Search Documents

By Robert M. Doerr

The research objective was to determine the effect of vanadium alloy additions on the oxidation behavior of cobalt-nickel Alloys. Eighteen alloys were reacted with 0 2 at 0.5 arm and 1,351°, 1,389°, and 1,429° K. The alloy compositions consisted of Co-Ni master alloys (0, 22, 50, 70, 91, and 100 wt pct Ni) with V additions of 0, 0.9, and 2.7 wt pct. Large early deviations from, or changes in, the parabolic rate constant were encountered, but the reaction rate in most cases declined approximately in accordance with the parabolic rate law. Relatively, the vanadium degraded the oxidation resistance most at the highest nickel contents. In some cases, melting of the oxide was inferred from microscopic evidence and X-ray diffraction measurements disclosed the presence of low-melting vanadates.

Jan 1, 1970

By David Rahal, Des Erasmus, Ken Major

"Over the past twenty years there has been an increased emphasis on fine grinding in the minerals industry. This spurred the development of a range of new fine grinding equipment in the 1990s. At that time, the Knelson-Deswik mill was developed in South Africa for the pigments industry.Knelson Milling Solutions currently offers a wide range of laboratory, pilot and production scale mills. These mills bridge the gap between traditional low speed vertical mills and the high speed horizontal mills (tip speed < 3 and > 15 m/s respectively). They are designed to run at tip speeds between 10 and 12 m/s and are capable of operating with very dense grinding media. The result is a power intensity that is higher than the low speed mills and overlaps that of the high speed mills. This allows the mill to be customized for a wide range of grinding applications.A case study at Aquarius Platinum’s Kroondal Mine shows that the Knelson-Deswik technology can produce a consistent product size despite feed variations. It also shows that the throughput was proportional to the slurry density at Kroondal. The case study identified increasing the slurry density as a process change that can increase throughput and reduce the specific energy consumption.INTRODUCTIONThe increasing complexity and finer grain sizes of modern ore bodies have increased the importance of effective mineral liberation in obtaining acceptable grades and recoveries (Jankovic, Valery and La Rosa, 2003; Lichter and Davey, 2006; Napier-Munn, Morell, Morrison and Kojovic, 1996). This trend has increased the significance of fine grinding technology because the input energy increases exponentially as the required product size decreases from 100 to 10 microns (Gao and Weller, 1993a).The US Department of Energy recently provided the context for the potential energy savings in the US Mining Industry (BCS, 2007). They reported that grinding consumes approximately 494 TBtu/year. This was over double the consumption of the second highest equipment category, diesel materials handling systems (211 TBtu/yr). The proportion of grinding energy allocated to fine grinding can only be expected to increase as finer ore deposits are mined. It is therefore critical that fine grinding efficiency continue to improve through the selection of appropriate equipment and the development of best practices for existing applications."

Jan 1, 2011

By Carl Johnson, D. R. Todd

The Blue Ridge Low Level Outlet (LLO) was a design/build contract to provide a secondary means of discharging water from the Blue Ridge Reservoir. The project involved driving a 3.25 m (11 ft) modified horseshoe tunnel by 293.5 m (963 ft) long utilizing conventional drill and blast methodology. The intake shaft and structure were constructed inside of a sheet pile cofferdam surrounded by a maximum of 20.1 m (66 ft) of water. The shaft was excavated 4.87 m(16 ft) diameter to a depth of 12.8 m (42 ft) below the tremie slab elevation. Steel lining, including a transition from 3.66 m to 2.74 m (12 to 9 ft) diameter and a90 degree elbow were installed in the inlet shaft and then backfilled with concrete. This paper will describe the RFP phase, the design phase, challenges of the underground construction and contractual challenges.

