Search Documents

By R. F. Stewart

A key step in changing coals to fluid fuels and chemicals is the conversion of coal to synthesis gas by gasification with steam and oxygen. As oxygen represents one of the largest single expenses in gasification, its cost is a vital factor in the economy of the process. At present, the most economical method for producing tonnage oxygen is by the conventional rectification of liquefied air. Several alternate methods have been proposed for producing oxygen from air: (1) methods based on physical or chemical sorption of oxygen from air by liquids or solids or (2) the oxidation of certain inorganic com-pounds to higher oxides unstable at higher temperature levels. Economic limitations are discussed by which these methods may be evaluated. Chelated metals of the salcomine type are promising chemical sorbents of oxygen from air. This report covers a study of the reversible sorption of oxygen by salcomine and other chelates. The presence of water in the salcomine structure was verified; it is the loss of this water that causes slow deterioration of salcomine during cycling.

Jan 1, 1959

By William M. Thornton

[Owing to the comparatively high freezing point of nitroglycerin (14, 15, 16, 17, 18, 23, 37, 38)3/ - 1.9° C. and 13.0° C. for the labile and stabile modifications, respectively, as determined by Hibbert (16) - manufacturers of dynamites have incorporated into the liquid portion of these composite explosives various substances capable of participating in an explosion, to depress the above-mentioned freezing point. Aromatic nitro-compounds, chiefly nitrobenzenes, nitrotoluenes, and nitronaphthalenes, have been used to a considerable extent (11), but such nitrosubstitution products have not proved altogether satisfactory, as has been shown clearly by Naoúm. (14). Consequently there has been a strong tendency in recent years to replace them with one or more of several nitric esters, among which the following (29, 35) have been prominent: Dinitrochlorhydrin (monochlorhydrin dinitrate); nitrosugars, for example, sucrose octanitrate (19); tetranitrodiglycerin (diglycerin tetranitrate); nitroglycol (ethyleneglycol dinitrate); and diethyleneglycol dinitrate (13, 46, 47). Of these, nitroglycol (33, 4l, 45, 48, 49, 65) is outstanding in importance. As the Bureau of fines is naturally interested in the analytical chemistry of the "explosive oils," it seemed desirable to bring together in this report the widely scattered experimental work covering the problem of differentiation that has appeared in various chemical and physicochemical publications.]

Jan 1, 1941

By Joan C. Biordi

A molecular beam-mass spectrometer-low pressure flat flame apparatus has been constructed for the purpose of examining the chemical microstructure of normal methane-oxygen-argon flames and those inhibited with Halon extinguishants. Details of construction and performance of this apparatus and of related flame temperature measurements are given. Particular attention is paid to the empirical characterization of the perturbation to the flame caused by the sampling probes. The composition profiles obtained for normal flames are compared to those of flames inhibited by CF3Br. In addition to the usual stable species (CH4, O2, CO, CO2, H2O, H2, and H2CO), the inhibitor, its products and intermediates associated with its reactions could be followed. In particular, hydrogen bromide, bromine atoms, hydrogen fluoride, and carbonyl fluoride were observed. The relatively rapid disappearance of inhibitor and early appearance of fluorinated reaction products suggest a short lifetime for the CF3 radical in this system. Observation of COF2 suggests that CF3Br is effective as an inhibitor, at least in part, by virtue of its interference with the oxygen containing species of the normal chain reaction. Profiles of the 17+ peak at low electron energy suggests that the hydroxyl radical may also be sampled, but the profiles obtained are not yet sufficiently accurate to determine the effect of inhibitor on this important flame radical.

Jan 1, 1973

This summary of State laws on explosives wag compiled primarily to ascertain what subjects relating to their control have been acted upon by each State legislature and, in general, how they have been treated. It does not Include any legislation passed after 1942, or any proclamations, regulations, or administrative orders. It does not purport or attempt to be authoritative. If any problem arises involving interpretation of the statutes of any particular State, the original source must be consulted for the exact words used by the legislature. This summary, however, will be useful in determining whether relevant statutes exist, and in locating them quickly, with a minimum of effort. It will be of value also in comparing statutes in other States to determine what construction has been placed upon them by the courts of these jurisdictions or to contrast the varying provisions of many States upon a similar subject. To make these comparisons easier, the statutory provisions for each State have been grouped under several major topics in outline form. Although this sometimes has resulted in disruption of the continuity of individual acts, the increased general clarity and availability of comparable sections have more than justified the procedure followed.

