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By Qidong Zhang, Yongsheng Song, Wenjuan Li, Guiying Zhou, Kun Song

"Molybdenum is a very important rare mineral resources, which exists largely in oxidized ores and sulphide ores in nature. About 99% of metallic molybdenum comes from molybdenite. The talcose molybdenum resources are abundant but the resources utilization is low, because the talc is naturally hydrophobic and the floatability of talc is similar with molybdenite, which lead to difficult separation by flotation. Talc is easy entry into concentrate in flotation which can cause the content of MgO overhigh, therefore the molybdenum concentrate grade can not meet the industrial requirements. Thus the utilization level of talcose molybdenum resources has been restricted greatly.The adsorption of water on talc and molybdenite surfaces and natural floatability of minerals were studied by density functional theory method. The results showed that molybdenite and talc were layered minerals which exhibited similar surface wettability and H2O molecule prefers to stay with water rather than the minerals surfaces. N2 is adsorbed on talc and molybdenite surfaces more easily than H2O. The interaction and flotation behavior were studied by SEM and flotation experiments. The reason why talc interferes with the flotation molybdenite has been revealed. The agglomeration between molybenite and talc was caused easily in neutral or acidity solution, and it was dispersing between molybenite and talc particles in alkaline solution. The flotation results showed that good floatability of talc was the key factor causing a low grade of concentrate in alkaline solution. Thus, it is the key factor to enlarge floatability difference between molybdenite and talc.INTRODUCTIONMolybdenum is a kind of important rare metal and strategic reserve resources (Zhitao Y et al, 2016a). Due to excellent characteristic, such as high melting point, good thermal property and et al, it’s widely used in metallurgy, machinery, chemical, aerospace, and many other areas. It has become an indispensable metal in modern industry. Molybdenum generally exist in the form of molybdenite which is a kind of mineral with excellent natural floatability. Talc is a kind of typical hydrous and layered magnesium silicate minerals (Beattie D et al,2006a), which is one of the most common gangue mineral of the platinum group metal ores and metal sulfide ores (Tao L et al,2011). Due to its good native floatability, talc is easy entry into the concentrate product with foam in the process of sulfide ore flotation (Kelebek S and Smith S, 2006b), which resulted in decreasing concentrate indexes. Not on that, the high-content MgO of concentrate will also produce a series of adverse impact to the subsequent smelting (Lotter N O et al, 2008). Therefore, it is difficult to separate talc from sulfide ore concentrate effectively."

Jan 1, 2018

By E. Hulthén

Cone crushers are used in the mineral, mining, and aggregate industry for fragmentation of rock materials. Control systems for cone crusher settings are widely used to compensate for wear and to protect the machines. The eccentric speed in a cone crusher affects the number of compressions the material is exposed to and thus the particle size distribution of the product. Eccentric speed also affects crusher capacity. However, the speed of the crusher is mostly fixed, because speed changes must be made by shifting pulleys, a process which is quite time-consuming. By applying a frequency converter, which has decreased in cost during recent years, it has become possible to adjust the speed continuously. By also applying mass-flow sensors to the process, the crusher can be run optimally to yield the most sellable products in a given moment. Existing systems normally only protect the machine. The sensors can be mass-flow meters, e.g., conveyor-belt scales. To analyze data from the process and calculate the appropriate value for the speed, an algorithm has been developed. The developed algorithm was tested and evolved at a crushing plant for aggregates that produces around 350 kton a year. The algorithm was implemented in a computer that could communicate with the frequency controller, retrieve data from four mass-flow meters, and also interact with the opera-tor. The computer was reachable over the Internet for the researchers at Chalmers and the algorithm was tuned and improved on-line. The result is a crushing stage that consistently and maximally produces the most desirable product. The performance (yield of required products) increased by 4%. As a bonus, the lifetime of the mantles increased 27% on the evaluated crusher.