Jan 1, 2005

This paper describes the new legislative regime that will apply to the regulation of the minerals industry in New Zealand. The reform of New ZealandÆs minerals legislation was initiated in January 1988 when the Minister for the Environment, Rt Hon Geoffrey Palmer, announced the Governments intention to review all the major laws governing New ZealandÆs resources. The Resource Management Bill is scheduled for introduction to the House in December 1989 and its date of enactment is scheduled for June 1990. With some matters still to be determined (at the time of writing), this paper cannot be a definitive review and description of the new legislation, it is instead an attempt to outline the major features of the Bill, to date, that are seen as important to the mining industry.

Jan 1, 1990

By Matthew N. Plis

This U.S. Bureau of Mines report presents the documentation for COALVAL, a coal property evaluation software package developed on Lotus 1-2-3,4 version 2.2, spreadsheets. The software is compatible with version 3.1 as well, and may provisionally be run on the earlier 2.01 version. COALVAL is a menu-driven program that produces a prefeasibility-level cost analysis of mine-planned coal resources. The package contains cost models for each of five coal mining methods commonly employed in Appalachia: auger, contour strip, mountain top removal, continuous miner, and longwall. Other models, such as a dragline cost model, will be incorporated as the Bureau&apos;s Coal Recoverability Program matures. COALVAL allows mine operators, evaluators, consultants, and Government entities to input resource data and the various production, operating, and cost variables that pertain to their property. The program can evaluate up to 25 seams, each to be mined with up to five different mining methods, within a given area. Summary spreadsheets listing the cost per clean ton to mine the resources, f.o.b. the tipple, are produced for each property, seam, and mining method/seam combination.

Jan 1, 1993

By Herry Poernomo, Agus Prasetya, Iga Trisnawati, Himawan Tri Bayu Murti Petrus, Gyan Prameswara, Panut Mulyono

We studied yttrium extraction from untreated zircon sand processing waste tailings. Xenotime mineral as the rare earth element source with an abundance of yttrium (REY) was detected in sufficient grade for extraction. As much as 9.03% yttrium exists in zircon tailings (analysed by X-ray fluorescence spectrometry). The presence of yttrium was confirmed by X-ray diffractometry in xenotime minerals, which are yttrium carriers (Y-PO4). The purpose of this research was to determine the effect of leaching conditions on yttrium recovery from zircon sand after alkaline fusion treatment. Alkaline fusion was chosen to decompose phosphate into hydroxide in the xenotimemineral,which will reduce further required hydrometallurgical processing.Alkaline fusionwas carried out for 3 h at 450 °C, with a ratio of sodium hydroxide to zircon tailings sand of ~ 1:1. The alkaline fusion product was leached with water, followed by hydrochloric acid treatment to leach the yttrium. Yttrium recovery reached 87% under optimum conditions (60 °C, 1MHCl, and solid-to-liquid ratio = 1/10 for 7.5 min). A suitable model for yttrium dissolution with hydrochloric acid was diffusion through a solid particle ash layer. The calculated activation energy (EA) for this model was 20.21 kJ/mol.

May 26, 2020

By A. E. Lewis

The emphasis of this paper is on the characterization and testing of the slag produced by a secondary lead refinery. This work forms part of a broader investigation aimed at reducing loss of valuable product from the process as well as minimizing the environmental impact of the process wastes. It was this work that led to a critical examination of the standard waste classification tests. Characterization of the slag was carried out using a number of complementary techniques. In the broader context, the slag characterization aided in identifying process deficiencies and thus was a critical tool in suggesting potential for process optimization. For this study, the slag characterization provided a relatively comprehensive picture of the composition and properties of the slag, which facilitated understanding the behaviour of the slag under batch test conditions. On the basis of quantity of hazardous components alone, the slag is hazardous according to South African Acceptable Risk Limits (ARL). However, when both the quantity and the leach potential of the hazardous components is taken into account, standard waste tests carried out by three independent agencies indicate that the slag should not be classified as hazardous according to local regulations. Also, according to United States Environmental Protection Agency (US EPA) limits, which are independent of the quantity of the waste, the slag would not be classified as hazardous. The standard waste tests used by the independent agencies was the Toxicity Characteristic Leach Procedure (TCLP), a test which was developed by the US EPA to classify hazardous wastes. One of the requirements of this batch test is that it should be quick, simple to carry out and that the results should be reproducible. Previously, the applicability of the TCLP test to mineral processing and metallurgical wastes has been challenged on a number of points. Additional testing of the slag was carried out using both the TCLP and the Synthetic Precipitation Leach Procedure (SPLP) recommended by the American National Mining Association as being more appropriate for mineral processing wastes. The particular physical and chemical characteristics of the secondary lead slag highlighted additional limitations of both the TCLP and SPLP tests as standard laboratory batch procedures. Keywords: environmental protection, secondary lead processing, slag, leach testing, TCLP, SPLP, ARL, hazardous waste, batch tests

