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By André Alexandrino Lotto

A demanda global por energia renovável vem aumentando ao longo dos últimos anos. A energia solar é uma energia limpa e abundante, mas seu uso ainda é limitado por causa dos preços altos e baixa eficiência das células fotovoltaicas. O silício bruto, também chamado de silício de grau metalúrgico, tem sido alvo de muitos estudos visando sua purificação a um nível suficiente para aplicações de energia solar por processos mais baratos do que o processo convencional, chamado Processo Siemens. Neste trabalho, 3 kg de silício de grau metalúrgico foram fundidos por plasma térmico numa atmosfera de vapor de água, hidrogênio e argônio. O teor de boro foi reduzido de 10 ppm para 0,09 ppm em 18.000s (5 horas), mostrando que o processo poderia ser uma alternativa viável ao processo tradicional por via química

Aug 8, 2018

By Felipe da Silva Siqueira, Mariana Sizenando Lyrio, Aline Cristine Lemos Duarte, Weslley Luiz da Silva Assis, Harison da Silva Ventura, André Luiz Moraes Alves, Paulo Rangel Rios

A nucleação nos contornos de grão é um fenômeno muito recorrente em materiais metálicos. Essa situação foi tratada por diversos autores como Cahn e Rios e Villa, usando a abordagem de nucleação em planos e linhas aleatórias. Neste trabalho estudou-se a nucleação nos contornos do polígono de Poisson-Voronoi e de uma matriz hexagonal em 2-d com métodos analíticos e simulação computacional. Utilizou-se uma equação baseada no método de Cahn para nucleação nos contornos de grão. Para nucleação nos contornos do polígono de Voronoi a equação não mostrou adequação total com os resultados simulados para dois tipos diferentes de casos, já para os contornos da matriz hexagonal, notou-se que quanto maior a quantidade de pontos sorteados na matriz, mais os resultados simulados concordaram com a equação proposta.

Nov 13, 2019

By Marcus Vinicius Laudares Mendonça

SMS calculates and improves tooth and flank profiles individually to realise a homogeneous pressure distribution over the complete load flank. With a tooth profile and flank profile according to AGMA, ISO or DIN standard the contact pressure varies along the load flank. To realize a homogeneous distribution of the contact pressure and to avoid a premature mesh, SMS improves the tooth profile and flank profile in three steps. First SMS is doing a preliminary calculation and design according ISO, DIN or AGMA standard, with safety factors based on more than 125 years of experience. Second SMS calculates and checks the local contact pressure at the load flank under consideration of shaft, gearing and housing deformation, as well as the bearing behaviour. Finally SMS calculates and designs an improved tooth profile and flank profile to receive a homogeneous contact pressure at the load flank. The result is an increase of the torque transmitting capacity of up to 30% of the SMS advanced gears with the same outer dimensions than traditional gears.

Aug 17, 2017

By Niander Aguiar Cerqueira

A construção civil é um setor de extremo impacto na economia brasileira, tanto em termos de empregos quanto no consumo de matérias-primas e geração de resíduos. Resíduos de Construção Civil (RCC) representam uma grande parte da massa total de rejeitos sólidos em médias e grandes cidades. Neste trabalho, um estudo foi realizado para produzir concreto com substituição de areia por RCC, em diferentes porcentagens, a fim de reduzir, reciclar e reutilizar esta grande quantidade de rejeitos da indústria da construção civil. Este trabalho teve como objetivo estudar as propriedades mecânicas de concreto estrutural com substituição total e parcial (25%, 50%, 75% e 100% de substituição de areia). Os resultados do teste de compressão indicaram boa qualidade para os concretos com substituição em massa de até 75% de RCC.