Jan 1, 1943

By William L. Crentz

Pike County in the easternmost portion of Kentucky is one of the major coal-producing areas in the eastern Kentucky coal field. The county contains numerous coal beds, many of which are too thin to support mining. The commercially important beds are usually 4 feet or more thick, but selective mining at some places calls for removal of a much thinner section of the bed. The variation in quality of the beds from place to place and the large number of coal beds make correlation uncertain. Samples were collected from 14 different coal beds, of which the Elkhorn group is by far the most important. In addition to the Upper Elkhorn No. 3, Upper Elkhorn No. 2, Upper Elkhorn No. 1, and Lower Elkhorn beds that comprise the Elkhorn group, the Winifrede, Williamson, and Bingham beds constitute the principal coal deposits in Pike County.

Jan 1, 1952

By S. S. Peng

Successful longwall mining requires a good roof control. A good roof control implies that: (1) no excessive pressure is build up in the face powered supports, and (2) chain pillars are designed in such a way that panel entries are well protected and interactions between adjacent panels are minimized. A clear understanding of strata behavior around longwall panels due to face movement is, therefore, the foremost requirement for achieving better roof control. This dissertation is designed to analyze the effects of strata behavior on longwall panels due to the mining activities. The following topics are studied: (1) the weighting, phenomena and their effects on front abutments, and (2) the chain pillar stability and pillar design under various roof conditions. Three dimensional finite element analysis was employed. The effect of parameters such as overburden depth, mechanical properties of the immediate roof and main roof, panel width, and size of chain pillar on (t) and (2) were analyzed. Four typical models were utilized to simulate various phases of panel extraction under various combinations of the above parameters; model one is to simulate the beginning of panel mining; model two is to simulate the situation that longwall face has passed more than half of panel length; model three is to simulate the completion of panel production; and model four is to simulate the second panel mining. The following formulae have been developed by applying multiple regression model to analyze the finite clement results: (1) a formula that classifies the type of root strata at the face area. (2) formulae that predict the first weighting and periodic weighting lengths. (3) a formula for design of the chain pillar size. Case studies were performed to check the validity of the formulae proposed. Comparison of the formulae proposed for the chain pillar design with other formulae were also performed.

Jan 1, 1984

By D. J. Parker

In attempting to discuss a subject of this character it should be clearly understood at the outset that the purpose is not to emphasize the mere fact of occurrence of such catastrophes, the memory of which time has largely relegated to oblivion, but rather to stress the means of their prevention, available not only subsequent to but also at the time of occurrence. A careful, conscientious, unbiased study of the causes of mine explosions leads inevitably and definitely to the conclusion that the human element is the most important factor. The human factor should however, be evaluated in terms of responsibility--responsibility on the part of the employer to recognize the existing hazards and take the necessary remedial action, and on the part of the employee to perform his duties faithfully, diligently, scrupulously, and in strict conformity with State mining laws and company rules or other regulations.

Jan 1, 1933

By Nancy Estrada, Jane Nowell, Cathy Jennings, Debra Yniguez, Carol Lavery, Kristin Harrer

