation of about -80 feet; ? Intermediate Sand - A medium dense to very dense silty sand unit which is about 30 feet thick near the shore, but thins and disappears offshore; ? Lower Silts - Sandy silts and clayey silts in a medium stiff to stiff condition; ? Deep Sand - A very dense overconsolidated sandy soil encountered at an elevation of about -145 feet.

Jan 1, 1990

By Holger Witthaus

Beside the traditional geomechanical evaluation methods the geotechnical parameters are recognized as important facts of the planning work for multiple seam mining. Standards for applied monitoring and investigation methods for geotechnical determination of drill cores, laboratory rock-tests and observation of roadheadings are the basics for rock mechanics classification and support design. The geomechanical classification is in this context an essential element. The planning procedure, as it is becoming more and more detailed, beginning with the panel layout up to the technical instructions of roadway development and design of roadheading machinery, nowadays uses a lot of geotechnical information that also are expanding to include quantitative determination of more parameters. The current monitoring system includes the description of separation planes using drill cores and roadheading observation as well as laboratory tests of rock-strength and geophysical borehole examinations. This information is analyzed within the geomechanical standard-classification. The re-engineering process of comparison the predicted support success to the actual monitoring results provides the opportunity for continuous optimization of the planning work und support design. This way of empirical analysis is used for basic planning work in Germany for decades. But using the technical standard of information technology and a centralized database now it is possible to reach quick-win effects in implementing research results on the one hand and actual experiences on the other hand.

Jan 1, 2006

Copper Recovery from Printed Circuit Board by Carbonisation

Sep 13, 2010

By A. Flora, E. Bilotta, F. Foria, V. Nappa

"All the typical applications of deep mixing rely on the good mechanical properties of the improved columns to strengthen or stiffen the ground for a number of geotechnical applications.This paper focuses on a completely different kind of deep mixing, carried out in order to obtain columns much softer than the surrounding soil. This kind of deep mixing, named Soft Deep Mixing (SDM), is introduced as an original means to tackle seismic risk, and can be convenient when the existing structure to be protected has a historic relevance that cannot be altered with structural modifications. The idea is that properly assembled layers made of partially overlapped SDM columns, with dynamic impedance much smaller than that of the surrounding soil, will filter and reflect most of the seismic energy.The paper presents the results of some 2D parametric numerical analyses aimed to investigate the seismic performance of this innovative approach. Simplified dynamic inputs (Ricker wavelets, having only one largely predominant frequency) were adopted to better understand the effect of signal frequency. The analyses show that the effectiveness of the soft grouted isolating barrier depends on soil and SDM geometrical, physical and mechanical properties, as well as on the frequency content of the seismic input.INTRODUCTIONPassive structural systems installed at the foundation level of existing buildings are a common solution to protect them against earthquakes. However, installation procedures are expensive and not always feasible, as for instance in the case of valuable buildings. As an alternative, ground improvement techniques can be used to modify ground properties, in order to mitigate the intensity of shaking at ground level. The propagation of shear waves in the ground can be modified by introducing a layer of artificially modified material, having a dynamic impedance (defined as n =p VS, where p is the material density and VS the velocity of shear waves) very different from that of the natural soil. Both very high or very low values of the dynamic impedance of the grouted soil (nt) can be effective in reducing the overall transmitted energy, with the difference that – for a given reduction of the transmitted energy - stiff grouted layers tend to filter the low frequency components of the amplitude spectrum without modifying in a significant way the high frequency components, while soft grouted layers have the opposite effect. Then, ideally the choice of the best grouting technique should be made considering the effects of the different frequency components on the building to be protected. These effects are detrimental for the structure when they are close to its natural frequency: high frequency components result into large structural loads on massive squat structures (high natural frequency), and low frequency components may be critical for tall and flexible structures (low natural frequency). Therefore, the typical procedure of stiffening the uppermost soil layers regardless of the kind of building to be protected is not necessarily beneficial, and for the case of squat structures soft grouting should be preferred. However, this procedure has not been taken into account yet in the engineering practice, and may pose static problems at ground level (i.e. excessive static settlements)."

Jan 1, 2015

Tailings embankments can develop a high phreatic surface if the original design for the embankment does not include drainage facilities or if existing drainage facilities become ineffective. Subsequent raises can develop a seepage surface due to a high phreatic surface that can lead to stability problems. The U. S. Bureau of Mines amended contract J0100013 to initiate this study of horizontal drains in tailings embankments. This study developed a technique for determining the length of and spacing between parallel drains through the use of the finite element model UNSAT2. The analysis is based on the combined output of a vertical planar mesh and a horizontal planar mesh. The slot opening in the drain pipe and the length of the perforated section are determined from an analogy to water well design. The pipe diameter and gradient can be determined from Manning's equation. To the authors' knowledge, this is the first attempt at horizontal drain design using a finite element model. Additional research is recommended in this area.