Jan 1, 2014

By M. Kargar Razi

According to the unique properties and many applications of nano silver powder, it was prepared from acid leaching tail solution. The low value residual gold and silver ions were occurred with fellow heavy metals as pollutants (Fe2+, Cu 2+and Zn2+) in acid leaching tail solution in Mouteh gold mine in Iran. Preparation of nano silver particles was achieved in two steps: first, by addition of ammonia as separation step and second by using different reagents as precipitation and extraction steps. Different controlled parameters were including pH, residence time and temperature, mixing time, and reducing reagents to metals molar ratio. Acid leaching process was carried out with sulphuric and nitric acid via suitable reductants. In order to remove copper, zinc, and silver ions from solution, all of the conditions were controlled. The optimum conditions for preparation of nano silver powder with less than 90 nm were pH 10.5, hydrazine/methanol to silver molar ratio of 3 to 4, and reduction time of 5 min in 45 °C. The results were evaluated via SEM, A.A and UV- Vis spectroscopy analytical methods.

Jan 1, 2014

By Lilong Huang, Yuan Long, Li Shi, Guowang Zhang, Xiao Xiao

"Graphite is the key raw material of new carbon materials such as graphene and spherical graphite. The size and completeness of graphite flakes directly affect the performance of new carbonaceous materials.The research aims to increase the yield of large flake graphite by way of preventing the flake graphite from being damaged during the grinding process. A series of grinding and flotation studies on the flake graphite samples of Yichang in Hubei Province were carried out by vertical stirred mill . The damage coefficient L characterising the degree of graphite flake fractured and corresponding formula was proposed to determine the quality of the grinding and grinding of the flake graphite. The way the damage coefficient L of graphite flake would be affected if with different mill, different media material and size, stirrer speed were investigated. The test results show that vertical screw stirred mill helps the protection of large flake of graphite as well as the graphite liberation. When grinding to the same fineness, the damage coefficient L of graphite flake is 1.20 for vertical stirred mill, while the damage coefficient is 2.93 for ball mill. Minimum damage coefficient of graphite flake was obtained when using 6 mm polyurethane coated ball as grinding media, under the condition that rotation speed of the stirrer within the range of 100~130r/min. The grade of graphite in the concentrate floated from the ground product was 94.16%, the rate of recovery for graphite was 94.66%, and the content of +0.15mm was 54.83%.1 INTRODUCTION Flake graphite is a very important non-metallic mineral[1,2],and due to its special flake structure, the greater the scale and the higher the C grade, the value of its application is larger too. Therefore, in the grinding of graphite sorting process, We should minimize the destruction of graphite scales.. In this paper, graphite mine in Yichang, Hubei Province was used as the raw material for the study. Rough concentrate with C-grade of 36.49% was prepared by rough grinding and coarse separation. Then a series of grinding and flotation studies on the rough concentrate were carried out by vertical stirred mill , which aims to increase the yield of large flake graphite and to provide technical support for improving the beneficiation process of graphite ore."

Jan 1, 2018

By Osvaldo A. Bascur

One of the most vigorous of the continuous improvement methodologies is Six Sigma. While usually associated with improving manufacturing and product quality, leading manufacturers are using it to improve their extended supply chain and logistics capabilities. At the same time they are improving reliability, some companies have cut hundreds of millions of dollars of fat out of their supply chain. Mine to Mill optimization is a transformation of culture from processing tons to processing a quality feed size distribution which reduces the overall operational costs and add the highest value to the mine. This is not a constant endeavor. As such, a dynamic performance monitoring and diagnosis is necessary. We will review a systemic way to performance improvements and avoiding metal losses from the blast to the metals. We show the requirements of using raw data to analysis the data to define operational maps which provide assistance to run the mine and mill. A case study is provided with the mine and mill data was integrated combining process control and quality information resulting in reduction of water and energy consumption while improving the overall value of the mine. The results of reengineering the current system with this SIX SIGMA Strategy had the following results: an increase of ore milling: 4.6% decrease of mil power: 3.9%, decrease of fresh water consumption: 6.8%, with a total of net profits: US$ 31.8 million, the PI System infrastructure contribution: US$ 7.95 million. These estimates were for the period 2009/04/04 to 2009/12/31.