Pilots of the MH-60S helicopter are exposed to continuous whole body vibration (WBV). Pilot fatigue is a growing operational concern due to the increased frequency of extended durations of missions (6-8+hours) in support of Operations Iraqi Freedom and Enduring Freedom. Endurance aspects of the currently used rotary wing seating systems were not optimized for the longer missions and wide range of pilot anthropometric measurements, which is now typical of naval aviation. The current seating systems were designed primarily to meet crashworthiness requirements, not for the wide range of pilot anthropometry or to mitigate WBV. Albeit, an issue, pilot fatigue and reduced mission effectiveness are also critical concerns. Current Hazard Reports indicated that pain in pilots’ legs and backs begin two to four hours into the flight and increase with time. Mission readiness also decreases with an increase in flight duration due to the constant distraction of pilots shifting in their seats while trying to get comfortable. Froom, et al [2] reported a dose-response relationship between the length of military helicopter flights and back discomfort. He also concluded that this pain is typically dull, over the lower back, and its prevalence and intensity are dependent on the total flight hours of exposure. Methods This study evaluated WBV produced in the pilot seating systems onboard the MH-60S. The purpose of the study was to test and compare the effectiveness of two different seat cushions, the current seat cushion versus an anti-vibration seat cushion. Both seat cushions were measured for acceleration levels averaged over five-minute intervals using a triaxial seat pad accelerometer. The recordings were completed for a 3-hour straight and level flight. A frequency analysis from 0-80 hertz (Hz) was conducted on all acceleration measurements to determine the dominant axis and frequency of the pilots’ vibration exposure. The results were then compared to the applicable Threshold Limit Values (TLVs) established by the American Conference of Governmental Industrial Hygienists (ACGIH) [1] and the International Organization for Standardization (ISO) 2631.1 [3] to determine the MH-60S pilots’ permissible exposure time for both seat cushions. Results The results of the study showed that for both seat cushions the vibration levels of the z-axis at 16 Hz had the shortest allowable exposure duration, according to the ACGIH TLVs. In the z-axis at 16 Hz, the MH-60S’s current seat cushion’s acceleration levels indicated an exposure time limit of approximately 6 hours, while the anti-vibration seat cushion’s acceleration levels pierced the 8-hour exposure time limit curve. This is shown in the graph below.

Jan 6, 2006

By W. R. Herrera

A research effort was conducted to present or develop methodology for evaluating candidate potting materials intended for use in explosion-proof enclosures. The primary purpose was to develop acceptance guidelines based on arc decomposition products. Acceptance criteria can be based on: ? Inherent thermo-chemophysical, mechanical and electrical properties; ? Arc decomposition products: ? Nature of volatile products produced, e.g., flammability, explosivity, synergistic effects on existing environment in the enclosure, toxicity; ? Quantity produced as a function of arc power and duration; ? Acceleration aging tests to evaluate breakdown under electrical stress.

Jan 1, 1982

By E. T. Bowers

Pneumatic conveying of coal underground is not widely used in the United States, although it is becoming increasingly popular in Great Britain, the Federal Republic of Germany, and South Africa. The question of safety has been raised repeatedly: Will the system be prone to dust or gas explosions, and, if so, can it withstand such occurrences safely? The work reported here was done under a Bureau of Mines contract and deals with the safety aspects of pneumatic transport of underground coal, as well as the hazards inherent in more conventional haulage systems. Included are three designs for different applications of pneumatic haulage: off-loading a continuous-mining machine on a room- and-pillar section, vertical hoisting through a 1,200-ft shaft, and off-loading a tunnel-boring machine driving a 2,000-ft tunnel.

Jan 1, 1985

By R. V. Higgins

This report presents computer instructions for calculating the performance of three-phase flow of gas, oil, and water. The calculated results for an illustrative example are presented. The example is the waterflood of a reservoir containing free gas in the reservoir as a result of the partial depletion of the oil by the expansion of the gas initially in solution. The flood pattern for the example is a 5-spot.

Jan 1, 1967

By John F. Papp

The objective of this U.S. Bureau of Mines study is to calculate an accurate, reliable estimate of chromium and nickel content of stainless and heat-resisting steel produced in the United States. The columbium, manganese, molybdenum, titanium, tungsten, and vanadium contents of this steel are also calculated. Such contents are required for estimating the quantity of alloying element recovered from recycled stainless steel and consumed by market sectors. In this investigation, the elemental fraction of stainless and heat-resisting steel was calculated as the ratio of the weight of element contained in stainless steel to the weight of stainless steel produced. The elemental fraction has been calculated as a time-averaged, grade-averaged value. The elemental fraction was averaged from 1962 through 1983, and averaged over the grades for which production was reported by the American Iron and Steel Institute during that time period. The 1962-83 average elemental fraction of U.S.-produced stainless and heat-resisting steel was calculated for chromium to be about 0.17 ± 0.01; columbium, 0.00014 ± 0.00003; manganese, 0.015 ± 0.005; molybdenum, 0.004 ± 0.001; nickel, 0.07 ± 0.01; silicon, 0.009 ± 0.001; titanium, 0.0004 ± 0.0001; tungsten, 0.0001±0.00003; and vanadium, 0.00003±0.0000l.