Oct 30, 2017

By Wolfgang Kern

More and more coke oven plants worldwide face the task to improve their emission reduction at their coke oven batteries. In the 90’s PROven® was invented and developed by DMT to regulate the inner pressure of a single coke oven chamber. Generally, most of the coke oven chambers can only close and open their connection to the collecting main but without the possibility to regulate the pressure during the carbonization time. Through the installation of PROven® the load on the coke oven door sealing system and the charging lids will be decreased and so does the emissions of crude COG as well. The current PROven® system, installed in the collecting main, does not only regulate the chamber pressure, it replaces the valve between the goose neck and the collecting main, too. This variable pressure control allows decreasing the leakages at the emissions sources to a minimum and allows operating the collecting main under optimum pressure. Subsequently, this will lead to enhanced emission reduction. PROven® proved its value with more than 2,100 units installed by licensee worldwide. Nevertheless, DMT is always focused on its client’s needs and therefore enhance PROven® to provide the Best Available Technique (BAT). Among the main features of the now available system is the plain arrangement with a higher reliability and the possibility to install the system outside of the collecting main without modifying it. Hence, upgrading coke oven plants during operation is possible without any noticeable impact on the plant operation.

Aug 1, 2018

By Verônica Scarpini Candido

O conhecimento das características microestruturais de materiais utilizados como constituintes mássicos de cerâmica vermelha é de grande importância para a compreensão das propriedades das peças queimadas. Assim, este estudo tem por objetivo caracterizar microestruturalmente a escória granulada de aciaria proveniente de uma siderúrgica do estado do Pará visando a sua incorporação em argilas para produção de peças de cerâmica vermelha. O resíduo passou pela etapa de beneficiamento e, depois, foi realizada a difração de raios-X (DRX) e fluorescência de raios-X (FRX). Além disso, realizou-se também a análise morfológica por microscopia eletrônica de varredura (MEV). Os resultados mostraram que hematita, magnetita e wustita são as fases predominantes associadas aos óxidos de ferro. A análise química por FRX mostrou que o resíduo apresenta baixos teores de sílica (SiO2) e alumina (Al2O3), associados a elevados teores de óxidos de ferro e óxido de magnésio. Dessa forma, a caracterização da escória granulada de aciaria mostrou que esse resíduo apresenta-se como um potencial constituinte mássico cerâmico podendo contribuir para a formação de fase liquida durante o que acarretaria em melhoria das propriedades tecnológicas como absorção de água e resistência mecânica.

Oct 30, 2017

By Henrique Lacerda Eleutério, Aldo Henrique de Almeida Barbosa, Vicente Tadeu Lopes Buono

The automotive industry’s interest in galvannealed (GA) boron steel for hot forming processes application has been steadily increasing due to its excellent surface quality, galvanic protection provided to the parts, good paint adhesion and better weldability in relation to other coatings for this application. In this study, samples of 22MnB5 galvannealed steel were heat treated and hot stamped on a water cooled die in laboratory scale. The influence of heat treatment on stability of coating and steel was assessed by using initial heating rates 11.0ºC/s and 15.0ºC/s. Microstructural evolution of galvannealed coating and structural integrity of steel during hot forming were investigated by scanning electron microscopy with energy dispersive spectroscopy analysis (SEM/EDS/Line scan), X-ray diffraction (XRD) and optical microscopy (OM). It was possible to quantify the Fe-Zn phase evolution during hot forming, to understand the effect of these heating rates on the product properties and to establish an optimized heat treatment for hot forming of these steel. The heat treatment with the heating rate of 15.0ºC/s presented greater operational flexibility and final products free from surface defects or cracks in the substrate.

Oct 1, 2019

By Eleir Mundim Bortoleto

A finite element modeling approach was developed to study adhesion phenomena during the unidirectional contact between a two-dimensional plane-strain square and a flat slab. Surfaces were metallic or ceramic, different pairs of materials were analyzed and their adhesion was considered by means of a FORTRAN subroutine (DLOAD), which was connected with commercial finite element code Abaqus and provided surface attractive forces based on the Lennard-Jones interatomic potential. Adhesive loads were considered both during approximation and separation of the surfaces. During the separation step, material transfer between surfaces, due to adhesion, was modeled by means of damage initiation and propagation at the flat slab. The parameters considered in the simulations were normal load, chemical affinity and system size and the different conditions were analyzed by comparison of the interaction forces during approach and withdrawal. This work also presents detailed descriptions of: (i) the evolution of energy dissipation due to adhesion hysteresis, (ii) the formation-growth-breakage of adhesive junctions and (iii) the evolution of stress distribution during the process. Results have indicated that chemical affinity between the bodies in contact is more relevant for adhesion than the applied load. Besides, smaller asperities are less prone to promote adhesive wear, but they may be subjected to high stress concentration effects.