Sep 1, 2012

By Derek Caizergues, Hurman Eric

The principle of carbothermic reduction has been around for many years. In principle it is a simple process, yet with a multitude of problems. The temperature required to affect reduction is in the region of 2200ºC and results in aluminium oxy-carbide formation rather than metallic aluminium. From a thermodynamic point of view, reducing the temperatures of reaction which would suppress oxy-carbide formation would only be possible by lowering the total pressure of the system. A decrease in thermodynamic activity of product aluminium by dissolving it in another phase would also help preventing the formation of oxy-carbides and would also increase the yield of the reduction reaction. Thus experiments have been conducted at around 1700ºC to determine the possibility of carbothermic reduction of alumina under the presence of a metallic solvent. Total pressure of the system was reduced to around 30kPa and metallic nickel, iron, copper and tin were selected as the solvent. The highest recovery of aluminium was achieved with the nickel solvent followed by iron, copper and tin. This ranking for the first three was also in accord with the extent of negative deviation form ideality in the respective binary solutions of these solvents with aluminium. The tin-aluminium system displays positive deviation form ideality. The rate and extent of reduction was found to be highly dependent on temperature and pressure. The pseudo first order reaction rate was found to be applicable to the process in all the solvents used. Rate constants were calculated and it is also suggested that the reduction was controlled primarily by the chemical reaction rate.

Jan 1, 2003

By Y. E. Brylyakov, M. A. Kostrova

"The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. In this connection, the magnitude of cation exchange, along with the content of P2O5 and CO2, is an important property of apatite staffelite ore, which largely determines the performance of concentration processes. In the examined ASO samples, the magnitude of cation exchange measured in terms of Ca2+ is 2546-4790 g/ton. The conducted laboratory studies of apatite staffelite ores with various mineral composition showed that adding calcined soda improves the recovery of P2O5 into the flotation concentrate. Full-scale tests were conducted at the apatite staffelite ore processing plant at Kovdor Mining and Concentration Operation and demonstrated the high performance of the proposed agent treatment. The test results showed that in the flotation of apatite staffelite ores, the optimum calcined soda feed rates range from 3,500 to 5,000 g/ton of the flotation feed. With close flotation feed and concentrate grade parameters, the P2O5 recovery gain is 17%. The effect of adding soda is associated with the desorption of the hardness cations from the minerals, precipitation in the pulp and, accordingly, improvement in the ionic composition of the liquid phase of the flotation feed due to a reduced content of calcium ions. Based on the test results, the proposed agent treatment with an elevated feed rate of calcined soda was implemented at Kovdor Mining and Concentration Operation in the flotation of apatite staffelite ore. The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. These minerals have certain properties requiring a more detailed examination for a better understanding of the flotation properties of apatite staffelite ores."

Jan 1, 2018

By M. Tang

The phosphate ore sample was taken from the iron tailings after recovering most of magnetite by magnetic separation in Longlin, Yunnan Province of China. Batch flotation tests had been conducted to upgrade the phosphate concentrate by conventional fatty acids reagents under 70% -75 µm of the particle size; however, the unsatisfied results (P2O5 grade of 27.84% and recovery of 49.25%) were obtained. Also there are a large amount of slimes trapped in the concentrate and high-dosages consumption of reagents, for example, more than15 kg/t soda ash and 2 kg/t sodium silicate at only one-staged roughing. Based on the analysis of X-ray diffraction (XRD) for the sample, most of gangues are clay, quartz, and chlorite, which may easy to over-grind and deteriorate the flotation process either on reagents consumption or slurry fluidity or viscosity. A hydro-cyclone had been introduced to pre-concentrate the phosphate ore by scrubbing the slime before flotation, which can result obviously in reducing the dosages of soda ash from 15 Kg/t to 4 Kg/t, and raising the grade of P2O5 in the concentrate from 27.84% to 36.13% at the expense of about 4% recovery of P2O5. They also substantially reduced the time of sedimentation of concentrate after flotation from ~10 to ~1 min. In this paper, the effects on the recovery of P2O5 by the different dosages of flotation reagents with or without de-sliming were studied, with the objective of determining the different effects on the functions of flotation reagents by slime during flotation. Keywords: de-sliming, phosphate, soda ash, flotation