Jan 1, 1991

By Marvin W. Wilson

The Federal Bureau of Mines has conducted laboratory experiments simulating underground gasification of coal to study the feasibility and mechanism of the process and determine the chemical and physical characteristics of a coal-bed during gasification. Laboratory and small-scale field experiments also were made to investigate the properties of coal and other factors affecting the electrolinking-carbonization method of preparing a path through a coalbed before gasification. Laboratory experiments simulating underground gasification of coal: Experiments with a laboratory retort indicated that bituminous-coal deposits could be gasified in place to produce a combustible gas.

Jan 1, 1960

By E. C. Fitch

This report discusses fire-resistant hydraulic fluid safety from three different directions. First, results of a survey prepared for the Fire Resistant Hydraulics Journal by the staff of the Fluid Power Research Center are analyzed. Second, operational limitations of fire-resistant hydraulic fluids are examined. Finally, laws and standards of various foreign countries are investigated. Three conclusions are derived from a close study of fire-resistant hydraulic fluid safety from these three directions. First, a significant number of experts in the fluid power industry are no in agreement about aspects of fire-resistant hydraulic fluid fire-resistance and toxicity. This indicates a need for more in depth research. Second, the use of fire-resistant hydraulic fluids involves a compromise between the decreased fire hazards and increased toxicity and machine incompatibility problems. Finlly, major foreign governmental agencies have thorough laws and standards concerning fire-resistant hydraulic fluids. These laws and standards may provide a solid framework for further international research into fire-resistant hydraulic fluid safety.

Jan 1, 1979

By J. F. Neill, O&apos

[The Cartersville mining district is in Bartow County, Ga., about 40 miles northwest of Atlanta. Barite, limonite, ocher, amber, hematite, and, manganese oxide ores have been produced from the strict since about 1840. In the search for a possible source of manganese ore, Bureau of Mines engineers made a preliminary study of the district from September 1950 to January 1951. During this study 139 deposits were examined, and many mineral exposures were sampled. Manganese mineralization occurs as fine oxide and concretionary pellets in residual clays, as fine oxides in umberous clay, in brown-iron deposits, and in a limited quantity in mud ponds and Jig-tailing piles. The future supply of ferrograde manganese ore from the district, using current mining and benefication methods, appears limited to the recovery of the hard manganese ores deposits. Rough estimates indicate a reserve of manganese-bearing clays of about 8,000,000 long tons. This type of deposit has been extensively exploited and the larger deposits mined out to depths of from 50 to 200 feet. The remainder of these deposits are low grade, are covered with deep layers of colluvium, or lie below the ground-water table. Any future production from this source will require systematic prospecting, improved concentration, and an increase in the price of concentrate.]

Jan 1, 1954

By Richard Stayner

Suspended seats perform two functions: Reduce effect of occasional large bumps; Reduce more continuous vibration at a lower level. The former needs high damping. The latter needs low damping. For most mobile work machines the inevitable compromise is generally better than a simple cushion seat, because that amplifies vibration at around 4 Hz which is a sensitive frequency for human vertical WBV. Why have standard tests for seat suspensions? • Seat suspensions are non-linear so any measure of performance depends on operating conditions. For comparison these need to be defined. • Seat manufacturers need benchmarks for product development; • Machine makers choose dynamic characteristics appropriate to their products; • Occupational health specialists wish to control operator exposure to Standard tests should be representative, repeatable and reproducible. These requirements are reviewed in relation to the history of seat test standards and the current position. Current position and history The current position is that we have standard tests for seats for agricultural tractors, earthmoving machinery, industrial (fork-lift) trucks. These tests comprise measurement of vibration transmission and of the rate of damping. Current standards developed as the technology developed, starting around 1960: 1. Test on machine driven over standard surface1. 2. Test on shaker reproducing standard surface. 3. Shaker input replaced by representative spectrum2. 4. Human subject replaced by dynamic dummy. (Not yet settled). Are standard tests representative? The development process has gradually moved seat tests further from reality. 4 hr samples of work exposure suggest that seats do not on average provide large reductions of vertical WBV3. For specific magnitudes of vibration they can work well. For low vibration, performance is reduced by friction and for severe vibration by length of travel. Recent work has led to a new test to quantify how a suspension controls over-travel 9.

