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By A. Tsekov, Stefan Neufeind, T. Angelov, G. Savov

"A complementary ion exchange/solvent extraction process for the recovery of copper from low-grade ores developed by Iontech Engineering Ltd. is described. It has successfully been implemented on a full-scale plant level at the Buchim Copper Mine in Macedonia, yielding a maximum copper cathode production of 2400 tonnes per year. Technical and economic aspects of three years of operational experience are comprehensively compared with the Asarel Medet copper plant in Bulgaria, which is utilizing conventional solvent extraction in the enrichment/purification step. INTRODUCTION The concentration and separation of copper from primary leachates is one of the key operations in the hydrometallurgical processing of oxide ores (Langner, 2011). Conventionally, this basic operation is conducted by submitting the pregnant leach solution (PLS), with a 1–5 g/L Cu content, from the initial sulfuric acid leach to a solvent-extraction (SX) process in which copper reports to the organic phase (see Figure 1). After phase separation, the metal is stripped from the extractant/diluent mixture employing sulfuric acid to furnish a concentrated metal solution, usually containing 40–50 g Cu/L. The final products of the overall process are copper cathodes, which are obtained from a terminal electrowinning step.Although considered as “technology of choice”, SX to date is still suffering from several drawbacks, such as the risk of poor phase disengagement and the high capital costs of solvent-extraction plants. Especially, the processing of leachates with lower copper tenors (< 1 g/L) is often economically less attractive. As a result, tremendous efforts have been dedicated to the evaluation of alternative technologies to address these challenges."

Jan 1, 2015

By J Deen, P Sterk, W Forsyth

Homestake Mining Company has made a firm commitment to develop a functional and cost effective perimeter blasting program. The goal of the program is to develop smooth, sound walls in all development ends. A good perimeter blasting method will improve safety, reduce waste rock handling, allow easier support installation and reduce scaling time. All the benefits will contribute to an overall reduction in total development costs.

Jan 1, 1997

By Harvey W. Parker

Our industry has developed to the skilled, experienced and productive industry that we now enjoy as a result of the visions of great engineers throughout history, but, in particular for their visions in the last 1 centuries. Unfortunately for our forefathers, the technology lagged so far behind that these exceptional visions could not be realized for decades, sometimes for a century. All that has changed in recent time and many bold and visionary projects can now be constructed and operated because of dramatic advances in technology. Before, say, 1950, tunnel technology developed very slowly. However, technology is now developing at such a fast rate that planners and decision makers are challenged to stay ahead. Moreover, new technology will develop during the lifetime of any project that can dramatically improve under-ground space projects. One of the best examples of this technological advancement is that of closed-face TBMs which now make tunneling feasible in previously impossible ground conditions. Since it usually takes a decade or more to plan, overcome environmental and political issues, construct, and put into service major projects, planners and designers are challenged by the changes in technology that occurs during the long time span of planning and construction. This is particularly true of large infrastructure projects such as transportation, water and wastewater systems and other major underground schemes. Also, since the serviceable life of many of these tunnels is often over one century, planners must consider not only lessons learned from the past but also what new concepts and innovations may develop over an extremely long time. These and other issues create a great challenge to planners and illustrate the great importance of careful but creative vision and flexibility during planning of long-term tunnel and underground space projects.