Sep 1, 2012

By L. A. Vaisberg

"Mining processing plants are the most high-performing industrial enterprises in the world economy system. Even at an average-scale mining enterprise, the grain-size separation equipment continuously processes 105 to 106 dissimilar mineral particles per hour. In separation by physical properties, their number increases by at least 10 to 50 times. Mathematical modeling of such a high flow of discrete particles is carried out using two different approaches: the discrete-particle and the phenomenological methods. The calculations demonstrate the possibility of handling big data when describing the processes of separation of granular material. INTRODUCTION The interest to the screening process and the process of formation of new screen designs in Mekhanobr is traditional since the moment of its foundation. It is symbolical that the first publication of the Mekhanobr proceedings in 1924 was the monograph dedicated to screens and screening products as such, which was the first one in the world at that moment. It was a book of Prof. L. B. Levenson, one of the founders of Mekhanobr, who headed the Technical Bureau of the Institute. Vibratory screening is the most mass process in the technologies of solid minerals processing, which determines significantly the energy demands of crushing and grinding cycles, and at some enterprises determines the quality of the final product, for example in case of crushed stone, coal or abrasive materials production. The general understanding and simulation of the process of poly-dispersed granular materials vibratory screening was developed at several conceptual levels taking into account the features of classification of materials with different size and density.Considering the real industrial processes of vibration screening, it shall be noted that at the sieve surface of the screen in the initial part of the deck the classification in a thick material layer (in natural conditions) occurs, which further transfers to a thin layer (free movement). In the process of screening of light minerals, for example coal or metallurgic feedstock, screening is mainly performed in the thick layer."

Jan 1, 2018

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By M. K. Aydogan

Today, arsenic has become a much greater problem than before because of the limitations introduced by WHO and USEPA that are lowered from 0.05 ppm to 0.01 ppm. In the nature Arsenic is mostly found as inorganic compounds in the forms of arsenite (As+3) and arsenate (As+5) in aqueous solutions. Arsenic contamination in ground and surface waters has been encountered in almost every country. This element has a carcinogenic effect and can occur in natural sources and anthropogenic sources such as metal mining, groundwater usage and industrial activities. In this study adsorbing colloid flotation was applied in the presence of aluminum sulfates. In the experiments SDS and K-Oleate were used as collectors while MIBC was the frother employed. The effects of collectors and aluminum/arsenic ratios on the removal of arsenic were examined under various pH values. It was found that arsenic removal enhanced with increasing aluminum concentration. Furthermore, it was observed that pH was a very critical parameter in all experiments. The best results were obtained when initial As: SDS: Al concentrations were 10:40:40 ppm at pH 5.5. At this concentration, the efficiency of arsenic removal found to be 99.9%. Keywords: arsenic, adsorbing colloid flotation, aluminum sulfate

Sep 1, 2012

By Kazutoshi Haga, Ryo Kawarabuki, Atsushi Shibayama, Masato Kosugi, Masanobu Kawata, Refilwe S. Magwaneng, Kohei Mitsuhashi, Altansukh Batnasan

"The recovery of copper and iron from carbonaceous sulfide ore is of economic and environmental interest despite its processing difficulty. Hydrometallurgical methods can be used to concentrate sulfide metals of these hard-to treat ores in a simple and eco-friendly manner. In this study, high pressure acid leaching process was comprehensively studied to dissolve metals from an ore with organic carbon and carbonaceous gangue material using autoclave equipment. The sample used for the experiment was reduced to an average particle size of 75 µm after undergoing flotation to reduce carbonaceous gangue minerals. A comparative study on two leaching reagents of sulfuric acid and iron sulfate and their dosage was used to observe dissolution of copper and iron. Other parameters of temperature (90-170 0C), solid-liquid ratio (1:10, 1:5, 1:3 and 1:1) were investigated through kinetic studies to access the influence of organic carbon and carbonaceous material on recovery of copper and iron. Materials balancing analysis was used to evaluate the efficiency of metal dissolution. The effects of parameters on leaching rate and concentration was demonstrated. Results obtained from the experiment indicated low concentrations of copper and iron in pregnant leached solutions, which was attributed to acid consumption by organic carbon and carbonaceous material in feed. However, the high efficiency rates of 92.4% and 86.3 % for copper and iron respectively in sulfuric acid can be concluded that leaching of concentrates of carbonaceous ore is possible provided system control on type of acid, pH and temperature. The purpose of this research is important in understanding mechanism involved in dissolution of copper and iron in concentrates of carbonaceous ore and marks an improvement in leaching of highly contaminated ores."