Jan 6, 2006

By George A. Morgan

The 53 countries that constituted Africa in 1991 accounted for a significant portion of total world output of a number of mineral commodities. However, total output for the continent declined for many major mineral commodities produced compared with that of 1990. Also, Africa's share of total world output of these commodities generally declined. (See tables 1 and 2.) The most conspicuous declines were for cobalt and copper owing to mining and metal processing difficulties experienced by the world's two largest cobalt producers, Zaire and Zambia. Phosphate rock output declined primarily owing to a sharp fall in production from Morocco, also a leading world producer. Morocco's state corporation for phosphate production experienced marketing problems, leading to the decline.

Jan 1, 1993

By R. Hogg, S. Chander

"An overview of various physical and interfacial characterization methods for use in mineral processing is presented in this paper. The availability of a large number of characterization techniques and commercial instruments requires that the reliability and limitation of each be carefully examined. The choice of a method may depend upon the manner in which the information is to be used, for example in development of new processes, plant and process design, plant control, problem solving, etc. IntroductionThe behavior of particulate systems, in mineral processing and other applications, is primarily affected by the physical characteristics (size, shape, surface area, pore structure) of the particles and the nature of the different solid-fluid interfaces present. Mineral processing operations in general are either designed to modify and/or control physical and interfacial properties (grinding, classification, agglomeration, etc.) or are strongly influenced by them (flotation, flocculation, solid/liquid separation, etc.). Characterization of physical and interfacial properties should be an integral part of the development of new processes, plant and process design, and routine plant operation.Our purpose in preparing this article has been to present an overview of the current status of characterization, to point out areas of weakness, and to discuss the reliability and limitations of the various techniques, procedures, and instrumentation available. For more detailed discussion of methods, etc., the reader is referred to standard references.Sampling particulate solids.Sampling is a critical factor in any procedure for characterizing particulate materials — the reliability of characterization data is ultimately limited by the extent to which the sample used was truly represen¬tative of the population from which it was taken.Sampling from particulate solids involves two basic problems: (1) the selection of a random', unbiased sample and (2) choice of the appropriate sample size.The problem of sample selection involves the design of a sample collection procedure that ensures that every kind of particle in the population has the proper chance of being included in the sample without bias. Specific procedures such as the well-known cone-and-quarter technique have been developed and are discussed at length in the literature on particle characterization (Allen, 1981: Herdan, 1960: Gy, 1982)."

Jan 1, 1989

By Joseph M. Pugliese

The Bureau of Mines through its contract research program recently analyzed the mining and environmental requirements in the premining stage for copper mining in the northern highland of Wisconsin. The Critical-Path-Method (CPM) was used in this research. However, a step-by-step derivation of the CPM Diagram was beyond the scope of this effort. The Bureau of Mines objective now is to show, step by step, how the original hand-computed CPM Diagram was constructed. The streamlining (restructuring) of this diagram from the original effort is also summarized. The critical path time (longest time) through the original CPM Diagram was 25.12 yr, excluding public liaison effort. This diagram showed the involvement of the regulatory agency, mining applicant and public in the premining stage. Analysis of this diagram produced a streamlined version which reduced the critical path time by nearly 7 yr. The CPM construction methodology offered here may be applied to mine planning for any mining operation.

Jan 1, 1983

By C. T. Sheeran

The Bureau of Mines investigated a microprocessor-based real-time control and monitoring system for uranium mining applications. The system is capable of controlling and monitoring up to 768 stations within 3 km of the central processor on a common four-wire cable. It can be used in conjunction with detectors to continuously monitor and display radiation working levels at points throughout the mine. Surface alarms are sounded for critical situations such as rapid radiation buildup, loss of power to monitors or fans, and changes in air door position. Permanent records of all changes are automatically printed out with their time of occurrence. Printouts can also be obtained for shift reports or trend logs. The system can be used to remotely control fan startup and shut-down, and also can alert miners of underground conditions by blowing horns or turning on lights. Battery backup keeps the system operative for up to 4 h in case of a mine power outage. A special software feature permits automatic, time-delayed, sequential restart of fans.

Jan 1, 1984