Jul 31, 2018

By Florian Markus Penz

The increase in Basic Oxygen Furnace (BOF) plants in steelmaking has given rise to renewed interest in a dynamic simulation of the BOF process. Material and process costs can be saved with optimized process times and targeted charging of scrap and slag formers. Beside hot metal, scrap is the main source of iron in the BOF process. Furthermore, scrap is used as a coolant during the process due to exothermal chemical reactions occurring in the BOF. In this paper, the melting and dissolution behaviour of scrap in the BOF process is discussed. A new dynamic thermodynamic and kinetic Matlab® model used to simulate scrap melting behaviour as a function of various scrap surface parameters and particle size is presented, as well as the influence of scrap properties on liquid bath temperature and final crude steel composition after a defined blowing period.

Oct 30, 2017

By Daniel Horta Fernandes, Walter Gomes de Albuquerque, Adriano Cesar Carvalhido, Victor Dias Martins

O trabalho apresenta a experiência recente da troca de 38 staves contribuindo no prolongamento da campanha operacional do Alto-Forno 3. Durante 13 dias ocorreu a substituição dos Staves originais de FoFo instalados em 1999 por novos Staves de cobre fundido. Além da recuperação do sistema de refrigeração, a mudança no material dos Staves contribui para maior troca térmica favorecendo a formação carga inativa (cascão) que protege os Staves e o corpo do Alto-Forno. Esta substituição foi fundamental para recuperar a estabilidade da temperatura da carcaça e prolongar a vida útil do equipamento até o final de sua campanha. Diversos aspectos do projeto serão apresentados: engenharia, metodologia, planejamento, segurança, qualidade técnica, cronograma e outros.

Oct 1, 2019

By Hormando Leocadio, CWM van der Geld, Julio Cesar Passos

Impinging water jets promote high heat flux extraction rate. Steel industry widely employs the process for accurate temperature control to improve the microstructure and to ensure adequate mechanical properties. The range of surface temperatures, heat fluxes and cooling rates are very large, which makes it important to obtain an accurate value of the heat transfer coefficient. This paper presents an experimental and numerical study of the heat transfer behavior of a high temperature (450°C - 900°C) steel plate cooled by a water jet at 20°C to 70°C. High-speed imaging (up to 20,000 fps) within water jet impingement zone allowed the characterization of the boiling regimes in the early stages of cooling. The effects of initial temperature, water jet temperature and velocity on the heat transfer coefficient were analyzed by inverse heat conduction method that predicts the heat flux and temperature on the top surface from temperatures measured with thermocouples inserted in test plate. Heat transfer is strongly affected by the initial temperature of the hot steel, water jet temperature and, less intensely, by jet velocity. High cooling rates start when liquid water is in direct contact with surface temperatures above 700°C.The results will contribute to the enhancement of the temperature cooling control on the runout table and cooling model employed at Usiminas Hot Strip Mill.

Oct 1, 2019

By Dr. Steven G. Jansto

The market demand for reduced fuel consumption and CO2 emissions in the automotive, energy and construction sectors have further increased the demand for new and advanced higher quality microalloyed grades produced via TMCP. The technological integration of the process and physical metallurgical advancements of value-added niobium (Nb) microalloyed thermo-mechanical controlled process (TMCP) steels continue to be developed and is an important element for these more demanding end user requirements and cost-effective steel production. The reheat furnace process step has a profound effect on the TMCP performance, final hot rolled steel quality and mechanical property consistency during the production of hot rolled steels. The uniformity of heating applied across the entire width, thickness and length of the slab or billet is essential in the successful achievement of consistent customer properties regardless of the chemistry. The resultant ferrite grain size in the final hot rolled product is significantly governed by the initial prior austenite grain size. However, the transition from laboratory melted and TMCP hot rolled heats to the production scale is often quite challenging. Aberrations in the reheating process step at the industrial furnace are often the root cause of mechanical property quality issues. These combustion process metallurgy parameters connect directly to the resultant TMCP product quality and is defined as Combustion Metallurgy