Jan 1, 2008

By W. G. Pariseau

Introduction Caverns of 50 m in linear dimension at depths below 2300 m with a life of more than 25 years are proposed for the next generation of water-filled neutrino detectors. Little precedent exists for excavations in such an extreme environment, although some guidance is available from mining experience at great depths, for example, in South Africa, in Canada and at the former Homestake Mine in the U.S.A. Unlike mining for ore, there are choices available in the construction of such caverns that may mean the difference between success and failure. These choices should be informed by rock engineering principles. Recently proposed guidelines for orientation of brick-shaped caverns where the long dimension is a small multiple of the short dimension indicate that the most favorable orientation is with the long and short dimensions parallel to major and minor preexcavation principal stresses (Pariseau, 2005). Numerical analyses at reduced strength indicate some yielding at cavern walls should be expected but that an equilibrium state is quite possible and is aided by arching the back into a spherical dome when the cavern is an empty cylinder (Tesarik and others, 2002). The same indications of stability occur with brick-shaped caverns. However, the most dangerous situation occurs during the excavation sequence to final cavern dimensions. There are any number of excavation sequences that lead to the same final cavern shape, so there is an opportunity to partially optimize the sequence with construction guidelines that minimize peak stress concentrations during construction. This contribution discusses three practical excavation sequences that lead to the same brick-shaped cavern in the strong, massive Yates formation at the Homestake Mine where considerable rock mechanics data has accumulated through the years(e.g., Pariseau, 1985, Pariseau and others, 1995) and where actual mining on the 8000 Level indicates a strong possibility of successful investment in the next generation of large, deep neutrino detectors. The main results are: (1) a favorable brick-shape is one with dimensions in the same proportion as the preexcavation principal stresses (compressionpositive), and (2) favorable orientation of the most extreme but temporary shape of excavation is also best for the construction sequence. Analysis results from a mix of Homestake Mine data and possible excavation geometry illustrate the advantages of these guidelines.

Jan 1, 2006

By Peter Moser, G. Reihholf

Holcim, one of the world's leading suppliers of cement, aggregates and concrete, has set up a few years ago a working group “Quarry” in order to optimize the performance of its central European quarry operations in terms of work safety, environmental standards and economic performance. One of the activities of this working group "Quarry" addresses the subject of blast fragmentation in the quarries. A benchmark study of the blast work in all quarries has shown substantial differences for the various operations in terms of drill& blast costs. Especially big differences were found with respect to the drilling patterns as a function of the borehole diameters and with respect to the utilization of the borehole volume for charging the explosives.

Jan 1, 2006

By W. R. Byrnes

This project was initiated on October 1, 1980 and will be completed on December 31, 1983. The project was Initially approved and funded by the Office of Surface Mining and subsequently was moved to the jurisdiction of the Bureau of Mines. It was administered through the Indiana Mining and Mineral Resources Research Institute. The research was done to assess reforestation success and ultimate productivity for areas reclaimed under the Surface Mining Control and Reclamation Act of 1977 (P.L. 95-87). The Permanent Regulatory Program for implementation of P.L. 95-87 Includes provisions for revegetation that require seeding of ground cover plants to control erosion until permanent vegetation such as tree species Is established, and restoration of mined land to its original or better productivity. Much of the land to be surface-mined presently supports forest cover and it is anticipated that reconstructed minesoils will exhibit high productive potential for hardwood tree species. Hence, information was needed on compatibility of ground cover and tree seedlings when established concurrently as well as on revegetation success under postmining versus premining conditions.

Jan 1, 1983

By P. B. Grote

The report is concerned with the issue of the possible transfer of U.S. and other developed country deep ocean mining (DOM) technologies to developing countries. This subject is one of several major issues in current UN Law of the Seas negotiations. As background to the subject, the report provides a detailed critique of the various terms and conditions pertaining to technology transfer in recent negotiating texts. It also provides a description of the relevant DOM technology, sources of innovation, and methods of proprietary protection. Functional requirements for viable technology transfer are developed and used as a basis for the definition of alternative levels of programs and implementation approaches, including required changes in the negotiating text. The consequences of these technology transfer options on the various parties are investigated.

Jan 1, 1978

By Tyler Blake

This report describes a study designed to evaluate a pro-posed modification in the cap lamp battery cord intented to reduce the incidence of snagging and catching of the cord. A three phase evaluation was performed comparing a prototype with the standard, currently available cord. First, a ?pull test? equipment was run. The second evaluation was a body conformity study. The third evaluation involved subjects performing common tasks in a low seam coal mine simulator. The results of these evaluations clearly demonstrated significant safety advantages of incorporating coiled cord into the design of the cap cord. The coil cord presented less of a snagging hazard, allowed the wearer more time to respond to a snag, and transmitted lower levels of force to the helmet when snagged. The research team recommended that cap lamp cords be commercially developed which incorporate coiled cord at the battery and helmet.