Jan 1, 2000

By Allan H. Caverson

Over the past nine years a means for measuring the distance between the mine roof and floor has been developed at the White Pine Mine which yields relevant information utilized in the mining operation. The technique known as "convergence!&apos; is an efficient, low cost way for obtaining large quantities of data for predicting roof falls, caving activity, and overall mine stability. From a limited introduction in 1964 related to monitoring an experimental longwall project, the activity of convergence measurements has been expanded to become a production tool now found in all sections of the mine. Presently, the program involves four main types of activity: 1. Monthly measurements in areas known to be active, and in sample blocks scattered throughout the mine for a long-term stability study. 2. Semi-monthly measurements along vital travel roads, belt drifts and compressor sites. 3. Weekly measurements in areas where men are working. 4. Daily measurements in pillar-recovery and caving operations. Today, one field engineer and six technicians are involved full time in convergence work. Rock Mechanics technicians have installed approximately five thousand stations since the start of the program and of this number, over twenty-five hundred active stations still comprise the mine-wide network spread over the more than five square mile extent of the White Pine Mine workings.

Jan 1, 1973

By J. Dong

"Xanthate is a sulfide collector that has been widely used in flotation for almost a century. It is inexpensive, easy to synthesize and apply, and produces good metallurgy in the right applications. However, a major drawback of xanthate is that it decomposes easily and generates CS2 gas in transportation, storage and operation, which can be harmful to human health. Also, excessive xanthate in tailings pond leads to toxicity of the process water and potential damages to aqua-life systems. New regulations in Ontario require that the TWA (time-weighted-average) value of CS2 in the work place is below 1 ppm, which is 1/10 of the previous limit. The stringent regulation may eventually sweep other regions of Canada with the increased awareness of healthy working conditions and environment protection. Therefore, it becomes very important to find xanthate replacements which will be “green”, i.e., environmentally friendly.In this research work, a systematic procedure is used for collector evaluation using the Sudbury nickel sulfide ores from Vale’s Ontario operations, starting with the collector properties (MSDS) evaluation, followed by batch flotation tests, miniplant tests, plant trials and economic evaluation. It is found that the most promising xanthate replacement is dithiocarbamate.INTRODUCTIONSulfide mineral flotation has been practiced since the early 20th century. Its industrial importance is well recognized as mineral concentrates from flotation can be economically smelted and refined to provide primary metals. Collectors play a vital role in froth flotation. There are reagents possessing both a polar group that binds them to the mineral surface and a nonpolar group that is oriented away from the surface to attach air bubbles. The introduction of xanthate as a sulfide collector in 1925 was a remarkable development in froth flotation (Keller, 1925). It is low cost, easy to synthesize, water soluble, simple to control in application. Most importantly, it has strong capability and usually good selectivity for sulfide mineral flotation, which have been keeping its application prominent for almost a century."

Jan 1, 2011

By Peter Middendorp

Pile foundations are widely applied in the Netherlands because of the soft soil conditions. One of the popular pile types are cast-in-situ piles, which have to be integrity tested to get accepted. Integrity testing has been applied for more than 30 years, with the number of integrity test performed nowadays exceeding 400,000 per year and subsequently there is a substantial amount of practical experience with this testing method. This paper will deal with some basics of integrity testing and describe some of the techniques that have been adopted in the Dutch pile testing practice, like detection of pile head defects with a spike type hammer pulse, and the site average or pile group average for the qualitative interpretation of measured signals.