Jan 1, 2018

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

By M. L. Wu

A moderately thermophilic acidophiles strain had been isolated from the bio-heap leaching plant in Zijinshan Copper Mine, and the identification based on the PCR-16S rRNA gene sequence homology analysis with morphologic and physiologic methods was conducted by polyphasic taxono-my and phylogeny research. The results show that the strain by depurated belongs to Acidthiobacillus genus and is considered as Acidthiobacillus albertensis.

Jan 1, 2014

By Yuexin Han, Jie Liu, Shuai Yuan, Yanjun Li

"In order to improve recovery efficiency of iron minerals from iron ore tailings and to reduce its connected environmental pollution, this article investigated the reducing roasting of iron ore tailing in a laboratory fluidized magnetization roasting reactor to optimize the roasting method and conditions. The examined parameters included roasting temperature, roasting time and reducing atmosphere. The parameters evaluating magnetizing roast efficiency and theoretical value were determined. X-ray diffraction (XRD) analysis was used to investigate the conversion of iron phase after roasting. The results show that the best magnetizing roast conditions are roasting temperature of 540?, holding time of 15min, and CO concentration of 20%. The magnetization conversion ratio of roasting products is over 80%, under the best magnetic separation condition, the concentrate grade of iron is 65.61 % and the recovery of iron is 83.77 %. The XRD analysis shows that Fe exists in hematite and siderite before roasting and exists in magnetite after roasting. The technique not only recovers the iron minerals from tailings with good economic benefit, but also reduces the environmental pollution of tailings accumulation.INTRODUCTION Iron ore tailings are the solid wastes generated during the beneficiation process of iron ore concentration and are one of the main pollution concerns in the mining industry (Das et al., 1996). Continuous development of the iron and steel industry has led to the increasing amount of iron ore tailings; there are over 300 million tons of iron ore tailings discharged per year (Rao et al., 2016). The huge amount of stockpiled iron ore tailings brings a series of environmental and social problems. Comprehensive utilization of iron ore tailings can not only reduce environmental load but also conserve resources, promoting sustainable development of the society. In recent years, iron ore tailings as secondary resources have received considerable attention in many countries in the word and numbers of studies on utilization of iron ore tailings were carried out, such as recycling the valuable minerals (Datta et al., 1996; Jia et al., 2013; Panda et al., 2018), used in construction material compositions as alternative source of raw materials (Das et al., 2012; Zhou et al., 2012; Luo et al., 2016) and other utilization. The iron minerals were recovery by magnetization roasting (Rao et al., 2016; Yang et al., 2013; Yang et al., 2011) and flotation (Kumar and Mandre, 2016). By comparison the reduction roasting has more advantages, but it was found that the conventional roasting equipment was inefficient, high energy consumption and un-economically applied on an industrial-scale."

Jan 1, 2018

By H. G. Hedlund

Tailings in Mining Industry can be handled in different ways. Today tailings disposal is in focus by projecting new plants as well as treating and handling of old Tailings dams.The trend today is to process minerals, detoxify the Tailings and place them as dry surface Deposition or Underground Backfill. This paper will briefly present five different Mining plants in North and Central America, where Tailings have to be dewatered for dry depositing. The Metso-Sala VPA is a filter especially developed for dewatering and drying of Mineral Concentrate and Mineral Tailings. Keywords: tailings disposal, dewatering, drying, mineral tailings

