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By R. W. Nice

Presently about 60% of the world's nickel resources are tied up with lateritic ores while about 25% of the world's nickel is produced from sulphides. Based on this the industry has to focus on improving lateritic nickel economics in order to maintain the high use of the metal worldwide. In 1997 three junior mining companies in Australia organised finance against all odds and commenced development of three separate nickel and cobalt extraction plants treating lateritic nickel ores. All three projects utilise similar pressure acid leaching (PAL) technologies while each has unique metal recovery technologies All projects have experienced numerous processing and maintenance related difficulties such that full ore throughput has been reached by only one operation after five years. This shortfall in performance has caused the owners considerable angst and financial pain. In 2000 Cawse went into receivership and was purchased by an international corporation. Recently, Bulong also went into receivership and has undergone an orderly shutdown, awaiting sale to a new buyer. Murrin Murrin has settled with its financiers and is in a position to operate as planned for many years forward. This paper will discuss a number of the technical difficulties that affect the ore preparation, PAL and solution treatment circuits of these plants. The objective is to identify the cause of some of the difficulties and propose possible solutions so that the next generation of lateritic operations can emerge as technically and, more importantly, economic successes. A number of these process improvements have been identified by the existing operators and in many instances have been or are being implemented into the existing operations.

Jan 1, 2004

By Mark Freberg

"IntroductionThis chapter is intended to provide information on the operation and maintenance of several pieces of equipment used in heavy media separation. Most heavy media separation circuits, particularly those involving bath separators can be considered as high maintenance areas. Because of this the efficient operation and maintenance of these circuits is very important if the cost per ton of material treated is to be kept to an acceptable level.Heavy media separation (HMS), is a process used to separate particles of different specific gravities. Under laboratory conditions the ideal way to separate two types of particles which have different specific gravities is to suspend them in a heavy liquid which has a specific gravity between those of the two types of particles. Those particles with the lower specific gravities will float on top of the liquid while the higher specific gravity material will sink to the bottom. Given enough time and a sufficient volume of heavy liquid this process will be essentially insensitive to the sizes of the particles involved.Heavy media separation circuits make use of the same principles described above. The material to be treated is introduced into a mixture of finely ground solids, called media, and water which takes the place of the heavy liquid; the mixture of solids and water is known as medium. The separating force can be either gravity or centrifugal force. The type of solids used as media varies but it is usually a high specific gravity material such as magnetite, galena or ferrosilicon.Heavy media separation is used extensively in the cleaning of coal and to a lesser extent as a preconcentration step in base metal and iron ore operations."

Jan 1, 1989

In terms of throughput, product size and power draw, grindcurves provide a measure of the response of the mill performance to changes in mill operating parameters ? usually mill filling. Since presenting the principle in 2006, grindcurves have been applied to a wide variety of AG and SAG mills. Mill response has been carefully measured for variations in: mill fillings from 15% to 40%; throughput by a factor of two; power by 50%; feed blends; liner profile; and mill speed from 65% to 80%. The outcomes of this extensive program of work are presented as the measured grindcurves. How they have enhanced our understanding of mill operation and how they may be applied to practical daily mill control is discussed. It is proposed that this technique provides a viable and valuable mill control tool that may find extensive application in the industry.

Jan 1, 2012

By Karen M. Moffitt

Developments in mining methods and rates have led to an increase in the frequency and size of waste dump failures that have not been adequately predicted or explained in terms of conventional slope stability analysis. Monitoring data and visual observations suggest a unique mode of failure responsible for large runout events. A numerical model has been developed to capture commonly observed patterns of deformation, and investigate the formation of the ensuing failure mechanism. The analyses have yielded a good correlation with observed field behaviour and have provided significant insight into the coincident stresses and deformations within the dump. Results indicate that while creep effects in the waste dump could have a significant effect on the magnitudes of displacement, the overall dump stability is governed by the strength of the foundation soils underlying the toe region. Consideration of both the stress and velocity fields leads to factors of safety for various dump heights and foundation slopes that are considerably less than predicted from limit equilibrium analysis. The results suggest that conventional limit equilibrium analysis techniques may not be adequate when assessing the stability and design of waste dumps on steeply sloping terrain.