Jan 1, 2006

By O. C. Blade

The use of Diesel fuel continues to increase. In the United States during 1951 over 120,000,000 barrels of Diesel fuel oil were sold. The railroads used approximately 43.5 percent of this volume; industries such as smelters, mines, and manufacturing plants used about 12 percent; trucks, busses, tractors and bulldozers 20 percent; water craft 14.5 percent; and the remaining 10 percent was consumed by gas and electric utilities, the military forces, and oil companies. These figures were calculated from data issued by the Bureau of Mines. 2/ Complete data for 1952 are not yet available, but it is known that by December 1952 over 13 3/4 million barrels of Diesel fuel per month were produced by the country&apos;s refineries and by April 1953 the monthly production had increased to 1 4,333,000 barrels.3/ Information on the properties of this type of engine fuel is very important to the petroleum industry, engine manufacturers, and consumers. To supply this information the American Petroleum Institute and the Bureau of Mines, United States Department of the Interior, under cooperative agreement, are conducting annual surveys of Diesel fuel oil produced in refineries in this country.

Jan 1, 1953

By S. L. Gerhard

In the United States the performance characteristics of permissible explosives are controlled by routine tests, which include firing the explosive into a gallery filled with a methane-air mixture. These tests are made by the staff of the Explosives Division of the Bureau of Mines and, are similar, in general, to those employed in other countries. This control has helped to reduce the frequency of accidents involving the ignition of firedamp by explosives but has not clarified the basic causes, of the ignition. To advance this control and to minimize potential hazards further, this fundamental knowledge is needed. Some of the results of recent research on the causes of the ignition are described herein. NATURE OF THE PROBLEM When an explosive ignites firedamp in the gallery tests, the source of the ignition must be one or more of the emissions from the steel borehole. It has been accepted generally that these emissions are (1) particles, (2) the shock wave, and (3) hot gases and flames. Photographs show that the shock wave emerges from the borehole first, followed closely by hot gases. At first the velocities of these are high and approximately equal, but the velocity of the gases decreases more&apos; rapidly than that of the shock wave, and by the time the reactions causing the flame are complete the shock wave travels in an otherwise undisturbed medium. The particles are originally enveloped in the hot gases but some soon begin to break through and eventually out-distance the shock wave. The approximate geometry of these emissions about I millisecond after the shpt is fired is illustrated in figure

Jan 1, 1939

By Adriano Corrêa Batista, Bernardo Antônio Perez da Gama, Camila Freitas de Araújo, Paulo Santos Assis

O mexilhão dourado Limnoperna fortunei é uma espécie invasora que tem causado diversos problemas no ambiente aquático em razão da sua habilidade de formar colônias em estruturas. A espécie adere nas superfícies por filamentos proteicos, causando sérios danos ambientais, sociais e econômicos.O combate à incrustação biológica através do tratamento de superfícies submersas em ambientes de água doce com produtos naturais, em especial os oriundos de algas vermelhas, é o desafio apresentado.Com o banimento, em dimensão mundial, de insumos à base de tributilestanho - TBT na composição de tintas, desde 2008, tratamentos alternativos e ambientalmente adequados ganham maior apelo, considerando os riscos dos produtos alternativos atualmente aplicados. É descrito um conjunto de condições para espécies produtoras de metabólitos secundários com atividade anti-incrustante importante. Portanto, o trabalho tem como objetivo reforçar uma linha de pesquisa ampla dedicada a consolidar informações sobre o potencial de organismos marinhos como produtores de metabólitos secundários (produtos naturais) com atividade anti-incrustante, à luz da produção científica a ser analisada no espaço destinado à apresentação de resultados.