Jan 1, 1982

By Larry Joe Linley

The Department of the Interior, Bureau of Mines is reviewing explosion protection methods for use in gassy coal mines. This performance criteria guideline is an evaluation of three explosion protection methods of machines electrically powered with voltages up to 15 000 volts AC. A sufficient amount of basic research has been accomplished to verify that the explosion-proof and pressurized enclosure methods can provide adequate explosion protection with the present state of the art up to 15 000 volts AC. The routine application of the potted enclosure as a stand alone protection method requires further investigation or development in order to clarify performance criteria and verification-certification requirements. An extensive literature search, a series of high voltage tests, and a design evaluation of the three explosion protection methods performed at White Sands Test Facility indicates that the explosion-proof, pressurized, and potted enclosures can all be used to enclose up to 15 000 volts AC, if the performance criteria and verification-certification requirements recommended in this guideline are implemented.

Jan 1, 1982

By W. C. Joughin

Problems with the stability and performance of rockpasses in deep-level mines are common. This paper presents the results of an investigation into the recorded performance of rockpasses in deep-level gold mines. Records relevant to the geological environment in which the passes are excavated, their excavation details, and their historical performance are not at all well documented on mines. In general, the quality of data available from mines is poor. The investigation showed that very large spans frequently developed in passes during use, and that rock mass quality, the orientation of the pass with respect to the dip of the strata, and the magnitude of the stress acting normal to the axis of the pass were the main factors of influence. From the historical information obtained, the risks of instability in rockpasses are identified.

Jan 1, 2005

By Thiago Pinto Silva

A Usiminas implementou dois ensaios para caracterização de minérios de ferro na sinterização, intitulados assimilação e penetração de fase líquida. O primeiro tem como objetivo avaliar as fases mineralógicas, a formação de poros e a resistência mecânica de partículas nucleantes e aderentes por meio da reação do minério com o calcário. O segundo objetiva medir o comprimento da penetração da fase líquida formada entre a calcioferrita e o minério. No presente trabalho, são descritas as principais características e potencialidades desses novos testes, os quais foram utilizados para a avaliação do comportamento metalúrgico de seis minérios distintos. Os resultados obtidos de assimilação e de penetração da fase líquida foram comparados com as características mineralógicas e químicas dos minérios, sendo observada uma boa correlação entre essas características e os resultados dos novos testes. Verificou-se também que a análise tradicional do minério não é suficiente para estimar seu comportamento metalúrgico na sinterização, o que reforça a importância da utilização dos novos testes implementados. Além disso, permitem avaliar o comportamento dos minérios em altas temperaturas, auxiliando na escolha da carga de minérios mais adequada para a sinterização.

Aug 1, 2018

By B. K. Shibler, W. G. Sandell, G. M. Potter, H. D. Snedden

"INTRODUCTION During the course of the investigation of the occurrence of manganese deposits in the western United States, examining 'engineers of the Bureau of Mines collected samples from seven manganese properties in Grand and beery Counties, Utah. These were supplemented by five samples submitted by property owners. Since all of the ores were too low-grade for use in producing ferromanganese for steel manufacture, some means of beneficiation was required to produce marketable concentrates, and metallurgical studies were made on each of the samples.Most of the ores Investigated are similar in one respect: At least part of the 'manganese oxide areas contains minute inclusions of gangue. This occurrence materially enhances the complexity of the ore, partly by .increasing the complexity of mineral association, but largely through making manganese-quartz liberation more difficult. In such ores, there is a marked tendency for the manganese minerals to be retained as shells or coatings on the surfaces of quartz particles when crushed. Particles of this type represent considerable loss of manganese in tailing, if gravity-concentration methods are employed, or tend to' float, thus carrying an appreciable quantity of gangue into the concentrate, if treated by flotation.Plus 48-percent manganese sinters were made from some of the ores tested, but, in general, intimate association of manganese minerals with silica limited the degree of beneficiation attainable."