Sep 1, 2012

By A. Vidyadhar

Using pure quartz and hematite minerals, the adsorption mechanism of mixed cationic/anionic reagent schemes was investigated through Hallimond flotation studies. The flotation response of quartz and hematite independently with cationic and anionic collectors as well as with mixed cationic/anionic collector systems is assessed. The flotation response as a function of pH and collector concentration was investigated. The single mineral flotation tests in the presence of anionic collectors, quartz does not respond to flotation, but the C12 amine flotation of quartz was observed to be pH and concentration dependent. It was observed that hematite flotation recovery is maximum at acidic pH with sodium dodecyl sulphate (SDS), neutral pH with oleate, and at basic pH about 9.5 with C12 amine. Flotation results with both quartz and hematite indicate an increased adsorption of cationic collector in the presence of anionic collector apart from its own co-adsorption. The incorporation of oleate in between C12 amine molecules decreases the electrostatic head-head repulsion and thereby increasing the adsorption of C12 amine due to attractive tail-tail hydrophobic bonds, besides forming a closely packed adsorbed layer enhancing the hydrophobicity. The increase in oleate concentration beyond C12 amine concentration leads to the formation of soluble C12 amine-oleate complex / precipitate and the adsorption of these species decreased the flotation since the alkyl chains are in chaotical orientation with a conceivable number of head groups directing towards the solution phase. Keywords: quartz, hematite, adsorption, mixed collector system, flotation, zeta-potential

Sep 1, 2012

By R. K. Rath

The low-grade iron ore sample contains both lumps and fines. It is mostly hematitic iron ore and considerable amount of goethitic/limonitic material is present in it. The major impurities present were quartz and clay. It is observed that the iron bearing phases are poorly liberated above 300 µm and the liberation improves below 300 µm. More than 80% liberation is achieved below 106 µm. Based on the liberation data, the feed for the different beneficiation methods was prepared by stage crushed the ROM followed by grinding passing to 106µm and the ground material (-106µm) was deslimed. The underflow was subjected to various beneficiation techniques such as tabling, enhanced gravity separator (EGS), wet high intensity magnetic separation (WHIMS), and flotation and the results are discussed. All the methods studied could able to produce pellet grade concentrate with iron content of 64.5%, however, a marginal higher yield was observed for WHIMS (81%). Keywords: beneficiation, gravity, magnetic, enhanced gravity separation, flotation, low-grade iron ore, desliming

Sep 1, 2012

By Matheus Tocchini, Henrique Kahn, Juliana Antoniassi, Carina Ulsen, Eldon Masini

"Sand and gravel are the second and third largest minerals in production in Brazil, and this is increasing noticeably. The extraction of natural sand from river beds is increasingly restricted and most of the sand used in large cities comes in from more than 150 km away, resulting in high transportation costs. As a result, it has become more common to use crushed rock as artificial sand. The main difficulties in this process are controlling the shape of the particles and the content of deleterious materials, such as mica. Within this situation, this paper presents an alternative to using artificial sand for concrete use. Our procedure involves the following steps: a) sampling sand from different production days, b) characterizing the bulk sample by particle size and shape distribution, chemical composition by X ray fluorescence and mineralogical composition by X ray diffraction, c) removing fine grains by air classifier, d) performing intensive attrition with high pressure washing and e) characterizing products. The results demonstrated that this sample contains a huge proportion of fine grains and a notable content of mica, which is distributed along all sieve fractions. The presence of mica makes the use of sand in concrete unfeasible, moreover scanning electron microscopy analysis demonstrated that this phylossilicate is finely grained and associated with coarse fractions. Thus, the removal of fine fractions made possible a partial reduction in mica content. Furthermore, intensive attrition demonstrated that the procedure was efficient to remove most of the mica while also reducing sharp edges, which improved the shape of these particles."

Jan 1, 2014

By Y. H. Zhang

Mechanism of BK501 in desiliconization from bauxite was studied by use of flotation test, EDS, ?-potential, FTIR. Results of flotation show that almost all of diaspore can be depressed when BK501 is put into pulp ranging from pH 4~12, in the meanwhile kaolinite is slightly activated. In the light of surface analyses, it is concluded that the adsorption of reagent on the diaspore is dominant by chemical interaction. Moreover, kaolinite may float more by addition of BK501 because of flocculation.

Jan 1, 2014