Jan 1, 1980

By L. W. Higley

Electrowinning metals from solutions leached from low-grade ores is becoming an increasingly important extraction method as the metal industry turns to pollution-free recovery processes. Lead-alloy anodes are used industrially in the electrolytic recovery of zinc and copper. However, associated with the use of these anodes are the inherent problems of stability and lead contamination of the cathode. In an effort to eliminate these problems, the Bureau of Mines has developed a relatively inexpensive lead dioxide anode for electrowinning metals from strong acid solutions. The anode was prepared by depositing Pb02 directly on a titanium blank in a strong HN03-Pb(N03)2 solution at 2.15 to 6.45 A/dm2 and 60° C. This anode was tested in zinc and copper electrowinning cells containing 200 gpl H2S04 and 35 to 100 gpl metal ions at the current density of 3.23 to 6.45 A/dm2. Contamination of the cathode by lead was =0.005 pet. A 30-day test at 6.45 to 12.90 A/dm2 in an electrolyte containing 200 gpl H2S04 and no metal ions resulted in a slight change in surface morphology of the Pb02 anode but no measurable change in anode weight or dimensions.

Jan 1, 1976

By Paul Kunze

We have been told many times by legal folks and insurance types about the importance of producing accurate blast reports should you ever get dragged into court. In that venue the investigators will look at the information regarding product type and quantity, it’s distribution among the holes, and delay information in order to arrive at some judgement regarding vibrations or other blast induced phenomena

Jan 1, 2003

By W. P. Yant

A previous report of the Bureau of Mines dealt with the toxicity of dichlorodifluoromethane5, a new refrigerant that has a remarkably low toxicity. Continued research by the Prigidaire Corporation6 and toxicological experiments performed in the Laboratory of Applied Physiology of the University of Cincinnati7 revealed another organic fluoride, dichlorotetrafluoroethane, whose toxicity also appeared to be of a very low order and whose physical-and chemical properties make it suitable for refrigeration purposes. In addition to low toxicity, safety in its use is further enhanced by its physical properties, which permit the design of equipment that operates at comparatively low pressures and hence mitigates the dangers and problems of leakage. The investigation described in this report was performed by the Bureau of Mines at the request and with the cooperation of the Frigidaire Corporation.

Jan 1, 1932

This report describes the work performed by Mine Research Company in developing a prototype mobile roof shield during 1971-1972 for the U. S. Bureau of Mines, along with background information leading to the design decisions adopted for the project. In addition, the report evaluates the choice of design and analysis and the results of the project in terms of future possibilities of mobile roof support systems. The report begins with the discussion of the problems of designing, building, and using mechanical and hydraulic roof support in coal mines. It then gives a historical summary of past work with discussions of the design choices made for previous roof support systems.

Jan 1, 1973

By Arnold Hammons

Automated temporary roof support (ATRS) systems have been incorporated into roof bolters since the 1970?s. During roof bolting, many injuries have occurred from large pieces of draw rock falling inby the ATRS beam and tipping back into the operator?s area. Other injuries have occurred due to smaller, sharp rocks falling onto the operator?s hand and arm during initiation of roof bolt drilling. These injuries are attributed to weak immediate roof, sometimes called roof skin failure. Even though ATRS systems support the roof and provide a measure of protection against roof skin failure, additional hazards sometimes do exist immediately inby and outby the supported roof. Design innovations such as the ATRS mounted rocker pad deflector systems have been designed to improve the roof bolter operator safety. This paper will inform the reader of the hazards, machine evolution through different design solutions, and the current state of the art in preventing roof skin failure injuries when roof bolting.

Jan 1, 2009

By R. W. Charles

The Los Alamos National Laboratory, under the sponsorship of the U.S. Department of Energy; is involved with laboratory and field experiments to assist in development of the Hot Dry Rock concept of geothermal energy. The field program consists of experiments in which hot rock of low permeability is hydraulically fractured between two wellbores. Water is circulated from one well to the other through the fractured hot rock. Our field experiments are designed to test reservoir engineering parameters such as heat-extraction rates, water-loss rates, flow characteristics including impedance and buoyancy, seismic activity, and fluid chemistry. Laboratory experiments were designed to provide information on the mineral-water reactivity encountered during the field program. Two experimental circulation systems tested the rates of dissolution and alteration during dynamic flow. SOlubil ity of rock in agitated systems was studied. Moreover, pure minerals, samples of the granodiorite from the actual reservoir, and Tijeras Canyon granite have been reacted with distilled water and various solutions of NaCl, NaOH, and Na.CO.. The results of these experimental systems are compared to the observations made in field experiments done within the hot dry rock reservoir at a depth of approxi-mately 3 km where the initial rock temperature was 150 to 200°C.