Oct 1, 2019

By Mathias Woydt

The tribological and mechanical properties of binderless and metal-bonded niobium carbides (8 or 12 vol.-% of Cobalt, 12 vol.-% of Fe3Al) are presented. Rotating disks made of niobium carbide bearing hard metals were mated against alumina (99.7%) under unlubricated (dry) unidirectional sliding tests (0,1 m/s to 12,0 m/s; 22°C and 400°C) as well as in oscillation tests (f= 20 Hz, ?x= 0,2 mm, 2/50/98% rel. humidity, n= 105/106 cycles). Microstructure and phase compositions were determined as well. The tribological data obtained were benchmarked with different ceramics, cermets, hard metals and thermally sprayed coatings, where NbC bonded with 8% and 12% Co presented above 8 m/s the lowest wear rates so far in such a benchmark. Binderless NbC (HP-NbC1) and the metal bonded NbCs exhibited low wear rates under dry sliding associated with high P?V load carrying capacities. NbC-based hard metal bonded with 12 vol.-% of Fe3Al resulted in a higher hardness level than for 12 vol.-% cobalt. The tribological profile established revealed a strong position of NbC bearing materials under tribological considerations and for closed tribosystems against established reference tribo-couples.

Jul 31, 2018

By D. F. Rodríguez-Pérez, J. Salinas-Reyes, Luis R. Salazar-Garza, C. A. Gómez-De-La-Garza

The Pickling Line Tandem Cold Mill (PLTCM) from Ternium Pesquería started in 2013. It is a line with 5 stands, 6 high; focused mainly on the exposed automotive market, with a wide spread of products with high quality requirements. In addition the operational continuity is very important, for this, one of the greatest challenges is to ensure operational discipline, the order of production, the quality of the input (hot band), operational interruptions, equipment failure, breakage of strip in the mill, among others. In relation to this, it has a strong impact on productivity, customer compliance, damage to equipment, rolls, safety, quality, reprocessing among others. Here is present the results obtained in the project "decrease of strip breaks" which focused on several fronts, discipline in the order of production, previous review of raw material in surface and dimensional defects with automatic inspection equipment in the hot mill, as well as in PLTCM, generation of logic in the redundant systems of alerts and prevention to avoid or minimize strip breaks that were high impact in the past. All these multidisciplinary actions led as a whole to a significant improvement in the performance indicators of the PLTCM, in productivity, compliance, reprocessing and quality in the cold rolled mill.

Oct 1, 2019

By J. Bas A. F. Smeulders

Traditional laboratory lubrication tests, including those for cold rolling lubricants often involve measurement of neat oils. To achieve increased levels of test severity, such tests are often carried out at high temperatures and prolonged durations. However, we found that the levels of lubricant degradation and wear in these tests can be much higher than in the field. Moreover, steel rolling is not done with neat oils, but with emulsions, where the presence of water influences film formation, surface chemistry and oil composition in the roll bite. To better approach the situation in the field, and thus to be able to develop rolling oils with improved lubrication performance, several lubrication tests were developed for emulsions: direct measurement of film formation and measurement of Stribeck curves, in which the emulsions can be assessed in terms of their boundary lubrication and elastohydrodynamic behaviour. The key innovation is that also another test method was developed, which focuses on boundary lubrication and wear, and the role of extreme pressure and anti-wear additives. Realistic levels of test severity are achieved in the tribometer by mimicking frictional power intensities and flash temperatures for typical cold rolling or tinplate mills. Test conditions can be adapted according to the mill stand or pass number and other cold rolling process parameters. The emulsions are kept at normal operational temperature. Clear differences could be observed between emulsions of various concentration and composition. The viability of the method is illustrated by a number of field cases, in which a good correlation is demonstrated between the laboratory tests and the performance in a pilot or production mill.