May 1, 2001

By J. H. Bernard, K. Žák

The three traditional types of Variscan vein Pb-Zn-(Ag) mineralization recognized in the Bohemian massif from historic paragenetic studies are confinned by modem metallogenic studies. Stable C, S, and O isotope data, as well as Pb and Sr isotopic ratios of the deposits, indicate a predominantly crustal origin of the constituents in all three types. Although the data also suggest differences in temperature and pressure of formation, and the oxidation conditions and nature of the hydrothermal fluids, nonetheless they are consistent with prevailing metallogenic classifications of the vein mineralization

Jan 1, 1992

By David McMullen

Radiation plays a critical role in the thermal behaviour of hydrometallurgical process equipment. This effect is particularly important when designing refractory lined equipment used in pressure leach/oxidation processes. In order to simplify this non-linear mode of heat transfer, the effects of radiation had previously been incorporated in an equivalent convective film coefficient in finite element methods (FEM). This prior method omits the effects of radiosity, a critical aspect of radiation heat transfer, which affects the design of refractory lining systems in autoclave vessels. Given that 60% of the heat loss in actual plant practice of an autoclave is due to radiation, reliability in the FEM is therefore impacted. This study validates the use of radiosity in FEM through thermal loading using a combination of simple geometries to be applied to complex environments such as vessel nozzle clusters. The added benefits of using a radiosity load includes an increase in confidence in thermal distribution results, greater accuracy in determining appropriate refractory lining systems, weld overlay sizing, and increased accuracy in structural analysis.

Jan 1, 2014

By T. R. Chari

The safe-level dilution of low-level radioactive wastes in large volumes of selected granular material is proposed as an alternative method of permanent waste disposal to current Canadian practice of concentration and encapsulation. Accepting the fact that a "background level" of radioactivity exists throughout the world, the authors feel that the concept of controlled dilution of radioactive wastes to a level in keeping with "background" is a plausible alternative to current thinking on the subject and is worthy of equal consideration.

Jan 1, 1979

By M. E. Hurst

Introduction Between 1903 and 1905, W. Mclnnis, of the Geological Survey of Canada, made a micrometer traverse of the Kawinogans (Crow) river from Kapkichegimaga lake to its junction with the Otoskwin river. He reported that a belt of Keewatin rocks, 1 to 4 miles wide, was exposed along the course of the river for 17 miles east of Kapkichegimaga lake. Prospectors and exploration companies paid little attention to the mineral possibilities of this belt until the summer of 1928 when, with the adoption of airplane transportation, the area became readily accessible. Within a short time widespread interest was aroused by the announcement of attractive finds, and a mild rush followed. During the winter months, hundreds of claims were staked on either side of Crow river for 12 miles east of Pickle lake. In the summer of 1929, much of this ground was systematically explored and a considerable amount of development work was done on the known deposits.

Jan 1, 1930

By S. G. Shabestari

Thermal analysis is a tool that is generally employed to predict the structure of the alloy before the actual casting is carried out. By cooling a sample of the molten alloy and recording the temperature-time curve, important solidification events may be analyzed by using the first derivative-cooling curve. In this research, strontium is added to (AS5U3G) 319 aluminum alloy and its influence on the formation of intermetallic compounds e.g. Al15(Mn,Fe)3Si2, Al2Cu, Al5Mg8Cu2Si6 formed during pre- and post-eutectic reaction have been investigated. Also any changes in solidification parameters such as temperature of Al-Si eutectic under cooling and temperatures of nucleation and growth of each phases caused by strontium addition, have been determined via the first derivative cooling curves. The effect of strontium on the formation of various intermetallic compounds has been studied by using very accurate thermal analysis equipment and the microstructures were analyzed using an optical microscope. The various phases reported in this paper were identified using Scanning Electron Microscopy (SEM) and linked to Energy Dispersive Spectroscopy (EDS). Formation of all pre- and post-eutectic phases was interpreted by comparing the phases formed in the microstructure and the reactions detected by using cooling curves. The results of this research indicate that thermal analysis technique can be used as an on-line process control in the production lines in aluminum casting industries.