Jan 1, 1981

By Huleatt M, Perkin D, McLeod I, Mock C, Pratt R, Gourlay A, Timoney E, Knight N, Ward J

Generally speaking, Australia&apos;s reserves of its more important minerals (in terms of export earnings) are adequate to sustain forecast rates of production to the year 2000. The rate of forecast production increases of these commodities (aluminium - whether as bauxite, alumina or metal, black coal, iron ore and ferro-alloy minerals, base metals, tin, uranium, and mineral sands) reflects a well- ordered and sustained growth phase of Australia&apos;s mineral industry.

Jan 1, 1981

By Tarrant Elkington

Underground mine planning practices are typically manual and time consuming and will often produce sub-optimal solutions due to the application of generic rule-of-thumb assumptions or ?tried and tested? choices. The development of computer-automated tools for underground mine planning enable a wide range of scenarios to be considered rapidly in arriving at an optimised solution, subject to input assumptions. We have applied these tools to demonstrate ?optimised? solutions that challenge industry standard practices. Further, we have incorporated grade and price/cost uncertainty into these tools to gain an understanding on how the consideration of uncertainty may further alter strategy selection. Finally, we enable the tools to dynamically adjust cut-off grades in conjunction with the evolution of prices/cost.

May 1, 2010

This work presents: 1.) the results obtained from measurements of temperature profiles in pillars and at working faces of three coal mines located in Colorado and New Mexico, 2) a comparison of the experimental results with theoretical predictors based on linear heat flow models, and 3) temperature profile predictions based on a two dimensional coal mine model with an inclined crack located in the roof or wall of the opening. The thermal properties of the coal and shale samples taken from the mines were used as input data for the computer model. Good agreement was found between the measured profiles and the theoretical values obtained with the one dimensional model. The two dimensional model results show that a visible crack (0.01-0.07-ft thick) in a coal roof causes a surface temperature difference from 0.2 to 1°F at the edge of the crack for rock exposed to air from 1 hr to 288 hrs and with the air to rock temperature differences from 2°-6°F. A temperature difference of 0.3 °F was found between solid and broken rock in a shale roof with a 0.03-ft thick crack inclined 45° to the horizontal after a ventilating time of 48 hrs and the air to rock temperature difference of 2.1°F.

Jan 1, 1972

By E. Martinez

The effect of ultrasonic energy transmitted through a liquid on chrysotile asbestos was investigated. Ultrasonic energy was effective in fiberization of chrysotile crudes as well as standard grades of milled asbestos fibers. Treated samples of several grades of milled fibers had increased wet bulk volumes and decreased settling and filtration rates compared to untreated fibers. Ultrasonics may be a method for fiberization of chrysotile without decreasing length or use of chemical additives that alter surface properties. Cavitation of the liquid on the surface of fiber bundles is believed to be the cause of the fiberization. It was found that ultrasonic energy greatly increased the rate of precipitation of latex on asbestos. When chrysotile asbestos fibers require additional opening or fiberization, the usual method employed is some type of high speed impact or grinding to open the fibers and produce a larger surface area. These methods always cause some degradation in length due to breaking of fibers. In addition, the efficiency of mechanical methods decreases as the diameter of fiber bundles decreases. Chemical methods have been proposed and it is claimed that fiberization down to individual fibers of 200-300 A diam is possible with some wetting agents. However, large amounts of reagent are required, approximately EDWARD MARTINEZ is with Central Research Laboratories, American Smelting and Refining Co., South Plain-field, N.J. TP 63H226. Manuscript, Aug. 12, 1963. Discussion of this paper, submitted in duplicate prior to Mar. 15, 1964, will appear in SME Transactions, September 1964, and AIME Transactions, 1964, vol. 229. 50 pct of the weight of fiber treated, and some of the wetting agent remains on the surface of the chrysotile and cannot be removed by any solvent which does not destroy the asbestos.&apos; This investigation was directed at determining whether ultrasonic energy transmitted through a liquid would be effective in fiberizing chrysotile asbestos. Samples of asbestos crudes and commercially milled fibers were treated; settling and filtration rates of treated and untreated milled fibers were obtained. EQUIPMENT A Westinghouse Corp. ultrasonic cleaning system WEHH was used in this investigation. See Table I for a breakdown of this ultrasonic unit. RESULTS AND DISCUSSION Fiberization of Chrysotile Crudes: Samples of chrysotile crudes were pulled apart with tweezers so that coarse bundles of fiber approximately 1/16 in. in diam were obtained. The bundles were put into a bottle with 200 ml of methanol and the mixture placed into the ultrasonic tank for 30 min at a power output of 1200 w. The test was repeated using water instead of methanol. During the irradiation it was noted that the surfaces of the bundles were being fiberized. The liquid eventually became cloudy with dispersed solids. Fig. 1 is an electron micrograph of the fibers, some reduced to unit dimensions, and a fine material released by the ultrasonic energy. The platy particles in Fig. 1 were identified by electron diffraction and differential thermal analysis as brucite, Mg(OH)2, which must have been intergrown in the chrysotile crudes. Electron micrographs of bulk specimens of chrysotile have shown a fine material filling the interstices between tubular fibers.2,3 Electron diffraction patterns of the fine material collected after ultrasonic treatment indicate that it is amorphous. After decanting the solution, bundles of chrysotile remained somewhat decreased in diameter. Continuing the ultrasonic irradiation of the remaining material resulted in additional fiberization. The opening of the fibers occurred in both methanol and water. Cavitation of the liquid by the ultrasonic energy is undoubtedly responsible for the fiberization. When sound waves are transmitted through a liquid at a

