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By I. J. Brown

Paper prepared for presentation at Industrial minerals and the environment, held in Leeds, 24-35 September 1990. The need to submit an environmental statement (EIS) has certainly increased the workload of those concerned with both its production and assessment. However, there is now good evidence that the system is enhancing public confidence in the minerals industry in particular and improving relationships between the developer, planning authority and those consulted such as statutory bodies, parish councils, civic societies, nature conservation interests and ramblers

Jan 1, 1991

By A. R. Naderian

Laboratory strength and deformation testing of freshly blasted sandstone and claystone overburden from Jeebropilly colliery in Queensland and in-situ plate-bearing tests on four backfills of different ages showed that the bearing capacity of backfill is a function mainly of compaction, not of age. The modulus or stiffness of the backfill is significantly increased by previous loading, in some cases up to threefold. Backfill material experiences some compaction through the passage of mining vehicles, likely to provide a bearing capacity that will support normal construction activities; the limited testing performed suggested that completed backfills are capable of supporting loads of up to 200 kN/m2 while sustaining displacements acceptable for a wide range of residential and industrial uses, but may be susceptible to collapse settlements due to saturation in the long term

Jun 19, 1905

By R. C. Courtney, D. J. Forrester

Modern advances have led to sweep and multibeam bathymetric surveying techniques that yield three-dimensional images of the sea floor and have also produced high-powered personal computers with which to control the data and analyse the results. At Sydney, in Nova Scotia, the topography of the sea floor over the longwall workings was observed before and after mining with a precision echo-sounder in 1987-89, with sweep bathymetry in 1993 and with multibeam bathymetry in 1994-95. The results of the latter programme produced what was probably the first observation of a complete three-dimensional subsidence trough over a longwall panel 2 500 m x 168 m. The subsidence has been quantified to a sufficient degree of accuracy to allow simple trend analysis, which has shown that the pattern and shape of movements are similar to those found elsewhere but with significantly smaller maximum subsidence. A prediction model has been calibrated

Jun 19, 1905

By B. M. England, C. Y. Yang, L. T. Matthews, J. Y. Yin

The domestic concentrate used by the Shanghai Meishan Metallurgical Corporation in Nanjing contains significant siderite, magnetite and haematite, the siderite having a substantial influence on its sintering behaviour. On the basis of experimental findings and published information it is proposed that siderite decomposition starts at c.400 degrees C and results in the formation of CO and/or H2, which then reduces the haematite to magnetite prior to the initiation of high-temperature sintering; inter-mixed particles of Australian haematite and pisolite ores also undergo significant reduction. As the gaseous reduction process is so effective, low-temperature forms of silico-ferrite of Ca and Al (SFCA) cannot form even at high sinter basicity. The bench-scale results were confirmed in a pilot-scale facility whose sinters consisted mainly of magnetite, high-temperature SFCA and glass, which is typical of sinters formed from mixes with high magnetite levels

Aug 1, 1995

By J. L. Robson, C. M. Bristow

mass flow rates of particles and air (the loading ratio).

Dec 1, 1994

By E Oktay, I Yusufoglu, C Kahruman

Powder and spherical pellets of MoO2 were oxidised under controlled conditions in the temperature range 674-791 K at oxygen partial pressures of 8.1-30.4 kPa. Weight increase during the reaction was determined by thermogravimetric analysis. It was concluded that the reaction is 0.6th order with respect to oxygen concentation and that the activation energy is 148 kJ/mole. In experiments conducted with powder, fast transfer of reaction heat to the gas phase created isothermal conditions, but the temperature of pellets rose by a maximum of 54 K at 674 K and 105 K at 791 K. The rise in temperature caused structural changes such as sintering and crack formation, which had a considerable effect on the reaction rate. The findings should be taken into account in the design of equipment and choice of operating conditions for roasting MoS2

Jun 21, 1905

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By R. G. Kidel, S. C. Doming

The project has shown that it is feasible for a junior company to reopen a narrow vein-style gold mine and successfully take it into production. An intimate understanding of the mineralisation and a flexible approach to mining are crucial, as are stringent cost control and efforts to keep overheads low. The project has confirmed the geological complexity of the Main Lodes, which consist of highly sheared quartz-sulphide infill in strongly sericitised granodiorite. The existence of discrete high-grade zones within the Hangingwall Lodes has also been confirmed. Broad low-grade zones continue to be recognised and require the local application of bulk longhole mining methods. The initial mine plan called for predominantly longhole stoping, but adverse ground conditions have meant that a switch to air-leg mining has produced higher run-of-mine grades. The excess capacity at the processing plant can best be used by batch processing, with its reduced maintenance requirements