Dec 1, 1947

By M. A. Trevits

Mine seals are used in underground coal mines throughout the United States to isolate abandoned mining areas from the active mine workings. The objective of adding inert gas to a sealed mine area is to quickly reduce the oxygen concentration in the sealed area to a level that will not support combustion. In the US, this process is typically conducted from the ground surface and because surface-to-mine access is constrained by so many variables, it is very difficult to provide a source of inert gas to the place where it is needed underground. To alleviate this problem On Site Gas Systems, under a NIOSH contract, built a nitrogen (N2) generation plant that operates in the underground environment. The purpose of this work was to create a reliable in-mine mobile plant that would extract N2 gas from the mine atmosphere and use the gas to create and maintain a safe sealed mine area. The plant is based on a novel design using pressure swing adsorption technology and is sized to fit on a standard shield car or mine dolly for easy transport in and around an underground coal mine. The plant is capable of producing about 900 scf/min of N2 gas at ambient mine conditions. After an exhaustive series of laboratory tests, the plant was field tested at the NIOSH Safety Research Coal Mine (SRCM) where a portion of the mine was sealed and rendered inert. During the test, the movement of the injected gas was monitored at several underground points to observe the progress and extent of the inerting process. This paper describes the plant design and the results of the field test at the SRCM. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of NIOSH.

Jan 1, 2009

By Francisco Morganti

In order to support hot rolling mill managers in improving the utilization of their plants, SMS group offers well defined Performance Modules. These are technologies, components, automation solutions or services, which can be implemented in existing plants to increase competitiveness in categories of efficiency, productivity, quality and process and product control referred to as “Industry 4.0”. Except the Performance Modules dedicated to the last category, targeting overall process controls, Performance Modules are characterized by quantifiable benefits. Performance Modules related to hot rolling mills are e.g. camber free rolling, modular laminar strip cooling system, new edge masking and intelligent components.

Oct 30, 2017

By I. Nimmo

Since the beginning of Aluminum mining and refining the industry has lived with distributed control rooms and suffered from many behavioral problems common with this design. When Human Factor/Ergonomic design is introduced to a Western Australian installation a common centralized control room realized many improvements including economic payback. Communications issues were resolved, better coordination of materials, improved situation awareness during startups, abnormal operations and an opportunity to make improvements during normal operations characterize the changes at the Worsley Refinery. This presentation will review the reasons for the change. Since the beginning of Aluminum mining and refining the industry has lived with distributed control rooms and suffered from many behavioral problems common with this design. When Human Factor/Ergonomic design is introduced to a Western Australian installation a common centralized control room realized many improvements including economic payback. This presentation will review the reasons for the change, what changed and the process of changing the culture from reactive to predictive and what difference that has made.

Jan 1, 2011

By W. M. Dressel

In producing feed for a lead blast furnace, concentrates analyzing 70 to 80 pct Pb are sintered to produce a physically acceptable low-sulfur product which contains only about 50 pct Pb. Mixtures of PbS with varying amounts of SiO2, CaO, Fe 20., and ZnS were heated in an oxidizing atmosphere at 1,000° C; the products were cooled and examined to determine the problems involved in producing sinter with substantially higher lead levels. Microscopic and electron microprobe studies of the above products as well as experimental and commercial sinters indicate that sinters consist essentially of lead silicates, lead-zinc silicate, calcium zinc silicate, and spinel (ferrite). Lead oxide and lead sulfate areas appear to result from insufficient mixing of the materials prior to sintering. The data give an insight into the process and show that sintering results from a complex interaction of all constituents and that sintering is not simply a matter of diluting the mixture to control the oxidation of lead sulfide.

Jan 1, 1975

By Gray Mullins

The construction of drilled shafts as well as other cast in place foundation alternatives relies heavily on good practices from the contractor, engineer, and inspector in order to produce a quality foundation element. As many of the installation methods involve blind concreting processes, it is difficult to be certain of an intact concrete mass of the intended dimensions. A new integrity test has been developed that provides additional insight into the integrity of drilled shaft concrete. By measuring the temperature throughout the shaft via standard access tubes, the measured temperature profile can be compared to the normal signature associated with a shaft of the specified size. This article provides an overview of the new method development, test procedure, analysis, and results.

Jan 1, 2010

By F. Habashi

Asbestos, an extremely useful natural resource, has been studied extensively mineralogically and for industrial application. Its extraction from ores has been greatly improved with respect to safety in the work place. In spite of that, there is a decisive effort in many countries to ban its use on the grounds that it is a toxic substance. This action resulting in drastic decrease in production and the possibility of destroying the industry. The chelation of asbestos with organic dyes seems to be a promising way to abate its toxicity. Dyeing can be done when the fibers are slurred in water at ambient conditions in the same way as textile fibers.

Jan 1, 2009