Jan 1, 1963

By Anna Carolina Cerqueira Neves

Muito se tem estudado sobre materiais alternativos, como os compósitos de matriz polimérica reforçados por fibras lignocelulósicas. Isso se justifica pelo fato das fibras naturais terem vantagens no que tange ao meio ambiente, bem como relativo baixo custo. Além disso, a fibra natural apresenta características de interface com a matriz polimérica que favorecem as propriedades mecânicas pela estrutura do compósito. Esse presente trabalho objetiva analisar as propriedades de tração de compósitos de matriz de poliéster reforçados com 10,20 e 30% em fração volumétrica de fibras de cânhamo, que foram preparados alinhando as fibras em moldes e deixando-os curar por 24 horas em temperatura ambiente. Os corpos de prova foram testados numa máquina de ensaios Instron e os resultados mostraram um aumento na tensão máxima de ruptura com o aumento da porcentagem de fibra incorporada.

Aug 17, 2017

By X. Pan

Slag-metal equilibrium experiments were conducted at 1500ºC and 1580ºC under 0.03 atm, 0.05atm and 0.83 atm CO partial pressures using silica and Cr-oxide crucibles. The complex slags belonged to SiO2-CaO-Al2O3-MgO-FeOx-CrOxand the metal phase to the Cr-Fe-C-Si-(S)systems. The carbon saturation of the metal phase was avoided using oxide crucibles and thus the results are pertinent to ferrochromium refining slags and processes. From equilibrium data and thermodynamic calculations the CrO /(CrO+Cr2O3) ratio in the slag was determined as 0.75, 0.80and 0.86 under 0.83 atm and 0.05 atm of CO pressure at 1500ºC and 0.03 atm and CO pressure at1580ºC respectively. The results clearly demonstrated that a higher chromium content of the metal results in higher Cr in the slag, and chromium in slag decreases with increasing SiO2. The results were also sensitive to the crucibles used as these oxide crucibles saturated the slag either with respect to SiO2or Cr-oxides. It was also demonstrated that the relative amount of CrO in the slag was higher when SiO2crucibles were used in accord with thermodynamic calculations. Iso-concentration curves for carbon and chromium of the metal phase in equilibrium with the slag were drawn on pseudo ternary SiO2–(AI2O3+CaO+MgO)–(Cr2O3+Fe2O3) diagram. The activity coefficients and activities of carbon and chromium of the metal phase were also calculated from the experimental data and available thermodynamics information and were plotted as iso-activity curves in the same pseudo ternary diagram. Keywords: Chromium, slag, equilibrium

Jan 1, 2004