Jun 21, 1905

By A. R. Biggart

Twenty-sixth Sir Julius Wernher memorial lecture, presented at the Tunnelling '94 symposium held in London, 5-7 July 1994. In describing 18 projects with which he has been involved over a period of 36 years, the author aims to illustrate how technological change and an increase in scientific knowledge have influenced tunnelling practice, which he nevertheless maintains does continue to be an art. Tunnels discussed are: the Silver Street, Blackfriars, Whitechapel, St. Paul's and Waterloo Post Office tunnels, 1958-1969; metro tunnels on the Victoria Line, London, 1962-1970; the introduction of tunnel boring machines (TBMs), 1971-1978, in the Empingham reservoir diversion tunnels in Rutland, the bentonite tunnelling machine experiment at New Cross, the Southern tunnel water main section of the London Ring Main and the Warrington sewer in Cheshire; tunnels in rock 1975-1981, for the Lune Wyre and Megget Manor aquaducts, Weymouth sea outfall and Bristol interceptor sewer; Priestley TBM tunnels 1969-1982; the Greater Cairo wastewater project 1983-1987; Anacostia River crossing, Washington DC 1985-1987; the Channel Tunnel 1987-1992; and the Storebaelt eastern tunnel in Denmark, 1992-1994.

Dec 1, 1994

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

By Bakker J. de, P. A. Leest, W. L. Dalmijn, H. J. Glass

The test facility at the Delft University of Technology, in the Netherlands, was characterised. Advantages include the possibility of separating particles with high but different densities up to 9 g/cm3, the ease of adjustment to any required separation density and the absence of moving parts. Simultaneous separation of more than two types of particles is possible and the magnetic fluid is safe and convenient to use compared with other heavy liquids. Disadvantages include loss of magnetic fluid with outgoing particles (cost approx US $10/l) and degeneration of fluid due to bacterial activity, reaction with particles and with surroundings. Only non-magnetic materials can be separated, there is limited potential for scaling up and high investment is required on account of the cost of magnets. Future improvements in the design of the apparatus and the properties of the magnetic fluids can only enhance its attractiveness for commercial applications

Jun 18, 1905

By P. A. Rossouw, G. A. Fourie

Several attempts have been made over the latter half of the twentieth century to devise a system for the classification of underground mining methods. None of these are found to be totally successful. A revised classification is suggested with three main categories being identified by reference to fill requirements, steep stopes and stratified geological environments. Methods always needing lasting mass or structure fill include methods with timber-structured stopes and those with mass-filled (or cut-and-fill) stopes. Methods associated with steep stopes are subdivided into steep-stope-specific caving and steep-stope-specific non-caving (or self-supporting) methods. Methods not in the first two categories, often used in stratified geological situations, are not necessarily restricted to stratified environments and include caving as well as non-caving varieties. This category is further divided into room-and-pillar mining, longwall and shortwall coal mining and the type of open stoping found in gold or platinum reefs comprising overhand, underhand and breast-stoping variations

Dec 1, 1996

By M. Bustillo, S. Ordonez

"Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The Mississippi Valley-type deposits occur in massive, homogeneous dolostones from which diagenesis has obliterated all primary sedimentary structures. The mineralisation forms irregular, lens-shaped stratabound bodies, mostly in the lower part of the dolostones. They are composed exclusively of sphalerite, galena, pyrite, marcasite and barite, with white sparry dolomite a common cementing phase. Mineral zoning can be recognised from pyrite and marcasite in the east to barite in the west. Sphalerite, the most common sulphide, occurs basically as colloform and banded crusts and galena as isolated cubic or skeletal crystals, mainly in the centre of the banded botryoidal sphalerite. The combined observations of the deposits' geology, geochemistry and ore petrology suggest a three-stage genetic model: carbonate sedimentation in a shallow-water environment; dolomitisation, probably after compaction, by fluids of connate origin and lateral evolution; and mineralisation by migrating solutions, perhaps related to oil-field brines, that originated in deep zones of the basin during diagenesis of the basinal mudrocks in the NE"

Apr 1, 1995

By T. Ogasawara, J. P. Barbosa, A. J. Monhemius, F. T. Da Silvia

A thermodynamic analysis of the sulphation of rare-earth phosphates and the water-leaching of rare-earth sulphates was used to guide experimental work on the sulphation and leaching of concentrates from Pitinga. It was concluded that the sulphuric acid digestion of xenotime is technically feasible and could be used industrially to produce yttrium and other rare-earth oxides. Yttrium extractions of more than 90% were obtained by digestion at 503 K for 4 h at an acid:concentrate ratio of 2:1 with particle size -0.053 mm. The apparent activation energy at temperatures less than 473 K, as determined from the Arrhenius plot, was 11.0 kJ/mol, indicating that the reaction is controlled by the diffusion of the reactants or products through the sulphate layer