Nov 6, 2019

By Thomas J. Wright

The evaluation and development of the Eastern North Carolina phosphate deposit resulted in one of the world&apos;s largest and most modern phosphate mines and fertilizer complexes at an investment in excess of $90,000,000. The resulting ore beneficiation process showed excellent correlation with pilot plant data. A number of variations from current industrial practices were introduced and projected from bench scale tests through pilot plant to production. Principal among these variations were the following: 1) removal of magnesium by classification, 2) simultaneous flotation of coarse and fine phosphate, 3) the use of saponified fatty acid, 4) utilization of filter wash water for deoiling, 5) utilization of a rougher concentrate for acidulation, 6) calcination of flotation concentrates, and 7) elimination of grinding prior to the manufacture of phosphoric acid.

Jan 1, 1971

This report presents the results of studies of Kennecott Copper Corporation&apos;s tailings embankment at Magna, Utah. The stability studies described were performed on only one cross section of the embankment, utilizing; data obtained from drilling, sampling, and testing, which was limited in nature. The main objective of the data collection was to provide background information to support the overall research effort. Because of this limited scope, it is not possible to evaluate the degree of safety or adequacy of the embankment or disposal system, and the information and data contained in the body of this report must be judged in that light. The first part of this report contains discussion of site geology and seismicity, pertinent information on the refuge disposal system, a discussion of the tailings materials characteristics, a summary of the engineering analyses, and A bibliography. The second tart (appendices) contains basic geologic and engineering data supporting the discussions in the first part of the report.

Jan 1, 1974

By H. G. Oltmann

The equilibrium nitrogen solubility in the CaO-SiO2system was studied by a slag-gas equilibration technique, in graphite crucibles at 1823K under a CO-N2 atmosphere. The nitrogen content of the slags was determined by the Kjeldahl method. A reliable technique was used to obtain an initial nitrogen content in the master slags, from the addition and pre-melting of silicon nitride. Reduction of silica by graphite was found to occur during the equilibration experiments, resulting in compositional changes of the slags. The results were extrapolated to equilibrium by kinetic evaluation of the data. The nitrogen solubility showed good agreement with the result of Suito and Sano, while Fruehan?s results were lower. However, the results of the present study do not support the maximum nitrogen solubility values found by Sano.

Jan 1, 1999

By D. Komljenovic, V. Kecojevic

Selection of the best possible truck type (model) is of crucial importance for the mine decision-makers. In this paper, authors contribute to the body of knowledge by developing a novel methodology for the selection of mining truck. Both the Coefficient of Technical Level (CTL) and Analytic Hierarchy Process (AHP) methods were used in this study. The CTL represents a mathematical function which takes into consideration the interrelations among the main technical parameters of mining trucks. The authors developed a hierarchical structure where both attribute categories and their importance, i.e. priority or weight in the selection process were determined. For each category, a number of sub-attributes and their priorities were assigned, and a pairwise comparison among them was performed using the AHP method. In the final part of the study, the CTL was integrated into the AHP and represents a holistic approach in the selection of mining trucks. A case study on 180 tonnes truck category offered by five manufacturers was carried out. A sensitivity study of obtained results was also performed indicating a very stable solution. The methodology presented in this paper may be used by mining operators to help in the selection of a specific type when acquiring a new truck. It may also be used by equipment manufacturers to help in analysis of potential benefits of envisaged modifications concerning an existing truck type and/or development of a new type.

Jan 1, 2007

By E. T. C. Spooner, Ioannou S. E.