Jan 1, 2004

By Per Hedvall, Jan-Eric Ståhl

"The main objective of this study is to introduce the new Sandvik’s production cost-model within Crushing & Screening (C&S) technology. So far, there have been different ways of determining different production costs in the industry, however, the previously published and presented methods have not been very efficient in calculating the costs per product and metric ton. Accordingly, the current study has been planned and started in collaboration with Lund University to provide an accurate and easy to implement cost estimation program to determine the costs for crushing and screening plants worldwide.The proposed model has been adapted to fit the C&S processes of different rocks/ores fractions. The result is presented as cost per ton of the end product(s).Within this paper the cost estimation results for 3 different crushing and screening plants are presented based on the information obtained from the following sources: a) documents at Sandvik SRP, b) Sandvik’s crushing & screening internal/external machines/plants data and information, c) literature studies, including the use of Sandvik’s internal/external simulation and software programs, d), visiting the crushing and screening plants ,e) interviews, information systems’ data, and, f) testing and observations by ourselves.In order to improve the level of accuracy and the validity of the attained results, simplistic Monte-Carlo simulations have been used, where needed. The achieved results, so far, have proven the reliability of the model. The calculated cost estimations have shown an accuracy over 80% when they compared with real cost data obtained from plant practices.The current cost calculation model, will offer the possibility of:•,Calculating the production costs in proposed and/or existing C&S plant.•,Making detailed cost analyses for the end product(s) in proposed and/or existing C&S plants.•,Determining the profitability of each finished product when it’s required.•,Cost optimization by potentially cutting the cost for part of C&S plant with an existing plant practice"

Jan 1, 2016

By Charles Tkaczuk

In order to remain competitive the mining industry must keep up with changes in technology. Many innovative technologies from the mining perspective are commonplace in other industries. A ?Global? review of technologies will often reveal existing technologies that can be innovatively applied in the mining industry. Industries, which are rife with proven solutions include, medicine, biotechnology, security, manufacturing, telecommunications, etc. This paper addresses the communications aspect of mining where greater productivity, lower costs and the ability to quickly react to mining related events is obtained through an increase in remote monitoring and operating control. A review of the communications systems in place globally reveals technologies that, with minimal modification, can be immediately applied to the mining environment. We discuss the concept, advantages and implementation of existing communications technology from an industry that is not usually associated with the mining industry. This technology will form the basis of a solid platform on which can be built a state-of-the-art process monitoring, control, and communication system. This lays the groundwork for providing one solution to the underground mining industry?s most difficult problem, establishing a reliable, maintainable and cost-effective underground bi-directional wired/wireless data, video and analog communications system. We need look no further than our own doorsteps to find such a solution. The cable that you see coming from the simple green or brown box on the boulevard into your home contains hundreds of television broadcast channels, FM radio channels and data channels. And if you have a set-top box, you are in control of it all. The Cable Television Broadcast Distribution System suppliers of today are at the leading edge of converging all the different methods of communications onto a common carrier, coaxial cable or fibre optic cable. There is no fundamental difference between providing a reliable communications network to a city/neighbourhood/home/personal computer than there is to a mining operation/underground level/equipment or person. The principle is the same. Only the application is different. Realizing this, we can capitalize on the efforts of other industrial sectors, to solve our communications problem. Where else can you find a solution to a problem that is mature, having been developed with the input of thousands of engineers, and having hundreds of millions of dollars spent on research and development, manufacturing, distribution, global presence and engineering support?

May 1, 2003

By A. Farzanegan, D. A. Lowther, A. R. Laplante

"Off-line optimization studies are often necessary to improve the efficiency of grinding circuits. These studies are primarily based on the mathematical modelling of processing units (e.g., ball mills and hydrocyclones) and computer simulations. To complete an optimization task, process engineers must possess skills and knowledge of different subtasks involved in such efforts, e.g., plant audit, laboratory tests, and data analysis. Such know-how can be in part provided by Knowledge-Based Systems (KBSs). One such system, being developed in C Language Integrated Production System (CLIPS), is presented here, with focus on the estimation of ball mill selection functions for the purpose of both diagnostic and simulation, and its use for the optimization of ball size. Some of the interpretation and diagnostic rules will be presented, as well as grinding kinetics and classification data likely to fire them.IntroductionSince the late eighties there has been a growing trend in applying Knowledge-Based Systems (KBSs) to mineral processing [Meech 1990, Bearman and Milne 1992). Table l lists some KBS (often referred to as expert systems) applications that have been used mainly as tools for improving on-line monitoring and control of grinding circuits. However, there has been fewer attempts to add the symbolic processing powers of KBSs to conventional off-line grinding simulators. Figure 1 shows a relatively standard procedure to perform an off-line optimization study [Napier-Munn and Lynch 1992]. In brief, a typical program includes taking representative samples from a number of streams, running laboratory tests on collected samples, estimating model parameters which describe physical processing units (e.g. ball mills and hydrocyclones) validating model predictions and using models for simulation trials. One inevitably needs to be familiar with concepts of process modelling and simulation as well as various computer programs to be able to complete all steps of the study. Much of this ""expertise"" can be captured by KBSs, given their inherent capabilities for symbolic knowledge representation and manipulation."