Jun 19, 1905

By H. R. Thorpe

A floating gold dredge operating in coarse alluvial gravels of the Grey River on the west coast of the South Island, New Zealand, generated high concentrations of clay and colloidal particles in the dredge pond, which entered the groundwater system. Sampling was carried out at depths down to 20 m and it was found that variation of the length of the flow path occurred because of the movement of the dredge towards the piezometers. The alluvial gravels, the suspended sediments, the groundwater system and the water chemistry were all studied. Sediment concentrations were found to be highly variable with depth, but the relative concentrations in the depth profile were generally consistent as the flow distance shortened. The sediments were extremely fine and travelled further through the gravels than predicted. Comparison of field results with the available theory of deep filtration in clean beds of porous media gives some basis for estimating the behaviour of fine sediments in other alluvial systems

Jun 19, 1905

By Jinsheng Chen, S. S. Peng

The relationship between support performance parameters and parameters representative of mining and roof conditions is characterised by uncertainty, non-linearity and dependence, so the theory of artificial neural networks was selected as a basis for shield design. A computer program based on a back-propagation training algorithm was written to derive the weighting factors between inputs and outputs from field data; once these had been established two mathematical models were developed to describe the relationship. Back-calculation of field data indicates that the results generated from the neural network models are much more accurate than those derived by traditional methods and can be used with a higher level of confidence. The support density, possible yield frequency of face supports and interval of periodic roof weighting under specific mining and roof conditions can be determined by application of the models

Jun 21, 1905

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By S. G. Ozkan

An investigation was carried out into the effect of physical parameters, such as particle size of the sample, residence time, solid/liquid ratio and impeller speed in the flotation cell, on the solubility in soft tap-water of colemanite (calcium-bearing borate) from Emet, in Turkey. Solubility increased steadily with residence time from 5 to 20 min but only minimally thereafter. There was a similar increase with impeller speed from 500 to 1 500 rev/min, beyond which a solubility of around 1.05 g/l was again established. There was a slight decline in solubility as the solid/liquid ratio was increased from 1 to 30%, with stable values around 1.05 g/l at a 20% ratio, while a sharp decrease was observed with decrease in size down to the -20 micrometre fraction. The effect of solubility should be taken into account if the application of a wet-processing method is being considered for the ore, while it can also result in losses of material during handling and storage

Jun 21, 1905

By G. G. Barbante

The oxidation behaviour of selenide matte with a substantial Cu content and low Ag differs significantly from that of high-Ag matte. Low-Ag selenide mattes display a large oxygen solubility and the upper boundary of the miscibility gap in the Ag-Cu-Se-O system is depressed to quite low Se contents. As a result, the formation of Ag metal is considerably delayed. The oxidised selenide matte, low in Se and with a relatively high oxygen content, has previously been termed oxymelt. With further oxidation, its composition enters the misciblity gap and crude Ag is formed. The sodium silicate slag captures very little of the SeO2 and the dissolved Ag2O(s) content of the slag is relatively small, with a Raoultian activity coefficient of 0.57. This value was found to be independent of the slag's Cu2O content

Jun 19, 1905

By A. H. G. Mitchell

Most, if not all, of the six recognised post-Cretaceous, predominantly andesitic mineralised belts in the region are now thought to be subduction-related magmatic arcs. The Inner Carpathian arc and the Eastern Bosnia or Drina-Rhodope arc host numerous vein and replacement deposits with epithermal features and Zn-Pb+/-Ag as the predominant economic minerals. In contrast, the south Apuseni Mountains have produced over 1 600 t Au from epithermal veins but very little Zn-Pb. Recent age determinations and geophysical data from the Baia Mare district of the Inner Carpathians suggest that mineralisation succeeded volcanism by 1-2 m.y. and accompanied crustal extension and the cooling of a large, mushroom-shaped pluton whose boundaries define the mineral district. In the south Apuseni district, mineralisation can be explained by mixing of meteoric with low-salinity metamorphic water expelled during intrusion of mafic rocks into the middle or lower crust. The more continental or cratonic crust in the Drina-Rhodope and Inner Carpathian arcs precluded the input of low-salinity, Au-bearing metamorphic water; the Zn-Pb deposits formed where convecting meteoric water mixed with saline water, possibly introduced through carbonate rocks in the basement

Aug 1, 1996