"Abstract- The Dixie Zone Au-Ag deposit is a low sulfidation (adularia-sericite) epithermal system located 1.4 km from the producing Ken Snyder mine (7.0 M oz Au equivalent reserve/resource), Midas Mining District, north-central Nevada. This WNW striking, steep south dipping, fault system is hosted by mid-Miocene (17 Ma to 14 Ma) felsic volcanic rocks that were erupted from a vent(s) to the northeast. The system was mineralized by approximately 250 ± 20°C (n = 86), near-neutral pH, ascending fluids of predominantly meteoric origin [volatile corrected salinity = 0.52 ± 0.35 eq.wt% NaCl (n = 86)]. Bulk analytical fluid inclusion gas chromatography identified a mineralizing fluid volatile composition of 99.68 ± 0.18 mole % H2O, 0.16 ± 0.09 mole % CO2, 0.11 ± 0.05 mole percent N2, 0.05 ± 0.04 mole % CH4, and 0.01 ± 0.01 mole % CnHn+i (n = 7). Sulfur species were not analyzed due to absorption within the chromatography system; however, a H2S concentration of 16 ppm to 160 ppm molar is estimated. The volatile content contributes approximately 50% of the microthermometrically measured freezing point depression. Cl- concentrations up to approximately 9000 ppm suggest an additional, probably magmatic, fluid component.Ascending fluids were channelled along approximately NW striking faults related to the same primary extension (17 Ma to 14 Ma) responsible for Nevada basin and range physiography. Boiling induced by CO2 effervescence led to precipitation of Au and Ag over a 150 m vertical interval. At the time, this interval was about 460 m below the water table (approximately 38 bars), but because of erosion, it is now within 90 m of the surface. A Ag:Au ratio of 25:1 has been calculated for the Dixie Zone."

Jan 1, 2000

By Roney Eduardo Lino, Loyslene Rabelo Fernandes, Gustavo Henrique Sousa, Athos Fernandes Araujo, Wallace Crisólogo Souza Gonçalves

Nos processos de refino dos aços, as ferroligas exercem um papel muito importante. E deve-se conhecer o comportamento do rendimento dessas ligas para que não sejam feitas adições desnecessárias que possam elevar os custos de produção ou até mesmo acarretar em perdas de corridas por composição química fora da faixa de especificação. Nesse trabalho foi utilizado o simulador de refino secundário do Steel University para avaliar o comportamento do rendimento das principais ferroligas em estação de rinsagem com banho metálico desoxidado ao alumínio e em banho não desoxidado. Foi possível avaliar que o comportamento do rendimento das ferroligas tende a ser mais positivo quando se é feita a desoxidação do banho metálico utilizando Alumínio briquetado. Com isso feito um comparativo do custo de produção que mostrou que, quando se conhece o comportamento dos rendimentos, é possível gerar economia para o processo.

Oct 1, 2019

By M. G. Mena, M. S. Mena-Junio

Silver (Ag) filler is the most attractive choice among all the conductive fillers of die attach materials for the attachment of silicon devices because of its balanced properties and relatively low cost. However, a major problem of silver is that it electrochemically migrates in the presence of moisture and applied bias. In microelectronic devices, silver migration can occur between adjacent conductors/electrodes, which leads to the formation of dendrites and eventually results in short-circuit failure. In order to assess the reliability of these conductive fillers, an investigation for two types of Agfilled die attach materials was done using the water drop test at room temperature and using a 1000 hour temperature-humidity-bias (THB) test under 85 ºC and 85% RH conditions. Four different bias/voltages and six different electrode distance spacing were used. Both dendrite and cloud/lace-like growths were observed as a result of the electrochemical migration of silver, Water drop test results revealed that increasing the applied bias/voltage and decreasing electrode spacing causes migration to occur faster, thus resulting into shorter time to fail (TTF). It was also observed that the growth rate of the dendrites from the cathode increased linearly as the dendrite approached the anode, probably due to a combination of increased ion availability and electric field. A minimum applied bias of 3 volts was required for migration to occur in Epoxy A as compared to 2 volts for Epoxy C. The higher migration voltage requirement for Epoxy A was attributed to the higher volume resistivity of the said epoxy. In addition to the minimum voltage requirement, it was observed that a minimum electric field of about 1 volt/mm is required for migration to occur. The 1000 hour THB testing did not result into any failures. It is surmised that the presence of condensed moisture is another requirement for migration. Such condition is not present during the THB testing.

Jan 1, 2012