Jan 1, 1997

By J. Smit, F. Parada, R. Parra, E. Balladares, M. P. Merino

"In this study, a two-step process was developed for recovering copper, molybdenum, zinc and iron (hematite). In the first step, grinded slags (-65 mesh) were sulphated with SO3 at 350-500ºC to form iron, copper and zinc sulphates. In the next step, the formed sulphates were decomposed to hematite, copper and zinc sulphates and oxysulphates at 700-750ºC. The generated SO3 was recirculated back to the sulphation step. The generated calcine in the decomposition step is leached with 25 gpl acid at 50ºC to dissolve the copper, zinc and molybdenum for further conventional separation and recovery. The hematite residue, of intense red color, can be used as pigment, in the ceramic industry or as pellet feed. The fine crystalline silica remains in the hematite residue."

Jan 1, 2014

By E. A. G. Colls

PART I.-GASES IN INDUSTRY INTRODUCTION THE part played by gases in industry can be considered from at least four distinct viewpoints, viz: (1) As air to support combustion and life and do various kinds of work (2) As fuel, or as essential to certain chemical processes (3) As sources of danger from explosion or fire ( 4) As hazards to man's health The present paper deals with gases only insofar as they are sources of danger, or are hazards to health. It may be noted, however, that, in point of tonnage, air is one of the most important materials handled in any industrial plant. In the operations of the Consolidated Mining and Smelting Company, for example, 138,000 tons of air are handled daily, the only material exceeding this figure being water. The United States Bureau of Mines has listed no fewer than seventy-four gases and vapours that, under certain conditions, may be considered as ex-plosive or dangerous (poisonous). The commonest and most important of these are as follows : Carbon monoxide Methane Acetylene Hydrogen Oxygen Hydrogen sulphide Benzol vapour Ammonia Petroleum vapour Carbon disulphide Hydrochloric acid gas Cyanogen Carbon oxysulphide Chlorine ` Fluorine (and fluorides) Acetone vapour Acetic acid vapour Water gas Natural gas Gasoline vapour Coal gas Producer gas Ether vapour Nitrogen oxides

Jan 1, 1940

By Denis Blackburn

La Direction générale du développement de l?Industrie minérale (DGDIM) du ministère des Ressources naturelles et de la Faune (MRNF) du Québec tient un inventaire de toute l?activité minière sur le territoire. Cet inventaire s?est enrichi, au cours des dernières années, d?un grand nombre de projets dédiés au fer ou à des substances qui y sont associées (titane, vanadium, phosphate). Actuellement, cinq régions du Québec sont principalement touchées par la recrudescence de projets dédiés au fer : Fermont, Schefferville, Baie d?Ungava, Baie-James et Chibougamau. Fermont et Schefferville sont les régions les plus actives. Les infrastructures en place, telles que les routes, les chemins de fer, les ports, les lignes électriques et les municipalités, ont atteint, dans certains cas, leur capacité et de nouvelles infrastructures devront être construites pour satisfaire les besoins. À la Baie-James et sur le flanc ouest de la Baie d?Ungava, des projets d?exploration sont aussi en cours. Le manque d?infrastructure pourrait peser lourd sur le développement de projets miniers dans ces régions. Enfin, dans le secteur Chibougamau/Matagami et à quelques sites ailleurs au Québec, des projets d?exploration qui visent le vanadium, le titane ou le phosphate pourraient aussi fournir comme produit secondaire des concentrés de fer. Tous les projets, décrits dans cet article, sont situés sur le territoire du Plan Nord du gouvernement du Québec.