Jul 30, 2018

By Massimilinao Svetina

In 2010 Danieli & C. S.p.A. put into operation a new Pickling Tandem Mill in Cremona (Italy) at Acciaieria Arvedi, the last Pickling line coupled Tandem Cold Mill (PLTCM) in Europe. The plant was tailor-made to suit the specific requirements of this customer; a very broad range of sizes and grades (IF to AHSS as well as DP and TRIP1000) including ultra-thin hot band can be processed, achieving a total capacity of 1.6 Mt/y. The Danieli & C. S.p.A. Turboflo® process was selected because of its proven efficiency and ability to handle ultra-thin gauges at speeds exceeding 400 mpm in the pickling tanks. All the equipment, i.e. pickling section and rolling mills was provided with the last generation of Danieli market-oriented technologies. Danieli & C. S.p.A. - with the support of Arvedi and feedback from the field - is continuously improving its technical design solutions and optimizing plant operations.

Aug 16, 2017

By Jorge Madias

Durante la laminación de barras y alambrones para construcción civil; perfiles y ángulos estructurales y barras redondas y hexagonales de aceros de corte libre puede presentarse la apertura de la punta o la cola y el estallido central, con la consiguiente parada y caída de la productividad, y pérdida de rendimiento metálico. En este trabajo se analizan las diversas causas que confluyen para que este problema ocurra. Se analiza la influencia de posibles defectos en las palanquillas, las características del corte de las mismas y otros problemas de calidad. Se revisa el rol del precalentamiento previo a la laminación, la refrigeración de los cilindros, el diseño de pasadas y la respuesta del material en función de su ductilidad. Se presentan diversos casos industriales para ilustrar las diferentes razones detrás del problema de la apertura de punta.

Jul 30, 2018

By Marisa Martins

Este trabalho aborda o processamento de rejeito proveniente do circuito de flotação de minério de ferro da mina de Cauê. A amostra utilizada no presente estudo apresentou teores médios de 27% de Fe, 59% de SiO2 e 1,4% de Al2O3. A concentração de hematita contida neste rejeito foi avaliada, utilizando-se flotação aniônica em meio ácido e na presença do ânion SiF6 2-, como depressor da ganga silicatada. De posse da caracterização granulométrica, química e mineralógica do rejeito, ensaios tecnológicos de flotação foram executados, objetivando a avaliação dos variados sistemas de reagentes. Diferentes dosagens dos depressores H2SiF6 e Na2SiF6 e ainda de três diferentes tipos de coletores aniônicos foram avaliados. Os melhores resultados foram alcançados pelos coletores do tipo ácido graxo e sulfonato de petróleo, os quais geraram concentrados contendo 66% de Fe e 4% de SiO2, e recuperações metalúrgicas de Fe de 59% e 71%, respectivamente.

Aug 16, 2017

By Daniel Stickel

Current political, economic and ecological guidelines demand the increase of power densities of nearly all machinery parts today. In order to further lower the wear rate towards the ultra-mild sliding wear regime an integral approach is needed, which has to regard contact conditions, surface topography, surface chemistry, as well as sub-surface properties. Still there are no simple parameters to classify the performance of tribosystem. In this study the area and volume affected by tribocontacts are calculated by means of a three dimensional elastic-ideal plastic contact model. The surfaces are generated by means of conventional machining procedures and characterized by scanning white light interferometry. The further input data as to normal and friction forces are derived by ultra-mild sliding wear tests under boundary lubrication conditions of carburized steel against carburized steel and 52100 steel against case-hardened spheroidal cast iron. This contribution will depict the distinct influence of the topography on friction and ultra-mild sliding wear of common Fe-base materials and point on the marked importance of highly localized effects, which govern the acting mechanisms.

Jul 31, 2018

By Hiroshi Ichikawa

In 2013, Nippon Steel & Sumikin Engineering Co., Ltd. (hereafter referred to as NSENGI), Tenova HYL and Danieli have entered into an agreement to combine ENERGION DR technology into blast furnace technology and/or with syngas technologies. This new alliance will allow the three companies to combine research and development activities with their respective expertise in ENERGIRON DR technology, Blast Furnace technology and Syngas (by-pro gas and coal gasification) technology, with the ultimate objective to develop breakthrough iron making technologies and create such EPC projects. This paper introduces the concepts and the features of our breakthrough technologies of combining of ENERGIRON DR technology, Blast Furnace technology and Syngas technology.

Aug 16, 2017