May 1, 2011

By C. J. Simensen, R. Østhus, H. J. Roven, K. G. Skorpen, H. Kalager

"This work encompasses co-extrusion of alloy Al4.5Mg at the core and rapidly solidified Al4.5Mg1Ag forming the surface layer. The goal is to produce a multi-material by co-extrusion having a relatively hard surface as compared to a softer core. At the same time, work hardening in both alloys is expected to be significant due to Mg in solid solution. Precipitation hardening at 160°C is studied by applying solution heat treatments at 560°C. The hardness increased from 80 to 130 VH in the surface material after 236 h. Surprisingly, the Al4.5Mg alloy also shows pronounced aging at this temperature, i.e. from 70 to 90 VH. The relatively high solution heat treatment temperature introduces grain growth in the core, but this is insignificant for the RS surface alloy. Blisters forms at the surface and cracks follows large portions of the interface. However, the tensile ductility is significant in all conditions due to very pronounced work hardening, i.e. for the as co-extruded, T6, under- and over-aged. The elongation at fracture ranges between 40–45% and the tensile strengths 240–275 MPa. The tensile properties increase linearly with the thickness of the RS alloy, i.e. following the rule of mixtures.INTRODUCTION Al-Mg alloys in 5xxx-series are classified as non-heat treatable wrought alloys (Polmear, StJohn, Nie, & Ma, 2017). The formation of the binary ß-Al8Mg5 does not give a substantial increase in the strength of the alloys (Mondolfo, 1976). When a third element like Ag, Cu or Zn are added, G.P.?zones are formed at low temperatures and intermediate, partial coherent phases are nucleated somewhat higher temperatures and finally a ternary, equilibrium phase is formed (Auld, 1968; Cousland & Tate, 1986; Mondolfo, 1976). Both the formation of G.P.?zones and intermediate phases increase the hardness and strength of the materials. An intermediate, hexagonal T´?phase is formed in Al-5 wt%Mg-1wt%Ag, and finally the equilibrium, cubic phase (Al,Ag)9Mg5 is nucleated (Cousland & Tate, 1986; Mondolfo, 1976)."

Jan 1, 2018

By L. Li

Iron removal is a common procedure in hydrometallurgy of non-ferrous metallic ores. Chemical precipitation and solvent extraction are currently the main methods employed for separation of iron from copper leach solution. However, chemical precipitation methods have the problem of producing large amounts of iron precipitates, and/or requiring high temperature and high pressure conditions for precipitation. The precipitates are difficult to separate from the solution. Emulsification is a general problem for solvent extraction, which causes loss of extractants and contamination of the electrolyte. A common problem for solvent extraction and chelating ion exchange processes is the difficult iron stripping process. Therefore, finding an efficient and environmentally friendly method for iron removal is of great significance. In this paper, new processes of using ion exchange resins to remove iron from copper leach solution have been investigated. Salicylic acid, amino carboxylic acid, amino phosphonic acid and hydroxy-oxime resins were employed to adsorb iron from a simulated copper leach solution containing 40 g/L of Cu2+ and 36 g/L of Fe3+. It was found that a hydroxy-oxime resin, named Z-Fe, has excellent adsorption selectivity on Fe3+. Desorption behavior of the resin was studied by two step elution using dilute H2SO4 and oxalic acid solution, respectively. After optimizing the adsorption-elution processes, the extent of removal of iron from the simulated copper leach solution using resin Z-Fe was 90%, while copper recovery could reach 100% in closed circuit processing.

Jan 1, 2016

By F. Parada Luna, F. Parada Torres, J. Salvo, A. Reghezza

In the pyrometallurgical processes of copper concentrates, arsenic is preferentially concentrated in the dusts carried by the gases as a result of their volatility and subsequent condensation in the gas cleaning train. In this work results obtained by alkaline leaching of the dusts from Ministro Hales roasting plant, belonging to Codelco, are presented. For the Ministro Hales plant the alkaline leaching would be an alternative to the recirculation of dusts to the roasting furnace. The experimental study considered NaOH and NaOH plus NaHS leaching of two samples of dusts, with 4.24 and 2.55% arsenic respectively. The results show that it is feasible to extract 90% of the arsenic and 50% of the antimony at room temperature using only NaOH, and when the temperature increases to 95ºC, the extractions of As and Sb increase. Copper remains in the solid residue with less than 1% dissolution, and the NaOH net consumption was approximately 140 kg/t of dust. In leaching tests with NaOH + NaHS, two types of methods were tested, baking plus leaching with water and direct leaching with a NaOH+NaHS solution. With the second method arsenic extraction increased to 95% and copper dissolution was less than 0.01% at 85ºC, NaOH 100 g/L, NaHS 90 g/L, 1.5 h and L/S ratio of 5/1 (L/kg). The bismuth remains stable in the solid in all cases. INTRODUCTION The presence of arsenic in copper concentrates has increased with time and the environmental regulations are becoming increasingly more stringent. In concentrate treatment pyrometallurgical plants, most of the arsenic is volatilized condensing in the gas train and is collected along with the entrained solids to form the flue dusts. Under these conditions, in smelters of copper concentrates with high arsenic content, the dusts are being treated in hydrometallurgical plants to extract and stabilize the arsenic, which also means that most of the copper contained in the dust is co-extracted with the arsenic. This affects the recovery of copper in the smelter and an alternative such as the selective alkaline leaching of arsenic, would allow the copper from flue dust to be recovered.

Jan 1, 2019

By Michel Dagbert

"This paper illustrates the different ways grade-tonnage curves can be generated f or a mineral deposit. It emphasizes systematic discrepancies between reality, estimates and actual production according to different estimation methods and grade control programs. It does not offer a universal solution to the prediction of grade-tonnage curves. Hopefully, it will inspire caution to mineral economists who use estimated grade and tonnage data in the establishment of an optimum cut-off grade for a mining operation.IntroductionThe value of a mineral development venture often depends on a grade-tonnage curve. Statistics can help. The idea is to divide mentally the orebody into small blocks called selective mining units or SMUs. A SMU is an idealized version of the quantity of rock the grade of which will be tested against the cut-off at the time of mining. It could be as small as a truck load or a shovel load in very selective operations like some uranium mines where radiometric probing of each truck or car is performed. More typically, in an open pit operation, it will be the smallest zone flagged as ore from blast hole data, e.g. a 5 m by 5 m by 10m block, if blast holes are on a 5 m grid and bench height is 10m. Having defined the SMUs, the grade-tonnage curve determination amounts to evaluating the grade distribution of all the SMUs that can be mined in the depo sit. If we know this distribution we simply apply the cut-off to it and we get the number of SMUs above the cut-off (i.e. ore tonnage) and their average grade. .Assessment of the grade distribution of SMUs from exploration drill hole data is not an easy exercise and much has been published on the subject (David, 1972; Marechal , 1972; Huijbregts, 1975; Marechal, 1975; Guibal and Touffait, 1982). In this paper, we use a gold mine example to illustrate the influence of SMU size on the results. With the same example we also show that ""common-sense"" methods of grade-tonnage curve determination can sometimes be misleading."

Jan 1, 1987

By T. Moyo

Ammoniacal solutions are attractive and effective lixiviants for the dissolution of chalcopyrite, allowing for the formation of stable ammine complexes with copper while rejecting iron. Chalcopyrite dissolution in ammoniacal solutions is reviewed from literature, and results from a recently completed study evaluating it through electrochemical and controlled leach studies are discussed. Ammoniacal leaching of copper ores dates back to 1916 in the leaching of low grade copper ores in the Kennecott leaching plant and in the Calumet and Hecla mines, followed by the commercialisation of the Sherrit Gordon process for the ammoniacal leaching of sulphide copper ores in 1948. Since then ammoniacal leaching has received intermittent focus from researchers with the development of the Anaconda’s Arbiter process and the unsuccessful Escondida process. In these leaching processes, the formation of surface deposits has historically been reported to result in the passivation of the chalcopyrite surfaces, whereas oxygen mass transfer in solutions has been the focus of process design improvements. Results of studies on high grade chalcopyrite material is presented in this paper which show that although a surface deposit was formed, it did not result in the passivation of chalcopyrite in ammoniacal solutions, and that while oxygen transfer is critical, it is not the direct oxidant in the reaction. INTRODUCTION Ammonia and its salts have been used in the hydrometallurgical treatment of non-ferrous metals such as copper, cobalt and nickel from oxide ores. Its chemistry allows for the selective dissolution of desired metals, leaving behind gangue including iron. Chalcopyrite is a copper sulphide ore known to be very stable and hence recalcitrant to many hydrometallurgical processing methods. Thus, the dissolution of chalcopyrite continues to be an attractive area of research. The dissolution of chalcopyrite in ammoniacal solutions is possible due to the stabilisation of copper(I) and copper (II) ions by ammonia in alkaline media. Ammonia has become more attractive as a lixiviant during the present socio-economic climate due to its low toxicity, relatively low cost and ease of regeneration by evaporation (Meng & Han, 1996). Ammonia processes are ideal when the gangue minerals are acid consuming e.g. with calcareous or dolomitic gangue (Paynter, 1973).

Jan 1, 2019